CN101585693B - 凹凸棒膏状蓄能发光涂料 - Google Patents
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Abstract
本发明公开了一种凹凸棒膏状蓄能发光涂料，其技术方案的要点是，凹凸棒膏状蓄能发光涂料是由膏状凹凸棒石粘土、硅丙乳液、铝酸锶、聚乙烯醇超细粉末、速溶硅酸钠、金红石型钛白粉、辛醇和去离子水组成。凹凸棒膏状蓄能发光涂料的生产方法是：配料、粉碎、搅拌、分散、溶解、均质、乳化、消泡、研磨、罐装为凹凸棒膏状蓄能发光涂料的成品。凹凸棒膏状蓄能发光涂料具有涂膜坚韧、附着力强、耐磨性能好、发光效果显著和施工方便的特点。采用凹凸棒膏状蓄能发光涂料制成的产品，受到日光或灯光激发后，处在夜间和暗处能够长时间的自动发光，具有良好的指示和装饰美化效果。适用于制作应急标牌、地名标牌和道路标线等需要发光的产品。
Description
技术领域
本发明涉及涂料，具体涉及一种凹凸棒膏状蓄能发光涂料。
背景技术
蓄能发光涂料是一种新型功能性涂料，在暗处可呈现良好的指示效果和美化效果，在应急标牌、通道标识、电源开关、搪瓷地名标牌、公路标识、玩具、工艺品、钟表、仪表盘、纺织品、消防设备、军事、野营设施等方面都有广泛的用途。
现有的蓄能发光涂料附着力较差，容易产生老化，耐水性、耐候性和耐冻融性能达不到设计要求。
中国专利授权公告号为：CN1208402，授权公告日：2005年6月29日，名称为“水性发光涂料及其制造方法”，公开了“一种水性发光涂料，是由高分子聚合物乳液、光致发光材料、助剂和水组成。是一种非放射性的、无毒无污染、具有高亮度发光功能的环保水性发光涂料，采用本发明的水性发光涂料，其制造工艺简单、性能稳定，可广泛应用在室内外装饰、指示标牌、公共场所的应急指示。”
上述专利的不足之处是该项技术中选用膨润土和凹凸棒土作为增稠剂，而膨润土和凹凸棒土中常伴生有石英、玻屑、沸石、方解石、长石、黄铁矿等杂质，对膨润土和凹凸棒土的化学成分以及工艺性能影响较大，没有经过提纯的膨润土和凹凸棒土的胶体粘度、分散性和悬浮性能都比较差，因此会影响到水性发光涂料的产品质量。
发明内容
本发明的目的是克服现有技术中不足之处，提供一种凹凸棒膏状蓄能发光涂料。
凹凸棒膏状蓄能发光涂料是由膏状凹凸棒石粘土、硅丙乳液、铝酸锶、聚乙烯醇超细粉末、速溶硅酸钠、金红石型钛白粉、辛醇和去离子水组成。
凹凸棒膏状蓄能发光涂料的生产方法是：配料、粉碎、搅拌、分散、溶解、均质、乳化、消泡、研磨、罐装为凹凸棒膏状蓄能发光涂料的成品。
凹凸棒石粘土是一种含水富镁纳米级多孔纤维状硅酸盐粘土矿物，当凹凸棒石粘土中的凹凸棒含量≥80％以上时，其比表面积较大，可达500m2/g以上。使用“凹凸棒的湿法选矿工艺”和“凹凸棒矿造浆生产工艺”，将凹凸棒石粘土中的水云母、石英、蛋白石和碳酸盐等矿物筛选去除掉，得到一种凹凸棒矿泥浆；经过钠化处理和酸化处理后的膏状凹凸棒石粘土，是一种触变性和胶黏性特好的天然硅酸镁铝凝胶，pH值呈中性，凹凸棒石粘土的粘度、膨胀容、胶质价、白度、比表面积、吸附性能和悬浮率都得到了较大的提高。
凹凸棒石粘土土质细腻，表面光滑，质地较轻，潮湿时呈粘性和可塑性，其粘度可达到3000mPa·s以上，有利于原料之间的粘结；凹凸棒石粘土干燥收缩率小，且不产生龟裂，能提高涂料对道路的附着力，膏状凹凸棒石粘土加入涂料溶液中，在外力搅拌下快速形成稳定的不分层的凝胶体，有较好的粘滞性和触变性，凹凸棒石粘土涂料涂膜的显微照片显示，其晶体呈网状排列，均匀地分布在涂料中，所以涂膜表面耐磨性能好。
硅丙乳液是丙烯酸酯类和有机硅单体接枝共聚合而成的水性乳液，成膜有较高的光泽，较佳的耐盐雾性，耐碱性、防腐性、极强的附着力，耐水性好，耐候优异等特点。
铝酸锶是一种粉末状蓄光发光材料，通过吸收各种可见光实现发光功能，尤其对450纳米以下的短波可见光具有很强的吸收能力，并可多次循环使用。
聚乙烯醇超细粉末，具有良好的冷水速溶性、优异的成膜性、较强的粘接性和渗透性，能提高凹凸棒膏状蓄能发光涂料的附着力和耐摩擦性能，防止涂料施工后产生粉化、龟裂和剥离。
速溶硅酸钠能快速溶解于水，加入凹凸棒膏状蓄能发光涂料后，能渗入缝隙和孔隙中，固化的硅凝胶能堵塞毛细孔通道，提高涂料的密度和强度，从而提高凹凸棒膏状蓄能发光涂料的抗风化能力和耐寒性。
金红石型钛白粉耐光性非常强，对涂料的装饰性、耐候性、耐化学稳定性等方面起着关键作用。
辛醇是一种消泡剂，辛醇加入凹凸棒膏状蓄能发光涂料后，通过降低水的表面张力来达到消泡作用，同时还能起到助溶剂的作用。
本发明通过下述技术方案予以实现：
1、凹凸棒膏状蓄能发光涂料的配料按重量百分比由下列组分组成：膏状凹凸棒石粘土10～50％、硅丙乳液10～35％、铝酸锶5～35％、聚乙烯醇超细粉末1～10％、速溶硅酸钠1～10％、金红石型钛白粉0.1～5％、辛醇0.01～1％和去离子水1～40％。
所述膏状凹凸棒石粘土的生产工艺是：(1)选用凹凸棒矿泥浆为主体原料，凹凸棒矿泥浆按重量百分比由下列组分组成：凹凸棒石粘土15～35％和水65～85％；(2)钠化处理：将凹凸棒矿泥浆输送到搅拌机内，添加氢氧化钠后进行搅拌，经过搅拌后的凹凸棒矿泥浆输送到钠化池中陈化1～7天；钠化配料按重量百分比由下列组分组成：凹凸棒矿泥浆95～99.5％和氢氧化钠0.5～5％；(3)酸化处理：将钠化后凹凸棒矿泥浆输送到搅拌机内，添加浓度为98％的硫酸后进行搅拌，经过搅拌后的凹凸棒矿泥浆输送到酸化池中陈化1～3天；酸化配料按重量百分比由下列组分组成：钠化后的凹凸棒矿泥浆92～99.5％和浓度为98％的硫酸0.5～8％；(4)水洗和筛去杂质：将酸化后的凹凸棒矿泥浆输送到沉淀池中，重新加水浸泡，用气泵冲翻，筛去杂质，沉淀后放出浸泡水，并将沉淀后的泥浆输送到成品池内，沉淀后的泥浆为膏状凹凸棒石粘土；水洗配料按重量百分比由下列组分组成：酸化后的凹凸棒矿泥浆25～65％和水35～75％；膏状凹凸棒石粘土按重量百分比由下列组分组成：凹凸棒石粘土5～40％和水60～95％。
上述生产工艺是采用由本发明人于2008年8月25日申请的“膏状凹凸棒石粘土的生产工艺”，中国专利公开号为：CN101348257，公开日：2009年1月21日。
所述凹凸棒矿造浆生产工艺是：将凹凸棒矿输入搅拌机内搅拌，经挤出机挤压成片状后，再次输入搅拌机内搅拌，经挤出机挤压成片状后自然晾晒，晾干的凹凸棒矿输送到原料池中浸泡，用气泵冲翻，沉淀后放出浸泡水，筛去杂质，输入半成品池中，重新加水浸泡，用气泵冲翻，沉淀后放出浸泡水，并将沉淀后的泥浆输送到成品池内，即为凹凸棒矿泥浆成品。
上述生产工艺是采用由本发明人于2004年1月6日申请的“凹凸棒矿造浆生产工艺”，中国专利授权公告号为：CN1287965C，授权公告日：2006年12月6日。
2、凹凸棒膏状蓄能发光涂料的生产方法：①将凹凸棒膏状蓄能发光涂料的配料加入粉碎打浆机内进行粉碎，粉碎打浆混合均匀后为凹凸棒膏状蓄能发光涂料的混合物；②将步骤①获得的混合物输入高粘度真空搅拌机中，凹凸棒膏状蓄能发光涂料的配料在真空下经过搅拌、分散、溶解、均质、乳化和消泡后为凹凸棒膏状蓄能发光涂料的半成品；③将步骤②获得的凹凸棒膏状蓄能发光涂料的半成品输入多功能胶体磨中进行研磨，颗粒细度小于0.015毫米，罐装为凹凸棒膏状蓄能发光涂料的成品。
凹凸棒膏状蓄能发光涂料具有涂膜坚韧、附着力强、耐磨性能好、发光效果显著和施工方便的特点。
采用凹凸棒膏状蓄能发光涂料制成的产品，受到日光或灯光激发后，处在夜间和暗处能够长时间的自动发光，具有良好的指示和装饰美化效果。
凹凸棒膏状蓄能发光涂料适用于制作应急标牌、地名标牌和道路标线等需要发光的产品。
具体实施方式
下面结合实施例对本发明作进一步的描述：
1、凹凸棒膏状蓄能发光涂料的配料按重量百分比由下列组分组成：膏状凹凸棒石粘土32％、硅丙乳液30％、铝酸锶22％、聚乙烯醇超细粉末4％、速溶硅酸钠超3％、金红石型钛白粉2.8％、辛醇0.2％和去离子水6％。
2、凹凸棒膏状蓄能发光涂料的生产方法：①将凹凸棒膏状蓄能发光涂料的配料加入粉碎打浆机内进行粉碎，粉碎打浆混合均匀后为凹凸棒膏状蓄能发光涂料的混合物；②将步骤①获得的混合物输入高粘度真空搅拌机中，凹凸棒膏状蓄能发光涂料的配料在真空下经过搅拌、分散、溶解、均质、乳化和消泡后为凹凸棒膏状蓄能发光涂料的半成品；③将步骤②获得的凹凸棒膏状蓄能发光涂料的半成品输入多功能胶体磨中进行研磨，颗粒细度小于0.015毫米，罐装为凹凸棒膏状蓄能发光涂料的成品。
Claims (1)
1.一种凹凸棒膏状蓄能发光涂料，其特征在于，凹凸棒膏状蓄能发光涂料的配料按重量百分比由下列组分组成：膏状凹凸棒石粘土10～50％、硅丙乳液10～35％、铝酸锶5～35％、聚乙烯醇超细粉末1～10％、速溶硅酸钠1～10％、金红石型钛白粉0.1～5％、辛醇0.01～1％和去离子水1～40％；
所述膏状凹凸棒石粘土的生产工艺是：(1)选用凹凸棒矿泥浆为主体原料，凹凸棒矿泥浆按重量百分比由下列组分组成：凹凸棒石粘土15～35％和水65～85％；(2)钠化处理：将凹凸棒矿泥浆输送到搅拌机内，添加氢氧化钠后进行搅拌，经过搅拌后的凹凸棒矿泥浆输送到钠化池中陈化1～7天；钠化配料按重量百分比由下列组分组成：凹凸棒矿泥浆95～99.5％和氢氧化钠0.5～5％；(3)酸化处理：将钠化后凹凸棒矿泥浆输送到搅拌机内，添加浓度为98％的硫酸后进行搅拌，经过搅拌后的凹凸棒矿泥浆输送到酸化池中陈化1～3天；酸化配料按重量百分比由下列组分组成：钠化后的凹凸棒矿泥浆92～99.5％和浓度为98％的硫酸0.5～8％；(4)水洗和筛去杂质：将酸化后的凹凸棒矿泥浆输送到沉淀池中，重新加水浸泡，用气泵冲翻，筛去杂质，沉淀后放出浸泡水，并将沉淀后的泥浆输送到成品池内，沉淀后的泥浆为膏状凹凸棒石粘土；水洗配料按重量百分比由下列组分组成：酸化后的凹凸棒矿泥浆25～65％和水35～75％；膏状凹凸棒石粘土按重量百分比由下列组分组成：凹凸棒石粘土5～40％和水60～95％；
所述凹凸棒矿造浆生产工艺是：将凹凸棒矿输入搅拌机内搅拌，经挤出机挤压成片状后，再次输入搅拌机内搅拌，经挤出机挤压成片状后自然晾晒，晾干的凹凸棒矿输送到原料池中浸泡，用气泵冲翻，沉淀后放出浸泡水，筛去杂质，输入半成品池中，重新加水浸泡，用气泵冲翻，沉淀后放出浸泡水，并将沉淀后的泥浆输送到成品池内，即为凹凸棒矿泥浆。
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| US5874491A (en) * | 1994-06-09 | 1999-02-23 | Anders; Irving | Phosphorescent highway paint composition |
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| CN1434088A (zh) * | 2003-02-13 | 2003-08-06 | 海洋化工研究院 | 水性蓄能发光涂料 |
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| US5874491A (en) * | 1994-06-09 | 1999-02-23 | Anders; Irving | Phosphorescent highway paint composition |
| CN1396220A (zh) * | 2001-07-13 | 2003-02-12 | 大连路明发光科技股份有限公司 | 水性发光涂料及其制造方法 |
| CN1434088A (zh) * | 2003-02-13 | 2003-08-06 | 海洋化工研究院 | 水性蓄能发光涂料 |
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