CN101692832A - Composition for controlling harmful bio-organisms and method for controlling harmful bio-organisms using the same - Google Patents

Composition for controlling harmful bio-organisms and method for controlling harmful bio-organisms using the same Download PDF

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Publication number
CN101692832A
CN101692832A CN200910204985A CN200910204985A CN101692832A CN 101692832 A CN101692832 A CN 101692832A CN 200910204985 A CN200910204985 A CN 200910204985A CN 200910204985 A CN200910204985 A CN 200910204985A CN 101692832 A CN101692832 A CN 101692832A
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compound
disease
composition
fungicide
active component
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松尾宪総
三谷滋
荒木智史
泷井康子
山口朋奈
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Ishihara Sangyo Kaisha Ltd
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/50—1,3-Diazoles; Hydrogenated 1,3-diazoles

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
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Abstract

The present invention relates to a composition for controlling harmful bio-organisms, comprising (a) at least one imidazole compound represented by formula (I):wherein R represents a lower alkyl group or a lower alkoxy group; and n represents an integer of 1 to 5, as an active ingredient, and (b) at least one phycomycetes fungicide, and a method for controlling harmful bio-organisms comprising applying the composition for controlling harmful bio-organisms onto harmful bio-organisms.

Description

Composition of control pest and the method for preventing and treating pest with said composition
The application is application number the dividing an application for China's application of " composition of control pest and with the method for said composition control pest " that be CN200710112397.3 (applying date is on April 23rd, 1998), denomination of invention.
Technical field
The present invention relates to pest is had the composition of preventing and treating effect of remarkable enhancing,, and can be used in agricultural and the gardening especially to the effect that treats and/or prevents of plant disease; Use the method for said composition control pest; Method with the PCO effect that strengthens pest control agent.
Background technology
About being used for active component of the present invention (a) and composition (b) (hereinafter describing), European patent is pointed out for No. 298196: the imidazolium compounds as active component (a) can be used as pest control agent in the present invention, relates to the possibility of using this compound when needing in conjunction with other fungicide.European patent adds for No. 298196, be used as the imidazolium compounds of active component (a) and being used in combination of other fungicide (such as cyanoacetamide compound (for example 1-(2-cyano group-2-methoxyimino acetyl)-3-ethyl urea)) and organochlorine compound (for example daconil M) on the structure among analog the present invention, produce the effect that strengthens.In addition, European patent discloses a kind of pest control agent No. 337103, it contains at least a imidazolium compounds (being similar to the imidazolium compounds that is used as active component among the present invention on the structure) and at least aly is selected from following active component: cyanoacetamide compound, organochlorine compound (comprising daconil M), phenyl amide compound (comprising N-(2-methoxyl group acetyl)-N-(2, the 6-xylyl)-DL-methyl lactamine), cinnamic acid compound, copper compound and organic phosphorus compound (comprising phosethyl-Al).
Summarize these patents, be it seems by the present invention, they do not have to describe, do not point out as the imidazolium compounds of active component (a) and a kind of inorganic phosphorous compound, a kind of 'beta '-methoxy acrylic acid ester compounds Huo oxazolidinedione compound compositions yet.They had not both been described and had not pointed out the very outstanding effect of preventing and treating yet, these effects are that composition has, and described composition comprises as a kind of imidazolium compounds of active component and at least one and is selected from following member as another kind of active component: cyanoacetamide compound, organochlorine compound, phenyl amide compound, cinnamic acid compound, copper compound and organic phosphorus compound.
Composition about active component (a) and increased activity component (c) (hereinafter describing), European patent has been described the serviceability of imidazolium compounds of the present invention as pest control agent No. 298196, and point out: this compound can be formulated as various forms with adjuvant.JP-A-Heisei-3-11003 (term used herein " JP-A " is meant " the not Japanese patent application of examination bulletin ") discloses a kind of method of preventing and treating pest, this method comprises uses a kind of water-borne dispersions, and this dispersion contains at least a imidazolium compounds of the present invention and a kind of anhydro sorbitol higher fatty acid ester surfactant.
By imidazolium compounds and many other conventional pest control agents of formula (I) expression, has its several characteristic aspect the effect preventing and treating.Some produces the effect deficiency to some pest, or some effect aspect treatment is lower than the effect aspect prevention, or the duration of some residual effect is short relatively.Therefore, meet this situation sometimes, wherein its to pest to prevent and treat effect in fact not enough in some applications.In addition, although the imidazolium compounds of formula (I) shows the outstanding antifungal effect to Phycomycetes (Phycomycetes), according to the development of disease situation, it is tending towards producing enough effects that treats and/or prevents.From this aspect, also need to strengthen.
On the other hand, in the practical application of the pest control agent of the imidazolium compounds that comprises formula (I), preferably the consumption of this compound reduces to minimum, to save cost, attempt preventing and treating as much as possible diverse multiple pest simultaneously, the time of control disease outburst or the time of generation.In addition, although contain formula (I) imidazolium compounds as the pest control agent of active component outstanding especially aspect the prophylactic effect, required to strengthen its treatment effect.
Content of the present invention
In order to address the above problem, the present inventor finds after deliberation and therefore, as the imidazolium compounds of the formula (I) of active component (a) and being used in combination as the specific compound of active component (b), produce unexpected result, compare when making with its independent use, respectively estimating one's own ability of described compound can reduce, or prevention and treatment range separately can be widened.They also find, compare with independent use active component (a), and active component (a) is used in combination with increased activity component (c), causes preventing and treating the remarkable enhancing of effect, particularly treat effect and significantly strengthen, the feasible thus amount that can reduce active component (a).According to these discoveries, finished the present invention.
The present invention relates to comprise the composition of the control pest of following ingredients:
(a) at least a imidazolium compounds by formula (I) expression as active component;
Figure G2009102049859D0000031
Wherein R represents a low alkyl group or a lower alkoxy; And
N represent 1-5 integer and
(b) at least a inorganic phosphorous compound and/or at least a Phycomycetes fungicide as active component, or
(c) as a kind of spreading agent of increased activity component.
Implement optimal mode of the present invention
In formula (I), by the low alkyl group of R representative or the moieties of lower alkoxy, comprise alkyl with 1-6 carbon atom, such as methyl, ethyl, propyl group, butyl, amyl group or hexyl, it can or have straight chain or has side chain.When n is 2 or 2 when above, described a plurality of R can be identical or different.
Imidazolium compounds by formula (I) representative comprises following compound:
4-chloro-2-cyano group-1-dimethylamino sulphonyl-5-(4-aminomethyl phenyl) imidazoles (No. 1 compound);
4-chloro-2-cyano group-1-dimethylamino sulphonyl-5-(4-methoxyphenyl) imidazoles (No. 2 compounds);
4-chloro-2-cyano group-1-dimethylamino sulphonyl-5-(4-ethylphenyl) imidazoles (No. 3 compounds);
4-chloro-2-cyano group-1-dimethylamino sulphonyl-5-(3-methyl-4-methoxyphenyl) imidazoles (No. 4 compounds).
By for example disclosed known method in No. the 298196th, European patent or EP-A-705823, imidazolium compounds that can preparation formula (I).
Inorganic phosphorous compound as active component (b) comprises: phosphoric acid, phosphorous acid, hypophosphorous acid, condensed phosphoric acid, condensation phosphorous acid and their salt.Described salt comprises the salt that forms with following metal: light metal (proportion: be lower than 4), such as alkali metal, alkaline earth metal, aluminium etc.; Heavy metal (proportion: more than 4 or 4) is such as zinc, copper, nickel, manganese etc.; Also comprise and replacing or unsubstituted ammonium salt.
Phosphate comprises primary phosphate (for example sodium dihydrogen phosphate, potassium dihydrogen phosphate, aluminium dihydrogen phosphate, ammonium dihydrogen phosphate (ADP), calcium dihydrogen phosphate), two generation phosphate (for example sodium hydrogen phosphate, dipotassium hydrogen phosphate, diammonium hydrogen phosphate, phosphoric acid hydrogen two magnesium) and tertiary phosphates (for example tertiary sodium phosphate, tripotassium phosphate, trbasic zinc phosphate, aluminium phosphate, ammonium phosphate, ammonium magnesium phosphate, magnesium phosphate, calcium phosphate).
Phosphite comprise a generation or two generation phosphite (for example a generation or two generation sodium phosphite, a generation two generation potassium phosphite, a generation or two generation phosphorous acid calcium).
Hypophosphites comprises sodium hypophosphite, barium hypophosphite and calcium hypophosphite.
Condensed phosphoric acid and salt thereof comprise polyphosphoric acid (for example pyrophosphoric acid) and polyphosphate (for example sodium pyrophosphate, calcium pyrophosphate, Sodium Acid Pyrophosphate).
Condensation phosphorous acid and salt thereof comprise many metaphosphoric acids (for example three metaphosphoric acids, four metaphosphoric acids) and many metaphosphates (for example sodium trimetaphosphate, four sodium metaphosphates, calgon).
The fungicide that can be used as the Phycomycetes of active component (b) comprising:
The 'beta '-methoxy acrylic acid ester compounds
(for example ( E)-2-{2-[6 (2-cyano-benzene oxygen) pyridin-4-yl oxygen base] phenyl }-the 3-methoxy-methyl acrylate,
( E)-methoxyimino [α-(oxy-o-cresyl)-O-tolyl] methyl acetate);
The oxazolidinedione compound
(for example 3-anilino--5-methyl-5-(4-Phenoxyphenyl)-1,3-oxazolidine-2,4-diketone);
The cyanoacetamide compound
(1-(2-cyano group-2-methoxyimino acetyl)-3-ethyl urea (popular name: white urea cyanogen)) for example;
Organochlorine compound
(for example tetrachloro isophthalonitrile (popular name: tpn)),
Pcnb (popular name: Quintozene));
The phenyl amide compound
(for example N-(2-methoxyl group acetyl)-N-(2, the 6-xylyl)-DL-methyl lactamine (alaninate) (popular name: metalaxyl),
2-methoxyl group-N-(2-oxo-1,3-oxazolidine-3-yl) acetyl-2 ', 6 '-dimethylaniline (popular name: Wakil),
(±)-α-2-chloro-N-(2,6-xylyl acetamide)-gamma-butyrolacton (popular name: ofurace),
N-phenyl acetyl-N-(2, the 6-xylyl)-DL-methyl lactamine (popular name: M 9834),
N-(2-furoyl)-N-(2, the 6-xylyl)-DL-methyl lactamine (popular name: furalaxyl),
(±)-α-[N-(3-chlorphenyl) cyclopropane carboxamide]-gamma-butyrolacton (popular name: cyprofuram));
The cinnamic acid compound
(for example (E, Z)-4-[3-(4-chlorphenyl)-3-(3, the 4-Dimethoxyphenyl) acryloyl] morpholine (popular name: dimethomorph));
Copper compound
(for example organic or inorganic copper fungicide agent); With
Organic phosphorus compound
(for example three (ethylphosphonic acid) aluminium (popular name: phosethyl-Al),
D2EHDTPA O-2,6-two chloro-p-methylphenyl-O, the O-dimethyl ester (popular name: tolelofos-methyl),
Phosphonothiolic acid (R, S)-S-(R, S)-sec-butyl-O-ethyl-2-oxo-2-thiazolidinyl ester,
D2EHDTPA S-benzyl O, O-two-isopropyl esters (popular name: iprobenfos)
Phosphordithiic acid O-ethyl S, the S-diphenyl (popular name: edifenphos),
2-diethoxy thiophosphoryl oxygen base-5-methylpyrazole also (1,5-a) pyrimidine-6-Ethyl formate (popular name: pyrazophos)).
In these compounds, at Brighton Crop Prot.Conf.Pests and Diseases, 435-443 page or leaf (1992), in ibid 403-410 page or leaf (1992) and ibid the 21-26 page or leaf (1996) (E)-2-{2-[6-(2-cyano-benzene oxygen) pyrimidine-4-base oxygen base has been described respectively] phenyl }-3-methoxy acrylate (hereinafter referred to as " compound (a) "), (E)-methoxyimino [α-(oxy-o-cresyl)-O-tolyl] methyl acetate (hereinafter referred to as " compound (b) ") and 3-anilino--5-methyl-5-(4-Phenoxyphenyl)-1,3-oxazolidine-2,4-diketone (hereinafter referred to as " compound (c) ").
In above-mentioned organochlorine compound, preferred tetrachloro isophthalonitrile.In the phenyl amide compound, preferred N-(2-methoxyl group acetyl)-N-(2, the 6-xylyl)-DL-methyl lactamine.In organic phosphorus compound, preferred three (ethylphosphonic acid) aluminium.In copper compound, preferred inorganic copper fungicide agent.
Above-mentioned inorganic or organic copper fungicide also comprises the Fungicidal formulations that contains inactive ingredients (a) and chemicals (b) (such as fungicide etc.) except that copper compound.
Described inorganic copper fungicide agent comprises that hydroxyl copper sulphate (copper oxysulfate) is as living. those copper fungicide agent of property component, such as Sanpun Bordeaux (trade name, by Dai-ichiNoyaku K.K.and Hokko Chemical Industry Co., Ltd. produce) and SanpunBordeaux Dust DL (trade name, by Dai-ichi Noyaku K.K.and HokkoChemical Co., Ltd. produces); Oxygenated chlorinated copper (I) is as the copper fungicide agent of active component, such as San Bordeaux (trade name, by Sankei Chemical Co., Ltd. production), Doitsu Borudo A (trade name, by Dai-ichi Noyaku K.K.and HokkoChemical Industry Co., Ltd. production), Do-cal wetting powder (trade name, by Yashima Chemical Industry Co., Ltd. production), Do-jet (trade name, by NissanChemical Industries, Ltd. produces) etc.; Contain the copper fungicide agent of Kocide SD, such as Kocide Bordeaux, Kocide DF, Kocide SD (trade name is produced by Griffin) etc. as active component; With the copper fungicide agent that contains anhydrous cupric sulfate (II), such as Gandie wetting powder (trade name, by Agro-Kanesho Co., Ltd. produces) etc.
The Fungicidal formulations that contains non-component (a) and inorganic copper fungicide agent (b) and chemicals (as fungicide etc.) comprises the Bordeaux mixture that contains alkali formula sulfuric acid ketone calcium; Copper-sulphur fungicide is such as Engei Bordeaux (trade name, by Sankei Chemical Co., Ltd. produces) etc.; Copper-valida fungicide; Copper-valida-fthalide fungicide; Copper-pyrifenox fungicide; Copper (I)-ethene sclerotium agent fungicide; Copper-fthalide fungicide; Copper-procymidone fungicide is such as Scletane wetting powder (trade name, by Hokko Chemical IndustryCo., Ltd. produces); Copper (I)-phosethyl-Al wetting powder; Copper-metalaxyl fungicide is such as Ridomil copper wetting powder (trade name, by Nihon Nohyaku Co., Ltd. produces); Iprodione copper (I) fungicide is such as Daisedo wetting powder (trade name, by YashimaChemical Industry Co., Ltd. produces); The hot triacetate of biguanides-copper fungicide agent; Wakil copper (I) fungicide; Oxolinic acide-copper fungicide agent; Kasugarnycin-copper fungicide agent, such as Kasumin Bordeaux Dust 3DL (trade name, by Hokko Chemical Industry Co., Ltd. production), Kasumin Bordeaux (trade name, by Dai-ichi Noyaku K.K.andHokko Chemical Industry Co., Ltd. produces) etc.; Dithianon copper (I) fungicide, streptomycin-copper fungicide agent are such as Do-Stomy wetting powder (trade name, by NihonNohyaku Co., Ltd. produces) etc.; Sodium bicarbonate-copper fungicide agent is such as G-Fine wetting powder (trade name, by Yashima Chemical Industry Co., Ltd. produces); And copper-organic copper fungicide, such as Oxy Bordeaux (trade name, by Sankyo Co., Ltd. production), Kinset wetting powder (trade name, by Agro-Kanesho Co., Ltd. produce), Kinset wetting powder 80 (trade name, by Agro-Kanesho Co., Ltd. produces) etc.
In these inorganic copper fungicide agent, preferred especially the use contained those fungicides that are selected from one or more following active components: Kocide SD, sulfovinic acid copper, copper oxychloride, anhydrous cupric sulfate (II) and basic copper sulfate calcium.
Organic copper fungicide comprises copper 8-quinolinolate fungicide, such as Quinone-do wetting powder 40 or 80 (trade names, by Agro-Kanesho Co., Ltd. produce), Quinone-do granule (trade name, by Agro-Kanesho Co., Ltd. produce), but Quinone-do flowable (Flowable) (trade name, by Agro-Kanesho Co., Ltd. produce), oxine-copper (I) wetting powder (trade name, by Tomono Agrica Co., Ltd. produce), oxine-copper (I) wetting powder 75 (trade names, by Tomono Agrica Co., Ltd. produce), oxine-copper (I) wetting powder 80 (trade names, by Tomono Agrica Co., Ltd. with NissanChemical Industries, Ltd. produce), oxine-copper (I) but flowable (trade name, by TomonoAgrica Co., Ltd. with Nissan Chemical Industries, Ltd. produce), Dokirin wetting powder 80 (trade names, by Nihon Nohyaku Co., Ltd. produce) but and Dokirin flowable (trade name, by Nihon Nohyaku Co., Ltd. production) etc.; The agent of hydroxyl nonyl benzene sulfonic acid copper fungicide is such as Yonepon (trade name, by Yonezawa Kagaku K.K. produce) etc.; Two (ethylenediamines) two (benzene sulfonic acid lauryl) copper (II) fungicide is such as Sanyol (trade name, by Otsuka Chemical Co., Ltd. and Yonezawa Kagaku K.K. produce) etc.; With the agent of terephthalic acids copper fungicide.
The Fungicidal formulations that contains non-component (a) and organic copper fungicide (b) comprises iprodione (I)-organic copper fungicide, oxolinic acide-organic copper fungicide, captan (I)-thiuram-organic copper fungicide, captan (I)-organic copper fungicide, dithianon (I)-organic copper fungicide, streptomycin-organic copper fungicide, probenazole (I)-organic copper fungicide, Fenarimol (I)-organic copper fungicide, machine oil-organic copper fungicide and biguanides suffering (I) biguanides suffering-organic copper fungicide.
Spreading agent is as increased activity component (c).The example that is used for spreading agent of the present invention comprises surfactant (not comprising the anhydro sorbitol high-grade aliphatic ester), paraffin oil, animal and/or vegetable oil and mineral oil.Generally speaking, spreading agent is not limited classification.Some animal and/or vegetable oil and mineral oil are used as surfactant, and have some spreading agent that is called sticker not classify clearly.Suitably the imidazolium compounds physical characteristic (such as fixed characteristic, penetrability, spreadability and pore submergence characteristic) of enhanced (I), to strengthen any spreading agent of this compound effect, all can be used for the present invention.Usually, with this spreading agent can enhanced (I) imidazolium compounds physical characteristic, to produce such effect, make the control efficiency that obtains equal pest with more a spot of this compound.In above-mentioned spreading agent, preferably surfactant (not comprising the anhydro sorbitol high-grade aliphatic ester), animal oil and/or vegetable oil and mineral oil.Preferably non-ionic surface active agent (not comprising the anhydro sorbitol high-grade aliphatic ester), animal oil and/or vegetable oil and mineral oil again.
Can draw together the polyoxyethylene alkyl ether as the suitable ionic surfactant pack of increased activity component (c), polyoxyethylene alkyl phenylate, the polyoxyethylene aryl ether, polyethylene glycol alkyl ether, the polyoxyethylene fatty acid ester, the polyoxyethylene polyol fatty acid ester, the polyoxyethylene fatty acid amide, amine n-oxide, such as Aromox C/12W (trade name, produce by AkzoChemie), the polyoxyethylene alkylamine, fatty acid glyceride, polysiloxane surfactant, polyoxyethylene alkyl thioether polyphosphate surfactant, such as Reider (trade name is produced by American Trading Company), higher alcohol sulfate and dialkyl sulfosuccinate succinate.In these compounds, preferred polyoxyethylene alkyl ether, polyoxyethylene alkyl phenylate, polyoxyethylene fatty acid ester, polyoxyethylene fatty acid amide, polysiloxane surfactant, higher alcohol sulfate and dialkyl sulfosuccinate.Preferred again polysiloxane surfactant, polyoxyethylene alkyl phenylate and polyoxyethylene fatty acid ester.Preferred especially polysiloxane surfactant is DyneAmic (trade mark especially, produce by Setre Chemical) and KINETIC (trade mark is produced by Setre Chemical) and SILWETT L-77 (producing by Witco) and SLIPPA (producing by Interagro).
Following table 1 has been listed the instantiation of preferred nonionic.In addition, polyoxyethylene polysilane ether (a kind of polysiloxane surfactant), Renex (trade name, the polyoxyethylene alkyl ether of producing by Bayer AG), Crop Oil Extra (trade name of the polyoxyethylene alkyl phenylate of producing by Kalo Inc.), Ortho X-77 spreading agent (trade name, produce by Chevron Chemical Company) and COOP spreading agent activator (trade name is by Formland Industry production) be also included within the available non-ionic surface active agent.
Table 1
Non-ionic surface active agent
Table 1 (continuous table)
Figure G2009102049859D0000111
Table 1 (continuous table)
Figure G2009102049859D0000121
Can comprise sulfuric acid ester surfactant as the suitable anion surfactant of increased activity component (c), such as alkyl sulfate or its salt; The sulfonic acid surfactant is such as naphthyl mesylate and lignosulphonates; Soap; With fluorine-containing surfactant with sulfuric ester, preferred sulfonic acid surfactant.The example of preferred anionic surfactants surfactant is shown in the following table 2.
Table 2
Anion surfactant
Numbering Kind Name Trade name (manufacturer)
??40 Higher alcohol sulfate Higher alcohol sulfate ??Genapol?LRO?Fluid??(Hoechst?AG)
??41 Dialkyl sulfosuccinates Dialkyl sodium sulfosuccinate ??Lutensol?TO?7??(BASF?AG)
??42 ??” Two-2-ethylhexyl sodium sulfosuccinate ??Lutensol?ON?60(BASF??AG)
Numbering Kind Name Trade name (manufacturer)
??43 Oleoyl methyl tauride sodium ??AGRAL?30(ICI??Agrochemicals)
??44 Alkyl two glycerol ether sulfates based on natural fat family; RO-(EO) 2-SO 3Na ??AGRAL?90(ICI??Agrochemicals)
??45 ??linosulfa?to?de?calcio??20+12 ??ARKOPAL?N-100??(Hoechst?AG)
Can comprise dialkyl ammonium salt as the suitable cationic surfactants of increased activity component (c) such as NEEDS (trade mark is produced by Kao Corporation); With dialkyl ammonium salt, as shown in the following Table 3 such as ArguardT/50 (trade name is produced by Akzo Chemical).
Table 3
Cationic surfactant
Can comprise vegetable oil as the animal oil and/or the vegetable oil of increased activity component (c), such as corn oil, soya-bean oil, Linseed oil, sunflower oil, cottonseed oil and rape oil; And animal oil, such as butter and whale-bone oil (whale oil).Also comprise alkylation (for example methylating) vegetable oil, such as SCOIL (producing) by MVRC.The suitable animal oil and/or the instantiation of vegetable oil are shown in the following table 4.Wherein, preferred alkyl vegetable oil.
Table 4
Animal oil and/or vegetable oil
Figure G2009102049859D0000141
Can comprise the product that derives from animal oil and/or vegetable oil, product (for example oil) and their mixture that derives from mineral oil as the paraffin oil of increased activity component (c).Instantiation is shown in the following table 5.
Table 5
Paraffin oil
Numbering Kind Name Trade name (manufacturer)
??59 Paraffin oil ??ATPLUS?411F(ICI??Agrochemicals)
??60 ??” ??ATPLUS?411F?OIL??(ICI?Agrochemicals)
??61 ??” Non-ionic surface active agent SUN OIL adjuvant (Schering Agrochemicals Ltd.)
??62 ??” Paraffin oil non-ionic surface active agent based on oil ??OLEOTAN(Biomex)
??63 ??” ??” ??PRIME?OIL
Can comprise machine oil, fuel oil and silicone oil as the mineral oil of increased activity component (c).The example of preferred mineral oils is shown in the following table 6.Wherein, ISHIOIL (by IshiharaSangyo Kaisha, Ltd. produce) most preferably.
Table 6
Mineral oil
Numbering Kind Name Trade name (manufacturer)
??64 Mineral oil (machine oil) The machine oil emulsion
??65 ??” The machine oil emulsion (Toho Chemical Industty Co., Ltd.)
??66 Mineral oil (fuel oil) The diesel engine oil emulsion
??67 Mineral oil Mineral oil (98%)+tensio activo (2%) ??ISHIOIL(Ishihara??Sangyo?Kaisha，Ltd.)
??68 ??” The petroleum oil based on paraffin of heavy scope, polyol fatty acid ester and many ethyoxyls derivative AGRI-DEX or Agri-Dex (Helena Chemical Company)
Above-mentioned spreading agent is that surfactant (except that the anhydro sorbitol high-grade aliphatic ester), animal oil and/or vegetable oil, paraffin oil, mineral wet goods can suitably mix, with as increased activity component (c).The composition of two or more spreading agent comprises the surfactant that contains vegetable oil, such as Soy Dex (Helena Chemical Company) etc.; With the surfactant that contains paraffin oil, such as Oleo DP 11E (E.I.du Pont), Fyzol 11E (ScheringAgrochemicals), Agri Dex (Helena Chemical Co.), Atplas 411 (ICIAgrochemicals), Herbimax (Love Land Industries, Inc.), ComPetitorCrop Oil concentrate (Red Pancer Chemical), Actipron (Oil Co.), DASH (BASF AG), Atlas Adherb (Atlas Interlates, Ltd.), Cropspray (TribartFarm Chemical), Agravia 11E (Wakker Chemie), Penetrator (HelenaChemical Co.), Atlus auxiliary agent oil (Atlus Interlates, Ltd.) etc.The spreading agent that also comprises the mixing that is shown in table 7.
Table 7
Mix spreading agent
Numbering Name Trade name
??69 Mineral oil+vegetable oil Mineral oil emulsion+soya-bean oil emulsion
??70 2-Pyrrolidone (pyrrolidione)+1-octyl group-2-Pyrrolidone+1-vinyl-1-palmityl homopolymers+dodecyl benzene sulfonic acid calcium ?Agrimax?3H
As mentioned above, any spreading agent all can be used for the present invention, and no matter which kind of spreading agent it belongs to, as long as the physical property of its remarkable enhanced (I) imidazolium compounds gets final product with the effect that strengthens this compound.Can not be categorized as the instantiation of listing the useful spreading agent of kind more than any is shown in the following table 8.Certainly, contain at least a formula (I) imidazolium compounds mixes the control pest that can be used as increased activity component (c) in proportion as active component (a), according to the present invention composition, expection shows similar effect.
Table 8
Unclassified spreading agent
Figure G2009102049859D0000171
Table 8 (continuous table)
Numbering Name Trade name (manufacturer)
??85 ??Helena?Suraid(Helena?Chemical??Co.)
Numbering Name Trade name (manufacturer)
??86 Coassist agent natural oil (Stoller Chemical Co.)
??87 ??polioxy?ester?amino?graso?42 Coassist agent SP-SUPER
??88 Synthetic latex (45%)+aliphatic o-alkylation primary alconol (10%)+inert component (45%) ??Bond(Loveland?Industries，Inc.)
??89 Senior alkyl pyrrolidones combination water insoluble polymer (pseudo cationic polymerization thing) and surfactant Banka (ANKA in the past) (Interagro)
??90 Alkoxylated amines (alkoxylated alphatic amine polymer)/polysaccharide (based on the non-ionic surface active agent and the buffer of sugar) mixture ??ARMA(Interagro)
??91 The phthalic resin of modification/glycerine alkyl resin (77%)+butanols (23%) ??LATRON?B-1956(Rohm&??Haas?Co.)
??92 DL-1-is to menthene (96%)+inert component (4%) ??LASTIC(Helena?Chemical?Co.)
Above-mentioned fungicide characteristic ground as the Phycomycetes of active component (b) has one or more preventive effects, a kind of result of treatment and penetrability.Some inorganic phosphorous compound as active component (b) is not a fungicide, but they have and similar one or more preventive effects of Phycomycetes fungicide, a kind of result of treatment and penetrability.
Term " fungicide with preventive effect " is meant the fungicide with prevention plant disease ability.The example of this class fungicide comprises 'beta '-methoxy acrylic acid ester compounds, oxazolidinedione compound, cyanoacetamide compound, organochlorine compound, phenyl amide compound, cinnamic acid compound, copper compound and organic phosphorus compound.
Term " fungicide with result of treatment " is meant can be by the fungicide of plant corpus migration with control invasive pest.The example of this class fungicide comprises 'beta '-methoxy acrylic acid ester compounds, cyanoacetamide compound, phenyl amide compound, cinnamic acid compound and organic phosphorus compound.
Term " its microbial inoculum that kills with penetrability " is meant to have the fungicide that is penetrated into internal capacity through leaf surface.The example of this class fungicide comprises 'beta '-methoxy acrylic acid ester compounds, oxazolidinedione compound, cyanoacetamide compound, phenyl amide compound, cinnamic acid compound and organic phosphorus compound.
Except the fungicide of having named, expect that also other fungicide that is used for Phycomycetes with at least a preventive effect, a kind of result of treatment and penetrability will produce the observed identical effect with the present invention.For example, can mention that dithiocarbamate fungicide is as the fungicide that only has a kind of Phycomycetes of preventive effect.
Comprise the imidazolium compounds and at least a inorganic phosphorous compound as active component (b) of at least a formula as active component (a) (I) according to the composition of control of the present invention pest, described composition is particularly suitable for agricultural and horticultural use.Specifically, they show the outstanding effect of preventing and treating crop pest, and described disease is such as the rice blast that is caused by Pyricularia oryzae, the rice sheath eqpidemic disease (sheathblight) that causes by Rhizoctonia solani Kuhn (Rhizoctonia solani), the cucumber anthracnose that causes by Curcurbitaceae thorn dish spore (Colletotrichum lagenarium), the powdery mildew of cucumber that causes by monofilament shell (Sphaerotheca fuliginea), the cucumber downy mildew that causes by the false downy mildew of Cuba (Pseudoperonospora cubensis), the tomato late blight that causes by phytophthora infestans (Phytophthora infestans), by founding the early blight of tomato that withered chain lattice spore (Alternariasolani) causes, by the melanose of citrus (melanose) that causes of seat shell (Diaporthe citri) between citrus, the common green mould of citrus that causes by Penicillium digitatum (Penicillium digitatum), the pear scab that causes by Venturia bacterium Venturia nashicola, the apple chain lattice spore spot that causes by apple chain lattice spore (Alternaria mali), give birth to the downy mildew of garpe that single shaft mould (Plasmopara viticola) causes by grape, the gray mold that causes by Botrytis cinerea (Botrytis cinerea), the sclerotinite property that is caused by sclerotinite (Sclerotinia sclerotiorum) is rotted and the disease that caused by rest fungus etc.; With the soil disease that causes by phytopathogenic fungi such as Fusarium (Fusarium), pythium (Pythium), Rhizoctonia (Rhizoctonia), Verticillium (Verticillium) and knee Pseudomonas (Plasmodiophora) etc.Particularly, compositions table of the present invention reveals the outstanding effect of preventing and treating disease, and described disease is such as the potato late blight that is caused by phytophthora infestans (Phytophthora infestans), the bell pepper epidemic disease mouldiness fusarium wilt that causes by Phytophthora capsici (Phytophthora capsici), the watermelon epidemic disease mouldiness that is caused by moral thunder epidemic disease mould (Phytophthora drechsleri) rots, the black shank that causes by Phytophthora nicotianae (Phytophthora nicotianae var.nicotianae), the tomato late blight that causes by phytophthora infestans (Phytophthora infestans), the cucumber or the downy mildew of cucurbits that cause by the false downy mildew of Cuba (Pseudoperonospora cubensis), the cabbage or green vegetables (Chinese cabbage) downy mildew that cause by rape downy mildew (Peronospora brassicae), the onion downy mildew that causes by Peronospora destructor, onion shiroiro-eki-byo that causes by green onion epidemic disease mould (Phytophthora porri) and the watermelon brown rot that causes by Phytophthora capsici (Phytophthora capsici) and give birth to downy mildew of garpe that single shaft mould (Plasmopara viticola) causes and by for example Aphanomyces (Aphanomyces) by grape, the various soil diseases that pythium (Pythium) causes.The residual effect of described composition prolongs, and shows outstanding especially result of treatment.Therefore, it is in addition possible preventing and treating disease by treatment after infecting, because described composition has a kind of system activity, therefore the disease by soil treatment control stem and leaf is possible.
The imidazolium compounds and a kind of Phycomycetes fungicide that comprise at least a formula (I) according to the composition of control pest of the present invention as active component (b) as active component (a), described composition is applied to and infects or when suspecting the crop that infects pathomycete, have outstanding Fungicidally active, described crop for example is fruit vegetables (for example cucumber, tomato, an eggplant etc.); Cereal class (for example paddy rice, wheat etc.); The seed greengrocery; Fruit (for example apple, pears, grape, citrus etc.); Potato etc.They show the outstanding effect of preventing and treating disease, and described disease such as powdery mildew, downy mildew, anthracnose, gray mold, common green mould, sclerotinite property are rotted, scab, chain lattice spore spot, mottled rot disease, black spot, melanose of citrus, ripe rotten sick (ripe rot), late blight, early blight, fusarium wilt, sheath eqpidemic disease, damping off, southern eqpidemic disease (southernblight) etc.The control efficiency that described composition is also played very well to the soil disease that is caused by Phycomycetes (such as pythium) and other phytopathogen (such as Fusarium, Rhizoctonia, Verticillium, knee Pseudomonas etc.).The residual effect of described composition prolongs, and shows outstanding especially result of treatment.Therefore, it is possible preventing and treating disease by treatment after infecting.In addition, because described composition has a kind of system activity, therefore the disease by soil treatment control stem and leaf is possible.
Particularly, comprise the imidazolium compounds of at least a formula (I) and a kind of, be particularly suitable for agricultural and gardening as the Phycomycetes fungicide copper compound of active component (b) and/or the composition of organic phosphorus compound as active component (a).Specifically, described compositions table reveals the outstanding effect of preventing and treating crop pest, and described disease is such as the rice blast that is caused by Pyricularia oryzae, by the microbial rice sheath of miliary damping-off eqpidemic disease, the cucumber anthracnose that causes by Curcurbitaceae thorn dish spore, the powdery mildew of cucumber that causes by the monofilament shell, the cucumber downy mildew that causes by the false downy mildew of Cuba, the tomato late blight that causes by phytophthora infestans, by founding the early blight of tomato that withered chain lattice spore causes, by the melanose of citrus that causes of seat shell between citrus, the common green mould of citrus that causes by Penicillium digitatum, the pear scab that causes by Venturia bacterium Venturia nashicola, the apple chain lattice spore spot that causes by apple chain lattice spore, give birth to the mould downy mildew of garpe that causes of single shaft by grape, the gray mold that causes by Botrytis cinerea, rot by the microbial sclerotium of nuclear disk, rust, bacterial speck etc.; With the soil disease that causes by phytopathogenic fungi such as Fusarium, pythium, Rhizoctonia, Verticillium and knee Pseudomonas etc.Particularly, compositions table of the present invention reveals the outstanding effect of preventing and treating disease, described disease such as potato that is caused by phytophthora infestans or tomato late blight, the cucumber downy mildew that is caused by the false downy mildew of Cuba, gives birth to the mould downy mildew of garpe that causes of single shaft by grape; With the various soil diseases that cause by for example Phycomycetes of knee Pseudomonas, Aphanomyces, pythium etc.
The residual effect of the present composition prolongs, and makes them show outstanding preventive effect, also shows outstanding especially result of treatment.Therefore, by infecting the back treatment, it is possible preventing and treating disease.In addition, because they have a kind of system activity, therefore the disease by soil treatment control stem and leaf is possible.
Particularly, contain a kind of copper compound and reveal outstanding preventive effect, contain organic phosphorus compound and reveal outstanding result of treatment as the compositions table of Phycomycetes fungicide as the compositions table of Phycomycetes fungicide.
The cyanoacetamide compound, phenyl amide compound or the cinnamic acid compound compositions that comprise imidazolium compounds and a kind of Phycomycetes fungicide as active component (b) of at least a formula (I) as active component (a), the disease that is caused by Phycomycetes is shown outstanding control efficiency, described disease is such as plant disease, for example the downy mildew of cucumber, melon, cabbage, green vegetables, onion, custard squash and grape; The late blight of potato, red pepper, bell pepper, watermelon, custard squash, tobacco and tomato; Onion shiroiro-eki-byo; The watermelon brown rot; The soil disease that causes by phytopathogenic fungi such as pythium etc.It also has outstanding control efficiency to the disease that is caused by the knee Pseudomonas.
The composition that comprises the control pest of the 'beta '-methoxy acrylic acid ester compounds, oxazolidinedione compound of the imidazolium compounds of at least a formula (I) and a kind of Phycomycetes fungicide as active component (b) or organochlorine compound as active component (a), the disease that is caused by Phycomycetes is shown outstanding control efficiency, described disease is such as plant disease, for example rice blast; Rice sheath eqpidemic disease; Cucumber anthracnose; The downy mildew of cucumber, melon, cabbage, green vegetables, onion, custard squash and grape; The powdery mildew of wheat, barley and cucumber; The late blight of potato, red pepper, bell pepper, watermelon, custard squash, tobacco and tomato; The wheat tikka that rots; Early blight of tomato, melanose of citrus; The common green mould of citrus, pear scab; Apple chain lattice spore spot; Onion shiroiro-eki-byo; The watermelon brown rot; Various diseases, such as gray mold, sclerotinite property rot, rust and bacillary mottled rot disease; The various soil diseases that cause by phytopathogenic fungi such as Fusarium, pythium, Rhizoctonia, Verticillium etc.It also has outstanding control efficiency to the disease that is caused by the knee Pseudomonas.It is to also having outstanding especially control efficiency such as following disease: the epidemic disease mouldiness of potato, red pepper, bell pepper, watermelon, custard squash, tobacco, tomato etc. rots; Downy mildew with cucumber, melon, cabbage, green vegetables, onion, custard squash, grape etc.
In addition, comprise active component of the present invention (a) and composition (b) agricultural and the insect of gardening aspect are demonstrated outstanding control efficiency, described insect such as plant hopper (rice plant hopper section (Delphacidae)), diamond-back moth (Plutella xylostella), rice leafhopper (Nephotettixcincticeps), adzuki bean weevil (Caliosobruchus chinensis), prodenia litura (Spodopteralitura), black peach aphid (Myzus persicae) etc.; Mite is such as T.urticae Koch (Tetranychusurticae), tetranychus telarius (Tetranychus cinnabarinus), citrus red mite (crm) (Panonychuscitri) etc.; And nematode, such as southern root-knot eel-worm (Meloidigyne incognita) etc.
Comprise active component of the present invention (a) and increased activity component (c) be used to prevent and treat the pest composition and be specially adapted to agricultural and horticultural use.The pest that can prevent and treat with described composition comprises the plant disease that phytopathogenic fungi causes, such as rice blast; Rice sheath eqpidemic disease; Cucumber anthracnose; Powdery mildew of cucumber; The downy mildew of cucumber, melon, cabbage, green vegetables, onion and grape; The late blight of potato, red pepper, bell pepper, watermelon, custard squash, tobacco; Tomato epidemic disease mouldiness rots; Early blight of tomato; Melanose of citrus; The common green mould of citrus; Pear scab; Apple chain lattice spore spot; Various plant diseases, such as gray mold, sclerotinite property rot, rust etc.; Soil such as Fusarium, pythium, Rhizoctonia, wheel plate spore genus, knee Pseudomonas etc. passes the various plant diseases that pathomycete causes; Insect is such as plant hopper, diamond-back moth, rice leafhopper, adzuki bean weevil, prodenia litura, black peach aphid etc.; Mite is such as T.urticae Koch, tetranychus telarius, citrus red mite (crm) etc.; And nematode, such as southern root-knot eel-worm etc.More particularly, they the epidemic disease mouldiness of potato, red pepper, bell pepper, watermelon, custard squash, tobacco and tomato is rotted and the downy mildew of cucumber, melon, cabbage, green vegetables, onion, custard squash and grape effective.The residual effect that comprises the composition of active component (a) and increased activity component (c) prolongs, and not only shows outstanding preventive effect, but also shows outstanding result of treatment.Therefore, by infecting the back treatment, it is possible preventing and treating disease.
Comprise other insecticide hereinafter described and constitute the present invention and prevent and treat the active component (a) of the composition of pest and (B) and the active component of increased activity component (c), can be formulated as various ways by the various adjuvants in conventional Agrotechnical formulation, such as emulsifiable concentrate, pulvis, wetting powder, the aqueous solution, granula, suspending concentrate etc.Active component (a) (imidazolium compounds of formula (I)), active component (b) and other specific compound can be mixed and preparation, maybe every kind in them preparation respectively can be mixed then.During use, said preparation can directly use, or uses after being diluted to predetermined concentration with suitable diluent (for example water).
The example of operable adjuvant comprises carrier, emulsifier, suspending agent, thickener, stabilizing agent, dispersant, the spreading agent except that being used as increased activity component (c), surfactant, wetting agent, bleeding agent, antifreezing agent, defoamer etc.As required, suitably add these adjuvants.
Described carrier can be divided into solid-state carrier and liquid carrier.Solid-state carrier comprises animal and plant powder (for example starch, sugar, cellulose powder, cyclodextrin, active carbon, bean powder, wheat flour, rice husk powder, wood powder (wood powder), fish meal, milk powder etc.); With mineral matter powder (for example talcum powder, white bole, bentonite, bentonite-alkylamine compound, calcium carbonate, calcium sulphate, sodium bicarbonate, zeolite, diatomite, white carbon (white carbon), clay, aluminium oxide, silica, Cosan, white lime etc.).The example of liquid carrier comprises water, vegetable oil (soya-bean oil for example, cottonseed oil), animal oil (butter for example, whale oil etc.), alcohols (ethanol for example, ethylene glycol etc.), ketone (acetone for example, methyl ethyl ketone, methyl iso-butyl ketone (MIBK), isophorone etc.), ethers (diox for example, oxolane etc.), aliphatic hydrocarbon (kerosene for example, lam-oil, atoleine etc.), aromatic hydrocarbons (toluene for example, dimethylbenzene, trimethylbenzene, durene, cyclohexane, solvent naphtha etc.), halogenated hydrocarbons (chloroform for example, chlorobenzene etc.), acid amides (for example dimethyl formamide etc.), ester class (ethyl acetate for example, fatty glyceride etc.), nitrile (for example acetonitrile etc.), sulfur-containing compound (for example dimethyl sulfoxide (DMSO) etc.), the N-N-methyl-2-2-pyrrolidone N-, N, dinethylformamide etc.Described spreading agent (except that as those spreading agents of increased activity component (c)) or surfactant comprise the polyoxyethylene fatty acid esters of sorbitan.
In the composition of imidazolium compounds that comprises at least a formula (I) and at least a inorganic phosphorous compound as active component (b) as active component (a), (a) be generally 1: 300 to 300: 1 with (b) weight ratio, preferred 1: 100 to 100: 1, preferred again 1: 50 to 5: 1, most preferably 1: 50 to 1: 10.
In the composition of imidazolium compounds that comprises at least a formula (I) and at least a Phycomycetes fungicide as active component (b) as active component (a), (a) be generally 1: 10000 to 10000: 1 with (b) weight ratio, preferred 1: 1000 to 10000: 1, preferred again 1: 100 to 1000: 1.Especially in the composition of imidazolium compounds that contains at least a formula (I) and at least a cyanoacetamide compound (Phycomycetes fungicide), be preferably 1: 300 to 5: 1 as active component (b) as active component (a).At particularly copper compound and/or organic phosphorus compound as under the situation of active component (b) (Phycomycetes fungicide), (a) be generally 1: 2000 to 2000: 1 with (b) weight ratio, preferred 1: 300 to 300: 1, preferred again 1: 100 to 100: 1, be preferably 1: 50 to 5: 1 especially.
In the composition that contains active component (a) and increased activity component (c), (a) be generally 1: 5000 to 2000: 1 with (c) weight ratio, preferred 0.05: 99.95 to 90: 10, preferred again 0.2: 99.8 to 80: 20.
Comprise the PCO method of using the composition that the present invention prevents and treats pest, be also included within the scope of the present invention.
The use of composition that is used for preventing and treating pest at imidazolium compounds that comprises at least a formula (I) and at least a inorganic phosphorous compound as active component (b) as active component (a), active component (a) and working concentration (b) generally can not limit, because they change with the amount of for example pending crops, processing method, dosage form and preparation to be administered.For example, the imidazolium compounds of formula (I) and the working concentration of inorganic phosphorous compound are respectively 1-1000ppm and 1-5000ppm in leaf is handled, be respectively 10-10 in soil treatment, 000g/ha and 10-50,000g/ha.
(be selected from 'beta '-methoxy acrylic acid ester compounds oxazolidinedione compound at imidazolium compounds that comprises at least a formula (I) and at least a Phycomycetes fungicide as active component (b) as active component (a), the cyanoacetamide compound, organochlorine compound, phenyl amide compound and cinnamic acid compound) be used for preventing and treating the use of the composition of pest, the working concentration of described active component generally can not limit, because they change with following factor: the kind of used fungicide for example, pending crops, processing method, dosage form, the amount of preparation to be administered, the kind of processing time and harmful fungoid to be prevented and treated.For example, handle for leaf, the imidazolium compounds of formula (I) and the working concentration of fungicide are respectively 0.01-1000ppm and 0.01-1000ppm, preferably are respectively 0.1-500ppm and 0.1-500ppm.
The imidazolium compounds that comprises at least a formula (I) as active component (a) and a kind of as active component (b) copper compound and/or the use of the organic phosphorus compound composition that is used for preventing and treating pest, the working concentration of described active component generally can not limit, because they change with following factor: the kind of the amount of the kind of used fungicide, pending crops, processing method, dosage form, preparation to be administered, processing time and harmful fungoid to be prevented and treated for example.For example, the imidazolium compounds of formula (I) and the working concentration of described fungicide are respectively 0.01-1000ppm and 1-5000ppm in leaf is handled, be respectively 10-10 in soil treatment, 000g/ha and 10-50,000g/ha.
In the use of the composition that comprises active component (a) and increased activity component (c), the working concentration of these components generally can not limit, because they change with the amount of for example pending crops, processing method, dosage form and preparation to be administered.For example, the working concentration of active component (a) and increased activity component (c) is respectively 0.1-10 in leaf is handled, and 000ppm and 0.01-50ppm are respectively 0.01-100kg/ha and 0.1-0.5kg/ha in soil treatment.
Comprising active component (a) and composition (b) can use with mixture or in conjunction with for example other insecticide, fertilizer and safener, with effect and the effect that shows increase.Useful insecticide comprise except that as active component (a) and (b) bactericide, fungicide, insecticide, miticide, nematocide, antivirotic, attractant, weed killer herbicide and plant growth regulator.Particularly, the present invention prevents and treats the mixture or the composition of the composition of pest and one or more fungicide active components (removing as active component (a) and the fungicide (b)), can be for example in the scope of the pest that can prevent and treat, processing time with to acquisition humidification aspect the control activity of pest.The imidazolium compounds of the formula (I) of crop active component (a), as the Phos mixture of active component (b) and/or Phycomycetes fungicide and fungicide active component (except that as active component (a) and the fungicide (b)), can prepare respectively and mix in use, maybe can with wherein a kind of or at least two kinds mix and be formulated as unitary agent.
Under the imidazolium compounds of at least a formula (I) and at least a situation about combining as the inorganic phosphorous compound and/or at least a Phycomycetes fungicide of active component (b) as active component (a), just before use the compositions table of preparation reveal than the further control efficiency of enhancing of the composition of preparation before pre-.Therefore, the composition that contains active component (a) and (when needing) various adjuvants is packed respectively with the composition that contains active component (b) and (when needing) various adjuvants, and uses as the double pack preparation.For example, active component (a) and active component (b) can be dissolved in the liquid carrier separately and packing respectively, or the mixture of active component (a) and active component (b) and other fungicide is dissolved in separately the liquid carrier, and pack respectively.
Comprise in the PCO method of composition of active component (a) and increased activity component (c) in employing, described composition can use with the mixture with above-mentioned other insecticide, and this can produce the effect of further enhancing.The representative instance of other useful insecticide comprises azole compounds, such as fluorine bacterium azoles (popular name) etc.; Quinoxaline compounds is such as Quinomethionate (popular name) etc.; Benzimidazole compound is such as benomyl (popular name) etc.; The pyridine amines is such as fluazinam (popular name) etc.; The sulfenic acid compound is such as Dichlofluanid (popular name) etc.; Isoxazole compound is such as hydoxyisoxazole (popular name) etc.; The inferior amide compound of dicarboxyl is such as procymidone (popular name) etc.; N-benzanilide compound is such as flutolanil (popular name) etc.; And benzamide compounds, such as (R, S)-4-chloro-N-[cyano group (ethoxyl methyl] benzamide etc.
Be shown in according to the preferred embodiment that comprises the composition of active component (a) and control pest (b) of the present invention following, only be used for the explanation, be not restrictive.
(1) wherein at least a inorganic phosphorous compound and/or at least a Phycomycetes fungicide have the composition of the control pest of preventive effect.
(2) wherein at least a inorganic phosphorous compound and/or at least a Phycomycetes fungicide have the composition of the control pest of result of treatment.
(3) wherein at least a inorganic phosphorous compound and/or at least a Phycomycetes fungicide have the composition of the control pest of penetrability.
(4) wherein at least a inorganic phosphorous compound and/or at least a Phycomycetes fungicide have the composition of the control pest of preventive effect and result of treatment.
(5) wherein at least a inorganic phosphorous compound and/or at least a Phycomycetes fungicide have the composition of the control pest of preventive effect and penetrability.
(6) wherein at least a inorganic phosphorous compound and/or at least a Phycomycetes fungicide have the composition of the control pest of result of treatment and penetrability.
(7) wherein at least a inorganic phosphorous compound and/or at least a Phycomycetes fungicide have the composition of the control pest of preventive effect, result of treatment and penetrability.
(8) wherein active component (b) is the composition of the control pest of at least a inorganic phosphorous compound.
(9) wherein active component (b) is the composition of the control pest of at least a Phycomycetes fungicide.
(10) according to the composition of the control pest of above (9), wherein said Phycomycetes fungicide is to be selected from following compound: 'beta '-methoxy acrylic acid ester compounds, oxazolidinedione compound, cyanoacetamide compound, organochlorine compound, phenyl amide compound, cinnamic acid compound, copperization contain thing and organic phosphorus compound.
(11) according to the composition of the control pest of above (9), wherein said Phycomycetes fungicide is that the 'beta '-methoxy acrylic acid ester compounds is with/Huo oxazolidinedione compound.
(12) according to the composition of the control pest of above (9), wherein said Phycomycetes fungicide is to be selected from following compound: cyanoacetamide compound, organochlorine compound, phenyl amide compound, cinnamic acid compound, copper compound and organic phosphorus compound.
(13) according to the composition of the control pest of above (9), (10) or (11), wherein said Phycomycetes fungicide is the 'beta '-methoxy acrylic acid ester compounds.
(14) according to the composition of the control pest of above (13), wherein said 'beta '-methoxy acrylic acid ester compounds be ( E)-2-{2-[6-(2-cyano-benzene oxygen) pyrimidine-4-base oxygen base] phenyl-the 3-methoxy-methyl acrylate or ( E)-methoxyimino [α-(neighbour-tolyl oxygen base)-O-tolyl] methyl acetate.
(15) according to the composition of the control pest of (9), (10) or (11), wherein said Phycomycetes fungicide Wei oxazolidinedione compound.
(16) according to the composition of the control pest of (15), wherein said Phycomycetes fungicide is 3-anilino--5-methyl-5-(4-Phenoxyphenyl)-1,3-oxazolidine-2,4-diketone.
(17) according to the composition of the control pest of (9), (10) or (12), wherein said Phycomycetes fungicide is the cyanoacetamide compound.
(18) according to the composition of the control pest of (17), wherein said cyanoacetamide compound is 1-(2-cyano group-2-methoxyimino acetyl)-3-ethyl urea.
(19) according to the composition of the control pest of (9), (10) or (12), wherein said Phycomycetes fungicide is organochlorine compound.
(20) according to the composition of the control pest of (19), wherein said organochlorine compound is tetrachloro isophthalonitrile or pcnb.
(21) according to the composition of the control pest of (19), wherein said organochlorine compound is the tetrachloro isophthalonitrile.
(22) according to the composition of the control pest of (9), (10) or (12), wherein said Phycomycetes fungicide is the phenyl amide compound.
(23) according to the composition of the control pest of (22), wherein said phenyl amide compound is at least a following compound: N-(2-methoxyl group the acetyl)-N-(2 that is selected from, the 6-xylyl)-the DL-methyl lactamine, 2-methoxyl group-N-(2-oxo-1,3-oxazolidine-3-yl) acetyl-2 ' 6 '-dimethylaniline, (±)-α-2-chloro-N-(2,6-xylyl acetamide)-gamma-butyrolacton, N-phenyl acetyl-N-(2, the 6-xylyl)-the DL-methyl lactamine, N-(2-furoyl)-N-(2, the 6-xylyl)-DL-methyl lactamine and (±)-α-[N-(3-chlorphenyl)-cyclopropane carboxamide)-gamma-butyrolacton.
(24) according to the composition of the control pest of (22), wherein said phenyl amide compound is N-(2-methoxyl group acetyl)-N-(2, the 6-xylyl)-DL-methyl lactamine.
(25) according to the composition of the control pest of (9), (10) or (12), wherein said Phycomycetes fungicide is the cinnamic acid compound.
(26) according to the composition of the control pest of (25), wherein said cinnamic acid compound be (E, Z)-4-[3-(4-chlorphenyl)-3-(3, the 4-Dimethoxyphenyl) acryloyl] morpholine.
(27) according to the composition according to the control pest of (9), (10) or (12), wherein said Phycomycetes fungicide is copper compound and/or organic phosphorus compound.
(28) according to the composition of the control pest of (27), wherein said copper compound is inorganic copper fungicide agent and/or organic copper fungicide.
(29) according to the composition of the control pest of (28), the active component of wherein said inorganic copper fungicide agent is at least a following member that is selected from: Kocide SD, sulfovinic acid copper, copper oxychloride, anhydrous cupric sulfate (II) and basic copper sulfate calcium.
(30) according to the composition of the control pest of (27), wherein said organic phosphorus compound is to be selected from least one following member: three (ethylphosphonic acid) aluminium, D2EHDTPA O-2,6-two chloro-p-methylphenyl-O, O-dimethyl ester, phosphonothiolic acid (R, S)-S-(R, S)-sec-butyl-O-ethyl-2-oxo-2-thiazolidinyl ester, D2EHDTPA S-benzyl diisopropyl ester, phosphordithiic acid O-ethyl diphenyl and 2-diethoxy thiophosphoryl oxygen base-5-methylpyrazole also (1,5-a) pyrimidine-6-Ethyl formate.
(31) according to the composition of the control pest of (27), wherein said organic phosphorus compound is three (ethylphosphonic acid) aluminium.
(32) according to the composition of the control pest of (27), the imidazolium compounds of wherein at least a formula (I) and the weight ratio of described copper compound and/or organic phosphorus compound are 1: 2000 to 2000: 1.
Below describe the preferred embodiment of using the composition that contains active component (a) and increased activity component (c), described embodiment only is used for explanation, but is not restrictive.
(1) composition that contains active component (a) and increased activity component (c) can be applied to pest with the form of water-borne dispersions.In the method, exist pest or expection to exist the position (such as leaf or the soil of useful plant) of pest to go up the described water-borne dispersions of sprinkling.Described water-borne dispersions is effective especially for using of leaf.For example prepare described water-borne dispersions by the following method:
(i) preparation with described active component is scattered in the water, to wherein adding described increased activity component; The preparation mark that (ii) will contain active component and increased activity component is in water; Or this method is similar to (i) or (ii).By using every 0.1-10, composition 1 premium on currency of 000mg control pest prepares water-borne dispersions to be administered, make active component concentration be 0.1-10,000ppm.The sprinkling amount of described water-borne dispersions is 100-10,000l/ha.
(2) composition that contains active component (a) and increased activity component (c) can be used with the water-borne dispersions form identical with above-mentioned water-borne dispersions.The concentration of active component is 0.1-10 in this water-borne dispersions, 000ppm.The sprinkling amount of this water-borne dispersions is 100-10,000l/ha.
Provide the test implementation example of composition aspect agricultural or horticultural fungicide purposes of control pest of the present invention below, these embodiment only are used for explanation.
Test implementation example 1
Test to the cucumber downy mildew result of treatment
Mix by the wetting powder with the water-borne dispersions concentrate of No. 1 compound and 20% inorganic phosphorous compound (being shown in the following table 9), preparation contains the composition of the control pest of No. 1 compound being respectively 100ppm and 2000ppm concentration and described inorganic phosphorous compound.According to the reference preparation embodiment that hereinafter provides, prepare the wetting powder of 20% described inorganic phosphorous compound.
At polyethylene flowerpot (diameter: cultivate cucumber (cultivar: Suyo) 7.5cm).When plant reaches two leaves during the phase,, inoculate to plant by spraying the spore suspension of downy mildew fungi (the false downy mildew of Cuba).After 24 hours, utilize spray gun to spray the composition of the above preparation of 10ml/ basin for this plant.As a comparison, by containing this inorganic phosphorous compound of 2000ppm, do not contain the 10ml composition of No. 1 compound or contain No. 1 compound of 100ppm, do not contain the 10ml composition of inorganic phosphorous compound, carry out identical test.Plant was kept 6 days in being set in 22-24 ℃ chamber, measure the infringement area of first leaf, calculate the incidence of disease (%) of disease by it according to following formula.What obtain the results are shown in the table 9.
The incidence of disease (%)=(a/b) * 100
Wherein a is for handling the infringement area of plant; And b is the infringement area of contrast (non-processing plant).
Can calculate the theoretical incidence of disease (%) according to the formula of following Colby.The incidence of disease in test composition is lower than under the situation of theoretical value, and this test composition can produce synergistic effect.In these cases, the theoretical incidence of disease (%) is represented in bracket in table 9.
The theoretical incidence of disease (%)=(X 1* Y 1)/100
X wherein 1The incidence of disease (%) for the plant of only using No. 1 compound treatment; And Y 1The incidence of disease (%) for the plant of only handling with this inorganic phosphorous compound.
Table 9
Result of treatment to cucumber downy mildew (the incidence of disease; %)
Figure G2009102049859D0000321
Test implementation example 2
Test to the cucumber downy mildew result of treatment
Mix by the wetting powder with the water-borne dispersions concentrate of No. 1 compound and 20% inorganic phosphorous compound (being shown in the following table 10), preparation contains the composition of control pest of the described inorganic phosphorous compound of No. 1 compound of indication concentration and 250ppm concentration.According to the reference preparation embodiment that hereinafter provides, prepare the wetting powder of 20% described inorganic phosphorous compound.
At polyethylene flowerpot (diameter: cultivate cucumber (cultivar: Suyo) 7.5cm).When plant reaches two leaves during the phase,, inoculate to plant by spraying the spore suspension of downy mildew fungi (the false downy mildew of Cuba).After 24 hours, utilize spray gun to spray the composition of the above preparation of 10ml/ basin for this plant.As a comparison, by using the 10ml/ basin to contain this inorganic phosphorous compound of 250ppm, not containing No. 1 compound compositions or the 10ml/ basin contains No. 1 compound of indicating concentration, the composition that does not contain inorganic phosphorous compound, carry out identical test.Plant was kept 4 days in being set in 22-24 ℃ chamber, measure the infringement area of first leaf, calculate the incidence of disease (%) of disease by it according to following formula.What obtain the results are shown in the table 10.
The incidence of disease (%)=(a/b) * 100
Wherein a is for handling the infringement area of plant; And b is the infringement area of contrast (non-processing plant).
Can calculate the theoretical incidence of disease (%) according to the formula of following Colby.The incidence of disease in test composition is lower than under the situation of theoretical value, and this test composition can produce synergistic effect.In these cases, the theoretical incidence of disease (%) is represented in bracket in table 10.
The theoretical incidence of disease (%)=(X 2* Y 2)/100
X wherein 2The incidence of disease (%) for the plant of only using No. 1 compound treatment; And Y 2The incidence of disease (%) for the plant of only handling with this inorganic phosphorous compound.
Table 10
Result of treatment to cucumber downy mildew (the incidence of disease; %)
Figure G2009102049859D0000331
Test implementation example 3
Field trial to the cucumber downy mildew effect
On May 10th, 1997,5 strains, two leaf phases cucumber seedling (cultivar: No. 3, TokiwaKohai Hikari, P type) is planted in being positioned at Japanese Kusatsu City, the cut section in the land for growing field crops of Shiga (every district 3m 2) in.June 10 and 17 days, utilize the amount of miniaturised nebuliser with every district 500ml, spray the composition that contains inorganic phosphorous compound shown in No. 1 compound of 50ppm and the 1500ppm following table 11.As a comparison,, only contain the composition of this inorganic phosphorous compound of 1500ppm or only contain No. 1 compound compositions of 50ppm, to carry out identical field trial, to observe all blades, to obtain the contrast index according to following deciding grade and level system by using June 23.What obtain the results are shown in the table 11.Do not carry out the artificial infection pathomycete, so disease is spontaneous.
The contrast index The seriousness of disease
5 Infringement area or length are less than 3% of contrast (area is untreated).
4 Infringement area or length are more than 3% or 3% and less than 5% of contrast.
3 Infringement area or length are more than 5% or 5% and less than 10% of contrast.
2 Infringement area or length are more than 10% or 10% and less than 30% of contrast.
1 Infringement area or length are more than 30% or 30% of contrast.
Table 11
Field trial (contrast index) to cucumber downy mildew
Figure G2009102049859D0000341
Note: * has the aqueous solution of the phosphoric acid (deriving from Masso) of 600g/l concentration.
* has the aqueous solution of the phosphoric acid (deriving from Horticura cc) of 200g/l concentration.
Test implementation example 4
Test to the cucumber downy mildew result of treatment
At polyethylene flowerpot (diameter: cultivate cucumber (cultivar: Suyo) 7.5cm).When plant reaches two leaves during the phase,, inoculate to plant by spraying the spore suspension of downy mildew fungi (the false downy mildew of Cuba).After 24 hours, utilize spray gun contain 10ml separately shown in compound compositions shown in the table 12-19 of concentration be sprayed onto on the plant.Plant was kept 6 days in being set in 22-24 ℃ chamber, measure the infringement area of first leaf, calculate the incidence of disease (%) of disease by it according to following formula.What obtain the results are shown among the table 12-19.
The incidence of disease (%)=(a/b) * 100
Wherein a is for handling the infringement area of plant; And b is the infringement area of contrast (non-processing plant).
Can calculate the theoretical incidence of disease (%) according to the formula of following Colby.The incidence of disease in test composition is lower than under the situation of theoretical value, and this test composition can produce synergistic effect.In these cases, the theoretical incidence of disease (%) is represented in bracket in table 12-19.
The theoretical incidence of disease (%)=(X 3* Y 3)/100
X wherein 3The incidence of disease (%) for the plant of only using 1,2 or No. 3 compound treatment; And Y 3For only use compound (a) (promptly ( E)-2-{2-[6-(2-cyano-benzene oxygen) pyrimidine-4-base oxygen base] phenyl-the 3-methoxy-methyl acrylate), compound (b) (promptly ( E)-methoxyimino [α-(o-tolyl oxygen base)-O-tolyl] methyl acetate), the incidence of disease (%) of the plant of white urea cyanogen, metalaxyl or dimethomorph processing.
Table 12
Result of treatment to cucumber downy mildew (the incidence of disease; %)
Figure G2009102049859D0000351
Table 13
Result of treatment to cucumber downy mildew (the incidence of disease; %)
Figure G2009102049859D0000361
Table 14
Result of treatment to cucumber downy mildew (the incidence of disease; %)
Figure G2009102049859D0000362
Table 15
Result of treatment to cucumber downy mildew (the incidence of disease; %)
Figure G2009102049859D0000371
Table 16
Result of treatment to cucumber downy mildew (the incidence of disease; %)
Figure G2009102049859D0000372
Table 17
Result of treatment to cucumber downy mildew (the incidence of disease; %)
Figure G2009102049859D0000381
Table 18
Result of treatment to cucumber downy mildew (the incidence of disease; %)
Figure G2009102049859D0000382
Table 19
Result of treatment to cucumber downy mildew (the incidence of disease; %)
Test implementation example 5
Test to the cucumber downy mildew result of treatment
At polyethylene flowerpot (diameter: cultivate cucumber (cultivar: Suyo) 7.5cm).When plant reaches two leaves during the phase,, inoculate to plant by spraying the spore suspension of downy mildew fungi (the false downy mildew of Cuba).After 18 hours, utilize spray gun that 20ml is contained the composition sprayed of No. 1 compound of respective concentration shown in the table 20 and compound (c) (3-anilino--5-methyl-5-(4-Phenoxyphenyl)-1,3-oxazolidine-2,4-diketone) to 2 strain seedling.Plant was kept 5 days in being set in 22-24 ℃ chamber, obtain the average infringement area of 2 strain seedling, to calculate the incidence of disease (%) of disease by it with test implementation example 1 identical mode.What obtain the results are shown in the table 20.
Can calculate the theoretical incidence of disease (%) according to the formula of following Colby.The incidence of disease in test composition is lower than under the situation of theoretical value, and this test composition can produce synergistic effect.In these cases, the theoretical incidence of disease (%) is represented in bracket in table 20.
The theoretical incidence of disease (%)=(X 4* Y 4)/100
X wherein 4The incidence of disease (%) for the plant of only using No. 1 compound treatment; And Y 4For only using the incidence of disease (%) of the plant that compound (c) handles.
Table 20
Result of treatment to cucumber downy mildew (the incidence of disease; %)
Figure G2009102049859D0000401
Test implementation example 6
Test to the tomato late blight result of treatment
At polyethylene flowerpot (diameter: cultivate tomato (cultivar: Ponderosa) 7.5cm).When plant reaches four leaves during the phase,, inoculate to plant by spraying the zoosporangium suspension of late blight fungi (phytophthora infestans).After 6 hours, utilize spray gun that the 10ml/ basin is contained the composition sprayed of No. 1 compound of respective concentration shown in the table 21-23 and white urea cyanogen, metalaxyl or dimethomorph to plant.Plant was kept 3-5 days in being set in 22-24 ℃ chamber, measure the infringement area, to calculate the incidence of disease (%) of disease by it with test implementation example 1 identical mode.What obtain the results are shown among the table 21-23.
Can calculate the theoretical incidence of disease (%) according to the formula of following Colby.The incidence of disease in test composition is lower than under the situation of theoretical value, and this test composition can produce synergistic effect.In these cases, the theoretical incidence of disease (%) is represented in bracket in table 21-23.
The theoretical incidence of disease (%)=(X 5* Y 5)/100
X wherein 5The incidence of disease (%) for the plant of only using No. 1 compound treatment; And Y 5The incidence of disease (%) for the plant of only handling with white urea cyanogen, metalaxyl or dimethomorph.
Table 21
Result of treatment to tomato late blight (the incidence of disease; %)
Figure G2009102049859D0000411
Table 22
Result of treatment to tomato late blight (the incidence of disease; %)
Figure G2009102049859D0000412
Table 23
Result of treatment to tomato late blight (the incidence of disease; %)
Figure G2009102049859D0000421
Test implementation example 7
Field trial to cucumber downy mildew
On May 9 nineteen ninety-five, 7 strain cucumber seedlings (cultivar: No. 3, Tokiwa KohaiHikari, P type) are planted in being positioned at Japanese Kusatsu City, the cut section in the land for growing field crops of Shiga (every district 5m 2) in.May 30 and June 6, utilize the amount of miniaturised nebuliser with every district 500-750ml, the composition sprayed that will contain No. 1 compound of respective concentration shown in the following table 24 and tpn is to plant.June 14, observe all blades, to obtain the contrast index according to following deciding grade and level system.What obtain the results are shown in the table 24.Do not carry out the artificial infection pathomycete, so disease is spontaneous.
The contrast index The seriousness of disease
5 Infringement area or length are less than 7% of contrast (area is untreated).
4 Infringement area or length are more than 7% or 7% and less than 10% of contrast.
3 Infringement area or length are more than 10% or 10% and less than 20% of contrast.
2 Infringement area or length are more than 20% or 20% and less than 30% of contrast.
1 Infringement area or length are more than 30% or 30% of contrast.
Table 24
Field trial to cucumber downy mildew (contrast index)
Figure G2009102049859D0000431
Test implementation example 8
Test to the cucumber downy mildew preventive effect
At polyethylene flowerpot (diameter: cultivate cucumber (cultivar: Suyo) 7.5cm).When plant reaches two leaves during the phase, utilize spray gun 10ml to be contained No. 1 compound and the Doitsu Borudo A (trade name of respective concentration shown in the following table 25, by Hokko Chemical Industry Co., the copper oxychloride wetting powder that Ltd. produces) composition sprayed is to seedling.After 24 hours,, inoculate to seedling by spraying the spore suspension of downy mildew fungi (the false downy mildew of Cuba).Plant was kept 6 days in being set in 22-24 ℃ chamber, measure the infringement area of first leaf, calculate the incidence of disease (%) of disease by it according to following formula.What obtain the results are shown in the table 25.
The incidence of disease (%)=(a/b) * 100
Wherein a is for handling the infringement area of plant; And b is the infringement area of contrast (non-processing plant).
Can calculate the theoretical incidence of disease (%) according to the formula of following Colby.The incidence of disease in test composition is lower than under the situation of theoretical value, and this test composition may be the composition that produces synergistic effect.In these cases, the theoretical incidence of disease (%) is represented in bracket in table 25.
The theoretical incidence of disease (%)=(X 6* Y 6)/100
X wherein 6The incidence of disease (%) for the plant of only using No. 1 compound treatment; And Y 6The incidence of disease (%) for the plant of only handling with DoitsuBorudo A.
Table 25
Preventive effect to cucumber downy mildew (the incidence of disease; %)
Figure G2009102049859D0000441
Test implementation example 9
Test to the tomato late blight preventive effect
At polyethylene flowerpot (diameter: cultivate tomato (cultivar: Ponderosa) 7.5cm).When plant reaches four leaves during the phase, utilize spray gun that 10ml is contained the composition sprayed of No. 1 compound of respective concentration shown in following table 26 and 27 and Kocide Bordeaux (trade name of the copper hydroxide wettable powder of being produced by Griffin) or Doitsu Borudo A (by Hokko ChemicalIndustry Co., the trade name of the copper oxychloride wetting powder that Ltd. produces) to seedling.After 24 hours,, inoculate to seedling by spraying the zoosporangium suspension of late blight fungi (phytophthora infestans).Plant was kept 3 days in being set in 22-24 ℃ chamber, measure the infringement area, to calculate the incidence of disease (%) of disease by it with test implementation example 1 identical mode.What obtain the results are shown in table 26 and 27.
Can calculate the theoretical incidence of disease (%) according to the formula of following Colby.The incidence of disease in test composition is lower than under the situation of theoretical value, and this test composition may be the composition that produces synergistic effect.In these cases, the theoretical incidence of disease (%) is represented in bracket in table 26 and 27.
The theoretical incidence of disease (%)=(X 7* Y 7)/100
X wherein 7The incidence of disease (%) for the plant of only using No. 1 compound treatment; And Y 7The incidence of disease (%) for the plant of only handling with Kocide Bordeaux or Doitsu Borudo A.
Table 26
Preventive effect to tomato late blight (the incidence of disease; %)
Figure G2009102049859D0000451
Table 27
Preventive effect to tomato late blight (the incidence of disease; %)
Figure G2009102049859D0000452
Test implementation example 10
Test to the cucumber downy mildew result of treatment
At polyethylene flowerpot (diameter: cultivate cucumber (cultivar: Suyo) 7.5cm).When plant reaches two leaves during the phase,, inoculate to plant by spraying the spore suspension of downy mildew fungi (the false downy mildew of Cuba).After 24 hours, utilize spray gun that 10ml is contained the composition sprayed of No. 1 compound of respective concentration shown in the table 28 and three (ethylphosphonic acid) aluminium (phosethyl-Al) to plant.Plant was kept 6 days in being set in 22-24 ℃ chamber, measure the infringement area of first leaf, to calculate the incidence of disease (%) of disease by it with test implementation example 1 identical mode.What obtain the results are shown in the table 28.
Can calculate the theoretical incidence of disease (%) according to the formula of following Colby.The incidence of disease in test composition is lower than under the situation of theoretical value, and this test composition can produce synergistic effect.In these cases, the theoretical incidence of disease (%) is represented in bracket in table 28.
The theoretical incidence of disease (%)=(X 8* Y 8)/100
X wherein 8The incidence of disease (%) for the plant of only using No. 1 compound treatment; And Y 8The incidence of disease (%) for the plant of only handling with phosethyl-Al.
Table 28
Result of treatment to cucumber downy mildew (the incidence of disease; %)
Test implementation example 11
Test to the cucumber downy mildew result of treatment
The preparation of water-borne dispersions:
With 500 times or 1000 times of the spreading agent shown in the following table 29 (increased activity component) dilute with waters, to wherein adding No. 1 compound that concentration is 100ppm or 12.5ppm, the preparation water-borne dispersions.As a comparison, prepare the water-borne dispersions that No. 1 compound that contains 100Ppm or 12.5ppm does not contain the increased activity component in the same manner.
Test method and result:
At polyethylene flowerpot (diameter: cultivate cucumber (cultivar: Suyo) 7.5cm).When plant reaches two leaves during the phase,, inoculate to plant by spraying the spore suspension of downy mildew fungi (the false downy mildew of Cuba).After 15-24 hour, utilize spray gun with every 0.25m 2This water-borne dispersions of 20ml is sprayed onto on the plant.Plant was kept 4-6 days in being set in 22-24 ℃ chamber, measure the infringement area of first leaf, to obtain the contrast index according to following deciding grade and level system.What obtain the results are shown in the table 29.
The contrast index The seriousness of disease
4 Infringement area or length are less than 20% of contrast (plant of being untreated).
3 Infringement area or length are more than 20% or 20% and less than 40% of contrast.
2 Infringement area or length are more than 40% or 40% and less than 60% of contrast.
1 Infringement area or length are more than 60% or 60% of contrast.
Table 29
Figure G2009102049859D0000481
Continued
Table 29 (continuous table)
Figure G2009102049859D0000491
Test implementation example 12
Test to the tomato late blight result of treatment
The preparation of water-borne dispersions:
With 500 times of the spreading agent shown in the following table 30 (increased activity component) dilute with waters, to wherein adding No. 1 compound that concentration is 400ppm or 12.5ppm, the preparation water-borne dispersions.
As a comparison, prepare water-borne dispersions in the same manner, only be to use the fatty acid esters of sorbitan surfactant shown in the following table 30 (contrast spreading agent A, B or C), and add No. 1 compound of 400ppm concentration as spreading agent.As further contrast, preparation contains the water-borne dispersions that 400ppm or No. 1 compound of 12.5ppm do not contain the increased activity component in the same manner.
Table 30
Test method and result:
At polyethylene flowerpot (diameter: cultivate tomato (cultivar: Ponderosa) 7.5cm).When plant reaches four leaves during the phase,, inoculate to plant by spraying the zoosporangium suspension of late blight fungi (phytophthora infestans).After 4 hours, utilize spray gun with every 0.25m 2The water-borne dispersions of the above preparation of 20ml is sprayed onto on the plant.Plant kept 3 days in being set in 22-24 ℃ chamber after, measure the infringement area, to obtain the contrast index by it according to the identical deciding grade and level system in the test implementation example 11.What obtain the results are shown in the table 31.
Table 31
Result of treatment (contrast index) to tomato late blight
Figure G2009102049859D0000511
Test implementation example 13
Test to the tomato late blight result of treatment
The preparation of water-borne dispersions:
With 2000 times of the spreading agent shown in the following table 32 (increased activity component) dilute with waters, to wherein adding No. 1 compound that concentration is 100ppm, the preparation water-borne dispersions.As a comparison, preparation contains the water-borne dispersions that No. 1 compound of 100ppm does not contain the increased activity component in the same manner.
Test method and result:
At polyethylene flowerpot (diameter: cultivate tomato (cultivar: Ponderosa) 7.5cm).When plant reaches four leaves during the phase,, inoculate to plant by spraying the zoosporangium suspension of late blight fungi (phytophthora infestans).After 4 hours, utilize spray gun with every 0.25m 2The water-borne dispersions of the above preparation of 20ml is sprayed onto on the plant.Plant kept 3 days in being set in 22-24 ℃ chamber after, measure the infringement area, to obtain the contrast index by it according to the identical deciding grade and level system in the test implementation example 11.What obtain the results are shown in the table 32.
Table 32
Result of treatment (contrast index) to tomato late blight
Figure G2009102049859D0000521
Test implementation example 14
Test to the tomato late blight preventive effect
The preparation of water-borne dispersions:
With 500 times of No. 58 or No. 91 spreading agents (increased activity component) dilute with waters, to No. 1 compound that wherein adds indication concentration, the preparation water-borne dispersions.As a comparison, prepare the water-borne dispersions that No. 1 compound that contains same concentrations does not contain the increased activity component in the same manner.
Test method and result:
At polyethylene flowerpot (diameter: cultivate tomato (cultivar: Ponderosa) 7.5cm).When plant reaches four leaves during the phase, utilize spray gun with every 0.25m 2The water-borne dispersions of the above preparation of 20ml is sprayed onto on the plant.Spray to handle after 24 hours, the zoosporangium suspension that sprays late blight fungi (phytophthora infestans) to be inoculating, and plant was kept 3 days in being set in 22-24 ℃ chamber.Measure the infringement area, to obtain the contrast index by it according to the identical deciding grade and level system in the test implementation example 11.What obtain the results are shown in the table 33.
Table 33
Preventive effect (contrast index) to tomato late blight
Figure G2009102049859D0000531
Test implementation example 15
Test to the cucumber downy mildew result of treatment
The preparation of water-borne dispersions:
With 500 times or 2000 times of the spreading agent shown in the following table 34 (increased activity component) dilute with waters, to wherein adding No. 1 compound that concentration is 12.5ppm, the preparation water-borne dispersions.As a comparison, prepare the water-borne dispersions that No. 1 compound that contains 12.5ppm does not contain the increased activity component in the same manner.
Test method and result:
At polyethylene flowerpot (diameter: cultivate cucumber (cultivar: Suyo) 7.5cm).When plant reaches two leaves during the phase,, inoculate to plant by spraying the spore suspension of downy mildew fungi (the false downy mildew of Cuba).After 15-24 hour, utilize spray gun with every 0.25m 2This water-borne dispersions of 20ml is sprayed onto on the plant.Plant was kept 5 days in being set in 22-24 ℃ chamber, measure the infringement area of first leaf, to obtain nothing-infringement area than (%).What obtain the results are shown in the table 34.
Table 34
Result of treatment (nothing-infringement area ratio to cucumber downy mildew; %)
Figure G2009102049859D0000541
(note: all umbers among following example of formulations 1-14 and the reference preparation embodiment are all represented with weight.)
Formulation examples 1
5 parts of (1) No. 1 compounds
(by weight, hereinafter identical)
(2) dipotassium hydrogen phosphate is 7 parts
(3) diatomite is 82 parts
(4) dialkyl sulfosuccinate is 2 parts
(5) polyoxyethylene alkyl phenyl ether sulfate is 4 parts
Above component is mixed, to obtain wetting powder.
Formulation examples 2
5 parts of (1) No. 1 compounds
(2) the tribasic sodium phosphate dodecahydrate is 16 parts
(3) diatomite is 73 parts
(4) dialkyl sulfosuccinate is 2 parts
(5) polyoxyethylene alkyl phenyl ether sulfate is 4 parts
Above component is mixed, to obtain wetting powder.
Formulation examples 3
5 parts of (1) No. 1 compounds
(2) dipotassium hydrogen phosphate is 18 parts
(3) kerosene is 63 parts
(4) dialkyl sulfosuccinate is 2 parts
(5) mixture of 12 parts of pure alkylates of polyoxyethylene alkylphenol derivative and polyoxyethylene dehydration sorb
Above component is mixed and grinds to form fine powder, to obtain the dispersion concentration thing.
Formulation examples 4
(1) white bole is 78 parts
(2) sodium-formaldehyde condensation products is 2 parts
(3) the polyoxyethylene alkyl aryl sulfate is 5 parts
(4) amorphous silicas of hydration is 15 parts
Mixture, dipotassium hydrogen phosphate and No. 1 compound of above component are mixed with 79: 20: 1 weight ratio, to obtain wetting powder.
Formulation examples 5
(1) white bole is 78 parts
(2) sodium-formaldehyde condensation products is 2 parts
(3) the polyoxyethylene alkyl aryl sulfate is 5 parts
(4) amorphous silicas of hydration is 15 parts
The mixture of above component, No. 1 compound and metalaxyl are mixed with 8: 1: 1 weight ratio, to obtain wetting powder.
System Liu example 6
0.5 part of (1) No. 2 compound
(2) metalaxyl is 0.5 part
(3) bentonite is 20 parts
(4) white bole is 74 parts
(5) sodium lignosulfonate is 5 parts
Above component and the suitable quantity of water that is enough to granulation are mixed together, and granulation then is to obtain granule.
Formulation examples 7
0.25 part of (1) No. 3 compound
(2) metalaxyl is 0.25 part
(3) calcium carbonate is 99.0 parts
(4) lower alcohol phosphoesterase 30 .5 part
Above component is mixed, to obtain pulvis.
Formulation examples 8
(1) white bole is 78 parts
(2) sodium-formaldehyde condensation products is 2 parts
(3) the polyoxyethylene alkyl aryl sulfate is 5 parts
(4) amorphous silicas of hydration is 15 parts
The mixture of above component, No. 1 compound and Kocide Bordeaux (trade name) are mixed with 0.8: 76.8: 22.4 weight ratio, to obtain wetting powder.
Formulation examples 9
(1) white bole is 78 parts
(2) sodium-formaldehyde condensation products is 2 parts
(3) the polyoxyethylene alkyl aryl sulfate is 5 parts
(4) amorphous silicas of hydration is 15 parts
The mixture of above component, No. 1 compound and Duitch Bordeaux A (trade name) are mixed with 5: 67.2: 27.8 weight ratio, to obtain wetting powder.
Formulation examples 10
0.25 part of (1) No. 1 compound
(2) Sanpun Bordeaux Dust DL (trade name, by 0.25 part of Noyaku K.K.and of Dai-ichi Hokko Chemical Industry Co., Ltd. produces)
(3) sodium carbonate is 99.0 parts
(4) lower alcohol phosphoesterase 30 .5 part
Above component is mixed, to obtain pulvis.
Formulation examples 11
0.5 part of (1) No. 1 compound
(2) Sanpun Bordeaux Dust DL (trade name, by 0.5 part of Noyaku K.K.and of Dai-ichi Hokko Chemical Industry Co., Ltd. produces)
(3) bentonite is 20 parts
(4) white bole is 74 parts
(5) sodium lignosulfonate is 5 parts
Above component and the suitable quantity of water that is enough to granulation are mixed together, and granulation then is to obtain granule.
Formulation examples 12
5 parts of (1) No. 1 compounds
5 parts in (2) three (ethylphosphonic acid) aluminium (phosethyl-Al)
(3) diatomite is 84 parts
(4) Lignosite is 2 parts
(5) dialkyl sulfosuccinate is 4 parts
Above component is mixed, to obtain wetting powder.
Formulation examples 13
11.1 parts of (1) No. 1 compounds (active component)
(2) dispersant SOPROPHOR FLK (trade name, by
Figure G2009102049859D0000581
1.1 part POULENC produces)
(3) dispersant and wetting agent Supragil MNS/90 (trade name) are 1.1 parts
(4) dispersant and suspending agent Vegum are 1.7 parts
(5) urea (as antifreezing agent) is 11.1 parts
(6) defoamer SM5572F (trade name) is 0.1 part
(7) distilled water is 73.8 parts
Above component (1)-(7) are mixed and carrying out wet lapping, is 2 μ m until the particle mean size of described active component, with the preparation dispersion.Add 10 parts of increased activity components in the dispersion of 90 parts of gained, jolting mixes then, with preparation water-borne dispersions concentrate.
Formulation examples 14
10.0 parts of (1) No. 1 compounds (active component)
(2) dispersant SOPROPHOR FLK (trade name, by 1.0 part POULENC produces)
(3) dispersant and wetting agent Supragil MNS/90 (trade name) are 1.0 parts
(4) dispersant and suspending agent Vegum are 1.5 parts
(5) urea (as antifreezing agent) is 10.0 parts
(6) defoamer SM5572F (trade name) is 0.1 part
(7) distilled water is 66.4 parts
(8) the increased activity component is 10.0 parts
Above component (1)-(8) are mixed and carrying out wet lapping, is 2 μ m until the particle mean size of described active component, with preparation water-borne dispersions concentrate.
The reference preparation example
(1) white bole is 78 parts
(2) sodium-formaldehyde condensation products is 2 parts
(3) the polyoxyethylene alkyl aryl sulfate is 5 parts
(4) amorphous silicas of hydration is 15 parts
Above component and a kind of Phos mixture are mixed with 4: 1 weight ratio, to prepare the wetting powder of 20% this Phos mixture.
Industrial usability
The present invention prevents and treats the composition of pest to suffering from the crops of the plant disease that is caused by pest, has the effect that treats and/or prevents of height, and can prevent and treat described pest.Particularly, contain the result of treatment that the compositions table of described increased activity component reveals and strengthen, make the amount that can reduce this active component.
Although described the present invention in detail with reference to specific embodiments, wherein can carry out variations and modifications without departing from the spirit and scope of the present invention, this will be apparent to those skilled in the art.

Claims (2)

1. be used to prevent and treat the composition of pest, said composition comprises:
(a) as at least a imidazolium compounds of active component by formula (I) expression:
Figure F2009102049859C0000011
Wherein R represents C1-6 alkyl or C1-6 alkoxyl, and n represents the integer of 1-5,
With
(b) be selected from following Phycomycetes fungicide as active component at least a:
(E)-and 2-{2-[6-(2-cyano-benzene oxygen) pyrimidine-4-base oxygen base] phenyl }-the 3-methoxy-methyl acrylate,
(E)-methoxyimino [α-(o-tolyl oxygen base)-O-tolyl] methyl acetate, 3-anilino--5-methyl-5-(4-Phenoxyphenyl)-1; 3-oxazolidine-2,4-diketone, 1-(2-cyano group-2-methoxyimino acetyl group)-3-ethyl urea, daconil M,
N-(2-methoxyl group acetyl group)-N-(2, the 6-xylyl)-DL-methyl lactamine, (E, Z)-4-[3-(4-chlorphenyl)-3-(3, the 4-Dimethoxyphenyl) acryloyl group] morpholine and three (ethylphosphonic acid) aluminium,
The weight ratio of wherein said imidazolium compounds and described fungicide is 1: 10000 to 10000: 1.
2. be used to prevent and treat the method for pest, comprise that the composition that will be used to prevent and treat pest is applied to pest, wherein said composition comprises:
(a) as at least a imidazolium compounds of active component by formula (I) expression:
Wherein R represents C1-6 alkyl or C1-6 alkoxyl, and n represents the integer of 1-5,
With
(b) be selected from following Phycomycetes fungicide as active component at least a:
(E)-and 2-{2-[6-(2-cyano-benzene oxygen) pyrimidine-4-base oxygen base] phenyl }-the 3-methoxy-methyl acrylate,
(E)-methoxyimino [α-(o-tolyl oxygen base)-O-tolyl] methyl acetate, 3-anilino--5-methyl-5-(4-Phenoxyphenyl)-1; 3-oxazolidine-2,4-diketone, 1-(2-cyano group-2-methoxyimino acetyl group)-3-ethyl urea, daconil M,
N-(2-methoxyl group acetyl group)-N-(2, the 6-xylyl)-DL-methyl lactamine, (E, Z)-4-[3-(4-chlorphenyl)-3-(3, the 4-Dimethoxyphenyl) acryloyl group] morpholine and three (ethylphosphonic acid) aluminium,
The weight ratio of wherein said imidazolium compounds and described fungicide is 1: 10000 to 10000: 1.
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