CN100408517C - Decoration glaze for inner wall tile and its prepn and detection method - Google Patents
Decoration glaze for inner wall tile and its prepn and detection method Download PDFInfo
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- CN100408517C CN100408517C CNB2006100365538A CN200610036553A CN100408517C CN 100408517 C CN100408517 C CN 100408517C CN B2006100365538 A CNB2006100365538 A CN B2006100365538A CN 200610036553 A CN200610036553 A CN 200610036553A CN 100408517 C CN100408517 C CN 100408517C
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- Prior art keywords
- frit
- glaze
- weight part
- titaniferous
- mineral materials
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Classifications
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/083—Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/083—Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound
- C03C3/085—Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound containing an oxide of a divalent metal
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/083—Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound
- C03C3/085—Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound containing an oxide of a divalent metal
- C03C3/087—Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound containing an oxide of a divalent metal containing calcium oxide, e.g. common sheet or container glass
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/089—Glass compositions containing silica with 40% to 90% silica, by weight containing boron
- C03C3/091—Glass compositions containing silica with 40% to 90% silica, by weight containing boron containing aluminium
- C03C3/093—Glass compositions containing silica with 40% to 90% silica, by weight containing boron containing aluminium containing zinc or zirconium
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/097—Glass compositions containing silica with 40% to 90% silica, by weight containing phosphorus, niobium or tantalum
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Ceramic Engineering (AREA)
- Glass Compositions (AREA)
Abstract
The present invention discloses one kind of decoration glaze for inner wall tile and its preparation process and test method on water permeating effect. The decoration glaze consists of mineral materials, including clay, zirconium silicate, ceramic stone powder, etc in 20-60 weight portions, and titanium containing clinker in 40-80 weight portions. Its material components include Li2O/Na2O/K2O 0.5-10 weigh portions, CaO 3-15 weigh portions, MgO 0.5-3.5 weigh portions, SiO2 55-80 weigh portions, Al2O3 5-25 weigh portions, B2O3 0.5-10 weigh portions, ZrO2 2.0-15 weigh portions, P2O5 0-10 weigh portions, TiO2 2-15 weigh portions, and BaO 2-15 weigh portions. Its preparation process includes the first preparing titanium containing clinker, mixing the titanium containing clinker with mineral materials and ball milling to 100-200 mesh. The decoration glaze for inner wall tile can result in beautiful artistic effect.
Description
Technical field
The present invention relates to the raw material and preparation method thereof and ceramic tile glaze detection method of ceramic, more particularly relate to a kind of cosmetic glaze and preparation method who is used for the internal wall brick base substrate, and the detection method of a kind of ceramic inner wall brick product glaze anti-(oozing) water effect.
Background technology
At present, before the general ceramic inner wall brick paving, certain hour need be soaked in water earlier, repave and be attached on the wall, can be on brick body glaze after so common paving produce the vestige of uneven water logging, thereby making that the ceramic tile glaze looks after the paving can produce ugly aberration, the reason that produces uneven water logging vestige after the ceramic inner wall brick paving on brick body glaze has two kinds usually, the one, water directly sees through cosmetic glaze layer and arrives under the cover-coat enamel, causes brick body glaze the water mark to occur; The 2nd, though seeing through cosmetic glaze layer, water do not arrive under the cover-coat enamel, the vestige of water sees through cosmetic glaze layer and cover coat, causes brick body glaze the water logging vestige to occur.At the solution of this problem, also do not retrieve relevant patent.In addition, whether possess anti-(oozing) water effect at the ceramic tile glaze, each ceramic tile manufacturer does not yet have unified detection method and judgment criteria at present.
Summary of the invention
The objective of the invention is in order to solve above-mentioned deficiency, and a kind of water-fast dipping that is used for the internal wall brick base substrate is provided and can produce the cosmetic glaze and the preparation method of water logging vestige at the ceramic tile glaze, another object of the present invention also needs to be to provide the detection method of a kind of ceramic inner wall brick product glaze anti-(oozing) water effect.
The present invention realizes above-mentioned purpose by following technical solution: it is to utilize present middle screening effect and the best titanium dioxide of devitrification effect in all milkiness phases to prepare titanium milkiness frit, utilize this frit to be mixed with ceramic tile cosmetic glaze layer then according to arrange in pairs or groups part raw mineral materials or other frit and clay of the firing condition of ceramics factory, reach fully after allowing cosmetic glaze layer burn on the one hand and do not absorb water, making water can not see through cosmetic glaze layer arrives under the cover-coat enamel, on the other hand, screening effect and devitrification effect that cosmetic glaze layer is had because of titanium milkiness frit, can be so that the vestige of water can't see through cosmetic glaze layer and cover coat, thus make the ceramic tile glaze reach complete waterproof effect.
The concrete technical solution that the present invention adopts is as follows:
A kind of cosmetic glaze that is used for the internal wall brick base substrate is characterized in that, is made of raw mineral materials and titaniferous frit, and its component and proportioning are: the mixture that 40～80 weight part titaniferous frits, 60～20 weight parts are made into by definite composition by raw mineral materials; This raw mineral materials includes clay, zirconium silicate, stone flour, silica powder, barium carbonate, aluminum oxide powder, Feldspar Powder and burning talcum powder, and wherein, stone flour is porcelain stone powder or pottery stone powder.
Wherein the chemical constitution of the mixture that is made into of raw mineral materials is: the Li of 0～10 weight part
2O/Na
2O/K
2O, the MgO of 0～10 weight part, the SiO of 50～80 weight parts
2, the Al of 5～25 weight parts
2O
3, the ZrO of 2.0～15 weight parts
2, the BaO of 0～15 weight part.
Titaniferous frit wherein, the coefficient of expansion is 190～230, is made of following chemical constitution: 2.0～10 weight part Li
2O/Na
2O/K
2O, 5～18 weight part CaO, 0～5 weight part MgO, 50～75 weight part SiO
2, 3～12 weight part Al
2O
3, 0～10 weight part B
2O
3, 0～12 weight part ZrO
2, 0～10 weight part P
2O
5, 3～18 weight part TiO
2, 0～3.0 weight part BaO.
A kind of cosmetic glaze preparation method who is used for the internal wall brick base substrate, its preparation process is, at first prepare the titanium frit, by above-mentioned titanium frit prescription batching, place in the mixing machine to mix, deliver to frit and found in the kiln, found into the melten glass shape through 1380 ℃～1600 ℃, become the granular or sheet of glass through shrend again, then with the titanium frit directly and other epipastic mineral raw materials be used by prescription; Or titanium frit elder generation ball milling become 100～200 order powderies, again with other epipastic mineral raw materials by cooperating, put into through the user and can use after ball mill is ground to certain fineness.
Simultaneously, detection at tile product glaze anti-(oozing) water effect, detection mode provided by the invention is: the plastic cylinder of a diameter 30mm size, height 30mm is placed the adobe back side, and use plasticine or Vaseline with its periphery sealing, and injecting the Methylene blue aqueous solution of 1g/500ml concentration then from opening part, the liquid level height is 30mm, after leaving standstill certain hour, pour out the Methylene blue aqueous solution, visual observation adobe glaze sees if there is vestige and occurs.Judge mode and standard are: by testing with upper type, time of repose is 30 minutes, and glaze does not have any vestige, and it is qualified to be.
The beneficial effect that the present invention adopts above-mentioned technical solution to reach is:
The ceramic internal wall brick of production of the present invention to wall, is not seen water logging vestige from brick body glaze through the water logging paving, thereby keeps the artistic attractive in appearance of ceramic tile.
Embodiment
The cosmetic glaze that is used for the internal wall brick base substrate of the present invention, be made of raw mineral materials such as clay or ball clay or calcined clay, zirconium silicate, porcelain stone powder or pottery stone powder, silica powder, barium carbonate, aluminum oxide powder, Feldspar Powder and burning talcum powder etc. and titaniferous frit, component during use and proportioning are: 60 weight part titaniferous frits, 40 weight parts by above-mentioned raw mineral materials by the above-mentioned mixture that is made into of forming.
In more than forming, the chemical constitution of the mixture that raw mineral materials is made into is: the Li of 5 weight parts
2O/Na
2O/K
2The SiO of the MgO of O, 3 weight parts, 60 weight parts
2, 10 weight parts Al
2O
3, 5 weight parts ZrO
2, 6 weight parts BaO.
In more than forming, the coefficient of expansion of titaniferous frit is 170～260, is made up of following chemical composition: 2.0 weight part K
2O, 5 weight part CaO, 0.5 weight part MgO, 67 weight part SiO
2, 10 weight part Al
2O
3, 5 weight part B
2O
3, 4 weight part ZrO
2, 3 weight part P
2O
5, 5 weight part TiO
2, 1.5 weight part BaO.
Its preparation process is, at first prepares the titanium frit, by above-mentioned titanium frit prescription batching, places in the stirrer to mix, and is delivered to frit and founds in the kiln, founds through 1380 ℃～1600 ℃ to become to melt glassy, becomes the granular or sheet of glass through shrend again; Secondly titanium frit ball milling is become 100～200 order powderies, then with other epipastic mineral raw materials by the prescription batching after, in stirrer, mix and get final product.
The present invention also has another embodiment, be made of raw mineral materials such as clay or ball clay or calcined clay, zirconium silicate, porcelain stone powder or pottery stone powder, silica powder, barium carbonate, aluminum oxide powder, Feldspar Powder and burning talcum powder etc. and titaniferous frit, component during use and proportioning are: the mixture that 70 weight part titaniferous frits, 30 weight parts are made into by definite composition by above-mentioned raw mineral materials.
In more than forming, the chemical composition of the mixture that raw mineral materials is made into is: the Li of 3 weight parts
2O/Na
2O/K
2O, the MgO of 7 weight parts, the SiO of 65 weight parts
2, the Al of 5 weight parts
2O
3, the ZrO of 10 weight parts
2, the BaO of 8 weight parts.
In more than forming, the coefficient of expansion of titaniferous frit is 170～260, is made of 4 weight part Na following chemical composition
2O, 6 weight part CaO, 0.3 weight part MgO, 60 weight part SiO
2, 6 weight part Al
2O
3, 4 weight part B
2O
3, 4 weight part ZrO
2, 5 weight part P
2O
5, 14 weight part TiO
2, 1.7 weight part BaO.
Its preparation method as mentioned above.
During use, with cosmetic glaze of the present invention to suitable quantity of water, place the ball mill endosphere to wear into the glaze slip that requires fineness, then this glaze slip is coated ceramic tile base surface, again at its surface coated pottery cover-coat enamel, add coloured silk, drying, burnt till fast through 1000～1160 ℃, 30～120 minutes and can become ceramic tile through general ceramic tile production process.
Use the tile product of cosmetic glaze of the present invention, the detection mode of its glaze anti-(oozing) water effect is: the plastic cylinder of a diameter 30mm size, height 30mm is placed the adobe back side, and use plasticine or Vaseline with its periphery sealing, inject the Methylene blue aqueous solution of 1g/500ml concentration then from opening part, the liquid level height is 30mm, leave standstill certain hour after, pour out the Methylene blue aqueous solution, visual observation adobe glaze sees if there is vestige and occurs.Judge mode and standard are: by testing with upper type, time of repose is 30 minutes, and glaze does not have any vestige, and it is qualified to be.
Claims (5)
1. a cosmetic glaze that is used for the internal wall brick base substrate is characterized in that, it is made of raw mineral materials and titaniferous frit, and its component and proportioning (weight part) are: the mixture that 40～80 titaniferous frits, 60～20 are made into by definite composition by raw mineral materials; This raw mineral materials includes clay, zirconium silicate, stone flour, silica powder, barium carbonate, aluminum oxide powder, Feldspar Powder and burning talcum powder, and wherein, stone flour is porcelain stone powder or pottery stone powder.
2. a kind of cosmetic glaze that is used for the internal wall brick base substrate according to claim 1 is characterized in that described clay is ball clay or calcined clay.
3. a kind of cosmetic glaze that is used for the internal wall brick base substrate according to claim 1 is characterized in that the chemical constitution of described raw mineral materials (weight part) is:
Li
2O/Na
2O/K
2O 0～10 MgO 0～10
SiO
2 50～80 Al
2O
3 5～25
ZrO
2 2.0～15 BaO 0～15；
The coefficient of expansion of described titaniferous frit is 190～230, and its chemical constitution (weight part) is:
Li
2O/Na
2O/K
2O 2.0～10 CaO 5～18
MgO 0～5 SiO
2 50～75
Al
2O
3 3～12 B
2O
3 0～10
ZrO
2 0～12 P
2O
5 0～10
TiO
2 3～18 BaO 0～3.0。
4. one kind prepares each described preparation method who is used for the cosmetic glaze of internal wall brick base substrate of claim 1-3, it is characterized in that these preparation method's concrete steps are:
A, at first prepare the titaniferous frit,, place in the mixing machine to mix, deliver to frit and found in the kiln, found into the melten glass shape through 1380 ℃～1600 ℃, become the granular or sheet of glass through shrend with forming the component prescription batching of titaniferous frit;
Secondly b, be (40～80) by weight with the mixture that raw mineral materials is made into directly with the titanium frit: (60～20) ratio cooperates and gets final product.
5. the preparation method who is used for the cosmetic glaze of internal wall brick base substrate according to claim 4, it is characterized in that, in the described b step, titanium frit elder generation ball milling can be become 100～200 order powderies, then with other epipastic mineral composition of raw materials batching, in stirrer, mix and get final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006100365538A CN100408517C (en) | 2006-07-18 | 2006-07-18 | Decoration glaze for inner wall tile and its prepn and detection method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006100365538A CN100408517C (en) | 2006-07-18 | 2006-07-18 | Decoration glaze for inner wall tile and its prepn and detection method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1887812A CN1887812A (en) | 2007-01-03 |
| CN100408517C true CN100408517C (en) | 2008-08-06 |
Family
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|---|---|---|---|
| CNB2006100365538A Active CN100408517C (en) | 2006-07-18 | 2006-07-18 | Decoration glaze for inner wall tile and its prepn and detection method |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101665346B (en) * | 2009-09-14 | 2012-06-20 | 佛山红狮陶瓷有限公司 | Manufacturing method of ceramic tiles with metallic luster |
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| CN101786905A (en) * | 2010-03-23 | 2010-07-28 | 咸阳天隆玻璃制品有限公司 | High-aluminum fusion cake for high initial-melting temperature ceramic glaze |
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| CN102584344A (en) * | 2012-01-19 | 2012-07-18 | 星谊精密陶瓷科技（昆山）有限公司 | Water seepage prevention ground coat and preparation method thereof |
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| CN103570380B (en) * | 2013-11-14 | 2014-10-01 | 广东三水大鸿制釉有限公司 | Wear-resistant antiskid glaze and preparation method thereof as well as preparation method of wear-resistant antiskid tile |
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| CN110482861A (en) * | 2019-09-16 | 2019-11-22 | 陕西理工大学 | The method that vanadium titano-magnetite tailing prepares preparing ceramic clinker glaze |
| CN112390533A (en) * | 2020-11-25 | 2021-02-23 | 珠海市斗门区旭日陶瓷有限公司 | Highlight brick and production process thereof |
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|---|---|---|---|---|
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| KR910005051B1 (en) * | 1988-12-05 | 1991-07-22 | 박영식 | Glaze composition |
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2006
- 2006-07-18 CN CNB2006100365538A patent/CN100408517C/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5537418A (en) * | 1978-09-02 | 1980-03-15 | Nippon Fueroo Kk | Silver-luster glaze |
| CN1031518A (en) * | 1987-08-22 | 1989-03-08 | 国家建筑材料工业局山东工业陶瓷研究设计院 | Titania milky glaze for making glazed brick |
| KR910005051B1 (en) * | 1988-12-05 | 1991-07-22 | 박영식 | Glaze composition |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101665346B (en) * | 2009-09-14 | 2012-06-20 | 佛山红狮陶瓷有限公司 | Manufacturing method of ceramic tiles with metallic luster |
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| CN1887812A (en) | 2007-01-03 |
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