CN101511753A - 使用低氧化硅与氧化铝比例减轻烷基化催化剂失活的方法 - Google Patents

使用低氧化硅与氧化铝比例减轻烷基化催化剂失活的方法 Download PDF

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Publication number
CN101511753A
CN101511753A CNA2007800324598A CN200780032459A CN101511753A CN 101511753 A CN101511753 A CN 101511753A CN A2007800324598 A CNA2007800324598 A CN A2007800324598A CN 200780032459 A CN200780032459 A CN 200780032459A CN 101511753 A CN101511753 A CN 101511753A
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alkylation
catalyst
logistics
preliminary
ratio
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Chinese (zh)
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J·巴特勒
X·肖
J·梅里尔
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Fina Technology Inc
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Fina Technology Inc
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
    • C07C2/66—Catalytic processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7049—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
    • B01J29/7057—Zeolite Beta
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
    • C07C15/02—Monocyclic hydrocarbons
    • C07C15/067—C8H10 hydrocarbons
    • C07C15/073—Ethylbenzene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/08—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond
    • C07C6/12—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring
    • C07C6/126—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring of more than one hydrocarbon
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/12—Purification; Separation; Use of additives by adsorption, i.e. purification or separation of hydrocarbons with the aid of solids, e.g. with ion-exchangers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00002—Chemical plants
    • B01J2219/00004—Scale aspects
    • B01J2219/00006—Large-scale industrial plants
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Materials Engineering (AREA)
  • Analytical Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CNA2007800324598A 2006-09-05 2007-08-27 使用低氧化硅与氧化铝比例减轻烷基化催化剂失活的方法 Pending CN101511753A (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US11/515,679 2006-09-05
US11/515,679 US20080058566A1 (en) 2006-09-05 2006-09-05 Processes for reduction of alkylation catalyst deactivation utilizing low silica to alumina ratio catalyst

Related Child Applications (1)

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CN2011100463851A Division CN102153435A (zh) 2006-09-05 2007-08-27 使用低氧化硅与氧化铝比例减轻烷基化催化剂失活的方法

Publications (1)

Publication Number Publication Date
CN101511753A true CN101511753A (zh) 2009-08-19

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CNA2007800324598A Pending CN101511753A (zh) 2006-09-05 2007-08-27 使用低氧化硅与氧化铝比例减轻烷基化催化剂失活的方法
CN2011100463851A Pending CN102153435A (zh) 2006-09-05 2007-08-27 使用低氧化硅与氧化铝比例减轻烷基化催化剂失活的方法

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Country Status (8)

Country Link
US (5) US20080058566A1 (enExample)
EP (1) EP2064168A4 (enExample)
JP (1) JP5486306B2 (enExample)
KR (3) KR101587786B1 (enExample)
CN (2) CN101511753A (enExample)
CA (1) CA2661021C (enExample)
MX (2) MX2009002350A (enExample)
WO (1) WO2008030722A2 (enExample)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102892731A (zh) * 2010-05-20 2013-01-23 埃克森美孚化学专利公司 改进的烷基化方法
CN109963828A (zh) * 2016-10-06 2019-07-02 埃克森美孚化学专利公司 芳族烃的甲基化方法

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US20080192226A1 (en) * 2004-06-07 2008-08-14 Nikon Corporation Stage Unit, Exposure Apparatus, and Exposure Method
US7645913B2 (en) 2007-01-19 2010-01-12 Exxonmobil Chemical Patents Inc. Liquid phase alkylation with multiple catalysts
US8134036B2 (en) * 2008-03-13 2012-03-13 Fina Technology Inc Process for liquid phase alkylation
US8865958B2 (en) * 2008-09-30 2014-10-21 Fina Technology, Inc. Process for ethylbenzene production
US8697208B2 (en) * 2009-07-24 2014-04-15 Fina Technology, Inc. Polystyrene nanocomposites for blow molding applications
US8455383B2 (en) 2009-09-28 2013-06-04 Fina Technology, Inc. Process for catalyst regeneration and extended use
US20120296142A1 (en) * 2011-05-22 2012-11-22 Fina Technology, Inc. Addition of basic nitrogen to alkylation reactions
US8785706B2 (en) * 2011-05-22 2014-07-22 Fina Technology, Inc. Addition of a base to enhance product yield in alkylation reactions
CN105709815B (zh) * 2014-12-02 2018-06-19 中国石油化工股份有限公司 一种甲苯与乙烯选择性烷基化催化剂及其制备方法
CN108698952B (zh) * 2016-02-17 2021-04-27 巴杰许可有限责任公司 制备乙苯的方法
KR20210088742A (ko) * 2016-10-06 2021-07-14 엑손모빌 케미칼 패턴츠 인코포레이티드 벤젠 및/또는 톨루엔의 메틸화에 의한 파라크실렌의 제조 방법
US10246387B2 (en) 2016-10-06 2019-04-02 Exxonmobil Chemical Patents Inc. Process for selectivating catalyst for producing paraxylene by methylation of benzene and/or toluene
US11673849B2 (en) 2016-12-21 2023-06-13 Exxonmobil Chemical Patents Inc. Process for selectivating catalyst for producing paraxylene by methylation of benzene and/or toluene

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US3308069A (en) 1964-05-01 1967-03-07 Mobil Oil Corp Catalytic composition of a crystalline zeolite
US4185040A (en) 1977-12-16 1980-01-22 Union Oil Company Of California Alkylation of aromatic hydrocarbons
US4358362A (en) * 1981-01-15 1982-11-09 Mobil Oil Corporation Method for enhancing catalytic activity
US4642226A (en) 1984-04-16 1987-02-10 Mobil Oil Corporation Process for the preparation of zeolite Beta using dibenzyldimethylammonium ions and the product produced
US5081323A (en) * 1987-12-17 1992-01-14 Chevron Research And Technology Company Liquid phase alkylation or transalkylation process using zeolite beta
US4992606A (en) 1988-10-06 1991-02-12 Mobil Oil Corp. Process for preparing short chain alkyl aromatic compounds
US5535817A (en) * 1989-07-28 1996-07-16 Uop Sorption cooling process and apparatus
US5334795A (en) * 1990-06-28 1994-08-02 Mobil Oil Corp. Production of ethylbenzene
US5258565A (en) 1992-05-04 1993-11-02 Mobil Oil Corp. Process for preparing short chain alkylaromatic compounds
US5362697A (en) 1993-04-26 1994-11-08 Mobil Oil Corp. Synthetic layered MCM-56, its synthesis and use
WO1994029245A1 (en) 1993-06-16 1994-12-22 Mobil Oil Corporation Liquid phase ethylbenzene synthesis
ES2173473T3 (es) * 1996-08-20 2002-10-16 Dow Chemical Co Procedimiento de produccion de bencenos alquilados.
WO1998009928A2 (en) * 1996-09-06 1998-03-12 Exxon Chemical Patents Inc. Alkylation process using zeolite beta
US5998687A (en) * 1997-07-29 1999-12-07 Uop Llc Ethylbenzene process using stacked reactor loading of beta and Y zeolites
US6057485A (en) * 1998-11-17 2000-05-02 Fina Technology, Inc. Gas phase alkylation with split load of catalyst
US6617482B1 (en) * 2000-08-16 2003-09-09 Exxonmobil Chemical Patents Inc. Removable of polar contaminants from aromatic feedstocks
US20020042548A1 (en) * 2001-07-11 2002-04-11 Dandekar Ajit B. Process for producing cumene
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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102892731A (zh) * 2010-05-20 2013-01-23 埃克森美孚化学专利公司 改进的烷基化方法
CN102892731B (zh) * 2010-05-20 2015-12-02 埃克森美孚化学专利公司 改进的烷基化方法
US9249067B2 (en) 2010-05-20 2016-02-02 Exxonmobil Chemical Patents Inc. Alkylation process
CN109963828A (zh) * 2016-10-06 2019-07-02 埃克森美孚化学专利公司 芳族烃的甲基化方法

Also Published As

Publication number Publication date
MX2009002350A (es) 2009-03-23
US20130225888A1 (en) 2013-08-29
MX374947B (es) 2025-03-06
CN102153435A (zh) 2011-08-17
KR101542785B1 (ko) 2015-08-07
US8680354B2 (en) 2014-03-25
CA2661021C (en) 2015-11-24
US20080058566A1 (en) 2008-03-06
US20140128651A1 (en) 2014-05-08
US9556083B2 (en) 2017-01-31
KR20140051390A (ko) 2014-04-30
JP5486306B2 (ja) 2014-05-07
JP2010502636A (ja) 2010-01-28
EP2064168A4 (en) 2010-12-15
CA2661021A1 (en) 2008-03-13
KR20090059139A (ko) 2009-06-10
KR101587786B1 (ko) 2016-01-25
KR20140051389A (ko) 2014-04-30
US20140005454A1 (en) 2014-01-02
US8552238B2 (en) 2013-10-08
US9556084B2 (en) 2017-01-31
US20110301396A1 (en) 2011-12-08
WO2008030722A3 (en) 2008-04-24
EP2064168A2 (en) 2009-06-03
WO2008030722A2 (en) 2008-03-13
KR101586629B1 (ko) 2016-01-19

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Application publication date: 20090819