CN101580342B - Self-cleaning antibacterial ceramic glaze and preparation method and ceramic product thereof - Google Patents
Self-cleaning antibacterial ceramic glaze and preparation method and ceramic product thereof Download PDFInfo
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- CN101580342B CN101580342B CN2009100406300A CN200910040630A CN101580342B CN 101580342 B CN101580342 B CN 101580342B CN 2009100406300 A CN2009100406300 A CN 2009100406300A CN 200910040630 A CN200910040630 A CN 200910040630A CN 101580342 B CN101580342 B CN 101580342B
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- 239000000919 ceramic Substances 0.000 title claims abstract description 63
- 238000004140 cleaning Methods 0.000 title claims abstract description 29
- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 28
- 238000002360 preparation method Methods 0.000 title claims abstract description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 26
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 9
- 229910052700 potassium Inorganic materials 0.000 claims description 13
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 8
- 238000001914 filtration Methods 0.000 claims description 8
- 239000004579 marble Substances 0.000 claims description 8
- 239000011591 potassium Substances 0.000 claims description 8
- 239000004576 sand Substances 0.000 claims description 8
- 229910052709 silver Inorganic materials 0.000 claims description 8
- 239000001038 titanium pigment Substances 0.000 claims description 8
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 5
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 5
- 239000012535 impurity Substances 0.000 claims description 5
- 238000012216 screening Methods 0.000 claims description 5
- MQWCQFCZUNBTCM-UHFFFAOYSA-N 2-tert-butyl-6-(3-tert-butyl-2-hydroxy-5-methylphenyl)sulfanyl-4-methylphenol Chemical compound CC(C)(C)C1=CC(C)=CC(SC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O MQWCQFCZUNBTCM-UHFFFAOYSA-N 0.000 claims description 3
- 239000000203 mixture Substances 0.000 abstract description 6
- 210000003298 dental enamel Anatomy 0.000 abstract description 3
- 239000011521 glass Substances 0.000 abstract description 2
- 238000000034 method Methods 0.000 abstract description 2
- FUJCRWPEOMXPAD-UHFFFAOYSA-N Li2O Inorganic materials [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 abstract 1
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 abstract 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- 229910052681 coesite Inorganic materials 0.000 abstract 1
- 229910052593 corundum Inorganic materials 0.000 abstract 1
- 229910052906 cristobalite Inorganic materials 0.000 abstract 1
- XUCJHNOBJLKZNU-UHFFFAOYSA-M dilithium;hydroxide Chemical compound [Li+].[Li+].[OH-] XUCJHNOBJLKZNU-UHFFFAOYSA-M 0.000 abstract 1
- 235000012239 silicon dioxide Nutrition 0.000 abstract 1
- 229910052682 stishovite Inorganic materials 0.000 abstract 1
- 229910052905 tridymite Inorganic materials 0.000 abstract 1
- 229910001845 yogo sapphire Inorganic materials 0.000 abstract 1
- 238000010304 firing Methods 0.000 description 5
- 230000006870 function Effects 0.000 description 5
- 239000010936 titanium Substances 0.000 description 5
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 4
- 230000003115 biocidal effect Effects 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000010410 layer Substances 0.000 description 4
- 229910052719 titanium Inorganic materials 0.000 description 4
- 238000002156 mixing Methods 0.000 description 3
- 239000004332 silver Substances 0.000 description 3
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 230000003373 anti-fouling effect Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000002070 germicidal effect Effects 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000011941 photocatalyst Substances 0.000 description 2
- 230000001954 sterilising effect Effects 0.000 description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000005202 decontamination Methods 0.000 description 1
- 230000003588 decontaminative effect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000002114 nanocomposite Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000008447 perception Effects 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 230000035807 sensation Effects 0.000 description 1
- -1 silver ions Chemical class 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 238000007669 thermal treatment Methods 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 1
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Abstract
The invention discloses a self-cleaning antibacterial ceramic glaze and a preparation method and a ceramic product thereof. The key of the self-cleaning antibacterial ceramic glaze provided by the invention is that the ceramic glaze contains Ti element and Ag element. The ceramic glaze comprises the following components in percentage: 52-72% of SiO2, 5-9% of Al2O3, 6-10% of CaO, 2-6% of K2O, 0.5-1.5% of Na2O, 0.5-3% of ZnO, 1-3% of Li2O, 4-8% of Ti2O, 1-3% of V2O5 and 1-5% of Ag2O3. The ceramic product of the invention comprises a ceramic noumenon, which is characterized by containing a self-cleaning antibacterial ceramic glaze layer on the surface of the ceramic noumenon. The composition of the invention is suitable to be adopted in primary glazing process, and the surface of the ceramicglaze has high flatness, fined and delicate crystalloid, good smooth finish, no needle pole, extremely soft and good glass like and smooth in touch and reaches the self-cleaning antibacterial effect of ultra smooth glaze layer enamel.
Description
Technical field
The present invention relates to a kind of ceramic glaze and utilisation technology thereof.
Background technology
Traditional ceramics is main with white, and glaze only adopts zirconium silicate to play white effect, does not have other functions, and the traditional ceramics glaze is rough under reading lens, makes that dirt, bacterium are easy to hide, breed; Afterwards, after traditional ceramics is fired finished product, add the later stage thermal treatment of filming, and do not pass through high-temperature firing, the poor stability of filming is prone to peel off, and has finally lost the antifouling and antibiosis effect.
Chinese invention patent ZL02125311.0 discloses a kind of Nano self-cleaning overglaze sanitary ware that have, and its characteristics are that cover-coat enamel contains Ag
2O
3With the ZnO composite nano germicide, and be through twice glazing, once be fired into required sanitary ware.The sanitary ware of this invention, because cover-coat enamel contains nano composite material, its microcosmos area is even, smooth surface has the anti-soil antibacterial.But should invent owing to must pass through twice glazing, cost is higher.
Summary of the invention
The objective of the invention is to overcome the deficiency on the prior art, a kind of ceramic glaze with self-cleaning antibacterial function is provided.
Self-cleaning antibacterial ceramic glaze of the present invention, topmost characteristics are to contain Ti element and Ag element.It specifically consists of: SiO
252～72%, Al
2O
35～9%, CaO 6～10%, K
2O2～6%, Na
2O 0.5～1.5%, ZnO 0.5～3%, Li
2O 1～3%, TiO
24～8%, V
2O
51～3%, Ag
2O
31～5%.Percentage ratio is weight percentage.
Another object of the present invention provides the preparation method of above-mentioned self-cleaning antibacterial ceramic glaze, comprises the steps:
(1) with potassium felspar sand 37～45 weight %, marble 10～15 weight %, silica 35～40 weight %, antiseptic-germicide 2～4 weight % and white titanium pigment 5～8 weight % mix, and grind; The composition of said antiseptic-germicide is Ag
2O
3
(2) adopt vibratory screening apparatus to filter deironing;
(3) heavy dirty through 2～4 day time again after the deironing, make impurity sink to bottom, after filtering, make self-cleaning antibacterial ceramic glaze.
Further purpose of the present invention provides the ceramic product that utilizes above-mentioned self-cleaning antibacterial ceramic glaze to prepare.
One deck self-cleaning antibacterial ceramic glaze is fired on ceramic body surface at existing ceramic product, can obtain having the ceramic product of self-cleaning antibacterial function.The temperature of firing is preferably 1200～1270 ℃.
Compared with prior art, advantage of the present invention and beneficial effect are:
(1) self-cleaning antibacterial ceramic glaze of the present invention has been filled up the pin hole of traditional ceramics glaze owing to after having added titanium elements, float behind the titanium metal high temperature., after high temperature is arranged, make the spectrographic frequency produce and jump at glaze layer specific molecular, the atom electronic shell changes; Absorb airborne negatron; Produced that one deck is invisible to the naked eye, the hydroxide ion isolated protective layer of electronegative son also just formed the photocatalyst effect of titanium oxide; Decontamination, antibacterial ability have obtained performance, also have certain hydroxide ion antibacterial ability.
(2) self-cleaning antibacterial ceramic glaze of the present invention is owing to add silver element, and sterilizing ability heightens, and has dual antibiotic and sterilizing effect, and permanent action is in the glaze of product, thereby has antifouling, antibiotic, self-cleaning function.
(3) self-cleaning antibacterial ceramic glaze prescription of the present invention is suitable for adopting glazing process one time, has not singly simplified manufacture craft, has also reduced cost.
(4) self-cleaning antibacterial ceramic glaze of the present invention is fired behind the ceramic body surface, and the glaze surface evenness is high, and crystalloid is careful closely, smooth finish is good, free of pinholes, glass sense are extremely gentle splendid, and touch perception is very level and smooth.
Description of drawings
Fig. 1 is existing traditional ceramics product glaze electron microscope picture;
Fig. 2 is embodiment 1 a said ceramic product glaze electron microscope picture.
Embodiment
Embodiment 1
Prepare ceramic glaze by following proportioning: potassium felspar sand 39%, marble 11%, silica 38%, antiseptic-germicide 4%, white titanium pigment 8%.All be weight percentage.
(1) potassium felspar sand, marble, silica, antiseptic-germicide and white titanium pigment are mixed through ball mill, mill is 20 hours in ball mill;
(2) behind the uniform mixing, again through No. 3 vibratory screening apparatus filtrations, deironing;
(3) heavy dirty through 2 day time again after the deironing, make remaining small amount of impurities sink to low layer, after filtering, make the finished product ceramic glaze, through measuring, its composition and ratio are: SiO
252%, Al
2O
39%, CaO 10%, K
2O 6%, Na
2O 1%, ZnO 3%, Li
2O 3%, TiO
28%, V
2O
53%, Ag
2O
35%;
(4) the finished product ceramic glaze is sprayed on the ceramic idiosome through 1200 ℃ of high-temperature firings gets finished product again.
Utilize microscope that existing traditional ceramics product glaze is observed, result such as Fig. 1 find that traditional ceramics product glaze is uneven.
Utilize microscope that embodiment 1 said ceramic product glaze is observed, result such as Fig. 2 find that glaze is very uniform and smooth, can realize self-cleaning function.
Embodiment 2
Prepare ceramic glaze by following proportioning: potassium felspar sand 40%, marble 13%, silica 38%, antiseptic-germicide 4%, white titanium pigment 5%.All be weight percentage.
(1) potassium felspar sand, marble, silica, antiseptic-germicide and white titanium pigment are mixed through ball mill, mill is 26 hours in ball mill;
(2) behind the uniform mixing, again through No. 4 vibratory screening apparatus filtrations, deironing;
(3) heavy dirty through 3 day time again after the deironing, make remaining small amount of impurities sink to low layer, after filtering, make the finished product ceramic glaze, through measuring, its composition and ratio are: SiO
268%, Al
2O
38%, CaO 9%, K
2O 5%, Na
2O 0.5%, ZnO 0.5%, Li
2O 1%, TiO
26%, V
2O
51%, Ag
2O
31%;
(4) the finished product ceramic glaze is sprayed on the ceramic idiosome through 1270 ℃ of high-temperature firings gets finished product again.
Embodiment 3
Prepare ceramic glaze by following proportioning: potassium felspar sand 43%, marble 12%, silica 38%, antiseptic-germicide 2%, white titanium pigment 5%.All be weight percentage.
(1) potassium felspar sand, marble, silica, antiseptic-germicide and white titanium pigment are mixed through ball mill, mill is 24 hours in ball mill;
(2) behind the uniform mixing, again through No. 5 vibratory screening apparatus filtrations, deironing;
(3) heavy dirty through 4 day time again after the deironing, make remaining small amount of impurities sink to low layer, after filtering, make the finished product ceramic glaze, through measuring, its composition and ratio are: SiO
272%, Al
2O
35%, CaO 6%, K
2O 2%, Na
2O 1.5%, ZnO 2.5%, Li
2O 2%, TiO
24%, V
2O
52%, Ag
2O
33%;
(4) the finished product ceramic glaze is sprayed on the ceramic idiosome through 1260 ℃ of high-temperature firings gets finished product again.
The ceramic product of the prepared self-cleaning antibacterial ceramic glaze of embodiment 1～3; (1) from visually; The ceramic product of self-cleaning antibacterial ceramic glaze changed product in the past since ceramic glaze be prone to glaze in the zirconium particle react; Make glaze very tangible circular point-like occur, and the irregular phenomenon that on product, distributes, make glaze very smooth, careful; (2) from sense of touch, the sensation that the ceramic product of self-cleaning antibacterial ceramic glaze touches with hand is than product was smoothly very many in the past; (3) owing to added titanium elements in the self-cleaning antibacterial ceramic glaze, behind high temperature, absorbed airborne negatron; Formed the photocatalyst effect of titanium oxide, thereby filled up the pin hole of product surface in the past, made the overglaze density higher; Intensity also obtains increasing simultaneously; Thereby be difficult for drawing flower, and effectively isolate dirt, play self-cleaning action; (4) because self-cleaning antibacterial ceramic glaze has added two kinds of environmental protection materials such as titanium, silver simultaneously, harmless, and silver ions has and can play permanent antibiotic, germicidal action after high gentle the burning.
Claims (2)
1. self-cleaning antibacterial ceramic glaze is characterized in that said ceramic glaze is made up of following components in weight percentage: SiO
252～72%, Al
2O
35～9%, CaO 6～10%, K
2O 2～6%, Na
2O 0.5～1.5%, ZnO 0.5～3%, Li
2O 1～3%, TiO
24～8%, V
2O
51～3%, Ag
2O
31～5%.
2. the preparation method of the said self-cleaning antibacterial ceramic glaze of claim 1 is characterized in that may further comprise the steps:
(1) with potassium felspar sand 37～45 weight %, marble 10～15 weight %, silica 35～40 weight %, antiseptic-germicide 2～4 weight % and white titanium pigment 5～8 weight % mix, and grind;
(2) adopt vibratory screening apparatus to filter deironing;
(3) heavy dirty through 2～4 day time again after the deironing, make impurity sink to bottom, after filtering, make self-cleaning antibacterial ceramic glaze.
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|---|---|---|---|
| CN2009100406300A CN101580342B (en) | 2009-06-26 | 2009-06-26 | Self-cleaning antibacterial ceramic glaze and preparation method and ceramic product thereof |
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|---|---|---|---|
| CN2009100406300A CN101580342B (en) | 2009-06-26 | 2009-06-26 | Self-cleaning antibacterial ceramic glaze and preparation method and ceramic product thereof |
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| Publication Number | Publication Date |
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| CN101580342A CN101580342A (en) | 2009-11-18 |
| CN101580342B true CN101580342B (en) | 2012-01-25 |
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| CN109824352A (en) * | 2019-04-03 | 2019-05-31 | 福建省德化正和陶瓷有限公司 | A kind of highly effective nano antibiotic functional ceramic product and its manufacturing process |
| CN109970341B (en) * | 2019-04-23 | 2022-03-08 | 潮州市华利达陶瓷制作有限公司 | Antifouling antibacterial ceramic glaze and preparation method thereof |
| CN110128015A (en) * | 2019-04-26 | 2019-08-16 | 苏州工业园区职业技术学院 | A glaze-making method for increasing the flatness of the glaze surface |
| CN111233325A (en) * | 2020-02-27 | 2020-06-05 | 福建省德化县华瓷新材料科技有限公司 | Nano TiO (titanium dioxide)2Self-cleaning functional ceramic and preparation method and application thereof |
| CN112759258B (en) * | 2020-07-06 | 2022-06-17 | 蒙娜丽莎集团股份有限公司 | Antibacterial rock plate and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1333193A (en) * | 2001-05-30 | 2002-01-30 | 和成欣业股份有限公司 | Anti-dirt and anti-bacterial high-temp. ceramic glaze material ceramic glaze surfance and making method thereof |
| TW528741B (en) * | 2001-01-16 | 2003-04-21 | Hocheng Corp | High-temperature glaze with anti-dust and anti-bacteria functions, and the preparation thereof |
| CN1458128A (en) * | 2002-05-13 | 2003-11-26 | 福建省测试技术研究所 | Method for producing anti-bacteria ceramic |
| CN1524826A (en) * | 2003-02-05 | 2004-09-01 | 松下电器产业株式会社 | Oxide ceramic materials, ceramic substrates, ceramic laminate devices and power amplifier modules |
-
2009
- 2009-06-26 CN CN2009100406300A patent/CN101580342B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TW528741B (en) * | 2001-01-16 | 2003-04-21 | Hocheng Corp | High-temperature glaze with anti-dust and anti-bacteria functions, and the preparation thereof |
| CN1333193A (en) * | 2001-05-30 | 2002-01-30 | 和成欣业股份有限公司 | Anti-dirt and anti-bacterial high-temp. ceramic glaze material ceramic glaze surfance and making method thereof |
| CN1458128A (en) * | 2002-05-13 | 2003-11-26 | 福建省测试技术研究所 | Method for producing anti-bacteria ceramic |
| CN1524826A (en) * | 2003-02-05 | 2004-09-01 | 松下电器产业株式会社 | Oxide ceramic materials, ceramic substrates, ceramic laminate devices and power amplifier modules |
Non-Patent Citations (2)
| Title |
|---|
| 周桂欣.无机抗菌剂及抗菌陶瓷制品.《陶瓷研究与职业教育》.2003,第1卷(第3期),46-48. * |
| 邝钜炽,等.银-光触媒复合抗菌陶瓷的研究.《佛山陶瓷》.2004,(第12期),6-9. * |
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Address after: 515646, Guangdong Province, Chaoan County, Chaozhou County town of Phoenix floating village top Lake slice Patentee after: GUANGDONG AOLITAI CERAMIC INDUSTRIAL CO.,LTD. Address before: 515646, Guangdong Province, Chaoan County, Chaozhou County town of Phoenix floating village top Lake slice Patentee before: Chaozhou City Aolitai Industry Co.,Ltd. |