CN101690481B - 螺螨酯多重乳状液及其制备方法 - Google Patents
螺螨酯多重乳状液及其制备方法 Download PDFInfo
- Publication number
- CN101690481B CN101690481B CN 200910040911 CN200910040911A CN101690481B CN 101690481 B CN101690481 B CN 101690481B CN 200910040911 CN200910040911 CN 200910040911 CN 200910040911 A CN200910040911 A CN 200910040911A CN 101690481 B CN101690481 B CN 101690481B
- Authority
- CN
- China
- Prior art keywords
- water
- emulsion
- spirodiclofen
- spiral shell
- hlb value
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000839 emulsion Substances 0.000 title claims abstract description 85
- 239000005664 Spirodiclofen Substances 0.000 title claims abstract description 28
- DTDSAWVUFPGDMX-UHFFFAOYSA-N spirodiclofen Chemical compound CCC(C)(C)C(=O)OC1=C(C=2C(=CC(Cl)=CC=2)Cl)C(=O)OC11CCCCC1 DTDSAWVUFPGDMX-UHFFFAOYSA-N 0.000 title claims abstract description 28
- 238000004945 emulsification Methods 0.000 title claims description 29
- 238000002360 preparation method Methods 0.000 title abstract description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 102
- 239000002904 solvent Substances 0.000 claims abstract description 24
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 9
- 238000000034 method Methods 0.000 claims abstract description 6
- 150000002148 esters Chemical class 0.000 claims description 67
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Natural products CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 40
- 239000003921 oil Substances 0.000 claims description 40
- -1 polyoxyethylene Polymers 0.000 claims description 28
- 239000000203 mixture Substances 0.000 claims description 20
- 229910019142 PO4 Inorganic materials 0.000 claims description 18
- 239000010452 phosphate Substances 0.000 claims description 18
- 239000004094 surface-active agent Substances 0.000 claims description 18
- 239000003795 chemical substances by application Substances 0.000 claims description 16
- 239000002518 antifoaming agent Substances 0.000 claims description 15
- 229920001296 polysiloxane Polymers 0.000 claims description 15
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 14
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims description 14
- 239000003814 drug Substances 0.000 claims description 14
- 229920000858 Cyclodextrin Polymers 0.000 claims description 13
- 230000003750 conditioning effect Effects 0.000 claims description 13
- HFHDHCJBZVLPGP-UHFFFAOYSA-N schardinger α-dextrin Chemical compound O1C(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(O)C2O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC2C(O)C(O)C1OC2CO HFHDHCJBZVLPGP-UHFFFAOYSA-N 0.000 claims description 13
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 11
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 11
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 10
- 239000003945 anionic surfactant Substances 0.000 claims description 10
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 9
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 9
- 230000002528 anti-freeze Effects 0.000 claims description 9
- 239000004359 castor oil Substances 0.000 claims description 9
- 235000019438 castor oil Nutrition 0.000 claims description 9
- 239000013530 defoamer Substances 0.000 claims description 9
- 150000002170 ethers Chemical class 0.000 claims description 9
- 150000002191 fatty alcohols Chemical class 0.000 claims description 9
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 9
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 9
- 229920000136 polysorbate Polymers 0.000 claims description 9
- 229950008882 polysorbate Drugs 0.000 claims description 9
- 239000002562 thickening agent Substances 0.000 claims description 9
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 claims description 8
- 239000002202 Polyethylene glycol Substances 0.000 claims description 8
- OVXRPXGVKBHGQO-UHFFFAOYSA-N abietic acid methyl ester Natural products C1CC(C(C)C)=CC2=CCC3C(C(=O)OC)(C)CCCC3(C)C21 OVXRPXGVKBHGQO-UHFFFAOYSA-N 0.000 claims description 8
- OVXRPXGVKBHGQO-UYWIDEMCSA-N methyl (1r,4ar,4br,10ar)-1,4a-dimethyl-7-propan-2-yl-2,3,4,4b,5,6,10,10a-octahydrophenanthrene-1-carboxylate Chemical compound C1CC(C(C)C)=CC2=CC[C@H]3[C@@](C(=O)OC)(C)CCC[C@]3(C)[C@H]21 OVXRPXGVKBHGQO-UYWIDEMCSA-N 0.000 claims description 8
- 229920001223 polyethylene glycol Polymers 0.000 claims description 8
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 7
- 125000000217 alkyl group Chemical group 0.000 claims description 7
- 229920001400 block copolymer Polymers 0.000 claims description 7
- 239000007788 liquid Substances 0.000 claims description 7
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 7
- 229920000151 polyglycol Polymers 0.000 claims description 7
- 239000010695 polyglycol Substances 0.000 claims description 7
- 239000001294 propane Substances 0.000 claims description 7
- 229920001285 xanthan gum Polymers 0.000 claims description 7
- 150000008051 alkyl sulfates Chemical class 0.000 claims description 6
- 150000008052 alkyl sulfonates Chemical class 0.000 claims description 6
- 239000011324 bead Substances 0.000 claims description 6
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 6
- ZORQXIQZAOLNGE-UHFFFAOYSA-N 1,1-difluorocyclohexane Chemical class FC1(F)CCCCC1 ZORQXIQZAOLNGE-UHFFFAOYSA-N 0.000 claims description 5
- BWDBEAQIHAEVLV-UHFFFAOYSA-N 6-methylheptan-1-ol Chemical compound CC(C)CCCCCO BWDBEAQIHAEVLV-UHFFFAOYSA-N 0.000 claims description 5
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 5
- QYDYPVFESGNLHU-UHFFFAOYSA-N elaidic acid methyl ester Natural products CCCCCCCCC=CCCCCCCCC(=O)OC QYDYPVFESGNLHU-UHFFFAOYSA-N 0.000 claims description 5
- 235000011187 glycerol Nutrition 0.000 claims description 5
- QYDYPVFESGNLHU-KHPPLWFESA-N methyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC QYDYPVFESGNLHU-KHPPLWFESA-N 0.000 claims description 5
- 229940073769 methyl oleate Drugs 0.000 claims description 5
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 claims description 4
- 229920000053 polysorbate 80 Polymers 0.000 claims description 4
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 3
- 229920001213 Polysorbate 20 Polymers 0.000 claims description 3
- 150000001335 aliphatic alkanes Chemical class 0.000 claims description 3
- 125000005600 alkyl phosphonate group Chemical group 0.000 claims description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 3
- 229940049964 oleate Drugs 0.000 claims description 3
- 229910052760 oxygen Inorganic materials 0.000 claims description 3
- 239000001301 oxygen Substances 0.000 claims description 3
- 235000010486 polyoxyethylene sorbitan monolaurate Nutrition 0.000 claims description 3
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 claims description 3
- 239000000600 sorbitol Substances 0.000 claims description 3
- 125000000218 acetic acid group Chemical group C(C)(=O)* 0.000 claims description 2
- 230000015572 biosynthetic process Effects 0.000 claims description 2
- 231100000419 toxicity Toxicity 0.000 abstract description 5
- 230000001988 toxicity Effects 0.000 abstract description 5
- 230000002349 favourable effect Effects 0.000 abstract description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 239000000575 pesticide Substances 0.000 abstract description 3
- 238000003860 storage Methods 0.000 abstract description 2
- 239000002635 aromatic organic solvent Substances 0.000 abstract 1
- 230000015556 catabolic process Effects 0.000 abstract 1
- 238000006731 degradation reaction Methods 0.000 abstract 1
- 229960000583 acetic acid Drugs 0.000 description 21
- 241000196324 Embryophyta Species 0.000 description 10
- 239000003960 organic solvent Substances 0.000 description 10
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 7
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 239000003905 agrochemical Substances 0.000 description 6
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 6
- 239000002994 raw material Substances 0.000 description 6
- 238000003756 stirring Methods 0.000 description 6
- 241000488581 Panonychus citri Species 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 238000005338 heat storage Methods 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 4
- 238000009472 formulation Methods 0.000 description 4
- 235000011069 sorbitan monooleate Nutrition 0.000 description 4
- 239000000375 suspending agent Substances 0.000 description 4
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- 230000000895 acaricidal effect Effects 0.000 description 3
- 239000000642 acaricide Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 230000000749 insecticidal effect Effects 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 230000000361 pesticidal effect Effects 0.000 description 3
- 230000003449 preventive effect Effects 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
- 102000002322 Egg Proteins Human genes 0.000 description 2
- 108010000912 Egg Proteins Proteins 0.000 description 2
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 2
- URLKBWYHVLBVBO-UHFFFAOYSA-N Para-Xylene Chemical group CC1=CC=C(C)C=C1 URLKBWYHVLBVBO-UHFFFAOYSA-N 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 239000002537 cosmetic Substances 0.000 description 2
- 239000006184 cosolvent Substances 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- 239000002563 ionic surfactant Substances 0.000 description 2
- CDOSHBSSFJOMGT-UHFFFAOYSA-N linalool Chemical compound CC(C)=CCCC(C)(O)C=C CDOSHBSSFJOMGT-UHFFFAOYSA-N 0.000 description 2
- 210000004681 ovum Anatomy 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000001593 sorbitan monooleate Substances 0.000 description 2
- 229940035049 sorbitan monooleate Drugs 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 230000002195 synergetic effect Effects 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- 239000000341 volatile oil Substances 0.000 description 2
- 239000001490 (3R)-3,7-dimethylocta-1,6-dien-3-ol Substances 0.000 description 1
- CDOSHBSSFJOMGT-JTQLQIEISA-N (R)-linalool Natural products CC(C)=CCC[C@@](C)(O)C=C CDOSHBSSFJOMGT-JTQLQIEISA-N 0.000 description 1
- 150000000211 1-dodecanols Chemical class 0.000 description 1
- 241000675108 Citrus tangerina Species 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- LTTLGWXESLIUHQ-UHFFFAOYSA-N O(Cl)Cl.[F] Chemical compound O(Cl)Cl.[F] LTTLGWXESLIUHQ-UHFFFAOYSA-N 0.000 description 1
- 241000207834 Oleaceae Species 0.000 description 1
- 241000218641 Pinaceae Species 0.000 description 1
- 241001093501 Rutaceae Species 0.000 description 1
- 241000221035 Santalaceae Species 0.000 description 1
- 235000008632 Santalum album Nutrition 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- WUOACPNHFRMFPN-UHFFFAOYSA-N alpha-terpineol Chemical compound CC1=CCC(C(C)(C)O)CC1 WUOACPNHFRMFPN-UHFFFAOYSA-N 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000000306 component Substances 0.000 description 1
- SQIFACVGCPWBQZ-UHFFFAOYSA-N delta-terpineol Natural products CC(C)(O)C1CCC(=C)CC1 SQIFACVGCPWBQZ-UHFFFAOYSA-N 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 230000000857 drug effect Effects 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 230000013020 embryo development Effects 0.000 description 1
- 230000037149 energy metabolism Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 229930007744 linalool Natural products 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- PEQJBOMPGWYIRO-UHFFFAOYSA-N n-ethyl-3,4-dimethoxyaniline Chemical class CCNC1=CC=C(OC)C(OC)=C1 PEQJBOMPGWYIRO-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 235000013599 spices Nutrition 0.000 description 1
- 238000013112 stability test Methods 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 235000007586 terpenes Nutrition 0.000 description 1
- 229940116411 terpineol Drugs 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 229960002415 trichloroethylene Drugs 0.000 description 1
- UBOXGVDOUJQMTN-UHFFFAOYSA-N trichloroethylene Natural products ClCC(Cl)Cl UBOXGVDOUJQMTN-UHFFFAOYSA-N 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 239000012905 visible particle Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
贮存温度 | 贮存14天 | 贮存30天 | 贮存90天 | 贮存180天 |
54±2℃ | 螺螨酯分解率1.5%热贮稳定性合格 | 螺螨酯分解率1.8%热贮稳定性合格 | 螺螨酯分解率2.4%热贮稳定性合格 | 螺螨酯分解率3.1%热贮稳定性合格 |
0±2℃(备注) | 恢复至室温合格 | 恢复至室温合格 | 恢复至室温合格 | 恢复至室温合格 |
-15±2℃(备注) | 恢复至室温合格 | 恢复至室温合格 | 恢复至室温合格 | 恢复至室温合格 |
Claims (3)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 200910040911 CN101690481B (zh) | 2009-07-07 | 2009-07-07 | 螺螨酯多重乳状液及其制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 200910040911 CN101690481B (zh) | 2009-07-07 | 2009-07-07 | 螺螨酯多重乳状液及其制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN101690481A CN101690481A (zh) | 2010-04-07 |
CN101690481B true CN101690481B (zh) | 2013-09-11 |
Family
ID=42079229
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN 200910040911 Active CN101690481B (zh) | 2009-07-07 | 2009-07-07 | 螺螨酯多重乳状液及其制备方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN101690481B (zh) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101606521B (zh) * | 2009-07-20 | 2012-12-05 | 深圳诺普信农化股份有限公司 | 一种增效杀螨剂 |
CN102524246A (zh) * | 2010-12-08 | 2012-07-04 | 福建诺德生物科技有限责任公司 | 一种农用组合溶剂及其应用 |
CN103442574B (zh) * | 2011-01-28 | 2015-11-25 | 迪帕克·普兰吉万达斯·沙阿 | 包括硫、杀虫剂和农业化学赋形剂的杀虫剂组合物 |
CN109392922A (zh) * | 2018-12-11 | 2019-03-01 | 深圳诺普信农化股份有限公司 | 一种含有乙螨唑的增效杀螨组合物 |
CN112341998A (zh) * | 2020-11-16 | 2021-02-09 | 成都理工大学 | 一种堵漏材料及其制备方法 |
CN113558051A (zh) * | 2021-08-30 | 2021-10-29 | 广东中迅农科股份有限公司 | 杀螨组合物 |
CN114451408A (zh) * | 2022-01-17 | 2022-05-10 | 江苏凯元科技有限公司 | 一种适用于多种农药水乳剂的乳化剂及其制备方法 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2002089573A1 (en) * | 2001-05-04 | 2002-11-14 | Bayer Cropscience Gmbh | Pesticide oil-in-water-in-oil emulsion |
CN1449862A (zh) * | 2002-03-14 | 2003-10-22 | 瓦克化学有限公司 | 多重乳状液 |
WO2006020233A1 (en) * | 2004-07-29 | 2006-02-23 | Dow Corning Corporation | Silicone emulsions and their preparation |
CN101297646A (zh) * | 2008-06-30 | 2008-11-05 | 陕西上格之路生物科学有限公司 | 一种含螺螨酯的杀螨剂组合物 |
-
2009
- 2009-07-07 CN CN 200910040911 patent/CN101690481B/zh active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2002089573A1 (en) * | 2001-05-04 | 2002-11-14 | Bayer Cropscience Gmbh | Pesticide oil-in-water-in-oil emulsion |
CN1449862A (zh) * | 2002-03-14 | 2003-10-22 | 瓦克化学有限公司 | 多重乳状液 |
WO2006020233A1 (en) * | 2004-07-29 | 2006-02-23 | Dow Corning Corporation | Silicone emulsions and their preparation |
CN101297646A (zh) * | 2008-06-30 | 2008-11-05 | 陕西上格之路生物科学有限公司 | 一种含螺螨酯的杀螨剂组合物 |
Also Published As
Publication number | Publication date |
---|---|
CN101690481A (zh) | 2010-04-07 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN101690481B (zh) | 螺螨酯多重乳状液及其制备方法 | |
CN101606517B (zh) | 一种农药乳油制剂 | |
CN102655740A (zh) | 绿色消毒/杀菌合成物及其制备过程 | |
WO2019047004A1 (zh) | 一种天然替代的植物精油防腐剂及在化妆品中的应用 | |
CN104823969A (zh) | 脂肪酸甲酯作为环保溶剂在农药制剂中的开发应用 | |
CN101642114A (zh) | 一种含螺螨酯的悬浮剂及其制备方法 | |
CN104920443A (zh) | 一种环境友好型高效氯氰菊酯水乳剂及其制备方法 | |
CN102132698A (zh) | 一种农药用绿色溶剂及其应用 | |
JP2018517682A (ja) | カプセル化された揮発性化合物の安定なエマルジョン配合物 | |
CN110338197A (zh) | 一种植物型杀菌除螨素及制备方法 | |
CN1033419C (zh) | 有机磷农药水乳剂 | |
CN102475092A (zh) | 含毒死蜱和螺虫乙酯的复配杀虫悬乳剂及制备方法 | |
CN104663701B (zh) | 一种呋虫胺增效悬浮剂及其制备方法 | |
JP2011153118A (ja) | 水性エマルション型除草剤組成物 | |
CN101690475A (zh) | 虱螨脲多重乳状液及其制备方法 | |
CN105145619A (zh) | 一种拟除虫菊酯类农药水乳剂及其制备方法 | |
Fowsiya et al. | Promising insecticidal effect of Carissa edulis phytochemical loaded nanoemulsion using Ag2O and ZnO NPs: A synergistic combination by ultra-sonication against crop damaging insects | |
CN101606540A (zh) | 高效氯氟氰菊酯农药水乳剂及其制备方法 | |
CN105746501B (zh) | 桉叶油助剂及其制备方法与面料后整理工作液 | |
CN114145315A (zh) | 一种除虫菊提取物水乳剂及其制备方法 | |
CN101946794A (zh) | 一种氯氰菊酯水乳剂及其制备方法 | |
CN1306874C (zh) | 一种用于防治蔬菜苗期病害的种子处理剂 | |
CN109042635B (zh) | 倍硫磷水乳剂及其制备方法与应用 | |
CN113667703A (zh) | 一种酱油渣甘油酯、农用植物油乳剂及其制备方法和应用 | |
CN109303046A (zh) | 一种可分散油悬浮助剂及其制备方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Spirodiclofen multiple emulsion and its preparation method Effective date of registration: 20201231 Granted publication date: 20130911 Pledgee: Shenzhen hi tech investment small loan Co.,Ltd. Pledgor: Shenzhen Noposion Agrochemicals Co.,Ltd. Registration number: Y2020980010471 |
|
PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
CP03 | Change of name, title or address |
Address after: 518102 No. 113 Reservoir Road, Baoan District, Guangdong, Shenzhen, Xixiang Patentee after: Shenzhen Novozon Crop Science Co.,Ltd. Country or region after: China Address before: 518102 No. 113 Reservoir Road, Baoan District, Guangdong, Shenzhen, Xixiang Patentee before: SHENZHEN NOPOSION AGROCHEMICALS Co.,Ltd. Country or region before: China |
|
CP03 | Change of name, title or address | ||
PC01 | Cancellation of the registration of the contract for pledge of patent right |
Granted publication date: 20130911 Pledgee: Shenzhen hi tech investment small loan Co.,Ltd. Pledgor: SHENZHEN NOPOSION AGROCHEMICALS Co.,Ltd. Registration number: Y2020980010471 |
|
PC01 | Cancellation of the registration of the contract for pledge of patent right |