CN110482861A - The method that vanadium titano-magnetite tailing prepares preparing ceramic clinker glaze - Google Patents
The method that vanadium titano-magnetite tailing prepares preparing ceramic clinker glaze Download PDFInfo
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- CN110482861A CN110482861A CN201910872265.3A CN201910872265A CN110482861A CN 110482861 A CN110482861 A CN 110482861A CN 201910872265 A CN201910872265 A CN 201910872265A CN 110482861 A CN110482861 A CN 110482861A
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- CN
- China
- Prior art keywords
- glaze
- vanadium titano
- preparing ceramic
- magnetite tailing
- ceramic clinker
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
Abstract
The invention discloses a kind of methods that vanadium titano-magnetite tailing prepares preparing ceramic clinker glaze, vanadium titano-magnetite tailing, correction material and decolorising agent are first weighed by a certain percentage, the fusing of gas furnace high temperature is packed into after ball milling, it gained glaze high-temp liquid is placed in frit cuts and cut rapid cooling clamp dog in fast cool equipment, the finally grinding in vertical mill finally obtains preparing ceramic clinker glaze.The method has Composition Control precision height, and technology stability and repeatability are relatively strong, it can be achieved that the fine application of vanadium titano-magnetite tailing and high usage.
Description
Technical field
The present invention relates to glaze preparation technical field, in particular to a kind of vanadium titano-magnetite tailing prepares preparing ceramic clinker glaze
Method.
Background technique
The ingredient of vanadium titano-magnetite tailing is more complex, it is made to be dfficult to apply to fine materials, and using when need to add
Correction material ratio it is higher, reduce its utilization rate.Therefore, a kind of new method is found, the fine of vanadium titano-magnetite tailing is improved
It is most important to improve its utilization rate for Material Field application value.
It is cut by high temperature melting, melt and cuts fast cold treatment and vertical grinding, sufficiently improve the fine of vanadium titano-magnetite tailing
Material Field application value is the key means for improving its utilization rate.
Summary of the invention
It is difficult to be effectively improved the fine materials field application value of vanadium titano-magnetite tailing the present invention be directed to common approach
The research and development field status of problem provides a kind of method that vanadium titano-magnetite tailing prepares preparing ceramic clinker glaze.
To achieve the above objectives, the present invention, which adopts the following technical scheme that, is achieved:
A kind of method that vanadium titano-magnetite tailing prepares preparing ceramic clinker glaze, comprising the following steps:
1) gas furnace is packed into after taking vanadium titano-magnetite tailing, correction material and decolorising agent to obtain mixed-powder, then ball milling
Middle fusing obtains glaze liquid；Correction material includes silica, calcium carbonate, sodium carbonate, and decolorising agent is ceria, vanadium titanium magnetic
Iron ore mine, silica, calcium carbonate, sodium carbonate and ceria mass percent be (77.7~85.2): (8.6~
12.4): (2.3~4.2): (2.8~4.1): (1.1~1.6)；
2) it glaze liquid is placed in frit cuts and cut rapid cooling clamp dog in fast cool equipment, finally the grinding in vertical mill, finally obtains
Preparing ceramic clinker glaze.
As a further improvement of the present invention, mixed-powder ball milling use agitating ball mill, 50~70 turns of rotational speed of ball-mill/
Point.
As a further improvement of the present invention, 1510~1580 DEG C of fusion temperature.
As a further improvement of the present invention, cut cut fast cool equipment cut cut frequency be 1~2,89~95 DEG C of fast speed of cooling/
Point, the type of cooling is 0.5 DEG C of water cooling.
As a further improvement of the present invention, 30~40 revs/min of the vertical mill speed of mainshaft, 110~130 meters of air blast wind speed/
Second.
As a further improvement of the present invention, the average particle size of preparing ceramic clinker glaze material obtained is less than or equal to 3 μm, pine dress
Density is more than or equal to 3.53g/cm3, compressive strength is more than or equal to 240MPa, and shear strength is more than or equal to 450MPa.
Compared with prior art, the invention has the characteristics that and advantage:
The present invention first weighs vanadium titano-magnetite tailing, correction material and decolorising agent by a certain percentage, is packed into after ball milling natural
The fusing of steam stove high temperature, is placed in frit for gained glaze high-temp liquid and cuts and cut rapid cooling clamp dog in fast cool equipment, finally in vertical mill
Grinding；Wherein frit, which is cut, cuts fast cold treatment and accurately controls clinker quality, and by the prefabricated frit internal stress of rapid cooling, improves grinding
Efficiency.Vertical mill is conducive to control properties of powder performace and recycles gas furnace fume afterheat, energy-efficient.It is produced by the present invention
The average particle size of preparing ceramic clinker glaze material is less than or equal to 3 μm, and apparent density is more than or equal to 3.53g/cm3, compressive strength be greater than etc.
In 240MPa, shear strength is more than or equal to 450MPa.The method has Composition Control precision high, technology stability and repeatability compared with
By force, it can be achieved that the fine application of vanadium titano-magnetite tailing and high usage.
Further, during preparing preparing ceramic clinker glaze, the present invention is to solve existing method to be difficult to be effectively improved vanadium titanium magnetic
The problem of fine materials field application value of iron ore mine, but use a kind of high temperature melting, melt cut cut fast cold treatment with
Vertical grinding process, researching high-temperature melting process, melt, which are cut, cuts fast cold treatment method, vertical grinding process and preparing ceramic clinker glaze
The relationship of energy, it may be assumed that for preparing ceramic clinker glaze, the best high temperature melting technique of superior performance, melt is kept to cut and cut fast cold treatment side
Method, vertical grinding process.
Specific embodiment
A kind of method that vanadium titano-magnetite tailing prepares preparing ceramic clinker glaze of the present invention, includes the following steps:
(1) by mass percentage (77.7~85.2): (8.6~12.4): (2.3~4.2): (2.8~4.1): (1.1~
1.6) vanadium titano-magnetite tailing, silica, calcium carbonate, sodium carbonate and ceria are weighed, is packed into natural gas after stirring ball-milling
The fusing of furnace high temperature, 50~70 revs/min of the ball mill speed of mainshaft, 1510~1580 DEG C of the high temperature melting temperature of powder obtains glaze
High-temp liquid；
(2) it glaze high-temp liquid is placed in frit cuts and cut rapid cooling clamp dog in fast cool equipment, cut and cut cutting for fast cool equipment and cut frequency
It is 1~2,89~95 DEG C/minute of fast speed of cooling, the type of cooling is 0.5 DEG C of water cooling, finally the grinding in vertical mill, the speed of mainshaft 30
~40 revs/min, 110~130 meter per second of air blast wind speed finally obtains preparing ceramic clinker glaze.
Embodiment 1
(1) 79.9:12.4:3.3:2.8:1.6 weighs vanadium titano-magnetite tailing, silica, carbonic acid by mass percentage
Calcium, sodium carbonate and ceria, are packed into the fusing of gas furnace high temperature after stirring ball-milling, and 50 revs/min of the ball mill speed of mainshaft, powder
1510 DEG C of high temperature melting temperature of end, obtain glaze high-temp liquid；
(2) it glaze high-temp liquid is placed in frit cuts and cut rapid cooling clamp dog in fast cool equipment, cut and cut cutting for fast cool equipment and cut frequency
It is 2,89 DEG C/minute of fast speed of cooling, the type of cooling is 0.5 DEG C of water cooling, finally the grinding in vertical mill, 30 revs/min of the speed of mainshaft, drum
110 meter per second of wind wind speed, finally obtains preparing ceramic clinker glaze.
Embodiment 2
(1) 80.9:11.4:3.3:2.8:1.6 weighs vanadium titano-magnetite tailing, silica, carbonic acid by mass percentage
Calcium, sodium carbonate and ceria, are packed into the fusing of gas furnace high temperature after stirring ball-milling, and 55 revs/min of the ball mill speed of mainshaft, powder
1520 DEG C of high temperature melting temperature of end, obtain glaze high-temp liquid；
(2) it glaze high-temp liquid is placed in frit cuts and cut rapid cooling clamp dog in fast cool equipment, cut and cut cutting for fast cool equipment and cut frequency
It is 2,90 DEG C/minute of fast speed of cooling, the type of cooling is 0.5 DEG C of water cooling, finally the grinding in vertical mill, 32 revs/min of the speed of mainshaft, drum
115 meter per second of wind wind speed, finally obtains preparing ceramic clinker glaze.
Embodiment 3
(1) 80.9:11.4:3.3:3.3:1.1 weighs vanadium titano-magnetite tailing, silica, carbonic acid by mass percentage
Calcium, sodium carbonate and ceria, are packed into the fusing of gas furnace high temperature after stirring ball-milling, and 60 revs/min of the ball mill speed of mainshaft, powder
1530 DEG C of high temperature melting temperature of end, obtain glaze high-temp liquid；
(2) it glaze high-temp liquid is placed in frit cuts and cut rapid cooling clamp dog in fast cool equipment, cut and cut cutting for fast cool equipment and cut frequency
It is 2,90 DEG C/minute of fast speed of cooling, the type of cooling is 0.5 DEG C of water cooling, finally the grinding in vertical mill, 34 revs/min of the speed of mainshaft, drum
130 meter per second of wind wind speed, finally obtains preparing ceramic clinker glaze.
Embodiment 4
(1) 80.1:11.4:4.1:3.3:1.1 weighs vanadium titano-magnetite tailing, silica, carbonic acid by mass percentage
Calcium, sodium carbonate and ceria, are packed into the fusing of gas furnace high temperature after stirring ball-milling, and 65 revs/min of the ball mill speed of mainshaft, powder
1540 DEG C of high temperature melting temperature of end, obtain glaze high-temp liquid；
(2) it glaze high-temp liquid is placed in frit cuts and cut rapid cooling clamp dog in fast cool equipment, cut and cut cutting for fast cool equipment and cut frequency
It is 2,92 DEG C/minute of fast speed of cooling, the type of cooling is 0.5 DEG C of water cooling, finally the grinding in vertical mill, 36 revs/min of the speed of mainshaft, drum
130 meter per second of wind wind speed, finally obtains preparing ceramic clinker glaze.
The performance parameter that Examples 1 to 4 prepares preparing ceramic clinker glaze is shown in Table 1:
Table 1
From upper table, it can be concluded that, the average particle size of preparing ceramic clinker glaze material produced by the present invention is less than or equal to 3 μm, and pine fills close
Degree is more than or equal to 3.53g/cm3, compressive strength is more than or equal to 240MPa, and shear strength is more than or equal to 450MPa.
Embodiment 5
(1) 81.1:11.4:3.1:3.3:1.1 weighs vanadium titano-magnetite tailing, silica, carbonic acid by mass percentage
Calcium, sodium carbonate and ceria, are packed into the fusing of gas furnace high temperature after stirring ball-milling, and 70 revs/min of the ball mill speed of mainshaft, powder
1550 DEG C of high temperature melting temperature of end, obtain glaze high-temp liquid；
(2) it glaze high-temp liquid is placed in frit cuts and cut rapid cooling clamp dog in fast cool equipment, cut and cut cutting for fast cool equipment and cut frequency
It is 2,95 DEG C/minute of fast speed of cooling, the type of cooling is 0.5 DEG C of water cooling, finally the grinding in vertical mill, 40 revs/min of the speed of mainshaft, drum
130 meter per second of wind wind speed, finally obtains preparing ceramic clinker glaze.
Embodiment 6
(1) 81.1:11.9:3.1:2.8:1.1 weighs vanadium titano-magnetite tailing, silica, carbonic acid by mass percentage
Calcium, sodium carbonate and ceria, are packed into the fusing of gas furnace high temperature after stirring ball-milling, and 70 revs/min of the ball mill speed of mainshaft, powder
1580 DEG C of high temperature melting temperature of end, obtain glaze high-temp liquid；
(2) it glaze high-temp liquid is placed in frit cuts and cut rapid cooling clamp dog in fast cool equipment, cut and cut cutting for fast cool equipment and cut frequency
It is 2,95 DEG C/minute of fast speed of cooling, the type of cooling is 0.5 DEG C of water cooling, finally the grinding in vertical mill, 40 revs/min of the speed of mainshaft, drum
130 meter per second of wind wind speed, finally obtains preparing ceramic clinker glaze.
Embodiment 7
(1) 83.1:9.9:3.1:2.8:1.1 weighs vanadium titano-magnetite tailing, silica, carbonic acid by mass percentage
Calcium, sodium carbonate and ceria, are packed into the fusing of gas furnace high temperature after stirring ball-milling, and 58 revs/min of the ball mill speed of mainshaft, powder
1560 DEG C of high temperature melting temperature of end, obtain glaze high-temp liquid；
(2) it glaze high-temp liquid is placed in frit cuts and cut rapid cooling clamp dog in fast cool equipment, cut and cut cutting for fast cool equipment and cut frequency
It is 2,94 DEG C/minute of fast speed of cooling, the type of cooling is 0.5 DEG C of water cooling, finally the grinding in vertical mill, 37 revs/min of the speed of mainshaft, drum
120 meter per second of wind wind speed, finally obtains preparing ceramic clinker glaze.
Embodiment 8
(1) 83.4:9.9:2.8:2.8:1.1 weighs vanadium titano-magnetite tailing, silica, carbonic acid by mass percentage
Calcium, sodium carbonate and ceria, are packed into the fusing of gas furnace high temperature after stirring ball-milling, and 70 revs/min of the ball mill speed of mainshaft, powder
1570 DEG C of high temperature melting temperature of end, obtain glaze high-temp liquid；
(2) it glaze high-temp liquid is placed in frit cuts and cut rapid cooling clamp dog in fast cool equipment, cut and cut cutting for fast cool equipment and cut frequency
It is 2,95 DEG C/minute of fast speed of cooling, the type of cooling is 0.5 DEG C of water cooling, finally the grinding in vertical mill, 39 revs/min of the speed of mainshaft, drum
130 meter per second of wind wind speed, finally obtains preparing ceramic clinker glaze.
Embodiment 9
(1) 85.2:8.6:2.3:2.8:1.1 weighs vanadium titano-magnetite tailing, silica, carbonic acid by mass percentage
Calcium, sodium carbonate and ceria, are packed into the fusing of gas furnace high temperature after stirring ball-milling, and 50 revs/min of the ball mill speed of mainshaft, powder
1510 DEG C of high temperature melting temperature of end, obtain glaze high-temp liquid；
(2) it glaze high-temp liquid is placed in frit cuts and cut rapid cooling clamp dog in fast cool equipment, cut and cut cutting for fast cool equipment and cut frequency
It is 1,89 DEG C/minute of fast speed of cooling, the type of cooling is 0.5 DEG C of water cooling, finally the grinding in vertical mill, 30 revs/min of the speed of mainshaft, drum
110 meter per second of wind wind speed, finally obtains preparing ceramic clinker glaze.
Embodiment 10
(1) 77.7:12.4:4.2:4.1:1.6 weighs vanadium titano-magnetite tailing, silica, carbonic acid by mass percentage
Calcium, sodium carbonate and ceria, are packed into the fusing of gas furnace high temperature after stirring ball-milling, and 70 revs/min of the ball mill speed of mainshaft, powder
1580 DEG C of high temperature melting temperature of end, obtain glaze high-temp liquid；
(2) it glaze high-temp liquid is placed in frit cuts and cut rapid cooling clamp dog in fast cool equipment, cut and cut cutting for fast cool equipment and cut frequency
It is 2,95 DEG C/minute of fast speed of cooling, the type of cooling is 0.5 DEG C of water cooling, finally the grinding in vertical mill, 40 revs/min of the speed of mainshaft, drum
130 meter per second of wind wind speed, finally obtains preparing ceramic clinker glaze.
The performance parameter that embodiment 5~10 prepares preparing ceramic clinker glaze is shown in Table 2:
Table 2
The above is only a preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art
For member, without departing from the principle of the present invention, it can also make several improvements and retouch, these improvements and modifications are also answered
It is considered as protection scope of the present invention.
Claims (6)
1. a kind of method that vanadium titano-magnetite tailing prepares preparing ceramic clinker glaze, which comprises the following steps:
1) it is fitted into gas furnace and melts after taking vanadium titano-magnetite tailing, correction material and decolorising agent to obtain mixed-powder, then ball milling
Change, obtains glaze liquid；Correction material includes silica, calcium carbonate, sodium carbonate, and decolorising agent is ceria, vanadium titano-magnetite
Tailing, silica, calcium carbonate, sodium carbonate and ceria mass percent be (77.7~85.2): (8.6~12.4):
(2.3~4.2): (2.8~4.1): (1.1~1.6)；
2) it glaze liquid is placed in frit cuts and cut rapid cooling clamp dog in fast cool equipment, finally the grinding in vertical mill, finally obtains ceramics
Fritted glaze.
2. the method that vanadium titano-magnetite tailing as described in claim 1 prepares preparing ceramic clinker glaze, which is characterized in that mixed-powder
Ball milling use agitating ball mill, 50~70 revs/min of rotational speed of ball-mill.
3. the method that vanadium titano-magnetite tailing as described in claim 1 prepares preparing ceramic clinker glaze, which is characterized in that fusion temperature
1510~1580 DEG C.
4. the method that vanadium titano-magnetite tailing as described in claim 1 prepares preparing ceramic clinker glaze, which is characterized in that cut and cut rapid cooling
It is 1~2 that the cutting of equipment, which cuts frequency, 89~95 DEG C/minute of fast speed of cooling, and the type of cooling is 0.5 DEG C of water cooling.
5. the method that vanadium titano-magnetite tailing as described in claim 1 prepares preparing ceramic clinker glaze, which is characterized in that vertical mill master
30~40 revs/min of axis revolving speed, 110~130 meter per second of air blast wind speed.
6. the method that the vanadium titano-magnetite tailing as described in claim 1 to 5 any one prepares preparing ceramic clinker glaze, feature exist
In the average particle size of preparing ceramic clinker glaze material obtained is less than or equal to 3 μm, and apparent density is more than or equal to 3.53g/cm3, compression is by force
Degree is more than or equal to 240MPa, and shear strength is more than or equal to 450MPa.
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| CN103145449A (en) * | 2012-12-28 | 2013-06-12 | 北京科技大学 | Method for preparing iron tailing into ceramic frit glaze |
| CN103922808A (en) * | 2014-04-09 | 2014-07-16 | 陕西科技大学 | Method for preparing low temperature green antique glaze by utilizing iron-ore slag |
| CN103922807A (en) * | 2014-04-09 | 2014-07-16 | 陕西科技大学 | Method for preparing low temperature black glaze by utilizing iron-ore slag |
| CN104529549A (en) * | 2015-02-02 | 2015-04-22 | 王占一 | Tea-dust glaze prepared from iron tailings and preparation method thereof |
| CN106277781A (en) * | 2015-05-29 | 2017-01-04 | 宝山钢铁股份有限公司 | Utilize the method that high-temperature liquid state industrial slag produces pottery glaze |
| CN106277789A (en) * | 2015-05-29 | 2017-01-04 | 宝山钢铁股份有限公司 | A kind of method utilizing steel slag preparation pottery glaze |
| CN109987962A (en) * | 2019-04-26 | 2019-07-09 | 陕西理工大学 | The method that vanadium titano-magnetite tailing prepares porous ceramic film material |
| CN110228947A (en) * | 2018-03-06 | 2019-09-13 | 大田县永大工艺制品有限公司 | A kind of ashen glaze ceramics and its technique using iron tailings preparation |
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2019
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4312951A (en) * | 1979-09-07 | 1982-01-26 | Mobay Chemical Corporation | Low-melting, lead-free ceramic frits |
| CN1054410A (en) * | 1991-03-08 | 1991-09-11 | 重庆市硅酸盐研究所 | Prescription with making porcelain glaze with Ti-containing slag |
| CN1887812A (en) * | 2006-07-18 | 2007-01-03 | 广东三水大鸿制釉有限公司 | Decoration glaze for inner wall tile and its prepn and detection method |
| CN103145449A (en) * | 2012-12-28 | 2013-06-12 | 北京科技大学 | Method for preparing iron tailing into ceramic frit glaze |
| CN103922808A (en) * | 2014-04-09 | 2014-07-16 | 陕西科技大学 | Method for preparing low temperature green antique glaze by utilizing iron-ore slag |
| CN103922807A (en) * | 2014-04-09 | 2014-07-16 | 陕西科技大学 | Method for preparing low temperature black glaze by utilizing iron-ore slag |
| CN104529549A (en) * | 2015-02-02 | 2015-04-22 | 王占一 | Tea-dust glaze prepared from iron tailings and preparation method thereof |
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| CN106277789A (en) * | 2015-05-29 | 2017-01-04 | 宝山钢铁股份有限公司 | A kind of method utilizing steel slag preparation pottery glaze |
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Application publication date: 20191122 |