CN101550497A - 一步湿热法制备纳米银粒子包覆氧化锌复合材料的方法 - Google Patents
一步湿热法制备纳米银粒子包覆氧化锌复合材料的方法 Download PDFInfo
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- CN101550497A CN101550497A CNA2009100978795A CN200910097879A CN101550497A CN 101550497 A CN101550497 A CN 101550497A CN A2009100978795 A CNA2009100978795 A CN A2009100978795A CN 200910097879 A CN200910097879 A CN 200910097879A CN 101550497 A CN101550497 A CN 101550497A
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- ethylene glycol
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- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 title claims abstract description 54
- 239000011787 zinc oxide Substances 0.000 title claims abstract description 28
- 238000000034 method Methods 0.000 title claims abstract description 26
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 title claims abstract description 15
- 239000002245 particle Substances 0.000 title claims abstract description 15
- 238000010438 heat treatment Methods 0.000 title claims abstract description 13
- 239000002131 composite material Substances 0.000 title claims abstract description 11
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 120
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims abstract description 22
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims abstract description 22
- 239000011701 zinc Substances 0.000 claims abstract description 16
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 claims abstract description 13
- ZOIORXHNWRGPMV-UHFFFAOYSA-N acetic acid;zinc Chemical compound [Zn].CC(O)=O.CC(O)=O ZOIORXHNWRGPMV-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000000463 material Substances 0.000 claims abstract description 5
- 229910001961 silver nitrate Inorganic materials 0.000 claims abstract description 5
- 239000004246 zinc acetate Substances 0.000 claims abstract description 5
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims abstract description 3
- 239000000243 solution Substances 0.000 claims description 60
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 20
- 101710134784 Agnoprotein Proteins 0.000 claims description 14
- 239000000843 powder Substances 0.000 claims description 13
- 238000013019 agitation Methods 0.000 claims description 10
- 238000002360 preparation method Methods 0.000 claims description 9
- 241000237502 Ostreidae Species 0.000 claims description 5
- 235000020636 oyster Nutrition 0.000 claims description 5
- 238000010992 reflux Methods 0.000 claims description 4
- 239000003153 chemical reaction reagent Substances 0.000 claims description 2
- 239000007788 liquid Substances 0.000 claims description 2
- 239000011259 mixed solution Substances 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- 238000000746 purification Methods 0.000 claims description 2
- 230000003252 repetitive effect Effects 0.000 claims description 2
- 238000005201 scrubbing Methods 0.000 claims description 2
- 239000006228 supernatant Substances 0.000 claims description 2
- 238000006243 chemical reaction Methods 0.000 abstract description 4
- 230000001699 photocatalysis Effects 0.000 abstract description 4
- 230000015572 biosynthetic process Effects 0.000 abstract description 3
- 238000003786 synthesis reaction Methods 0.000 abstract description 3
- 239000002904 solvent Substances 0.000 abstract 2
- 229910052725 zinc Inorganic materials 0.000 abstract 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract 1
- 238000005260 corrosion Methods 0.000 abstract 1
- 239000002243 precursor Substances 0.000 abstract 1
- 239000004094 surface-active agent Substances 0.000 abstract 1
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
- 239000011159 matrix material Substances 0.000 description 6
- 230000000694 effects Effects 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- 230000005540 biological transmission Effects 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 239000010949 copper Substances 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 238000001291 vacuum drying Methods 0.000 description 3
- 238000006555 catalytic reaction Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 238000005286 illumination Methods 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002086 nanomaterial Substances 0.000 description 2
- 238000007146 photocatalysis Methods 0.000 description 2
- 238000013033 photocatalytic degradation reaction Methods 0.000 description 2
- 239000010970 precious metal Substances 0.000 description 2
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000011812 mixed powder Substances 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 230000006911 nucleation Effects 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- 238000007540 photo-reduction reaction Methods 0.000 description 1
- 238000006303 photolysis reaction Methods 0.000 description 1
- 230000015843 photosynthesis, light reaction Effects 0.000 description 1
- 238000006722 reduction reaction Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 238000010532 solid phase synthesis reaction Methods 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
- 239000002912 waste gas Substances 0.000 description 1
- 238000004065 wastewater treatment Methods 0.000 description 1
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CN2009100978795A CN101550497B (zh) | 2009-04-20 | 2009-04-20 | 一步湿热法制备纳米银粒子包覆氧化锌复合材料的方法 |
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CN2009100978795A CN101550497B (zh) | 2009-04-20 | 2009-04-20 | 一步湿热法制备纳米银粒子包覆氧化锌复合材料的方法 |
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CN101550497A true CN101550497A (zh) | 2009-10-07 |
CN101550497B CN101550497B (zh) | 2010-10-27 |
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Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102504759A (zh) * | 2011-10-26 | 2012-06-20 | 天津大学 | 氧化锌包覆钡铁氧体的复合吸波材料及其制备方法 |
CN102649060A (zh) * | 2011-02-24 | 2012-08-29 | 中国科学院合肥物质科学研究院 | 多孔氧化锌-银复合纳米棒及其制备方法和用途 |
CN103785822A (zh) * | 2012-10-26 | 2014-05-14 | 深圳市龙岗区华宇新材料研究中心 | 一种微米级复合材料及其制备方法 |
CN107180702A (zh) * | 2017-04-26 | 2017-09-19 | 浙江理工大学 | 银/氧化锆/碳复合纳米纤维膜材料、制备方法及应用 |
CN109261957A (zh) * | 2018-09-26 | 2019-01-25 | 云南大学 | 一种银包覆氧化锌复合粉体材料及其制备方法和应用 |
CN111171379A (zh) * | 2020-01-14 | 2020-05-19 | 哈尔滨理工大学 | 球状Ag@T-ZnOw粉体的制备方法以及制备高介电聚合物复合薄膜的方法和应用 |
CN112777626A (zh) * | 2021-01-11 | 2021-05-11 | 大连理工大学 | 一种粒径可控的高度均匀氧化锌亚微米球及其制备方法 |
-
2009
- 2009-04-20 CN CN2009100978795A patent/CN101550497B/zh not_active Expired - Fee Related
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102649060A (zh) * | 2011-02-24 | 2012-08-29 | 中国科学院合肥物质科学研究院 | 多孔氧化锌-银复合纳米棒及其制备方法和用途 |
CN102649060B (zh) * | 2011-02-24 | 2014-04-30 | 中国科学院合肥物质科学研究院 | 多孔氧化锌-银复合纳米棒及其制备方法和用途 |
CN102504759A (zh) * | 2011-10-26 | 2012-06-20 | 天津大学 | 氧化锌包覆钡铁氧体的复合吸波材料及其制备方法 |
CN103785822A (zh) * | 2012-10-26 | 2014-05-14 | 深圳市龙岗区华宇新材料研究中心 | 一种微米级复合材料及其制备方法 |
CN103785822B (zh) * | 2012-10-26 | 2016-12-21 | 深圳门德科技有限公司 | 一种微米级复合材料及其制备方法 |
CN107180702A (zh) * | 2017-04-26 | 2017-09-19 | 浙江理工大学 | 银/氧化锆/碳复合纳米纤维膜材料、制备方法及应用 |
CN109261957A (zh) * | 2018-09-26 | 2019-01-25 | 云南大学 | 一种银包覆氧化锌复合粉体材料及其制备方法和应用 |
CN111171379A (zh) * | 2020-01-14 | 2020-05-19 | 哈尔滨理工大学 | 球状Ag@T-ZnOw粉体的制备方法以及制备高介电聚合物复合薄膜的方法和应用 |
CN111171379B (zh) * | 2020-01-14 | 2021-07-27 | 哈尔滨理工大学 | 球状Ag@T-ZnOw粉体的制备方法以及制备高介电聚合物复合薄膜的方法和应用 |
CN112777626A (zh) * | 2021-01-11 | 2021-05-11 | 大连理工大学 | 一种粒径可控的高度均匀氧化锌亚微米球及其制备方法 |
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CN101550497B (zh) | 2010-10-27 |
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Assignee: Zhejiang Chempacific Chemical Co., Ltd. Assignor: Zhejiang Sci-Tech University Contract record no.: 2011330001461 Denomination of invention: Method of preparing zinc oxide composite coated with nano-silver particles by one step wet heating Granted publication date: 20101027 License type: Exclusive License Open date: 20091007 Record date: 20111221 |
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