CN101624241B - Detergent component and manufacturing method thereof - Google Patents
Detergent component and manufacturing method thereof Download PDFInfo
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- CN101624241B CN101624241B CN 200810130752 CN200810130752A CN101624241B CN 101624241 B CN101624241 B CN 101624241B CN 200810130752 CN200810130752 CN 200810130752 CN 200810130752 A CN200810130752 A CN 200810130752A CN 101624241 B CN101624241 B CN 101624241B
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Abstract
The invention discloses a detergent component and a manufacturing method thereof, which belong to the field of daily chemical industry. The method comprises the following steps of: subjecting overdue or rotten beer waste liquid serving as a principle preprocessing part to filteration, degerming, pH value adjustment and the like, and mixing the product obtained by the steps with a natural surfactant, and thus obtaining the detergent for human bodies or households. The detergent component and the manufacturing method thereof can solve the environment protection problem caused by the overdue or rotten beer waste liquid, make the overdue or rotten beer waste liquid into the detergent without adding a substance refined from oil and form a safe and harmless natural detergent.
Description
Technical field
The present invention relates to a kind of cleaning agent component and manufacture method thereof, relate in particular to a kind of by beer waste liquid expired or that addle is transformed into harmless liquid, after this harmless liquid mixes some nature surface-active agents, produce the antibacterial cleanser that can be used in human body or house usefulness, belong to filed of daily-use chemical industry.
Background technology
Beer is take Fructus Hordei Germinatus and water as raw material, and hops is that spices is through germination saccharification, the made low ethanol content fumet wine of a kind of ethanol content between the 2-5 degree of fermenting procedure.Because process by fermentation; can't do germicidal treatment with high temperature again; therefore the storage life is generally not long; expired problem is easily arranged; and beer belongs to seasonal commodity; when heat, be in great demand and sell fast; but achievement turns light during very cold; keep certain production capacity and the production line of Brewery is essential on manpower and mechanical advantage, but be limited to the dull and rush season of sale, also cause rolling up of expired beer; and when in a single day shutting down or cleaning; with remaining lot of beer waste liquid, derive the environmental issue of subsequent disposal between bucket groove and pipeline, have to be solved.
And the expired or beer waste liquid that addles is easily because of the effect of mould, cause Secondary Fermentation and produce the problem of acidifying and qualitative change, and through pre-treatment, comprise degerming, action and the programs such as filtration and pH regulator, beer expired or that addle is processed into the body material that is fit to as the person or house sanitising agent, and its contained alcohol (ethanol) is a kind of broad-spectrum solvent, can be with negatively charged ion and the isolated dirt stripping of non-ionic surfactant via natural coconut oil system, therefore reaching the purpose of cleaning, is a kind of technology of both having known and being widely used with ethanol as the constituent of sanitising agent.
From the hops that the beer dregs of rice extract, can bring into play the function of Antibacterial activity again.Hops (HumuluslupulusL.) is called again hops or hop, belongs to Cannabaceae, is a kind of climing rattan property plant, has the function of Antibacterial activity, and is all on the books in many scientific literatures.
Summary of the invention
One of the object of the invention is effectively to process the regeneration of expired or the beer waste liquid that addles, manpower when reducing the lot of beer liquid waste disposal and material resources expenditure and derivative environmental issue, a kind of regeneration method with expired or the beer waste liquid that addles is provided, can be used as human body or at home with the main ingredient of antibacterial cleanser by the resulting product of the method.
Two of the object of the invention provides a kind of sanitising agent that is applicable to human body or house usefulness, and this sanitising agent obtains by adding a certain amount of nature surface-active agent take the resulting product of the regeneration expired or beer waste liquid that addles as the chief component composition.
Above-mentioned purpose of the present invention is achieved through the following technical solutions:
The method of the expired or beer waste liquid that addles of a kind of regeneration may further comprise the steps: (1) is the expired or beer waste liquid that addles of the strainer filtering of 1 μ m～10 μ m with mesh; (2) adding of the filtrate after filtration degerming agent carries out degerming; (3) the pH value is adjusted into 4.5～8.5, and get final product.
In the aforesaid method, described degerming agent is bronopol (Bronopol) (Bronopol preferably, chemical name: 2-bromo-2-nitro-1, bronopol), iodo propinyl carboxylamine fourth (IodopropynylButylcarbamate) and the different plug azoles of methyl chloride quinoline Tong ﹠amp ammediol is called for short:; The different plug azoles of methyl quinoline ketone (Methylchloroisothiazolinone﹠amp; Methylisothiazolinone) (sanitas); By weight percentage, their amounts of adding per-cent of accounting for total amount is respectively 0.5%～1.0%, 0.3%～0.6% and 0.1%～0.3%.
The resulting product of above-mentioned regeneration method and a certain proportion of nature surface-active agent are mixed, can obtain a kind of sanitising agent that human body and household are used that is applicable to.
A kind of preferred technical scheme:
A kind ofly be applicable to the sanitising agent that human body and household are used, formed by each component of following weight percent:
15wt%～20wt% natural coconut oil series anion interfacial agent, 2wt%～5wt% natural coconut oil is non-ionic surfactant (), 1wt%～3wt% pearling agent (Polyoxyethylene Glyceryllsostearate; Polyoxyethylene Glyceryl Monstearate), 0.5wt%～1.5wt% silicon power health oil (Polyoxyethylene Methylpolysiloxane Copolymer; AminopropylDimethicone; Dimethicone Copolyol), surplus is according to the resulting product of above-mentioned regeneration method.
Described natural coconut oil series anion interfacial agent can be selected from linear alkyl benzene sulphonic acid (Linear alkyl benzene sulfonic acid) or Textone (Sodium chlorite);
Described natural coconut oil is that non-ionic surfactant can be Voranol EP 2001 (Polyoxyethylene alkyl ether);
The preferred selfpolyoxyethylene iso stearic acid of glycerine ester of described pearling agent (PolyoxyethyleneGlyceryl lsostearate) or polyoxyethylene Zerol (PolyoxyethyleneGlyceryl Monostearate);
Described silicon power health grease separation selfpolyoxyethylene methyl polysilicon alkyl copolymer (PolyoxyethyleneMethylpolysiloxane Copolymer), aminopropyl dimethyl siloxane (AminopropylDimethicone) or dimethicone copolyol (Dimethicone Copolyol);
The above-mentioned raw materials of using among the present invention all can be bought from common chemical industry shop and obtain.
A kind of method for preparing above-mentioned sanitising agent may further comprise the steps: (1) will stir in vat according to the resulting product of above-mentioned regeneration method; (2) adding natural coconut oil series anion interfacial agent, natural coconut oil are non-ionic surfactant, pearling agent and silicon power health oil, stir; (3) carry out neutralization reaction (lipid acid or ten DAADBSA and sodium hydroxide carry out neutralization reaction); (4) adjust the pH value to 6-8; (5) adjust glutinous valency (utilizing the viscosity of liquid in the NaCl adjustment tank); (6) weight balancing (utilize pure water to make weight balancing, make the weight of each groove all reach at last homogeneous); (7) filter; And get final product.
Another kind of preferred technical scheme:
A kind ofly be applicable to the sanitising agent that human body and household are used, formed by each component of following weight percent:
15wt%～20wt% natural coconut oil series anion interfacial agent, 2wt%～5wt% natural coconut oil is non-ionic surfactant, 0.1wt%～1wt%pH adjusting agent, the natural ionogen of 0.1wt%～1wt%, surplus is according to the resulting product of above-mentioned regeneration method.
A kind of method for preparing above-mentioned sanitising agent may further comprise the steps: (1) will stir in vat according to the resulting product of above-mentioned regeneration method; (2) adding natural coconut oil series anion interfacial agent, natural coconut oil are non-ionic surfactant, pH adjusting agent and natural ionogen, stir; (3) carry out neutralization reaction; (4) adjust the pH value; (5) adjust glutinous valency; (6) weight balancing; (7) filter; And get final product.
Wherein, described pH adjusting agent can be sodium hydroxide etc.; Described natural ionogen can be NaCl etc.
The present invention utilizes the contained constituent of beer itself, through the natural hops of beer dregs of rice extraction and negatively charged ion and the non-ionic surfactant of natural coconut oil system, add the beer waste liquid after making again, so that transformation of ownership gained sanitising agent, not only cost is low than prior art, and the manpower can reduce in a large number beer waste liquid and process the time and material resources expenditure and the environmental issue that derives.
The present invention utilizes the cleaning function that alcoholic content has in the beer, and the natural bacteriostatic effect that the hops that extracts has in the alcoholic process byproduct beer dregs of rice, create a kind of natural and have a sanitising agent combination of cleaning antibiotic effect, and utilize multiple amino acids contained in the beer and VITAMIN to provide skin essential nutrient, reach the effectiveness of not hindering skin and nourishes rough skin can be provided, give the new purposes of expired and the beer waste liquid that addles.
Antibacterial cleanser constituent of the present invention resulting product after to process through filtration, degerming, pH regulator, adds other raw material according to purposes again and consists of through mixing suitable natural coconut oil series anion and non-ionic surfactant as main body.See through filter action and remove impurity in the expired beer waste liquid that addles, seeing through the degerming action is suppressed the mushroom in the beer waste liquid, see through pH regulator and improve acidifying situation in the beer waste liquid, make the former unserviceable expired beer waste liquid that addles reach reusable purpose.Add the just effectively degerming of antiseptic-germicide that contains three kinds of compositions.The antiseptic-germicide composition is preferably and contains bronopol (Bronopol) (Bronopol, chemical name: 2-bromo-2-nitro-1, bronopol), iodo propinyl carboxylamine fourth (IodopropynylButylcarbamate) and the different plug azoles of methyl chloride quinoline Tong ﹠amp ammediol is called for short:; The different plug azoles of methyl quinoline ketone (Methylchloroisothiazolinone﹠amp; Methylisothiazolinone) (sanitas).Moreover pH regulator need be adjusted between 4.5～8.5, can improve acidifying situation in the beer waste liquid.
Another characteristics of the present invention, be to utilize the liquid that obtains after the above-mentioned manipulation of regeneration, formed sanitising agent after processing (person is used or used at home), utilize the originally natural ethanol arrival of institute's tool of beer to have the effect of cleaning, need not add under other industrial alcohol, just can effectively reach the purpose of cleaning, and residual without toxic substance.Use can't cause toxic substance residual by the sanitising agent of the beer waste liquid transformation of ownership after using.
Again characteristics of the present invention, being has bacteria resistance function through the hops in constituent-beer dregs of rice extraction liquid-its cording, not only can reach cleaning effect, and the simultaneously breeding of anti-bacteria.
Another characteristics of the present invention, except processing the expired beer waste liquid that addles, and can be as a corresponding method of beer production line production capacity adjusting.
Contained natural coconut oil is interfacial agent in the present invention's combination, belong to natural matter system, non-petroleum manually refines material, have better solubleness, foaminess, can tolerate larger temperature range and polyelectrolyte concentration, extremely gentle to skin, Biodegradable is good, and nontoxicity provides cleaning and the function of separate dirt in this composition.And beer itself also contains multiple amino acids and VITAMIN, can provide simultaneously user's skin essential nutrient, reaches the effect of maintenance user skin.
Description of drawings
Fig. 1 is schema of the present invention.
Description of reference numerals: 10: the expired and beer waste liquid that addles; 20: pre-treatment; 21: filter; 22: degerming; 23:pH adjusts; 30: enter vat (stirring); 40: nature surface-active agent (stirring); 50: neutralization reaction (stirring); 60: adjust the pH value; 70: adjust glutinous valency; 80: weight balancing; 90: refilter; A transfers; The B packing.
Embodiment
Further describe the present invention below in conjunction with specific embodiment, advantage and disadvantage of the present invention will be more clear along with description.But these embodiment only are exemplary, scope of the present invention are not consisted of any restriction.It will be understood by those skilled in the art that lower without departing from the spirit and scope of the present invention and can make amendment or replace the details of technical solution of the present invention and form, but these modifications and replacing all fall within the scope of protection of the present invention.
As shown in Figure 1, be embodiments of the present invention, at first beer waste liquid 10 expired or that addle transformed into the treatment technology that is used in the person or uses at home antibacterial cleanser.Processing 20 technological steps before when making sanitising agent is: filtration 21, degerming 22, pH adjust 23, wherein filtering 21 o'clock, the mesh that this impurity screening is used needs between 1 μ m～10 μ m, and, the consisting of of the degerming employed antiseptic-germicide of 22 processes: bronopol (Bronopol); Iodo propinyl carboxylamine fourth (IodopropynylButylcarbamate); Mixing solutions (the Methylchloroisothiazolinone﹠amp that is formed by the different plug azoles of methyl chloride quinoline ketone and the different plug azoles of methyl quinoline ketone; Methylisothiazolinone); At last with pH regulator between 4.5～8.5, can improve acidifying situation in the beer waste liquid, so just finish expired and addle and process 20 processes before the beer waste liquid.
Above-mentioned expired and addle beer waste liquid after removing impurity through pre-treatment 20, entering vat 30 stirs again, the natural coconut oil series anion that remix is suitable and non-ionic surfactant (stirring) 40, wherein, the one-tenth of this nature surface-active agent is grouped into the teepol of the natural coconut oil system that comprises at least 15～25wt%, the non-ionic surfactant of the natural coconut oil system of 2～8wt%, the silicon power health oil of the pearling agent of 1～5wt% and 0.5～3wt%, with the beer waste liquid that above-mentioned composition adds up to the treated expired of 100wt% and addles, its characteristics are to include in this beer waste liquid the natural hops of 1～5wt% beer dregs of rice extraction; So, after process neutralization reaction 50, adjustment pH value 60, adjustment stick valency 70, weight balancing 80, refilter 90, transfer A and pack the step of B again, be sanitising agent of the present invention, be particularly useful for personal use.
In addition, the present invention also can be used as the at home sanitising agent of usefulness, it is to utilize as above-mentionedly utilize identical pre-treatment 20 steps, stir the natural interface promoting agent of 30 rear addings and stir 40 entering vat, wherein, it is 15～25wt% that the composition of this natural interface promoting agent comprises natural coconut oil series anion interfacial agent at least, natural coconut oil is that non-ionic surfactant is the beer waste liquid of the treated mistake of 2～8wt% and 70～80wt%, other raw material adds up to proportion at 0.2～8wt%, afterwards, through identical neutralization reaction (stirring) 50, adjust pH value 60, adjust glutinous valency 70, weight balancing 80, refilter 90, transfer A and the step of packing B, namely finish being applicable to sanitising agent at home.
Through principal feature of the present invention as shown in the above description, be to see through filtration 21 actions, remove the impurity in the expired beer waste liquid that addles, see through degerming 22 actions, mushroom in the beer waste liquid is suppressed, adjust 23 through pH and improve acidifying situation in the beer waste liquid, make the former expired beer waste liquid that addles that can't bear to use reach the purpose of the recycling sanitising agent of making (person or house).
And, by the natural ethanol that has in the beer waste liquid and the cleaning efficacy of bringing into play thereof, need not add under other industrial alcohol, just can effectively reach the purpose of cleaning, and residual without toxic substance, and see through the natural bacteriostatic function of the hops in the constituent beer dregs of rice extraction liquid, and after reaching cleaning effect, breeding that can also anti-bacteria.
Claims (6)
1. method of processing expired or the beer waste liquid that addles may further comprise the steps: (1) is the expired or beer waste liquid that addles of the strainer filtering of 1 μ m～10 μ m with mesh; (2) adding of the filtrate after filtration degerming agent carries out degerming; (3) the pH value is adjusted into 4.5～8.5;
Described degerming agent is the mixture of bronopol, iodo propinyl carboxylamine fourth, the different plug azoles of the different plug azoles of methyl chloride quinoline ketone/methyl quinoline ketone; By weight percentage, their amounts of adding per-cent of accounting for total amount is respectively 0.5%～1.0%, 0.3%～0.6% and 0.1%～0.3%.
2. the product that is prepared by method claimed in claim 1.
3. a sanitising agent is characterized in that, is comprised of each component of following weight percent:
15wt%～20wt% natural coconut oil series anion interfacial agent, 2wt%～5wt% natural coconut oil is non-ionic surfactant, 1wt%～3wt% pearling agent, 0.5wt%～1.5wt% silicon power health oil, surplus is product claimed in claim 2;
Described natural coconut oil series anion interfacial agent is linear alkyl benzene sulphonic acid or Textone; Described natural coconut oil is that non-ionic surfactant is Voranol EP 2001; Described pearling agent is selected from polyoxyethylene iso stearic acid of glycerine ester or polyoxyethylene Zerol; Described silicon power health grease separation selfpolyoxyethylene methyl polysilicon alkyl copolymer, aminopropyl dimethyl siloxane or dimethicone copolyol.
4. method for preparing sanitising agent claimed in claim 3, may further comprise the steps: stir product claimed in claim 2 (1) in vat; (2) adding natural coconut oil series anion interfacial agent, natural coconut oil are non-ionic surfactant, pearling agent and silicon power health oil, stir; (3)
Carry out neutralization reaction; (4) adjust the pH value to 6-8; (5) adjust glutinous valency; (6) weight balancing; (7) refilter;
Described natural coconut oil series anion interfacial agent is linear alkyl benzene sulphonic acid or Textone; Described natural coconut oil is that non-ionic surfactant is Voranol EP 2001; Described pearling agent is selected from polyoxyethylene iso stearic acid of glycerine ester or polyoxyethylene Zerol; Described silicon power health grease separation selfpolyoxyethylene methyl polysilicon alkyl copolymer, aminopropyl dimethyl siloxane or dimethicone copolyol.
5. a sanitising agent is characterized in that, is comprised of each component of following weight percent:
15wt%～20wt% natural coconut oil series anion interfacial agent, 2wt%～5wt% natural coconut oil is non-ionic surfactant, 0.1wt%～1wt%pH adjusting agent, the natural ionogen of 0.1wt%～1wt%, surplus is product claimed in claim 2;
Described natural coconut oil series anion interfacial agent is linear alkyl benzene sulphonic acid or Textone; Described natural coconut oil is that non-ionic surfactant is Voranol EP 2001; Described pH adjusting agent is sodium hydroxide; Described natural ionogen is NaCl.
6. method for preparing sanitising agent claimed in claim 5, may further comprise the steps: stir product claimed in claim 2 (1) in vat; (2) adding natural coconut oil series anion interfacial agent, natural coconut oil are non-ionic surfactant, pH adjusting agent and natural ionogen, stir; (3) carry out neutralization reaction; (4) adjust the pH value to 6-8; (5) adjust glutinous valency; (6) weight balancing; (7) refilter;
Described natural coconut oil series anion interfacial agent is linear alkyl benzene sulphonic acid or Textone; Described natural coconut oil is that non-ionic surfactant is Voranol EP 2001; Described pH adjusting agent is sodium hydroxide; Described natural ionogen is NaCl.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200810130752 CN101624241B (en) | 2008-07-10 | 2008-07-10 | Detergent component and manufacturing method thereof |
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| CN 200810130752 CN101624241B (en) | 2008-07-10 | 2008-07-10 | Detergent component and manufacturing method thereof |
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| CN101624241A CN101624241A (en) | 2010-01-13 |
| CN101624241B true CN101624241B (en) | 2013-02-13 |
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| CN 200810130752 Expired - Fee Related CN101624241B (en) | 2008-07-10 | 2008-07-10 | Detergent component and manufacturing method thereof |
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Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102894001A (en) * | 2012-10-19 | 2013-01-30 | 陕西省石油化工研究设计院 | Antiseptic and mildew inhibitor composition for wet tissues and production method thereof |
| CN116621263B (en) * | 2022-08-19 | 2024-01-05 | 广东浪淘砂新型材料有限公司 | Defoaming agent for mixing station car washing wastewater, and preparation method and application thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB782081A (en) * | 1955-05-31 | 1957-08-28 | Lincoln Hair Products Ltd | Improvements in shampooing preparations for the hair |
| US4808330A (en) * | 1988-04-26 | 1989-02-28 | Chung C S | Non-toxic detergent for cleaning fruit and vegetables |
| CN2055062U (en) * | 1989-07-11 | 1990-03-28 | 陕西省微生物研究所 | Purification device for filtering bacterial |
| CN1670154A (en) * | 2005-04-16 | 2005-09-21 | 王浩贵 | Wild chrysanthemum flower cleaning products |
| TWI278512B (en) * | 2005-08-30 | 2007-04-11 | Taiwan Tobacco & Liquor Corp | Antiseptic detergent composition with grain fermentation solution as main body |
-
2008
- 2008-07-10 CN CN 200810130752 patent/CN101624241B/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB782081A (en) * | 1955-05-31 | 1957-08-28 | Lincoln Hair Products Ltd | Improvements in shampooing preparations for the hair |
| US4808330A (en) * | 1988-04-26 | 1989-02-28 | Chung C S | Non-toxic detergent for cleaning fruit and vegetables |
| CN2055062U (en) * | 1989-07-11 | 1990-03-28 | 陕西省微生物研究所 | Purification device for filtering bacterial |
| CN1670154A (en) * | 2005-04-16 | 2005-09-21 | 王浩贵 | Wild chrysanthemum flower cleaning products |
| TWI278512B (en) * | 2005-08-30 | 2007-04-11 | Taiwan Tobacco & Liquor Corp | Antiseptic detergent composition with grain fermentation solution as main body |
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| CN101624241A (en) | 2010-01-13 |
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Effective date of registration: 20170726 Address after: Chenghai District of Guangdong city in Shantou Province, under the town of Lian Jianyang Daping Industrial Zone factory building first in Hancock Patentee after: Shantou city of new Mstar Technology Ltd Address before: Taiwan County, Taipei, China Patentee before: Wu Cailian |
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Granted publication date: 20130213 Termination date: 20190710 |