CN101611876B - Carotenoid emulsion and carotenoid chewing gum added with emulsion - Google Patents
Carotenoid emulsion and carotenoid chewing gum added with emulsion Download PDFInfo
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- CN101611876B CN101611876B CN2009101594966A CN200910159496A CN101611876B CN 101611876 B CN101611876 B CN 101611876B CN 2009101594966 A CN2009101594966 A CN 2009101594966A CN 200910159496 A CN200910159496 A CN 200910159496A CN 101611876 B CN101611876 B CN 101611876B
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Abstract
The invention relates to carotenoid emulsion and carotenoid chewing gum added with the carotenoid emulsion. The carotenoid emulsion is prepared by adopting the following method: 1) mixing 1 to 99 percent carotenoid powder and soybean phospholipids according to a weight ratio of 1:1.0-1.5, putting the mixture into a colloid grinder, and grinding the mixture into emulsion particle solution; 2) adding the emulsion particle solution into vegetable oil according to a weight ratio of 1:0.5-1.5, and soaking the emulsion particle solution into the vegetable oil for 100 to 300 minutes so as to be embedded by the vegetable oil; and 3) crushing the embedding liquid into micro-particle emulsion in which the particle diameter of carotenoid is 5 to 10mu m in a super-micro crusher. The carotenoid chewing gum is prepared by the steps of adding the emulsion into chewing gums, sterilizing, softening, kneading and stirring, cutting, tabletting and shaping, enveloping and the like. The carotenoid emulsion and the chewing gum added with the emulsion have the advantages of high carotenoid content, good stability and high human body absorption rate.
Description
Technical field
The relevant a kind of nutritional health food of the present invention particularly relates to a kind of carotenoid emulsion and the carotenoid chewing gum that is added with this carotenoid emulsion with higher-class carotene carotene content and absorptivity.
Background technology
Carotenoid is the general name of one type of important natural colouring matter, belongs to compound.Be prevalent in the yellow in animal, higher plant, fungi, algae and the bacterium, orange red or red pigment, water insoluble, be slightly soluble in vegetable oil, moderate is dissolved in fat, and unstable chemcial property is prone to when illumination and heating, take place oxidation reaction.Therefore, when carotenoid is used in hope as food color or nutrition fortifier, need they be processed into form stable and that be easy to absorb.
Often use carotenoid to divide three types at food and medicine:
1, beta carotene, lycopene.
2, lutein, astaxanthin, astacin, zeaxanthin, capsanthin etc.
3, crocin, annatto and torularhodin etc.
Carotenoid can be converted into vitamin A and known by many people.Vitamin A is as the nutrient of a kind of key in the human body, and its shortage can cause people's skin thickening, drying, wrinkle increase and yctalopia etc.In fact, participate in the organism metabolism except being converted into vitamin A, increasing discovering, carotenoid anti-oxidant, regulate immunity, delay senility, and aspects such as multiple chronic disease such as prophylaxis of cancer have important effect.
We can not synthesize carotenoid by human body self, and fruits and vegetables are its important sources.If only considering carotenoid is vitamin a source, the beta carotene of general additional 4～5mg for each person every day is enough, but if consider to utilize carotenoid to treat and prevent disease, the demand of human body is then much bigger.Though fruits and vegetables contain carotenoid,, be difficult to reach prophylactic demand because its content is low.The method that the edible nutritional health food that contains carotenoid then can yet be regarded as and dealt with problems.
At present, the common nutritional health food that contains carotenoid has the carotenoid capsule, contains drinks, chewing gum of carotenoid etc.And wherein used carotenoid can adopt slurries with higher-class carotene carotene content or the micro mist that from the material that contains carotenoid, extracts.Yet with the nutritional health food that this carotenoid slurries or micro mist are made, the ratio that its carotenoid can be absorbed by the body is very low.Trace it to its cause, the one, processing technology in the past all take to add vegetable oil solve fat-soluble, yet carotenoid only is slightly soluble in vegetable oil, is difficult to absorbed by human consumption, great majority have been discharged from external; The 2nd, the carotenoid unstable chemcial property, highly volatile and oxidation cause the carotenoid loss, cause the content of carotenoid in the health food to reduce.
In order to improve the absorptivity of carrotene; It is to have adopted wall breaking technology that a kind of method is arranged; The carrot juice of raw material processing high carotene content is made in a kind of employing with carrot method is disclosed like prior art; Be after carrot meal is broken into particle, again daucus carrot particles carried out broken wall through colloid mill to the carrot cell wall and pulverize, obtain carrot juice through press filtration then than high carotene content.The carrot juice that this method obtains can make the carrotene recovery rate increase; But still have a large amount of carrotene to be dropped and not effectively utilization along with the carrot residue; And this method high temperature that carrotene still can produce because of processing in colloid mill broken wall process and, thereby cause the carrotene loss because of the dissolved oxygen oxidation in the carrot juice.
The another kind of method that prior art provides is to use oil dissolving carrotene; A kind of beta-carotene chewing gum manufacture craft is disclosed like prior art; It uses the beta carotene raw material to be distributed in maize germ oil or the palm oil; Add other auxiliary material again and process beta-carotin microcapsule dry powder, beta-carotin microcapsule dry powder is added in the chewing gum process beta-carotene chewing gum.This kind chewing gum is owing to be distributed to beta carotene earlier in maize germ oil or the palm oil; Make beta carotene be dissolved in maize germ oil or palm oil to a certain extent; Can improve the assimilation effect of beta carotene; But because beta carotene only is slightly soluble in vegetable oil, therefore the assimilation effect of beta carotene is also not obvious for its addition.And, also oxidation in air easily of the micro-capsule dry powder of processing.
Summary of the invention
To the problem that exists in the prior art, purpose of the present invention provides a kind of carotenoid content height, good stability, carotenoid emulsion that the human absorptivity is high.
Another object of the present invention provides a kind of carotenoid chewing gum that is added with above-mentioned carotenoid emulsion.
For realizing the foregoing invention purpose, the technical scheme that the present invention adopts is:
A kind of carotenoid emulsion, it adopts following method to process:
1) with the carotenoid powder of content 1～99% and soybean lecithin by weight 1: 0.5～1.5 mixed, put into colloid mill and grind into emulsion particle solution;
2) this emulsion particle solution and vegetable oil are soaked 100～300min and by the vegetable oil embedding by weight 1: 0.5～1.5 ratios;
3) above-mentioned embedding liquid is ground into the corpuscle emulsion of particle diameter 5～10 μ m in micronizer.
Wherein, said carotenoid can by in beta carotene, lutein, the zeaxanthin a kind of, two kinds or three kinds form.
Said vegetable oil is preferentially selected for use: wheat-germ oil, soybean oil, sunflower oil or maize germ oil, certainly, also can select other vegetable oil for use.Be good with wheat-germ oil wherein, it not only can embedding carotenoid particulate, isolated its with the contacting of air, avoid carotenoid in micronizer, because of high strength shearing oxidation.And, utilize soybean lecithin to help carotenoid to form emulsion particle solution, improve the absorptivity of carotenoid.The wheat-germ oil that adds is rich in vitamin E conjugated double bond in the carotenoid and the anti-oxidation of methyl branch is played a protective role.
Preferably, in the step 3) crushing process, control said embedding liquid temp and be not higher than 60 ℃, carotenoid stability is had a negative impact to avoid temperature.Temperature control can realize through cooling system is set in micronizer.
The invention still further relates to a kind of carotenoid chewing gum that is added with above-mentioned carotenoid emulsion, it adopts following method to process:
1) get carotenoid emulsion 0.01～10 weight portion, sweetener 20～80 weight portions are put into baking oven heat sterilization 70min under 50～60 ℃ of temperature;
2) get edible matrix 10～80 weight portions, be put in the baking oven in 40～65 ℃ of following thermoplastic 15～30min;
3) above-mentioned carotenoid emulsion, sweetener and edible matrix are fully rubbed up, stir, then cutting, compression molding.
Wherein, for sugar-free chewing gum, said sweetener can be combined by in maltitol, xylitol, D-sorbite, D-mannitol and the acesulfame potassium (acesulfame potassium) one or more, and for there being the said sweetener of sugared chewing gum can adopt sucrose.
In said step 3), add flavoring essence and acidity regulator simultaneously; Said flavoring essence can be the essence of various fruit tastes; Said acidity regulator can be citric acid, malic acid or fumaric acid; Said essence addition is 0.1～0.5 weight portion, and the acidity regulator addition is 0.1～1 weight portion.
The peppermint oil that in said step 3), also can add 0.05～0.4 weight portion simultaneously.
In said step 3), also can add the colouring agent of 0.2～0.5 weight portion simultaneously, this colouring agent can adopt titanium dioxide.
In order to make the chewing gum appearance looks elegant, after said compression molding step, also have a tunicle polishing step, the chewing gum that is about to compression molding is in fruit glaze agent adds polishing machine, and tunicle polishes, and this fruit glaze agent can be selected lac and Brazil wax for use.
Compared with prior art; The present invention utilizes soybean lecithin to carotenoid solubility height and emulsification property; Help to form emulsion particle solution, help the absorption of human body, solved the problem that carotenoid is difficult to be absorbed by the body carotenoid with carotenoid; The vegetable oil that adds can form oil film in above-mentioned emulsion particle solution surface, and with its abundant embedding, isolated carotenoid contacts with air (or oxygen), avoids the loss of carotenoid in ultramicro grinding machined and preservation process; And embedding liquid is crushed to 5～10 μ m with carotenoid powder wherein by particle diameter 150 μ m in micronizer; This granularity combines the dissolution of soybean lecithin to carotenoid; Human body is reached more than 95% effective absorptivity of carotenoid, thereby make the emulsion and the chewing gum that adopt the inventive method to make have good stable property and higher human absorptivity.Through stability test, the carotenoid emulsion and the chewing gum that adopt the inventive method to make were stored three months at normal temperatures, and the carotenoid loss in the sample is deposited the loss late up to 80～90% all less than 5% far below carotenoid naturally.In addition, soybean lecithin is except the effect of the dissolving that helps carotenoid, after emulsion adds chewing gum; Can also be as the NMF of chewing gum; And needn't add NMF in addition, can reduce the addition of additive, and soybean lecithin itself also is a kind of useful nutriment; Can increase the trophic function of chewing gum, make chewing gum of the present invention have multiple nutritive effect.
Above-mentioned carotenoid emulsion also can add to processes various candies and the nutraceutical that contains carotenoid in other food.
The specific embodiment
Describe the present invention below in conjunction with specific embodiment, the description of this part only is exemplary and explanatory, should any restriction not arranged to protection scope of the present invention.
Embodiment 1:
1, makes the beta carotene emulsion: after the beta carotene 1kg (containing beta carotene 0.1kg) that gets the content 10% that Shaanxi Sen Fu Bioisystech Co., Ltd produces mixes with the 1.2kg soybean lecithin, put into the colloid mill emulsifying, formation emulsion particle solution.Then above-mentioned emulsion particle solution is put into 2.6kg wheat-germ oil and soak 100min,, again embedding liquid is put into micronizer and carry out ultramicro grinding, make the beta carotene particle diameter in the embedding liquid reach 5～10 μ m through fully disperseing to process embedding liquid.The WZJ6 type vibration-type micronizer that micronizer can select for use Jinan Billionpowder Tech& Eng Co., Ltd to produce; In a mill body of this micronizer, refrigeration pipe is set; This refrigeration pipe is connected with a refrigeration system; Can the micronizer temperature be controlled at below 60 ℃ through this refrigeration system, make embedding liquid temp wherein not be higher than 60 ℃.Those skilled in the art can increase above-mentioned refrigeration system and not have any difficulty according to description of the invention in this micronizer, repeat no more at this.
2, make beta-carotene chewing gum:
At first, get beta carotene emulsion, maltitol and put into baking oven about 70min of heat sterilization under 50～60 ℃ of temperature respectively.Secondly, will eat matrix and be positioned in the softening dish, and put into baking oven and be heated to 40～65 ℃ of softening 15～30min.Then above-mentioned beta carotene emulsion, maltitol 15kg and edible matrix being put into z word rotation dough kneeding machine remains under 55 ℃ of temperature and rubs up stirring; And adding titanium dioxide, flavoring apple essence and peppermint oil stir; Take out matrix group material afterwards and cut into bulk of uniform size, put into the extruder extruding in flakes.Remaining 5kg maltitol evenly is sprinkling upon on the chopping board, the material of extruding is placed on rolls smooth on the maltitol and cut into the pillow formula particle of every 1.4kg.At last, above-mentioned pillow formula particle put into polishing machine and add lac carry out tunicle polishing, process the chewing gum that contains beta carotene.
Embodiment 2:
1, makes the lutein emulsion: after the lutein 1kg (containing lutein 0.1kg) that gets 99% content that Tianjin spike natural biological research and development Co., Ltd produces mixes with the 1.0kg soybean lecithin, put into the colloid mill emulsifying, formation emulsion particle solution.Then above-mentioned emulsion particle solution is put into the 1.0kg soybean oil and soak 200min,, again embedding liquid is put into micronizer and carry out ultramicro grinding, make the lutein particle diameter in the embedding liquid reach 5～10 μ m through fully disperseing to process embedding liquid.
2, make the lutein chewing gum:
At first, get sweeteners such as lutein emulsion and maltitol, D-sorbite, xylitol, D-mannitol, acesulfame potassium and put into baking oven about 70min of heat sterilization under 50～60 ℃ of temperature respectively.Secondly, will eat matrix and be positioned in the softening dish, and put into baking oven and be heated to 40～65 ℃ of softening 15～30min.Then above-mentioned lutein emulsion, sweetener and edible matrix being put into z word rotation dough kneeding machine remains under 55 ℃ of temperature and rubs up stirring; And adding peach flavor essence, titanium dioxide, citric acid and peppermint oil stir; Take out matrix group material afterwards and cut into bulk of uniform size, put into the extruder extruding in flakes.The material of extruding is placed on rolls smooth on the chopping board and cut into the pillow formula particle of every 1.4kg.At last, above-mentioned pillow formula particle put into polishing machine and add Brazil wax carry out tunicle polishing, process the chewing gum that contains lutein.
Embodiment 3:
1, makes the zeaxanthin emulsion: after the zeaxanthin 1kg (containing zeaxanthin 0.1kg) that gets 1% content that Tianjin spike natural biological research and development Co., Ltd produces mixes with the 1.2kg soybean lecithin, put into the colloid mill emulsifying, formation emulsion particle solution.Then above-mentioned emulsion particle solution is put into the 2.3kg sunflower oil and soak 300min,, again embedding liquid is put into micronizer and carry out ultramicro grinding, make the zeaxanthin particle diameter in the embedding liquid reach 5～10 μ m through fully disperseing to process embedding liquid.
2, make the zeaxanthin chewing gum:
At first, get zeaxanthin emulsion and sucrose and put into baking oven about 70min of heat sterilization under 50～60 ℃ of temperature respectively.Secondly, will eat matrix and be positioned in the softening dish, and put into baking oven and be heated to 40～65 ℃ of softening 15～30min.Then above-mentioned lutein emulsion, sucrose and edible matrix being put into z word rotation dough kneeding machine remains under 55 ℃ of temperature and rubs up stirring; And adding flavoring apple essence, titanium dioxide, fumaric acid and peppermint oil stir; Take out matrix group material afterwards and cut into bulk of uniform size, put into the extruder extruding in flakes.The material of extruding is placed on rolls smooth on the chopping board and cut into the pillow formula particle of every 1.4kg.At last, above-mentioned pillow formula particle put into polishing machine and add Brazil wax carry out tunicle polishing, process the chewing gum that contains zeaxanthin.
Embodiment 4:
1, make beta carotene, lutein and zeaxanthin mixed emulsion: the zeaxanthin 2kg that gets the lutein 0.5kg of the beta carotene 1kg of the content 10% that Shaanxi Sen Fu Bioisystech Co., Ltd produces, 10% content that Tianjin spike natural biological research and development Co., Ltd produces and 10% content that Tianjin spike natural biological research and development Co., Ltd produces is with after the 4.2kg soybean lecithin mixes; Put into the colloid mill emulsifying, form emulsion particle solution.Then above-mentioned emulsion particle solution is put into 7.7kg wheat-germ oil and soak 150min; Through fully disperseing to process embedding liquid; Again embedding liquid is put into micronizer and carry out ultramicro grinding, make beta carotene, lutein and zeaxanthin particle diameter in the embedding liquid reach 5～10 μ m.
2, make the chewing gum that contains beta carotene, lutein and zeaxanthin:
At first, get mixed emulsion and sweetener and put into baking oven about 70min of heat sterilization under 50～60 ℃ of temperature respectively.Secondly, will eat matrix and be positioned in the softening dish, and put into baking oven and be heated to 40～65 ℃ of softening 15～30min.Then above-mentioned mixed emulsion, sweetener and edible matrix being put into z word rotation dough kneeding machine remains under 55 ℃ of temperature and rubs up stirring; And adding blueberry essence, titanium dioxide, citric acid and peppermint oil stir; Take out matrix group material afterwards and cut into bulk of uniform size, put into the extruder extruding in flakes.The material of extruding is placed on rolls smooth on the chopping board and cut into the pillow formula particle of every 1.4kg.At last, above-mentioned pillow formula particle put into polishing machine and add lac carry out tunicle polishing, process the chewing gum that contains beta carotene, lutein and zeaxanthin.
The experiment of beta carotene stability and absorption of human body amount:
1, presses chewing gum that the method for embodiment 1 makes as sample 1, and with the same material of embodiment 1, add chewing gum that same content beta carotene processes as sample 2.
2, with sample 1 and sample 2 equally in normal temperature held 3 months; The content beta-carotene of test sample 1 and sample 2; The content beta-carotene of sample 1 is still more than 95% of former content, and the content beta-carotene of sample 2 is reduced to below 20% of former content.
3, sample 1 and sample 2 are respectively got 1, and in 20 minutes, chew food for respectively the volunteer and finish, every then content that detected beta carotene in volunteer's serum at a distance from 30 minutes, the beta carotene of converting out in the volunteer 3 hours is accumulated uptake.The result shows that the accumulation uptake of the beta carotene of sample 1 in volunteer's body is 4-5 times of sample 2.
The above only is a preferred implementation of the present invention; Should be pointed out that for those skilled in the art, under the prerequisite that does not break away from the principle of the invention; Can also make some improvement and retouching; Also can above-mentioned technology contents be combined to form other technical scheme, these improvement and retouching, and the other technologies scheme that forms also should be regarded as protection scope of the present invention.Also can adopt the pure article of carotenoid or other purity carotenoid to make like above-mentioned carotenoid emulsion, also should be regarded as protection scope of the present invention as long as content ratio is identical with the present invention.
Claims (10)
1. carotenoid emulsion is characterized in that adopting following method to process:
1) with content 1～99% carotenoid powder and soybean lecithin by weight 1: 0.5～1.5 mixed, put into colloid mill and grind into emulsion particle solution;
2) this emulsion particle solution and vegetable oil are soaked 100～300min and by the vegetable oil embedding by weight 1: 0.5～1.5 ratios;
3) above-mentioned embedding liquid is ground into the corpuscle emulsion of particle diameter 5～10 μ m in micronizer.
2. carotenoid emulsion according to claim 1 is characterized in that: said carotenoid by in beta carotene, lutein, the zeaxanthin a kind of, two kinds or three kinds form.
3. according to the said carotenoid emulsion of claim 1, it is characterized in that said vegetable oil comprises: wheat-germ oil, soybean oil, sunflower oil or maize germ oil.
4. carotenoid emulsion according to claim 1 is characterized in that: in the step 3) crushing process, control said embedding liquid temp and be not higher than 60 ℃.
5. carotenoid chewing gum that is added with the said carotenoid emulsion of claim 1 is characterized in that adopting following method to process:
1) get carotenoid emulsion 0.01～10 weight portion, sweetener 20～80 weight portions are put into baking oven heat sterilization under 50～60 ℃ of temperature;
2) get edible matrix 10～60 weight portions, be put in the baking oven in 40～65 ℃ of following thermoplastic 15～30min;
3) above-mentioned carotenoid emulsion, sweetener and edible matrix are fully rubbed up, stir, then cutting, compression molding.
6. according to the said carotenoid chewing gum of claim 5, it is characterized in that: said sweetener is to be combined by in maltitol, xylitol, D-sorbite, D-mannitol and the acesulfame potassium one or more, or sucrose.
7. according to the said carotenoid chewing gum of claim 5; It is characterized in that: in said step 3), add flavoring essence and acidity regulator simultaneously; Wherein said acidity regulator is citric acid, malic acid or fumaric acid; Said essence addition is 0.2～1 weight portion, and the acidity regulator addition is 0.1～2 weight portion.
8. according to the said carotenoid chewing gum of claim 5, it is characterized in that: the peppermint oil that in said step 3), also adds 0.05～0.4 weight portion simultaneously.
9. according to the said carotenoid chewing gum of claim 5, it is characterized in that: the colouring agent that in said step 3), also adds 0.2～0.5 weight portion simultaneously.
10. according to the said carotenoid chewing gum of claim 5, it is characterized in that: after said compression molding step, also have a tunicle polishing step, the chewing gum that is about to compression molding is in fruit glaze agent adds polishing machine, and tunicle polishes.
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| CN2009101594966A CN101611876B (en) | 2009-07-14 | 2009-07-14 | Carotenoid emulsion and carotenoid chewing gum added with emulsion |
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| CN101611876B true CN101611876B (en) | 2012-05-30 |
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Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101810265A (en) * | 2010-04-14 | 2010-08-25 | 尤新 | Xylitol-based chewing tablet for relieving asthenopia and improving macular degeneration |
| CN101982086A (en) * | 2010-11-24 | 2011-03-02 | 无锡健特药业有限公司 | Lutein gum and preparation method thereof |
| CN104274428B (en) | 2013-07-09 | 2016-04-13 | 浙江新维普添加剂有限公司 | The preparation method of oil-dispersing property carotenoid formulation |
| CN109957148A (en) * | 2017-12-22 | 2019-07-02 | 百达医企业有限公司 | Carry lutein edible film and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1367167A (en) * | 2001-01-24 | 2002-09-04 | 株式会社可乐丽 | Method for preparing carotenoid emulsion |
| CN1768033A (en) * | 2003-03-28 | 2006-05-03 | 株式会社可乐丽 | Process for producing carotenoid emulsion |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1367167A (en) * | 2001-01-24 | 2002-09-04 | 株式会社可乐丽 | Method for preparing carotenoid emulsion |
| CN1768033A (en) * | 2003-03-28 | 2006-05-03 | 株式会社可乐丽 | Process for producing carotenoid emulsion |
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