CN101768530B - 天然植物清洗剂 - Google Patents

天然植物清洗剂 Download PDF

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CN101768530B
CN101768530B CN2010101257147A CN201010125714A CN101768530B CN 101768530 B CN101768530 B CN 101768530B CN 2010101257147 A CN2010101257147 A CN 2010101257147A CN 201010125714 A CN201010125714 A CN 201010125714A CN 101768530 B CN101768530 B CN 101768530B
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张刚
樊如
刘俊勇
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Tianjin Liuhong Sci & Tech Dev Co Ltd
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    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G5/00—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents
    • C23G5/02—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents using organic solvents
    • C23G5/032—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents using organic solvents containing oxygen-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/90—Betaines
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2075—Carboxylic acids-salts thereof
    • C11D3/2086—Hydroxy carboxylic acids-salts thereof
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    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/43—Solvents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
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    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22—Organic compounds
    • C11D7/26—Organic compounds containing oxygen
    • C11D7/265—Carboxylic acids or salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
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    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22—Organic compounds
    • C11D7/40—Products in which the composition is not well defined
    • C11D7/44—Vegetable products
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
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Abstract

本发明涉及一种天然植物清洗剂，其特征在于：按重量份计，由柠檬烯70-80份、茶皂素2-10份、卵磷脂1-10份、柠檬醛2-10份、柠檬酸0.5-1份，在温度为15℃-25℃条件下混合均匀，配制而成。本发明对汽车及家电的漆膜、玻璃等无任何损害，而且避免了乳化后分层现象，提高了清洗效果。该清洗剂安全环保，去污力强，工艺简单，成本较低。

Description

天然植物清洗剂
技术领域
本发明涉及一种化学清洗剂，特别涉及一种天然植物清洗剂。 
背景技术
目前，市场上以及各行业普遍应用的清洗剂多为含有苯、甲苯、二甲苯或环壬烷等有机原料，其中苯为高致癌物质，甲苯和二甲苯对人体的危害主要是影响中枢神经系统、对呼吸道和皮肤产生刺激作用。经常使用，会对人体健康造成极大的伤害。制备清洗剂的上述原料多源于石油附属品，在生产时会造成严重的环境污染。而且由于其本身的毒性，在生产和运输过程中都会有很大的安全隐患。再有上述原料普遍存在闪点及燃点较低等弊端，对生产设备及环境有更严格的要求，从而加大实施的投入及生产成本。现在市场上虽然有一些以天然原料为主的清洗剂，但是由于乳化后不稳定，容易出现分层现象，不但使用不方便，而且清洗效果不明显；例如，人们通常采用上述各种清洗剂清洗汽车、家电等物品，往往得不到较佳的清洗效果。 
发明内容
本发明的目的在于克服上述不足之处，提供一种循环再生资源丰富、工艺简单、应用广泛、环保无污染的天然植物清洗剂。 
为实现上述目的本发明所采用的技术方案是：一种天然植物清洗剂，其特征在于：按重量份计，由柠檬烯70-80份、茶皂素2-10份、卵磷脂1-10份、柠檬醛2-10份、柠檬酸0.5-1份，在温度为15℃-25℃条件下混合均匀，配制而成。 
检测方法及结果： 
检测方法：按企业标准Q/12NK4971-2010天然植物清洗剂进行检测。
理化性能：包括不容物、闪点、pH值、热稳定性、冷稳定性，对金属材料的影响：全浸腐蚀、去镉，对涂层表面的影响，长期储存稳定性，检测完全达到标准。有害物质包括游离甲醛、苯、甲苯、二甲苯、二氯甲烷、1，2-二氯乙烷、1，1，2-三氯乙烷、三氯乙烯、重金属含量包括可溶性铅、可溶性镉、可溶性铬、可溶性汞等远远低于国家相关标准。清洗效率超过同类清洗剂并高出标准。 
本发明的有益效果是：该清洗剂的主要成分是从纯天然植物如桔子皮、柠檬皮、橙子皮中精蒸馏提取，环保无毒无污染。其中的主要组分柠檬烯具有较强的溶解力，茶皂素、卵磷脂增加表面活性，柠檬醛可平衡混溶度，柠檬酸增强溶解力。该清洗剂不含苯、甲苯、二甲苯、环壬烷等对人体有毒有害的物质，也不含铅、铬、镉和汞等重金属。生产过程中不会污染环境，没有安全隐患。不需乳化设备，生产工艺简单、操作方便、生产环境条件宽松、无需配套排除污染设施，具有显著的使用价值和经济效益。本发明无二次污染，其残留物可被生物分解，其闪点高、为45℃以上，燃点高、为200℃以上，使用储存安全可靠。采用原料为可循环再生资源，来源丰富且广泛。在废物利用、变废为宝的同时达到清除污染源，有效进行资源整合。本发明加入了茶皂素天然表面活性剂，避免了乳化后分层现象，提高了清洗效果。该清洗剂安全环保，去污力强，工艺简单，成本较低；作为替代苯类物的有机化工清洗剂，清洗、去污，特别是应用于汽车机部件，清洗效果极佳；且对汽车的漆膜、玻璃等无任何损害。同时，也可用于工业、家庭及公共场所等，如机场跑道、停机泊位、飞机、火车及油田重油垢的清洗；还可以用于清洗口香糖胶、不干胶以及家庭所需的各个方面的清洗。 
具体实施方式
以下结合较佳实施例，对依据本发明提供的具体实施方式详述如下： 
实施例1（每份按1 kg计，主成分含量均按质量分数计算）
将柠檬烯（主成分>95%）70kg、茶皂素（主成分>65%）5kg、卵磷脂（主成分>60%）7.5kg、柠檬醛（主成分>95%）2.5kg ，柠檬酸（主成分>95%）0.5kg，在温度为15℃-25℃条件下，以50-70转/min的速度搅拌均匀，配制成天然植物清洗剂。所采用原料均为市售产品。
实施例2（每份按1 kg计） 
将柠檬烯（主成分>95%）75kg、茶皂素（主成分>65%）5kg、卵磷脂（主成分>60%）5kg、柠檬醛（主成分>95%）3kg，柠檬酸（主成分>95%）0.5kg，在温度为15℃-25℃条件下, 以50-70转/min的速度搅拌均匀，配制成天然植物清洗剂。
实施例3（每份按1 kg计） 
将柠檬烯（主成分>95%）80kg、茶皂素（主成分>65%）3kg、卵磷脂（主成分>60%）2kg、柠檬醛（主成分>95%）3.5kg，柠檬酸（主成分>95%）0.5kg，在温度为15℃-25℃条件下，以50-70转/min的速度搅拌均匀，配制成天然植物清洗剂。
本发明的特点及用途： 
（1）本发明采用表面活性剂，以提高本剂的分散、乳化、去污能力。
（2）本发明采用柠檬烯为溶剂，有效提高去油污能力，且环保无污染。 
使用方法： 
选择本发明清洗剂均匀喷洒或涂刷到要清洗的物品上，用布直接擦洗，再用清水洗净，最后用布擦干即可；清洗效果显著；储存静置不沉淀、不分层，可直接使用，不必再搅拌摇匀，使用极为方便。
上述参照实施例对该天然植物清洗剂进行的详细描述，是说明性的而不是限定性的，按照组分配比限定范围可列举若干个实施例，因此在不脱离本发明总体构思下的变化和修改，应属本发明的保护范围之内。 

Claims (1)

1.一种天然植物清洗剂，其特征在于：按重量份计，由柠檬烯70-80份、茶皂素2-10份、卵磷脂1-10份、柠檬醛2-10份、柠檬酸0.5-1份，在温度为15℃-25℃条件下混合均匀，配制而成。
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CN102268334B (zh) * 2011-07-01 2013-09-25 湖南汉清生物技术有限公司 一种天然植物洗洁精
CN103602536B (zh) * 2013-11-29 2015-05-20 陈媛媛 一种高效环保的汽车用清洗剂及其制备方法
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CN106590139A (zh) * 2016-12-11 2017-04-26 钦州学院 一种天然植物型清洗剂及其制备方法
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