CN101633858B - Biodiesel complexing agent - Google Patents
Biodiesel complexing agent Download PDFInfo
- Publication number
- CN101633858B CN101633858B CN200910072738A CN200910072738A CN101633858B CN 101633858 B CN101633858 B CN 101633858B CN 200910072738 A CN200910072738 A CN 200910072738A CN 200910072738 A CN200910072738 A CN 200910072738A CN 101633858 B CN101633858 B CN 101633858B
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- CN
- China
- Prior art keywords
- biodiesel
- complexing agent
- diesel
- diesel oil
- composite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/10—Biofuels, e.g. bio-diesel
Abstract
The invention aims at providing a biodiesel complexing agent which has the advantages of easily available raw materials, low cost, simple process, convenient use, safe and reliable performance and good finished product quality, has a physicochemical index meeting the GB252-94 standard, exteriorly appears the same as standard diesel, works stably, discharges a small amount of waste gas, improves the combustion environment, can improve the power and reduce the dust content of residual carbon, can be mutually thawed the diesel without being mixed with the diesel, does not undergo demulsification in water, is adapted to a temperature ranging from -40 DEG C to 90 DEG C, performs stably in a freezing-thawing test, is free from dehydration and has high heat value.
Description
(1) technical field
The present invention is through several kinds of organic and lithotrophs and chemical feedstocks allotment synthetic biodiesel complexing agents, is specifically related to a kind of recombiner that is used for diesel oil and hydration reason are melted mutually the composite biodiesel that formation conforms to the diesel fuel characteristics index.
(2) background technology
Reducing energy dissipation and listed China's planning outline in the reduction exhaust gas emission, is not only China, and energy-saving and emission-reduction also are the problems that the people of the world need face.Petroleum resources limited; Each field tail gas such as communications and transportation, industrial and agricultural production, exhaust gas discharging make scientific workers constantly seek the environmental protection new way; Adding through various recombiners makes water resources instead of part petroleum resources, thereby reduces using and the generation of waste gas afterwards of burning of petroleum resources.Current, that composite biodiesel that the recombiner that exists on the market makes in application process exists is poor with the diesel oil mutual solubility, extended storage stability is bad, outward appearance and diesel oil have than big-difference, the back putty of burning and divides that carbon residue is big, oxidation rate is fast, calorific value is not enough, mixes afterwards degradation problem under the power with diesel oil.
(3) summary of the invention
The object of the present invention is to provide a kind of raw material to be easy to get; With low cost; Technology is simple, esy to use, safe and reliable; The composite biodiesel of processing is best in quality, physical and chemical index reaches the GB252-2000 standard, outward appearance and standard diesel oil is just the same, good stability, discharge amount of exhaust gas are few, improve burning situation, can improve power, reduce the carbon residue ash content, can dissolve each other with diesel oil, entry not breakdown of emulsion, spend to low temperature 40 degrees below zero, freezing and thawing test stable performance at high temperature above freezing 90, do not dewater, the biodiesel complexing agent of calorific value advantages of higher.
The objective of the invention is to realize like this: biodiesel complexing agent is to be that the ammoniacal liquor of 23% ~ 24% oleic acid, 4 ~ 6% Yelkin TTS, 2 ~ 3% isopropylcarbinol, 4 ~ 6% naphthenic acid and 4 ~ 6% stirs at the common response still and combines, cools to the 30-40 degree mutually together with massfraction; Add 1 ~ 2% thanomin, 2 ~ 3% propyl carbinol, 1 ~ 3% hydrogen peroxide, 0.04 ~ 0.06% borine, 2 ~ 3% methyl alcohol while stirring, add 45% ~ 55% at last and add water and stir and to process in 30 minutes.
The present invention also has some technical characterictics like this:
1, described biodiesel complexing agent and No. 0 diesel oil stir in high-speed shearing machine with 2: 3 ratio and are prepared into composite biodiesel.
The composite biodiesel Cheng Weihuang that the present invention and diesel oil generate is transparent, can be used for application such as oil motor, kiln, boats and ships, industrial burner.
The present invention has substituted part diesel oil with water and diesel oil and has acted as a fuel, and part greatly reduces the exhaust gas discharging amount with hydrogenate and oxide compound appearance in its products of combustion.
The Coulomb repulsion principle of utilizing of the present invention has solved composite biodiesel and the bad problem of diesel oil mutual solubility; Use the present invention and make composite biodiesel interior molecules surface tension reach unanimity, solved the problem of its extended storage stability difference; The present invention comprises water molecules with oil molecule after diesel oil and water are mixed, and makes molecule reach the 1-5 micron, forms hyalosome, from but the outward appearance of composite biodiesel conform to the diesel oil outward appearance; The present invention has added high active combustion agent---and hydrogen peroxide reduces composite biodiesel burning back putty branch and carbon residue amount greatly, and has solved the fast problem of diesel oil oxidation speed; The present invention utilizes the microexplosion principle to solve the composite biodiesel that generates mixes back power decline with diesel oil problem.
(4) description of drawings
Fig. 1 is the section structure photo of gained composite nano-powder after the thermal treatment in the embodiment 17.
(5) embodiment
Embodiment 1
Biodiesel complexing agent is to be that the ammoniacal liquor of 23.5% oleic acid, 5% Yelkin TTS, 2.95% isopropylcarbinol, 5% naphthenic acid and 5% stirs at the common response still and combines, cools to the 30-40 degree mutually together with massfraction; Add 1.5% thanomin, 2.5% propyl carbinol, 2% hydrogen peroxide, 0.05% borine, 2.5% methyl alcohol while stirring, add 50% at last and add water and stir and to process in 30 minutes.
Embodiment 2
Combine, cool to the oleic acid of 47kg, the Yelkin TTS of 10kg, the isopropylcarbinol of 5kg, the naphthenic acid of 10kg and the ammoniacal liquor of 10kg together the 30-40 degree mutually in the stirring of common response still; Add the thanomin of 3kg, the propyl carbinol of 5kg, the hydrogen peroxide of 4kg, the borine of 0.5kg, the methyl alcohol of 5.5kg while stirring, the water that adds 100kg at last stirs to be processed in 30 minutes.
Main performance index:
GB0# diesel oil detects contrast with composite biodiesel
| Sequence number | The test item title | 0# diesel oil | Composite biodiesel |
| 1 | Colourity number is not more than | 3.5 | 4.0 |
| 2 | Oxidation stability, total insoluble substance mg/100ml is not more than | 2.5 | 1.3 |
| 3 | Sulphur content, % (m/m) is not more than | 0.2 | 0.1 |
| 4 | Acid number, mgKOH/g | Actual measurement | 18.9 |
| 5 | 10% steams excess carbon residue, and % (m/m) is not more than | 0.3 | 0.1 |
| 6 | Ash content, % (m/m) is not more than | 0.01 | 0.01 |
| 7 | (50 degree, 3h), level is not more than in copper corrosion | 1 | 1 |
| 8 | Mechanical impurity | Do not have | Do not have |
| 9 | Condensation point ℃ is not higher than | 0 | -12 |
| 10 | Cold filter clogging temperature ℃ is not higher than | 4 | 4 |
| 11 | Flash-point (remaining silent) ℃ is not less than | 55 | 53 |
| 12 | Cetane value is not less than | 45 | 44 |
| 13 | Boiling range: 50% recovered temperature, ℃ be not higher than 90% recovered temperature, ℃ be not higher than 95% recovered temperature, ℃ be not higher than | ?300 355 365 | ?296 347 356 |
| 14 | Density (20 ℃), kg/m 3 | Actual measurement | 876.0 |
Conclusion: composite biodiesel each item performance index conform to close with GB0# diesel oil, even some index is superior to BG252-2000, prove to produce, use in the practical experience of life.
Claims (2)
1. biodiesel complexing agent; It is characterized in that: it is to be that the ammoniacal liquor of 23%～24% oleic acid, 4～6% Yelkin TTS, 2～3% isopropylcarbinol, 4～6% naphthenic acid and 4～6% stirs at the common response still and combines together mutually with massfraction; Cool to the 30-40 degree; Add 1～2% thanomin, 2～3% propyl carbinol, 1～3% hydrogen peroxide, 0.4～0.6% borine and 2～3% methyl alcohol while stirring, add 45～55% water at last and stir and processed in 30 minutes.
2. composite biodiesel that uses biodiesel complexing agent as claimed in claim 1 to make is characterized in that: described biodiesel complexing agent and No. 0 diesel oil are stirred in high-speed shearing machine with 2: 3 ratio is prepared into composite biodiesel.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200910072738A CN101633858B (en) | 2009-08-26 | 2009-08-26 | Biodiesel complexing agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200910072738A CN101633858B (en) | 2009-08-26 | 2009-08-26 | Biodiesel complexing agent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101633858A CN101633858A (en) | 2010-01-27 |
| CN101633858B true CN101633858B (en) | 2012-09-05 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200910072738A Expired - Fee Related CN101633858B (en) | 2009-08-26 | 2009-08-26 | Biodiesel complexing agent |
Country Status (1)
| Country | Link |
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| CN (1) | CN101633858B (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103911193B (en) * | 2013-01-09 | 2016-01-20 | 美国能源有限公司 | Additive of a kind of biofuel of polynary formula combination and preparation method thereof |
| CN104232178A (en) * | 2014-10-17 | 2014-12-24 | 广西丰泰能源防爆科技有限公司 | Vehicle biofuel |
| CN105670719A (en) * | 2016-03-10 | 2016-06-15 | 安徽辉源机电有限公司 | High-quality low-residual-carbon biomass diesel composite additive and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101067099A (en) * | 2007-06-27 | 2007-11-07 | 丽水市星光燃油有限公司 | Combustion catalyzing additive for biodiesel oil and its prepn |
| CN101210204A (en) * | 2006-12-28 | 2008-07-02 | 山西华顿实业有限公司 | Additive and its vehicular methanol diesel oil and preparing method |
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2009
- 2009-08-26 CN CN200910072738A patent/CN101633858B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101210204A (en) * | 2006-12-28 | 2008-07-02 | 山西华顿实业有限公司 | Additive and its vehicular methanol diesel oil and preparing method |
| CN101067099A (en) * | 2007-06-27 | 2007-11-07 | 丽水市星光燃油有限公司 | Combustion catalyzing additive for biodiesel oil and its prepn |
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| Publication number | Publication date |
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| CN101633858A (en) | 2010-01-27 |
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Granted publication date: 20120905 Termination date: 20130826 |