CN101589002B - Artificial marble having various designs and process for preparing the same - Google Patents

Artificial marble having various designs and process for preparing the same Download PDF

Info

Publication number
CN101589002B
CN101589002B CN2007800503329A CN200780050332A CN101589002B CN 101589002 B CN101589002 B CN 101589002B CN 2007800503329 A CN2007800503329 A CN 2007800503329A CN 200780050332 A CN200780050332 A CN 200780050332A CN 101589002 B CN101589002 B CN 101589002B
Authority
CN
China
Prior art keywords
base plate
artificial marble
fragment
chip sheet
marble
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN2007800503329A
Other languages
Chinese (zh)
Other versions
CN101589002A (en
Inventor
高海枡
房极必
金荣贤
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
LG Electronics Inc
LG Corp
Original Assignee
LG Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by LG Chemical Co Ltd filed Critical LG Chemical Co Ltd
Publication of CN101589002A publication Critical patent/CN101589002A/en
Application granted granted Critical
Publication of CN101589002B publication Critical patent/CN101589002B/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65F—GATHERING OR REMOVAL OF DOMESTIC OR LIKE REFUSE
    • B65F1/00—Refuse receptacles; Accessories therefor
    • B65F1/0033—Refuse receptacles; Accessories therefor specially adapted for segregated refuse collecting, e.g. receptacles with several compartments; Combination of receptacles
    • B65F1/0053—Combination of several receptacles
    • B65F1/0073—Flexible receptacles fixed on a frame or in an enclosure
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02—Macromolecular compounds
    • C04B26/04—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B26/06—Acrylates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44F—SPECIAL DESIGNS OR PICTURES
    • B44F9/00—Designs imitating natural patterns
    • B44F9/04—Designs imitating natural patterns of stone surfaces, e.g. marble
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65F—GATHERING OR REMOVAL OF DOMESTIC OR LIKE REFUSE
    • B65F1/00—Refuse receptacles; Accessories therefor
    • B65F1/04—Refuse receptacles; Accessories therefor with removable inserts
    • B65F1/06—Refuse receptacles; Accessories therefor with removable inserts with flexible inserts, e.g. bags or sacks
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65F—GATHERING OR REMOVAL OF DOMESTIC OR LIKE REFUSE
    • B65F1/00—Refuse receptacles; Accessories therefor
    • B65F1/14—Other constructional features; Accessories
    • B65F1/141—Supports, racks, stands, posts or the like for holding refuse receptacles
    • B65F1/1415—Supports, racks, stands, posts or the like for holding refuse receptacles for flexible receptables, e.g. bags, sacks
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65F—GATHERING OR REMOVAL OF DOMESTIC OR LIKE REFUSE
    • B65F1/00—Refuse receptacles; Accessories therefor
    • B65F1/14—Other constructional features; Accessories
    • B65F1/1468—Means for facilitating the transport of the receptacle, e.g. wheels, rolls
    • B65F1/1473—Receptacles having wheels
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65F—GATHERING OR REMOVAL OF DOMESTIC OR LIKE REFUSE
    • B65F2210/00—Equipment of refuse receptacles
    • B65F2210/18—Suspending means
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65F—GATHERING OR REMOVAL OF DOMESTIC OR LIKE REFUSE
    • B65F2220/00—Properties of refuse receptacles
    • B65F2220/106—Collapsible
    • B65F2220/1063—Collapsible foldable
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00612—Uses not provided for elsewhere in C04B2111/00 as one or more layers of a layered structure
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/54—Substitutes for natural stone, artistic materials or the like
    • C04B2111/542—Artificial natural stone
    • C04B2111/545—Artificial marble

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Finishing Walls (AREA)

Abstract

Disclosed is an artificial marble used in an exterior or interior constructional material for buildings and a process for preparing the same. The artificial marble is prepared by use of a chip sheet, to have various design patterns at a surface thereof.

Description

Has artificial marble of multiple layout and preparation method thereof
Technical field
The present invention relates to a kind of artificial marble and preparation method thereof with kinds of surface layout.More specifically, the present invention relates to a kind of artificial marble with multiple exterior design and preparation method thereof, this method comprises: will use the exterior design plate of fragment to insert in the mould; Base binder paste is poured into the said exterior design plate of covering in this mould; Through using this mould of vibrator vibration to remove the bubble that in base binder paste, comprises; Be cured and on this moulded product, carry out surface treatment operations.
Background technology
Usually; Prepare through following method as the outside of buildings or the artificial marble of internal building material: multiple decorative chips is sneaked in the base binder paste; Compacting or this mixture of casting; And at last resulting product is carried out surface treatment, so that the prepared artificial marble with granite exterior design to be provided.
But in the above-mentioned ordinary method that is used for preparing artificial marble, the problem of existence is that prepared artificial marble exists limitation when the multiple exterior design of performance.
As an instance, Korean Patent discloses 2003-0081652 number and has disclosed a kind of double-deck building panel that has, and this plate is made up of waste polyurethane substrate and marble layer.But it doesn't matter for building panel that is disclosed and artificial marble, and still do not exist like use chip sheet proposed by the invention and prepare method for imitation marble.
As another instance, korea patent registration has disclosed for No. 409084 a kind of for reducing the multilayer artificial marble plate that is used for the premade bath room wall that plastic flakes designs.But this publication does not still relate to uses chip sheet to prepare artificial marble.
Summary of the invention
Technical problem
Therefore, consider the problems referred to above and accomplished the present invention, and an object of the present invention is to provide artificial marble that has multiple exterior design and preparation method thereof.
Technical scheme
According to an aspect of the present invention; Above-mentioned and other purpose can realize through a kind of artificial marble is provided; Said artificial marble forms through using chip sheet, and this chip sheet prepares through following steps: with adhesive transfer to the base plate having predetermined pattern, and fragment is sprinkling upon on this base plate so that these fragments stick on the pattern that is transferred on this base plate; Wherein after this base plate was removed from artificial marble, said fragment was retained in the artificial marble with pattern.
Select tackiness agent to guarantee between said base plate and fragment, having enough binding propertys.Said tackiness agent can be for being selected from least a in the following material: SE (PVC) colloidal sol, thermoset acrylic adhesive agent (thermosetting acryl adhesive), thermosetting epoxy resin tackiness agent, contain TEB 3K (MMA) colloidal sol and unsaturated polyester (UPE) colloidal sol that contains stiffening agent of stiffening agent.Said tackiness agent is that thermosetting adhesive is necessary, so that it at room temperature can not hardened, thereby guarantees to be enough at room temperature with on adhesive transfer to the said base plate.
Said fragment can be for being selected from least a in the following material: resin chips comprises for example polymethylmethacrylate (PMMA) resin chips; Through pulverizing the natural marble fragment that natural marble obtains; Glass fragment; Color chip can be divided the fragment that spreads with other.
Said base plate must possess segregative character and surface grinding character, and can be paper film, resin molding, glassy membrane etc.Especially, this base plate is preferably processed by polyethylene terephthalate (PET) film.
Said artificial marble is as the outside or the internal building material of buildings, and can comprise, for example acryl resin, unsaturated polyester resin or epoxy resin for based on cement or based on the artificial marble of resin.
According to a further aspect in the invention, a kind of preparation method for imitation marble is provided, this method comprises: with adhesive transfer to the base plate to have predetermined pattern; Fragment is sprinkling upon on the base plate with the preparation chip sheet, and this chip sheet has the fragment that sticks on the pattern that is transferred on the base plate; Through using this chip sheet to form artificial marble; With the said base plate of removal.
In order effectively to prepare said chip sheet, this method may further include: after solidifying said chip sheet, remove and do not stick to the unnecessary fragment on the base plate.
Can shift said tackiness agent through graining roll method, silk screen print method or embossing etc.
Preferably, form artificial marble through following method: chip sheet is inserted in the mould; Be full of this mould with basic slurry; With bubble through using the vibrator removal in basic slurry, to comprise.
Said base plate can remove through peeling off this base plate after accomplishing in the formation of artificial marble, perhaps removes through on the artificial marble that forms, carrying out the surface grinding operation.
According to the present invention, in the method for imitation marble of outside that is used as buildings through applying pressure machine or vibrator preparation or internal building material, at first, spread the chip sheet that device prepares multiple pattern through using the fragment branch.Then, after being inserted into this chip sheet in the mould, fill up this mould with the preparation artificial marble with slurry.Resulting artificial marble carried out routine is solidified and surface treatment operations, with the multiple color and the layout of the artificial marble of the difference taste that obtains to satisfy the human consumer.
Description of drawings
From below in conjunction with will more being expressly understood above and other objects of the present invention, characteristic and other advantage the detailed description of accompanying drawing, wherein:
Fig. 1 explains to be used to prepare the schema according to method for imitation marble of the present invention;
Fig. 2 explains that preparation is used to provide the synoptic diagram according to the method for the chip sheet with required exterior design of artificial marble of the present invention;
Fig. 3 is the perspective illustration according to chip sheet of the present invention;
Fig. 4 explains to be used to prepare the skeleton view according to the detailed step of method for imitation marble of the present invention.
Embodiment
To the present invention be described in more detail with reference to accompanying drawing at present.
Fig. 1 explains to be used to prepare the schema according to method for imitation marble of the present invention.As shown in the figure, saidly be used to prepare method for imitation marble and comprise Materials Measurement and filling operation, married operation, exterior design plate process operation, shaping operation, surface treatment operations and cutting/check/packaging operation.
Fig. 2 explains that preparation is used to provide the synoptic diagram according to the method for the chip sheet with required exterior design of artificial marble of the present invention; As scheme said, at first, through plate feeding roller 10 charging base plates 70.
Base plate 70 is preferably the form of the film of being processed by paper, resin, glass etc., and has pre-determined thickness.Base plate 70 must have segregative character and surface grinding character.Consider that the paper film gets wet easily, so base plate 70 is preferably processed by the water-fast resin molding of for example polyethylene terephthalate (PET) etc.
Then, through use adhesive transfer device 20 with on adhesive transfer to the base plate 70 to have predetermined pattern.Adhesive transfer device 20 can comprise graining roll with multiple pattern, print roller, embossing device (stamp) etc.
Said tackiness agent can be selected from the following material: SE (PVC) colloidal sol, thermoset acrylic adhesive agent, thermosetting epoxy resin tackiness agent, TEB 3K (MMA) colloidal sol that contains stiffening agent and unsaturated polyester (UPE) colloidal sol that contains stiffening agent etc.
After transferring to tackiness agent on the base plate 70 fully, be sprinkling upon on the base plate 70 through using the fragment branch to spread the various fragments 80 that device 30 will have different colours and size each other.
Fragment 80 can be selected from the resin chips of using polymethylmethacrylate (PMMA) resin, glass fragment, colored glass chips, can divide the fragment that spreads through the colored natural marble fragment pulverizing natural marble fragment that natural marble obtains, obtain through the natural marble fragment dyeing that makes pulverizing and other.
Subsequently, after through the resulting chip sheet of use drying installation 40 sclerosis, the fragment through using garbage collection device 50 to remove on the specific part that does not have applied adhesives that is sprinkling upon base plate 70 does not promptly have adherent fragment.Can obtain having the chip sheet of multiple layout in this way.The chip sheet of accomplishing is directed to plate and reclaims roller 60.
Fig. 3 is the perspective illustration of chip sheet, and diagram a kind of exterior design, wherein a plurality of fragments 80 are sticked on the base plate 70 and produce mulle.Should be understood that, except the diagrammatic mulle, can produce various exterior design, and, the print roller of various patterns had and the fragment of various layouts can obtain other distinguishing layout through use.
Fig. 4 explains to be used to prepare the skeleton view according to the detailed step of method for imitation marble of the present invention.As shown in the figure, with before the chip sheet with multiple layout of preparation be inserted into the bottom of forming mould 90, fragment 80 is faced up.
Then, after pouring into base binder paste 100 in the forming mould 90, make base binder paste 100 moulding in mould 90 through working pressure machine and vibrator.Here, vibrator is used for removing the bubble that comprises in base binder paste 100.
In the case, employed base binder paste 100 can be included in employed resin (acryl resin etc.) or cement slurry in the conventional artificial marble of preparation, and can be selected and have multiple color to satisfy the different tastes of human consumer.
At last, with resulting moulded products be cured in proper order that operation, lock out operation and base plate are peeled off or conventional surface grinding operation to remove base plate 70, only stay fragment 80 simultaneously.Can prepare final artificial marble 11 in this way with multiple exterior design.In the present invention, as the result who removes base plate 70, final artificial marble 11 has only fragment 80 and does not have base plate 70.Therefore, through combining a plurality of fragments 80, final artificial marble 11 can realize multiple exterior design.
[embodiment 1]
Through using colored glass chips and natural marble fragment to prepare a kind of artificial marble based on cement.
At first, after the star silk screen that will design in advance is placed on the PET film, PVC colloidal sol is poured on this silk screen.Then, silk screen is rolled, so that PVC colloidal sol is transferred on the PET film to have mulle with the rubber roll shaft.
Subsequently, after the colored glass chips that with diameter is 3mm～6mm is sprinkling upon on the PET film, shake this PET film to remove the unnecessary colored glass chips on those privileged sites of not using PVC colloidal sol that are sprinkling upon the PET film.Then, under 180 ℃ temperature, in baking oven, toasted the PET film about 5 minutes, so that PVC colloidal sol generation gelation.After the gelation of PVC colloidal sol was accomplished, removing once more through shake PET film did not have adherent colored glass chips.
Resulting PET plate is put into the mould of long 450mm, wide 450mm and thick 30mm, colored glass chips is faced up.Then, the base water material-mud is poured in the mould.In the case; Based on the cement of 100 weight parts, employed cement slurry comprises that the diameter of 300～370 weight parts is the natural marble fragment of 1mm～9mm, the natural marble powder of 30～100 weight parts (No. 100～No. 350), the water of 25～35 weight parts and the water reducer of 1～3 weight part.
After pouring into cement slurry in the mould, used the vibrator swing die 1～5 minute, to remove the bubble that in cement slurry, comprises.Afterwards, under the condition of 40～50 ℃ temperature and constant humidity, cement slurry was solidified 12 hours.
After completely solidified,, carry out conventional grinding and cutting operation then, to obtain long 400mm, wide 400mm, thick 20mm and to have the artificial marble of stained glass mulle in its surface with formed cement slurry goods and mold separation.Should be noted in the discussion above that in grinding operation grinding the degree of depth must be less than the diameter of colored glass chips (less than 3mm～6mm).
Simultaneously, in order to satisfy human consumer's difference taste, to the not restriction of exterior design of artificial marble, and for the also not restriction of kind of the natural marble fragment that in cement slurry, uses.
Industrial applicibility
Can obviously find out from foregoing description, the invention provides a kind of artificial marble, it can use the chip sheet of various layouts to show distinguishing exterior design.Therefore, effect of the present invention not only is to provide the artificial marble of the exterior design with aesthetic feeling that satisfies the different tastes of human consumer, and is to have improved reliability of products.
Though disclose preferred implementation of the present invention from purpose of explanation; Those of skill in the art will understand; Under the situation that does not depart from disclosed scope of the present invention and essence in appended claims, have various improved procedures, addition manner and alternative.

Claims (4)

1. one kind is used to prepare method for imitation marble, and it comprises:
With adhesive transfer to the base plate to have predetermined pattern;
Fragment is sprinkling upon on this base plate with the preparation chip sheet, and this chip sheet has the fragment that sticks on the pattern that is transferred on this base plate;
Through using this chip sheet to form artificial marble; With
Remove said base plate,
Wherein, said artificial marble forms through following steps:
Said chip sheet is inserted in the mould;
Fill up this mould with basic slurry; With
Remove the bubble that in said basic slurry, comprises through using vibrator.
2. method according to claim 1, it further comprises:
After solidifying said chip sheet, remove and do not stick to the unnecessary fragment on the base plate.
3. method according to claim 1 wherein, shifts said tackiness agent through using graining roll, silk screen printing or embossing device.
4. method according to claim 1 wherein, removes this base plate through peeling off base plate after accomplishing in the formation of artificial marble, perhaps removes this base plate through on the artificial marble that forms, carrying out the surface grinding operation.
CN2007800503329A 2007-01-26 2007-12-17 Artificial marble having various designs and process for preparing the same Expired - Fee Related CN101589002B (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
KR10-2007-0008311 2007-01-26
KR1020070008311 2007-01-26
KR1020070008311A KR100888334B1 (en) 2007-01-26 2007-01-26 Artificial marble having various designs and process for preparing the same
PCT/KR2007/006586 WO2008091063A1 (en) 2007-01-26 2007-12-17 Artificial marble having various designs and process for preparing the same

Publications (2)

Publication Number Publication Date
CN101589002A CN101589002A (en) 2009-11-25
CN101589002B true CN101589002B (en) 2012-10-17

Family

ID=39644621

Family Applications (1)

Application Number Title Priority Date Filing Date
CN2007800503329A Expired - Fee Related CN101589002B (en) 2007-01-26 2007-12-17 Artificial marble having various designs and process for preparing the same

Country Status (4)

Country Link
EP (1) EP2132152A4 (en)
KR (1) KR100888334B1 (en)
CN (1) CN101589002B (en)
WO (1) WO2008091063A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104385566A (en) * 2014-09-23 2015-03-04 捷美特株式会社 Artificial marble with formed patterns, and manufacturing method thereof

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101285954B1 (en) * 2009-01-07 2013-07-12 (주)엘지하우시스 Artificial marble using chip of specific shape and process for preparing the same
KR101304149B1 (en) * 2010-09-27 2013-09-05 (주)엘지하우시스 Forming mold with dual structure and method of manufacturing exterior panel for household electric appliance using the forming mold
KR101255318B1 (en) * 2011-12-05 2013-04-15 우리산업기술개발 주식회사 Manufacturing Method for Artificial Stone with Porous Surface
CN104496271A (en) * 2014-12-15 2015-04-08 田忠和 Artificial quartzite plate and manufacturing method thereof
CN104496274A (en) * 2014-12-15 2015-04-08 田忠和 Fireproof artificial quartz stone plate and manufacturing method thereof
CN104496273A (en) * 2014-12-15 2015-04-08 田忠和 Artificial quartzite plate and manufacturing method thereof
CN104478293A (en) * 2014-12-15 2015-04-01 田忠和 Synthetic quartzite plate and preparation method thereof
CN104496272A (en) * 2014-12-15 2015-04-08 田忠和 Anti-aging artificial quartzite plate and manufacturing method thereof
US20200047372A1 (en) * 2018-08-13 2020-02-13 Myeong Hwa Chung Artificial stone slab with integrally formed pattern and manufacturing method for the same
KR102207950B1 (en) 2020-08-24 2021-01-26 곽호진 Construction Method of Building Walls Using Transparent Sheets
US11905714B1 (en) 2022-03-24 2024-02-20 Sawica International, LLC Mosaic tile assembly for installation on a floor or wall surface
CN116985419B (en) * 2023-09-26 2023-12-15 福建鹏翔实业有限公司 Device and method for processing artificial marble by adopting marble leftover materials

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2635734B2 (en) * 1988-12-09 1997-07-30 株式会社日本触媒 Production of patterned artificial stone
JPH06210648A (en) * 1993-01-18 1994-08-02 Okura Ind Co Ltd Production of inlay-like artificial marble
JPH08333147A (en) * 1995-06-06 1996-12-17 Yamaha Living Tec Kk Artificial stone and its production
JP3334476B2 (en) * 1996-02-02 2002-10-15 東陶機器株式会社 Patterned artificial stone, manufacturing method and apparatus therefor
JP2000016850A (en) * 1998-06-30 2000-01-18 Maeda Kosan Kogyo Kk Artificial marble and its production
KR100409084B1 (en) 2001-05-21 2003-12-11 주식회사 엘지화학 Artificial marble pannel and method for preparing thereof
KR20030081652A (en) 2002-04-12 2003-10-22 유창씨앤씨(주) Building board with two layer and manufacturing method thereof
JP3758599B2 (en) * 2002-04-15 2006-03-22 松下電工株式会社 Manufacturing method of artificial marble
KR20040097678A (en) * 2003-05-12 2004-11-18 기우성 Method of Practical use and Manufacture of Patterned Silk Screen and also Manufacture of Insulation Patterned Stone
KR100589279B1 (en) * 2003-10-16 2006-06-13 주식회사 엘지화학 Conductive marble flooring and method of making the same by continuous process
CN1301199C (en) * 2003-12-31 2007-02-21 杨德宁 Coloured resin three dimensional pattern artificial stone slab material
KR100663395B1 (en) * 2004-08-05 2007-01-02 주식회사 바체 Method for putting a pattern on artificial stone using paper materials and artificial stone manufactured by the same method
KR100739304B1 (en) * 2005-05-02 2007-07-12 주식회사 엘지화학 Acrylic artificial marble having discontinuous circular pattern utilizing press method and process for preparing the same

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
JP特开2000-16850A 2000.01.18

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104385566A (en) * 2014-09-23 2015-03-04 捷美特株式会社 Artificial marble with formed patterns, and manufacturing method thereof

Also Published As

Publication number Publication date
EP2132152A1 (en) 2009-12-16
EP2132152A4 (en) 2010-01-20
KR100888334B1 (en) 2009-03-12
KR20080070345A (en) 2008-07-30
CN101589002A (en) 2009-11-25
WO2008091063A1 (en) 2008-07-31

Similar Documents

Publication Publication Date Title
CN101589002B (en) Artificial marble having various designs and process for preparing the same
CN104040094A (en) Flooring using PVC and method of constructing the flooring
US12064900B2 (en) Stone slabs, systems, and methods
CN104924826B (en) Embossment slabstone calligraphy and painting manufacture craft
CN207790150U (en) A kind of extrusion coating paper for concrete retarding dew aggregate finish
CN101163651B (en) Artificial marble using low specific gravity material as chip and process for preparing the same
CN107234896A (en) A kind of manufacture craft of soft pottery decorative cover hard-cover notebook
CN102910015B (en) Inverse picture inversely-sticking technique
KR101238119B1 (en) Inorganic board having surface decoration and process for preparing thereof
CN109353154A (en) A kind of production method of ceramic-imitated sculpture
KR101695083B1 (en) New fabric using scrab of fabric and method for producing the same
CN100427294C (en) Production method of plastic package box first ornamented with color printing and pattern then molded
KR100884901B1 (en) Cement type artificial marble having natural marble appearance and process for preparing the same
CN103313861A (en) Decorative sheet for decorating surface of three-dimensional molded material, method for manufacturing same, and method for decorating the surface of the molded material by using same
CN107476529B (en) Resin decorative plate and preparation method thereof
KR101305955B1 (en) Method for transcribing of surface
CN102205770B (en) Method for using image in tabulate photo to make three-dimensional entity
KR20000065663A (en) Making Methods of Character Doll
CN105500984B (en) Imitative ceramic tile laminating and preparation method thereof
KR101260080B1 (en) Artificial marble having various designs using adhesive sheet and process for preparing the same
JPS6228750B2 (en)
KR20180104350A (en) manufacture method of tail and tail
JPH07195321A (en) Molding method of molded body having pattern by granule overlaid layer
CN2243494Y (en) Mould plate for concrete surface processing
CN205614904U (en) Emulation culture slabstone material preparation structure

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
C17 Cessation of patent right
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20121017

Termination date: 20131217