CN101589002A - Artificial marble having various designs and process for preparing the same - Google Patents

Artificial marble having various designs and process for preparing the same Download PDF

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Publication number
CN101589002A
CN101589002A CNA2007800503329A CN200780050332A CN101589002A CN 101589002 A CN101589002 A CN 101589002A CN A2007800503329 A CNA2007800503329 A CN A2007800503329A CN 200780050332 A CN200780050332 A CN 200780050332A CN 101589002 A CN101589002 A CN 101589002A
Authority
CN
China
Prior art keywords
artificial marble
base plate
fragment
marble
chip sheet
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CNA2007800503329A
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Chinese (zh)
Other versions
CN101589002B (en
Inventor
高海枡
房极必
金荣贤
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
LG Corp
Original Assignee
LG Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by LG Chemical Co Ltd filed Critical LG Chemical Co Ltd
Publication of CN101589002A publication Critical patent/CN101589002A/en
Application granted granted Critical
Publication of CN101589002B publication Critical patent/CN101589002B/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65FGATHERING OR REMOVAL OF DOMESTIC OR LIKE REFUSE
    • B65F1/00Refuse receptacles; Accessories therefor
    • B65F1/0033Refuse receptacles; Accessories therefor specially adapted for segregated refuse collecting, e.g. receptacles with several compartments; Combination of receptacles
    • B65F1/0053Combination of several receptacles
    • B65F1/0073Flexible receptacles fixed on a frame or in an enclosure
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02Macromolecular compounds
    • C04B26/04Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B26/06Acrylates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B44DECORATIVE ARTS
    • B44FSPECIAL DESIGNS OR PICTURES
    • B44F9/00Designs imitating natural patterns
    • B44F9/04Designs imitating natural patterns of stone surfaces, e.g. marble
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65FGATHERING OR REMOVAL OF DOMESTIC OR LIKE REFUSE
    • B65F1/00Refuse receptacles; Accessories therefor
    • B65F1/04Refuse receptacles; Accessories therefor with removable inserts
    • B65F1/06Refuse receptacles; Accessories therefor with removable inserts with flexible inserts, e.g. bags or sacks
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65FGATHERING OR REMOVAL OF DOMESTIC OR LIKE REFUSE
    • B65F1/00Refuse receptacles; Accessories therefor
    • B65F1/14Other constructional features; Accessories
    • B65F1/141Supports, racks, stands, posts or the like for holding refuse receptacles
    • B65F1/1415Supports, racks, stands, posts or the like for holding refuse receptacles for flexible receptables, e.g. bags, sacks
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65FGATHERING OR REMOVAL OF DOMESTIC OR LIKE REFUSE
    • B65F1/00Refuse receptacles; Accessories therefor
    • B65F1/14Other constructional features; Accessories
    • B65F1/1468Means for facilitating the transport of the receptacle, e.g. wheels, rolls
    • B65F1/1473Receptacles having wheels
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65FGATHERING OR REMOVAL OF DOMESTIC OR LIKE REFUSE
    • B65F2210/00Equipment of refuse receptacles
    • B65F2210/18Suspending means
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65FGATHERING OR REMOVAL OF DOMESTIC OR LIKE REFUSE
    • B65F2220/00Properties of refuse receptacles
    • B65F2220/106Collapsible
    • B65F2220/1063Collapsible foldable
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00612Uses not provided for elsewhere in C04B2111/00 as one or more layers of a layered structure
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/54Substitutes for natural stone, artistic materials or the like
    • C04B2111/542Artificial natural stone
    • C04B2111/545Artificial marble

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Finishing Walls (AREA)

Abstract

Disclosed is an artificial marble used in an exterior or interior constructional material for buildings and a process for preparing the same. The artificial marble is prepared by use of a chip sheet, to have various design patterns at a surface thereof.

Description

Has artificial marble of multiple layout and preparation method thereof
Technical field
The present invention relates to a kind of artificial marble and preparation method thereof with kinds of surface layout.More specifically, the present invention relates to a kind of artificial marble with multiple exterior design and preparation method thereof, this method comprises: will use the exterior design plate of fragment to insert in the mould; Base binder paste is poured into the described exterior design plate of covering in this mould; By using vibrator to vibrate this mould to remove the bubble that in base binder paste, comprises; Be cured and on this moulded product, carry out surface treatment operations.
Background technology
Usually, prepare by the following method as the outside of buildings or the artificial marble of internal building material: multiple decorative chips is sneaked in the base binder paste, compacting or this mixture of casting, and at last resulting product is carried out surface treatment, so that the prepared artificial marble with granite exterior design to be provided.
But in the above-mentioned ordinary method that is used for preparing artificial marble, the problem of existence is that prepared artificial marble exists limitation when the multiple exterior design of performance.
As an example, Korean Patent discloses 2003-0081652 number and has disclosed a kind of double-deck building panel that has, and this plate is made of waste polyurethane substrate and marble layer.But it doesn't matter for disclosed building panel and artificial marble, and still do not exist and use chip sheet to prepare method for imitation marble as proposed by the present invention.
As another example, Korea patent registration has disclosed for No. 409084 a kind of for reducing the multilayer artificial marble plate that is used for the premade bath room wall that plastic flakes designs.But the disclosure patent does not still relate to uses chip sheet to prepare artificial marble.
Summary of the invention
Technical problem
Therefore, consider the problems referred to above and finished the present invention, and an object of the present invention is to provide artificial marble that has multiple exterior design and preparation method thereof.
Technical scheme
According to an aspect of the present invention, above-mentioned and other purpose can realize by a kind of artificial marble is provided, described artificial marble forms by using chip sheet, this chip sheet prepares as follows: with adhesive transfer to the base plate to have predetermined pattern, and fragment is sprinkling upon on this base plate so that these fragments stick on the pattern that is transferred on this base plate, wherein after this base plate was removed from artificial marble, described fragment was retained in the artificial marble with pattern.
Select tackiness agent to guarantee between described base plate and fragment, having enough binding propertys.Described tackiness agent can be for being selected from least a in the following material: polyvinyl chloride (PVC) colloidal sol, thermoset acrylic adhesive agent (thermosetting acryl adhesive), thermosetting epoxy resin tackiness agent, contain methyl methacrylate (MMA) colloidal sol of stiffening agent and contain unsaturated polyester (UPE) colloidal sol of stiffening agent.Described tackiness agent is that thermosetting adhesive is necessary, so that it at room temperature can not hardened, thereby guarantees to be enough at room temperature adhesive transfer to described base plate.
Described fragment can be for being selected from least a in the following material: resin chips comprises for example polymethylmethacrylate (PMMA) resin chips; By pulverizing the natural marble fragment that natural marble obtains; Glass fragment; Color chip and other can divide the fragment that spreads.
Described base plate must possess segregative character and surface grinding character, and can be paper film, resin molding, glassy membrane etc.Especially, this base plate is preferably made by polyethylene terephthalate (PET) film.
Described artificial marble is as the outside or the internal building material of buildings, and can comprise, for example acryl resin, unsaturated polyester resin or Resins, epoxy for based on cement or based on the artificial marble of resin.
According to a further aspect in the invention, provide a kind of preparation method for imitation marble, this method comprises: with adhesive transfer to the base plate to have predetermined pattern; Fragment is sprinkling upon on the base plate with the preparation chip sheet, and this chip sheet has the fragment that sticks on the pattern that is transferred on the base plate; By using this chip sheet to form artificial marble; With the described base plate of removal.
In order effectively to prepare described chip sheet, this method may further include: remove the unnecessary fragment that does not stick on the base plate after solidifying described chip sheet.
Can shift described tackiness agent by graining roll method, silk screen print method or embossing etc.
Preferably, form artificial marble by the following method: chip sheet is inserted in the mould; Be full of this mould with basic slurry; With bubble by using the vibrator removal in basic slurry, to comprise.
Described base plate can remove by peeling off this base plate after finishing in the formation of artificial marble, perhaps removes by carry out the surface grinding operation on the artificial marble that forms.
According to the present invention, in the method for imitation marble of outside that is used as buildings by applying pressure machine or vibrator preparation or internal building material, at first, spread the chip sheet that device prepares multiple pattern by using the fragment branch.Then, after being inserted into this chip sheet in the mould, fill up this mould with the preparation artificial marble with slurry.Resulting artificial marble carried out routine is solidified and surface treatment operations, with the multiple color and the layout of the artificial marble of the difference taste that obtains to satisfy the human consumer.
Description of drawings
From below in conjunction with will more being expressly understood above and other objects of the present invention, feature and other advantage the detailed description of accompanying drawing, wherein:
Fig. 1 explains the schema that is used to prepare according to method for imitation marble of the present invention;
Fig. 2 explains that preparation is used to provide the synoptic diagram according to the method for the chip sheet with required exterior design of artificial marble of the present invention;
Fig. 3 is the perspective illustration according to chip sheet of the present invention;
Fig. 4 explains the skeleton view that is used to prepare according to the detailed step of method for imitation marble of the present invention.
Embodiment
The present invention is now described with reference to the accompanying drawings in more detail.
Fig. 1 explains the schema that is used to prepare according to method for imitation marble of the present invention.As shown in the figure, describedly be used to prepare method for imitation marble and comprise Materials Measurement and filling operation, married operation, exterior design plate process operation, shaping operation, surface treatment operations and cutting/check/packaging operation.
Fig. 2 explains that preparation is used to provide the synoptic diagram according to the method for the chip sheet with required exterior design of artificial marble of the present invention; As described in Figure, at first, by plate feeding roller 10 charging base plates 70.
Base plate 70 is preferably the form of the film of being made by paper, resin, glass etc., and has pre-determined thickness.Base plate 70 must have segregative character and surface grinding character.Consider that the paper film gets wet easily, so base plate 70 is preferably made by the water-fast resin molding of for example polyethylene terephthalate (PET) etc.
Then, by use adhesive transfer device 20 with adhesive transfer to the base plate 70 to have predetermined pattern.Adhesive transfer device 20 can comprise graining roll with multiple pattern, print roller, embossing device (stamp) etc.
Described tackiness agent can be selected from the following material: polyvinyl chloride (PVC) colloidal sol, thermoset acrylic adhesive agent, thermosetting epoxy resin tackiness agent, contain methyl methacrylate (MMA) colloidal sol of stiffening agent and contain unsaturated polyester (UPE) colloidal sol etc. of stiffening agent.
After transferring to tackiness agent on the base plate 70 fully, be sprinkling upon on the base plate 70 by using the fragment branch to spread the various fragments 80 that device 30 will have different colours and size each other.
Fragment 80 can be selected from the resin chips of using polymethylmethacrylate (PMMA) resin, glass fragment, colored glass chips, can divide the fragment that spreads by the colored natural marble fragment pulverizing natural marble fragment that natural marble obtains, obtain by the natural marble fragment dyeing that makes pulverizing and other.
Subsequently, after by the resulting chip sheet of use drying installation 40 sclerosis, the fragment by using garbage collection device 50 to remove on the specific part that does not have applied adhesives that is sprinkling upon base plate 70 does not promptly have adherent fragment.Can obtain having the chip sheet of multiple layout in this way.The chip sheet of finishing is directed to plate and reclaims roller 60.
Fig. 3 is the perspective illustration of chip sheet, and illustrates a kind of exterior design, wherein a plurality of fragments 80 is sticked on the base plate 70 and produces mulle.Should be understood that, except the diagrammatic mulle, can produce various exterior design, and, the print roller of various patterns had and the fragment of various layouts can obtain other distinguishing layout by use.
Fig. 4 explains the skeleton view that is used to prepare according to the detailed step of method for imitation marble of the present invention.As shown in the figure, the chip sheet with multiple layout of preparation before is inserted into the bottom of forming mould 90, fragment 80 is faced up.
Then, after pouring into base binder paste 100 in the forming mould 90, make base binder paste 100 moulding in mould 90 by working pressure machine and vibrator.Here, vibrator is used for removing the bubble that comprises in base binder paste 100.
In the case, employed base binder paste 100 can be included in employed resin (acryl resin etc.) or cement slurry in the conventional artificial marble of preparation, and can selectedly have multiple color to satisfy the different tastes of human consumer.
At last, resulting moulded products is cured in proper order that operation, lock out operation and base plate are peeled off or conventional surface grinding operation to remove base plate 70, only stay fragment 80 simultaneously.Can prepare final artificial marble 11 in this way with multiple exterior design.In the present invention, as the result who removes base plate 70, final artificial marble 11 has only fragment 80 and does not have base plate 70.Therefore, by in conjunction with a plurality of fragments 80, final artificial marble 11 can realize multiple exterior design.
[embodiment 1]
By using colored glass chips and natural marble fragment to prepare a kind of artificial marble based on cement.
At first, after the star silk screen that will design in advance is placed on the PET film, PVC colloidal sol is poured on this silk screen.Then, silk screen is rolled, so that PVC colloidal sol is transferred on the PET film to have mulle with the rubber roll shaft.
Subsequently, after the colored glass chips that with diameter is 3mm~6mm is sprinkling upon on the PET film, shake this PET film to remove the unnecessary colored glass chips on those privileged sites of not using PVC colloidal sol that are sprinkling upon the PET film.Then, under 180 ℃ temperature, in baking oven, toasted the PET film about 5 minutes, so that PVC colloidal sol generation gelation.After the gelation of PVC colloidal sol was finished, removing once more by shake PET film did not have adherent colored glass chips.
Resulting PET plate is put into the mould of long 450mm, wide 450mm and thick 30mm, colored glass chips is faced up.Then, the base water material-mud is poured in the mould.In the case, based on the cement of 100 weight parts, employed cement slurry comprises that the diameter of 300~370 weight parts is the natural marble fragment of 1mm~9mm, the natural marble powder of 30~100 weight parts (No. 100~No. 350), the water of 25~35 weight parts and the water reducer of 1~3 weight part.
After pouring into cement slurry in the mould, used the vibrator swing die 1~5 minute, to remove the bubble that in cement slurry, comprises.Afterwards, under the condition of 40~50 ℃ temperature and constant humidity, cement slurry was solidified 12 hours.
After completely solidified,, carry out conventional grinding and cutting operation then, to obtain long 400mm, wide 400mm, thick 20mm and to have the artificial marble of stained glass mulle in its surface with formed cement slurry goods and mold separation.Should be noted in the discussion above that in grinding operation grinding the degree of depth must be less than the diameter of colored glass chips (less than 3mm~6mm).
Simultaneously, in order to satisfy human consumer's difference taste, to the exterior design of artificial marble without limits, and for the kind of the natural marble fragment that in cement slurry, uses also without limits.
Industrial applicibility
Can obviously find out from foregoing description, the invention provides a kind of artificial marble, it can use the chip sheet of various layouts to show distinguishing exterior design.Therefore, effect of the present invention not only is to provide the artificial marble of the exterior design with aesthetic feeling that satisfies the different tastes of human consumer, and is to have improved reliability of products.
Though disclose preferred implementation of the present invention for purpose of explanation, those of skill in the art will understand, under the situation that does not depart from disclosed scope of the present invention and essence in appended claims, have various improved procedures, addition manner and alternative.

Claims (11)

1, a kind of artificial marble, it forms by using chip sheet, described chip sheet prepares as follows: with adhesive transfer to the base plate to have predetermined pattern, and fragment is sprinkling upon on this base plate so that these fragments stick on the pattern that is transferred on this base plate, wherein after this base plate was removed from artificial marble, described fragment was retained in the artificial marble with pattern.
2, artificial marble according to claim 1, wherein, described tackiness agent is to be selected from least a in the following material: polyvinyl chloride (PVC) colloidal sol, thermoset acrylic adhesive agent, thermosetting epoxy resin tackiness agent, contain methyl methacrylate (MMA) colloidal sol of stiffening agent and contain unsaturated polyester (UPE) colloidal sol of stiffening agent.
3, artificial marble according to claim 1, wherein, described fragment is to be selected from least a in resin chips, natural marble fragment and the glass fragment.
4, artificial marble according to claim 1, wherein, described fragment is a color chip.
5, artificial marble according to claim 1, wherein, described base plate is paper film, resin molding or glassy membrane.
6, artificial marble according to claim 1, wherein, described artificial marble is based on cement or based on the artificial marble of resin.
7, a kind ofly be used to prepare method for imitation marble, it comprises:
With adhesive transfer to the base plate to have predetermined pattern;
Fragment is sprinkling upon on this base plate with the preparation chip sheet, and this chip sheet has the fragment that sticks on the pattern that is transferred on this base plate;
By using this chip sheet to form artificial marble; With
Remove described base plate.
8, method according to claim 7, it further comprises:
After solidifying described chip sheet, remove the unnecessary fragment that does not stick on the base plate.
9, method according to claim 7 wherein, shifts described tackiness agent by using graining roll, silk screen printing or embossing device.
10, method according to claim 7, wherein, described artificial marble forms by following steps:
Described chip sheet is inserted in the mould;
Fill up this mould with basic slurry; With
Remove the bubble that in described basic slurry, comprises by using vibrator.
11, method according to claim 7 wherein, removes this base plate by peeling off base plate after finishing in the formation of artificial marble, perhaps removes this base plate by carry out the surface grinding operation on the artificial marble that forms.
CN2007800503329A 2007-01-26 2007-12-17 Artificial marble having various designs and process for preparing the same Expired - Fee Related CN101589002B (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
KR1020070008311 2007-01-26
KR10-2007-0008311 2007-01-26
KR1020070008311A KR100888334B1 (en) 2007-01-26 2007-01-26 Artificial marble having various designs and process for preparing the same
PCT/KR2007/006586 WO2008091063A1 (en) 2007-01-26 2007-12-17 Artificial marble having various designs and process for preparing the same

Publications (2)

Publication Number Publication Date
CN101589002A true CN101589002A (en) 2009-11-25
CN101589002B CN101589002B (en) 2012-10-17

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EP (1) EP2132152A4 (en)
KR (1) KR100888334B1 (en)
CN (1) CN101589002B (en)
WO (1) WO2008091063A1 (en)

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CN116985419A (en) * 2023-09-26 2023-11-03 福建鹏翔实业有限公司 Device and method for processing artificial marble by adopting marble leftover materials
US11905714B1 (en) 2022-03-24 2024-02-20 Sawica International, LLC Mosaic tile assembly for installation on a floor or wall surface

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KR101285954B1 (en) * 2009-01-07 2013-07-12 (주)엘지하우시스 Artificial marble using chip of specific shape and process for preparing the same
KR101304149B1 (en) * 2010-09-27 2013-09-05 (주)엘지하우시스 Forming mold with dual structure and method of manufacturing exterior panel for household electric appliance using the forming mold
KR101255318B1 (en) * 2011-12-05 2013-04-15 우리산업기술개발 주식회사 Manufacturing Method for Artificial Stone with Porous Surface
CN104385566A (en) * 2014-09-23 2015-03-04 捷美特株式会社 Artificial marble with formed patterns, and manufacturing method thereof
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US20200047372A1 (en) * 2018-08-13 2020-02-13 Myeong Hwa Chung Artificial stone slab with integrally formed pattern and manufacturing method for the same
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Publication number Priority date Publication date Assignee Title
US11905714B1 (en) 2022-03-24 2024-02-20 Sawica International, LLC Mosaic tile assembly for installation on a floor or wall surface
CN116985419A (en) * 2023-09-26 2023-11-03 福建鹏翔实业有限公司 Device and method for processing artificial marble by adopting marble leftover materials
CN116985419B (en) * 2023-09-26 2023-12-15 福建鹏翔实业有限公司 Device and method for processing artificial marble by adopting marble leftover materials

Also Published As

Publication number Publication date
EP2132152A1 (en) 2009-12-16
KR100888334B1 (en) 2009-03-12
EP2132152A4 (en) 2010-01-20
WO2008091063A1 (en) 2008-07-31
KR20080070345A (en) 2008-07-30
CN101589002B (en) 2012-10-17

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