WO2011113221A1 - 天然植物清洗剂 - Google Patents

天然植物清洗剂 Download PDF

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Publication number
WO2011113221A1
WO2011113221A1 PCT/CN2010/071849 CN2010071849W WO2011113221A1 WO 2011113221 A1 WO2011113221 A1 WO 2011113221A1 CN 2010071849 W CN2010071849 W CN 2010071849W WO 2011113221 A1 WO2011113221 A1 WO 2011113221A1
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parts
natural plant
cleaning agent
cleaning
principal component
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PCT/CN2010/071849
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English (en)
French (fr)
Inventor
张刚
樊如
刘俊勇
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天津鎏虹科技发展有限公司
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Publication of WO2011113221A1 publication Critical patent/WO2011113221A1/zh

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G5/00—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents
    • C23G5/02—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents using organic solvents
    • C23G5/032—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents using organic solvents containing oxygen-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/90—Betaines
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2075—Carboxylic acids-salts thereof
    • C11D3/2086—Hydroxy carboxylic acids-salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/43—Solvents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/50—Perfumes
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22—Organic compounds
    • C11D7/26—Organic compounds containing oxygen
    • C11D7/265—Carboxylic acids or salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22—Organic compounds
    • C11D7/36—Organic compounds containing phosphorus
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22—Organic compounds
    • C11D7/40—Products in which the composition is not well defined
    • C11D7/44—Vegetable products
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/50—Solvents
    • C11D7/5004—Organic solvents
    • C11D7/5027—Hydrocarbons

Definitions

  • the invention relates to a chemical cleaning agent, in particular to a natural plant cleaning agent.
  • benzene is a highly carcinogenic substance, and the harm of toluene and xylene to the human body mainly affects the central nervous system. It has a stimulating effect on the respiratory tract and skin. Frequent use can cause great harm to human health.
  • the above-mentioned raw materials for preparing cleaning agents are mostly derived from petroleum accessories, in the production book.
  • the above-mentioned raw materials generally have drawbacks such as a flash point and a low flash point, and have stricter requirements on production equipment and the environment, thereby increasing the input and production costs of the implementation.
  • cleaning agents based on natural raw materials on the market, they are prone to delamination due to instability after emulsification, which is not only inconvenient to use, but also has no obvious cleaning effect; for example, people usually use the above various cleaning agents to clean them. Cars, home appliances and other items often do not have a good cleaning effect.
  • the object of the present invention is to overcome the above-mentioned deficiencies and to provide a natural plant cleaning agent which is rich in recycling resources, simple in process, widely used, environmentally friendly and non-polluting.
  • a natural plant cleaning agent characterized by: 70-80 parts of limonene, 2-10 parts of tea saponin, 1-10 parts of lecithin, by weight 2-10 parts of citral and 0.5-1 parts of citric acid are mixed uniformly at a temperature of 15 ° C to 25 ° C to prepare.
  • Detection method According to the enterprise standard Q/12NK4971-2010 natural plant cleaning agent for testing. Physical and chemical properties: including inclusive, flash point, pH, thermal stability, cold stability, impact on metal materials: full immersion corrosion, cadmium removal, effect on coating surface, long-term storage stability, testing is fully up to standard .
  • Hazardous substances include free formaldehyde, benzene, toluene, xylene, methylene chloride, 1, 2- Dichloroethane, 1, 1, 2-trichloroacetamidine, trichloroethylene, heavy metal content including soluble lead, soluble cadmium, soluble chromium, soluble mercury, etc. are far below the relevant national standards. The cleaning efficiency is higher than the similar cleaning agent and higher than the standard.
  • the invention has the beneficial effects that: the main component of the cleaning agent is refined and distilled from pure natural plants such as orange peel, lemon peel and orange peel, which is environmentally friendly, non-toxic and non-polluting.
  • the main component of the lemon olefin has a strong solvency
  • tea saponin and lecithin increase the surface activity
  • citral can balance the miscibility
  • citric acid enhances the solvency.
  • the cleaning agent does not contain toxic substances harmful to human body such as benzene, toluene, xylene or guanidine, and does not contain heavy metals such as lead, chromium, cadmium and mercury. There is no environmental pollution during the production process and there are no safety hazards.
  • the invention has no secondary pollution, and the residue can be biodegraded, and has a high flash point of 45 ° C or higher, a high ignition point of 200 ° C or more, and is safe to use and store.
  • the raw materials are recyclable resources, and the sources are abundant and extensive. In the use of waste and turning waste into treasure, we can eliminate pollution sources and effectively integrate resources.
  • the invention adds several natural surfactants such as tea saponin, avoids delamination after emulsification, and improves the cleaning effect.
  • the cleaning agent is safe and environmentally friendly, has strong decontamination power, simple process and low cost; as an organic chemical cleaning agent for replacing benzene substances, cleaning and decontamination, especially for automotive parts, the cleaning effect is excellent; and the automobile is excellent Paint film, glass, etc. without any damage.
  • it can also be used in industrial, home and public places, such as airport runways, parking berths, aircraft, trains and oil fields. It can also be used to clean chewing gum, stickers and all aspects of household cleaning. .
  • Example 1 The content of the principal components is calculated by mass fraction per 1 kg
  • the raw materials used are all commercially available products.
  • the present invention employs a surfactant to improve the dispersing, emulsifying and decontaminating ability of the agent.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Metallurgy (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Detergent Compositions (AREA)

Description

天然植物清洗剂 技术领域
本发明涉及一种化学清洗剂， 特别涉及一种天然植物清洗剂。
背景技术
说
目前， 市场上以及各行业普遍应用的清洗剂多为含有苯、 甲苯、 二甲苯 或环壬垸等有机原料， 其中苯为高致癌物质， 甲苯和二甲苯对人体的危害主 要是影响中枢神经系统、 对呼吸道和皮肤产生刺激作用。 经常使用， 会对人 体健康造成极大的伤害。 制备清洗剂的上述原料多源于石油附属品， 在生产 书
时会造成严重的环境污染。 而且由于其本身的毒性， 在生产和运输过程中都 会有很大的安全隐患。 再有上述原料普遍存在闪点及燃点较低等弊端， 对生 产设备及环境有更严格的要求， 从而加大实施的投入及生产成本。 现在市场 上虽然有一些以天然原料为主的清洗剂， 但是由于乳化后不稳定， 容易出现 分层现象， 不但使用不方便， 而且清洗效果不明显； 例如， 人们通常采用上 述各种清洗剂清洗汽车、 家电等物品， 往往得不到较佳的清洗效果。
发明内容
本发明的目的在于克服上述不足之处， 提供一种循环再生资源丰富、 工 艺简单、 应用广泛、 环保无污染的天然植物清洗剂。
为实现上述目的本发明所采用的技术方案是： 一种天然植物清洗剂， 其 特征在于： 按重量份计， 由柠檬烯 70-80份、茶皂素 2-10份、 卵磷脂 1-10份、 柠檬醛 2-10份、 柠檬酸 0.5-1份， 在温度为 15°C-25°C条件下混合均匀， 配制 而成。
检测方法及结果：
检测方法： 按企业标准 Q/12NK4971-2010天然植物清洗剂进行检测。 理化性能： 包括不容物、 闪点、 pH值、 热稳定性、 冷稳定性， 对金属材 料的影响： 全浸腐蚀、 去镉， 对涂层表面的影响， 长期储存稳定性， 检测完 全达到标准。 有害物质包括游离甲醛、 苯、 甲苯、 二甲苯、 二氯甲垸、 1， 2- 二氯乙垸、 1， 1， 2-三氯乙垸、 三氯乙烯、 重金属含量包括可溶性铅、 可溶性 镉、 可溶性铬、 可溶性汞等远远低于国家相关标准。 清洗效率超过同类清洗 剂并高出标准。
本发明的有益效果是： 该清洗剂的主要成分是从纯天然植物如桔子皮、 柠檬皮、 橙子皮中精蒸馏提取， 环保无毒无污染。 其中的主要组分柠檬烯具 有较强的溶解力， 茶皂素、 卵磷脂增加表面活性， 柠檬醛可平衡混溶度， 柠 檬酸增强溶解力。 该清洗剂不含苯、 甲苯、 二甲苯、 环壬垸等对人体有毒有 害的物质， 也不含铅、 铬、 镉和汞等重金属。 生产过程中不会污染环境， 没 有安全隐患。 不需乳化设备， 生产工艺简单、 操作方便、 生产环境条件宽松、 无需配套排除污染设施， 具有显著的使用价值和经济效益。 本发明无二次污 染， 其残留物可被生物分解， 其闪点高、 为 45°C以上， 燃点高、 为 200°C以 上， 使用储存安全可靠。 采用原料为可循环再生资源， 来源丰富且广泛。 在 废物利用、 变废为宝的同时达到清除污染源， 有效进行资源整合。 本发明加 入了茶皂素等几种天然表面活性剂， 避免了乳化后分层现象， 提高了清洗效 果。 该清洗剂安全环保， 去污力强， 工艺简单， 成本较低； 作为替代苯类物 的有机化工清洗剂， 清洗、 去污， 特别是应用于汽车机部件， 清洗效果极佳； 且对汽车的漆膜、 玻璃等无任何损害。 同时， 也可用于工业、 家庭及公共场 所等， 如机场跑道、 停机泊位、 飞机、 火车及油田重油垢的清洗； 还可以用 于清洗口香糖胶、 不干胶以及家庭所需的各个方面的清洗。
具体实施方式
以下结合较佳实施例， 对依据本发明提供的具体实施方式详述如下： 实施例 1 (每份按 1 kg计， 主成分含量均按质量分数计算）
将柠檬烯（主成分>95%) 70kg, 茶皂素（主成分>65%) 5kg、 卵磷脂（主 成分 >60% ) 7.5kg, 柠檬醛 （主成分>95% ) 2.5kg ， 柠檬酸 （主成分>95% ) 0.5kg, 在温度为 15°C-25°C条件下， 以 50-70转 /min的速度搅拌均匀， 配制成 天然植物清洗剂。 所采用原料均为市售产品。
实施例 2 (每份按 l kg计）
将柠檬烯（主成分>95%) 75kg, 茶皂素（主成分>65%) 5kg、 卵磷脂（主 成分 >60% ) 5kg、 柠檬醛 (主成分>95%) 3kg, 柠檬酸 (主成分>95%) 0.5kg, 在温度为 15°C-25°C条件下， 以 50-70转 /min的速度搅拌均匀， 配制成天然植 物清洗剂。
实施例 3 (每份按 l kg计）
将柠檬烯（主成分>95%) 80kg, 茶皂素（主成分>65%) 3kg, 卵磷脂（主 成分 >60% ) 2kg、柠檬醛（主成分>95%) 3.5kg, 柠檬酸（主成分>95%) 0.5kg, 在温度为 15°C-25°C条件下， 以 50-70转 /min的速度搅拌均匀， 配制成天然植 物清洗剂。
本发明的特点及用途：
( 1 ) 本发明采用表面活性剂， 以提高本剂的分散、 乳化、 去污能力。
(2) 本发明采用柠檬烯为溶剂， 有效提高去油污能力， 且环保无污染。 使用方法：
选择本发明清洗剂均匀喷洒或涂刷到要清洗的物品上， 用布直接擦洗， 再用清水洗净， 最后用布擦干即可； 清洗效果显著； 储存静置不沉淀、 不分 层， 可直接使用， 不必再搅拌摇匀， 使用极为方便。
上述参照实施例对该天然植物清洗剂进行的详细描述， 是说明性的而不 是限定性的， 按照组分配比限定范围可列举若干个实施例， 因此在不脱离本 发明总体构思下的变化和修改， 应属本发明的保护范围之内。

Claims

权 利 要 求 书
1、 一种天然植物清洗剂， 其特征在于： 按重量份计， 由柠檬烯 70-80份、 茶皂素 2-10份、 卵磷脂 1-10份、 柠檬醛 2-10份、 柠檬酸 0.5-1份， 在温度为 15°C-25°C条件下混合均匀， 配制而成。
PCT/CN2010/071849 2010-03-17 2010-04-16 天然植物清洗剂 WO2011113221A1 (zh)

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CN2010101257147A CN101768530B (zh) 2010-03-17 2010-03-17 天然植物清洗剂
CN201010125714.7 2010-03-17

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