CN101475783B - High performance aqueous adhesive composition for artificial lawn back rubber - Google Patents
High performance aqueous adhesive composition for artificial lawn back rubber Download PDFInfo
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- CN101475783B CN101475783B CN2009100284360A CN200910028436A CN101475783B CN 101475783 B CN101475783 B CN 101475783B CN 2009100284360 A CN2009100284360 A CN 2009100284360A CN 200910028436 A CN200910028436 A CN 200910028436A CN 101475783 B CN101475783 B CN 101475783B
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Abstract
The invention discloses a high-performance aqueous adhesive composition for gum application in an artificial lawn. The adhesive composition can remarkably improve drawing force, reduce the use amount of gum substantially and reduce cost. The high-performance aqueous adhesive composition for gum application in the artificial lawn comprises the following compositions in portion by weight: 100 portions of carboxylic styrene butadiene latex, 5 to 60 portions of tackifying resin, 50 to 400 portions of filler, 0 to 5 portions of thickening agent and 0 to 3 portions of paint; and the portion of water is used to adjust the viscosity of an adhesive composition system between 5,000 and 50,000 MPa.s.
Description
Technical field
The present invention relates to a kind of adhesive compound, more specifically to a kind of high-performance water-based adhesive compound that is used for artificial grassplot back glue.
Background technology
In recent years, chinampa has obtained developing flourishingly.In the production process of chinampa, a topmost quality index is exactly the ability that prevents that the grass silk from coming off from end back.The end of in the production process of chinampa, the using back of the body normally natural or the synthetic filamentary material, as Chinese ephedra or polypropylene.Chinampa generally is that the grass silk is passed through the woven back on earth of tufting, and wherein one grass silk passes the end back of the body, is attached to end back.The position of each grass silk must be fixed, otherwise in use, the grass silk can come off.End back of the body gummed purpose is the dimensional stability of in use protecting the grass silk and improving the finished product.This characteristic is commonly called withdrawal force or pull-out force.High withdrawal force has been represented the high stable performance of chinampa.
It is to be coated with one deck latex at end back that an at present the most frequently used grass silk and the end back of the body bond together method.Such two faces (the grass silk and the end back of the body) are in the same place by glue bond, and whole then lawn can be sent to a big baking oven usually.The thermal treatment of baking oven has two effects: the moisture content in evaporation epoxy glue Ruzhong, and make latex solidify simultaneously, the grass silk and the end back of the body just bond together like this.After coming out from baking oven, cooling is stored after the rolling.Very natural, in the whole course of processing, the adhesive property of the grass silk and the end back of the body is a most critical.The present tackiness agent that uses, withdrawal force is on the low side, needs a large amount of use tackiness agent, causes cost than higher and production efficiency is lower.
Summary of the invention
The invention solves above-mentioned the deficiencies in the prior art and problem, a kind of high-performance water-based adhesive compound that is used for artificial grassplot back glue is provided, this adhesive compound is the raising withdrawal force significantly, can reduce the consumption of glue simultaneously, significantly reduces cost.
The present invention is achieved by the following technical solutions:
The high-performance water-based adhesive compound that is used for artificial grassplot back glue of the present invention, its each composition is composed as follows by weight:
100 parts of carboxylic styrene butadiene latexs
5～60 parts of tackifying resins
50～400 parts of fillers
0～5 part of thickening material
0～3 part of pigment
The deal of water water is this adhesive compound system
Viscosity be transferred to 5000～50000MPaS.
Adhesive compound of the present invention, its further technical scheme are that each composition is composed as follows by weight:
100 parts of carboxylic styrene butadiene latexs
10～30 parts of tackifying resins
80～300 parts of fillers
0.15～3 part of thickening material
1～3 part of pigment
The deal of water water is this adhesive compound system
Viscosity be transferred to 5000～30000MPaS.
Adhesive compound of the present invention, its further again technical scheme is that each composition is composed as follows by weight:
100 parts of carboxylic styrene butadiene latexs
10～30 parts of tackifying resins
100～200 parts of fillers
0.3～1.5 part of thickening material
1～3 part of pigment
The deal of water water is this adhesive compound system
Viscosity be transferred to 5000～20000MPaS.
In adhesive compound of the present invention, the solid content of its described carboxylic styrene butadiene latex is 45～60%, is preferably 53%.
Adhesive compound of the present invention, its further technical scheme can also be emulsive stable form water-based modified rosin resin, terpine resin or its combination for described tackifying resin, and further technical scheme is that described terpine resin is alpha-methyl styrene/terpene copolymer again.
Adhesive compound of the present invention, its further technical scheme can also be one or more a mixture in lime carbonate, kaolin, the clay for described filler, fineness is 200～1000 orders
Adhesive compound of the present invention, its further technical scheme can also be nonionic polyurethane thickening material, anionic acrylic thickening material or both mixtures for described thickening material.
Adhesive compound of the present invention, its further technical scheme can also be carbon black or black slurry for described pigment.
The present invention compared with prior art has following beneficial effect:
Tackiness agent of the present invention can be used for the production of chinampa, and this adhesive applicating in the end on lawn back of the body one side, is produced the end back of the body that tackiness agent covers.Also can be directly used in the grass silk to this tackiness agent in addition, perhaps be used for the grass silk and the end back of the body.Then the grass silk and the end back of the body that has adhesive coating are bonded together.The tackiness agent drying, the grass silk has just bonded together with the end back of the body that has tackiness agent like this.For drying, normally allow the lawn pass through a baking oven or one group of baking oven.In this exsiccant process, tackiness agent of the present invention has extraordinary wetting property, and after all moisture content volatilized in tackiness agent, the production on lawn had just been finished, and uses the chinampa of this tackiness agent to have extraordinary withdrawal force.
The characteristics of maximum of the present invention are to have added the water-based tackifying resin in addition, increase substantially the intensity of tackiness agent, make withdrawal force significantly improve, and can reduce glue consumption like this, thereby reduce cost.Make water as thinner simultaneously, easy to adjust, can regulate viscosity according to different service requirementss, easy to use.Aqueous adhesive of the present invention does not have deleterious chemical ingredients, compliance with environmental protection requirements owing to without solvent, have no irritating odor.
Embodiment
Below by specific embodiment explanation the present invention, but the present invention not merely is defined in these embodiment.
Embodiment 1
(1) taking by weighing 100g carboxylic styrene butadiene latex (DL8728 of DOW Chemical, solid content 53.0%), to place dispersion machine, low whipping speed be that 600rpm adds down emulsive stable form water-based modified rosin resin 5g, disperses 3～5min
(2) add 500 order lime carbonate 50g, disperse 15min
(3) add carbon black 1.5g, disperse 5min
(4) add nonionic polyurethane thickening material 5.0g, disperse 3min
(5) add water 1g, the viscosity of adhesive composition system is transferred to 5000MPaS, get promptly that the back of the body sticks with glue agent at the bottom of the lawn.
Use adhesive applicating of the present invention at the end of chinampa back, grass silk is fixed on back at the bottom of the lawn.In the exsiccant process, wet tackiness agent provides outstanding wettability.Use the test of omnipotent puller system the grass silk from the end back needed power of coming out.Use the withdrawal force on the lawn of tackiness agent of the present invention to be 45.6N, national standard is the mean value that this withdrawal force of 30N. is based on 10 sample testings.Example shows, after tackiness agent of the present invention has been used on the lawn, improved tackiness agent to the lawn at the bottom of the wettability of the back of the body.Withdrawal force significantly improves simultaneously.Adding tackifying resin another one advantage in the tackiness agent is to have improved the covering of tackiness agent to grass silk surface significantly.
Embodiment 2
(1) taking by weighing 100g carboxylic styrene butadiene latex (DL8728 of DOW Chemical, solid content 53.0%), to place dispersion machine, low whipping speed be that 500rpm adds down tackifying resin alpha-methyl styrene/terpene copolymer 10g, disperses 5min
(2) add 500 order lime carbonate 50g and 500 order kaolin 30g, disperse 15min
(3) add carbon black 1.5g, disperse 4min
(4) add anionic acrylic thickening material 4.0g, disperse 5min
(5) add water 1g, the viscosity of adhesive composition system is transferred to 10000MPaS, get promptly that the back of the body sticks with glue agent at the bottom of the lawn.
Use adhesive applicating of the present invention at the end of chinampa back, grass silk is fixed on back at the bottom of the lawn.In the exsiccant process, wet tackiness agent provides outstanding wettability.Use the test of omnipotent puller system the grass silk from the end back needed power of coming out.Use the withdrawal force on the lawn of tackiness agent of the present invention to be 46.3N, national standard is the mean value that this withdrawal force of 30N. is based on 10 sample testings.
Embodiment 3
(1) taking by weighing 100g carboxylic styrene butadiene latex (DL8728 of DOW Chemical, solid content 53.0%), to place dispersion machine, low whipping speed be that 700rpm adds down emulsive stable form water-based modified rosin resin 20g, disperses 5min
(2) add 200 order lime carbonate 100g, disperse 15min
(3) add black slurry 1.5g, disperse 5min
(4) add nonionic polyurethane thickening material 3.0g, disperse 3min
(5) add water 1g, the viscosity of adhesive composition system is transferred to 10000MPaS, get promptly that the back of the body sticks with glue agent at the bottom of the lawn.
Use adhesive applicating of the present invention at the end of chinampa back, grass silk is fixed on back at the bottom of the lawn.In the exsiccant process, wet tackiness agent provides outstanding wettability.Use the test of omnipotent puller system the grass silk from the end back needed power of coming out.Use the withdrawal force on the lawn of tackiness agent of the present invention to be 49.7N, national standard is the mean value that this withdrawal force of 30N. is based on 10 sample testings.
Embodiment 4
(1) taking by weighing 100g carboxylic styrene butadiene latex (solid content 45.0%), to place dispersion machine, low whipping speed be that 600rpm adds down emulsive stable form water-based modified rosin resin 60g, disperses 5min
(2) add 1000 purpose lime carbonate 500g, disperse 13min
(3) add carbon black 1.5g, disperse 3min
(4) add water 10g, the viscosity of adhesive composition system is transferred to 50000MPaS, get promptly that the back of the body sticks with glue agent at the bottom of the lawn.
Use adhesive applicating of the present invention at the end of chinampa back, grass silk is fixed on back at the bottom of the lawn.In the exsiccant process, wet tackiness agent provides outstanding wettability.Use the test of omnipotent puller system the grass silk from the end back needed power of coming out.Use the withdrawal force on the lawn of tackiness agent of the present invention to be 35.6N, national standard is the mean value that this withdrawal force of 30N. is based on 10 sample testings.
Embodiment 5
(1) taking by weighing 100g carboxylic styrene butadiene latex (solid content 60.0%), to place dispersion machine, low whipping speed be that 700rpm adds down emulsive stable form water-based modified rosin resin 60g, disperses 3min
(2) add 500 order lime carbonate 300g, disperse 15min
(3) add carbon black 1.5g, disperse 3min
(4) add water 10g, the viscosity of adhesive composition system be transferred to 30000MPaS,, get promptly that the back of the body sticks with glue agent at the bottom of the lawn.
Use adhesive applicating of the present invention at the end of chinampa back, grass silk is fixed on back at the bottom of the lawn.In the exsiccant process, wet tackiness agent provides outstanding wettability.Use the test of omnipotent puller system the grass silk from the end back needed power of coming out.Use the withdrawal force on the lawn of tackiness agent of the present invention to be 41.0N, national standard is the mean value that this withdrawal force of 30N. is based on 10 sample testings.
Embodiment 6
(1) taking by weighing 100g carboxylic styrene butadiene latex (DL8728 of DOW Chemical, solid content 53.0%), to place dispersion machine, low whipping speed be that 700rpm adds down emulsive stable form water-based modified rosin resin 30g, disperses 3～5min
(2) add 800 order clay 200g, disperse 15min
(3) add carbon black 1.5g, disperse 5min
(4) add anionic acrylic thickening material 0.5g, disperse 5min
(5) add water 5g, the viscosity of adhesive composition system be transferred to 20000MPaS,, get promptly that the back of the body sticks with glue agent at the bottom of the lawn.
Use adhesive applicating of the present invention at the end of chinampa back, grass silk is fixed on back at the bottom of the lawn.In the exsiccant process, wet tackiness agent provides outstanding wettability.Use the test of omnipotent puller system the grass silk from the end back needed power of coming out.Use the withdrawal force on the lawn of tackiness agent of the present invention to be 52.5N, national standard is the mean value that this withdrawal force of 30N. is based on 10 sample testings.
Embodiment 7
(1) taking by weighing 100g carboxylic styrene butadiene latex (DL8728 of DOW Chemical, solid content 53.0%), to place dispersion machine, low whipping speed be that 700rpm adds down emulsive stable form water-based modified rosin resin 25g, disperses 5min
(2) add 325 order lime carbonate 160g, disperse 10min
(3) add carbon black 1.5g, disperse 5min
(4) add anionic acrylic thickening material 0.5g, disperse 5min
(5) add water 5g, the viscosity of adhesive composition system is transferred to 15000MPaS, get promptly that the back of the body sticks with glue agent at the bottom of the lawn.
Use adhesive applicating of the present invention at the end of chinampa back, grass silk is fixed on back at the bottom of the lawn.In the exsiccant process, wet tackiness agent provides outstanding wettability.Use the test of omnipotent puller system the grass silk from the end back needed power of coming out.Use the withdrawal force on the lawn of tackiness agent of the present invention to be 55.6N, national standard is the mean value that this withdrawal force of 30N. is based on 10 sample testings.
Embodiment 8
(1) taking by weighing 100g carboxylic styrene butadiene latex (DL8728 of DOW Chemical, solid content 53.0%), to place dispersion machine, low whipping speed be that 700rpm adds down alpha-methyl styrene/terpene copolymer 15g, disperses 3～5min
(2) add 500 order lime carbonate 150g, disperse 15min
(3) add carbon black 1.5g, disperse 5min
(4) add anionic acrylic thickening material 0.5g, disperse 3min
(5) add water 3g, the viscosity of adhesive composition system is transferred to 10000MPaS, get promptly that the back of the body sticks with glue agent at the bottom of the lawn.
Use adhesive applicating of the present invention at the end of chinampa back, grass silk is fixed on back at the bottom of the lawn.In the exsiccant process, wet tackiness agent provides outstanding wettability.Use the test of omnipotent puller system the grass silk from the end back needed power of coming out.Use the withdrawal force on the lawn of tackiness agent of the present invention to be 50.5N, national standard is the mean value that this withdrawal force of 30N. is based on 10 sample testings.
Embodiment 9
(1) take by weighing 100g carboxylic styrene butadiene latex (DL8728 of DOW Chemical, solid content 53.0%) and place dispersion machine,, low whipping speed is that 700rpm adds emulsive stable form water-based modified rosin resin 25g down, disperses 3～5min
(2) add 500 order lime carbonate 250g, disperse 10～15min
(3) add water 10g, the viscosity of adhesive composition system is transferred to 20000MPaS, get promptly that the back of the body sticks with glue agent at the bottom of the lawn.
Use adhesive applicating of the present invention at the end of chinampa back, grass silk is fixed on back at the bottom of the lawn.In the exsiccant process, wet tackiness agent provides outstanding wettability.Use the test of omnipotent puller system the grass silk from the end back needed power of coming out.Use the withdrawal force on the lawn of tackiness agent of the present invention to be 49.5N, national standard is the mean value that this withdrawal force of 30N. is based on 10 sample testings.
Embodiment 10
(1) take by weighing 100g carboxylic styrene butadiene latex (DL8728 of DOW Chemical, solid content 53.0%) and place dispersion machine,, low whipping speed is that 600rpm adds emulsive stable form water-based modified rosin resin 20g down, disperses 5min
(2) add 500 order lime carbonate 150g, disperse 15min
(3) add carbon black 1.5g, disperse 5min
(4) add anionic acrylic thickening material 1.5g, disperse 5min
(5) add water 3g, the viscosity of adhesive composition system is transferred to 13000MPaS, get promptly that the back of the body sticks with glue agent at the bottom of the lawn.
Use adhesive applicating of the present invention at the end of chinampa back, grass silk is fixed on back at the bottom of the lawn.In the exsiccant process, wet tackiness agent provides outstanding wettability.Use the test of omnipotent puller system the grass silk from the end back needed power of coming out.Use the withdrawal force on the lawn of tackiness agent of the present invention to be 50.4N, national standard is the mean value that this withdrawal force of 30N. is based on 10 sample testings.
As can be seen from the above embodiments, after tackiness agent of the present invention has been used on the lawn, improved tackiness agent to the lawn at the bottom of the wettability of the back of the body.Withdrawal force significantly improves simultaneously.Adding tackifying resin another one advantage in the tackiness agent is to have improved the covering of tackiness agent to grass silk surface significantly.
Claims (7)
1. high-performance water-based adhesive compound that is used for artificial grassplot back glue is characterized in that each composition of this adhesive compound is composed as follows by weight:
100 parts of carboxylic styrene butadiene latexs
10～30 parts of tackifying resins
80～300 parts of fillers
0.15～3 part of thickening material
1～3 part of pigment
The deal of water water is this adhesive compound system
Viscosity be transferred to 5000～30000MPaS,
Wherein said tackifying resin is emulsive stable form water-based modified rosin resin, terpine resin or its combination; Described terpine resin is alpha-methyl styrene/terpene copolymer.
2. adhesive compound according to claim 1 is characterized in that each composition is composed as follows by weight:
100 parts of carboxylic styrene butadiene latexs
10～30 parts of tackifying resins
100～200 parts of fillers
0.3～1.5 part of thickening material
1～3 part of pigment
The deal of water water is this adhesive compound system
Viscosity be transferred to 5000～10000MPaS.
3. adhesive compound according to claim 1 and 2, the solid content that it is characterized in that described carboxylic styrene butadiene latex is 45～60%.
4. adhesive compound according to claim 3, the solid content that it is characterized in that described carboxylic styrene butadiene latex is 53%.
5. adhesive compound according to claim 1 and 2 is characterized in that described filler is one or more the mixture in lime carbonate, kaolin, the clay, and fineness is 200～1000 orders.
6. adhesive compound according to claim 1 and 2 is characterized in that described thickening material is nonionic polyurethane thickening material, anionic acrylic thickening material or both mixtures.
7. adhesive compound according to claim 1 and 2 is characterized in that described pigment is carbon black or black slurry.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009100284360A CN101475783B (en) | 2009-01-20 | 2009-01-20 | High performance aqueous adhesive composition for artificial lawn back rubber |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009100284360A CN101475783B (en) | 2009-01-20 | 2009-01-20 | High performance aqueous adhesive composition for artificial lawn back rubber |
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| Publication Number | Publication Date |
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| CN101475783A CN101475783A (en) | 2009-07-08 |
| CN101475783B true CN101475783B (en) | 2010-10-27 |
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| CN2009100284360A Active CN101475783B (en) | 2009-01-20 | 2009-01-20 | High performance aqueous adhesive composition for artificial lawn back rubber |
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| CN102206472B (en) * | 2011-05-10 | 2013-01-16 | 常州工程职业技术学院 | Adhesive composition for artificial turf |
| CN102786894A (en) * | 2011-05-17 | 2012-11-21 | 张晓龙 | Aqueous adhesive for rubber tube, and preparation method thereof |
| CN102876258A (en) * | 2012-10-18 | 2013-01-16 | 义乌市新彩虹工艺地毯有限公司 | Preparation method of microcapsule elastic glue for carpet |
| CN103740299B (en) * | 2014-01-15 | 2016-09-14 | 广州爱奇实业有限公司 | A kind of have artificial grass stamp gum inhaling wave energy and preparation method thereof |
| CN104017520B (en) * | 2014-05-27 | 2016-06-01 | 中国科学院广州能源研究所 | Terpine resin base water-based binder and the application in lithium ion battery negative or ultracapacitor thereof |
| JP6628799B2 (en) * | 2015-06-22 | 2020-01-15 | 株式会社ブリヂストン | Rubber composition, laminate, and conveyor belt |
| CN105924772A (en) * | 2016-05-16 | 2016-09-07 | 江苏共创人造草坪有限公司 | High pullout force artificial turf and preparing method thereof |
| CN106085290B (en) * | 2016-06-14 | 2017-12-05 | 江苏威腾人造草坪有限公司 | A kind of chinampa Adhesive composition of excellent performance |
| CN106854379A (en) * | 2016-12-05 | 2017-06-16 | 钦州市钦南区生产力促进中心 | A kind of chinampa and preparation method thereof |
| CN106608962B (en) * | 2016-12-30 | 2019-04-26 | 青岛青禾人造草坪股份有限公司 | Foam type polyurethane and preparation method thereof |
| CN112094605A (en) * | 2020-09-28 | 2020-12-18 | 杨益成 | Low-cost environment-friendly formaldehyde-free adhesive and preparation method thereof |
| CN112111243A (en) * | 2020-09-28 | 2020-12-22 | 杨益成 | Water-based adhesive added with filler and preparation method thereof |
| CN112920761A (en) * | 2021-03-30 | 2021-06-08 | 湖南盛天新材料有限公司 | Environment-friendly two-component polyurethane lawn adhesive with high initial adhesion and easy construction and preparation method thereof |
| CN115160955A (en) * | 2022-07-29 | 2022-10-11 | 乐陵泰山人造草坪产业有限公司 | Transparent bottom-back high-water-seepage integrally-recyclable artificial lawn and preparation method thereof |
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Address after: 223000 Guangzhou East Road, Huaian Economic Development Zone, Huaian, Jiangsu 66 Patentee after: Jiangsu created artificial lawn Limited by Share Ltd Address before: 223229 2 Shihe Industrial Park, Chuzhou, Huaian, Jiangsu Patentee before: Jiangsu Co-creation Grass Co., Ltd. |
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