Summary of the invention
The object of the invention is to the defect overcoming above-mentioned prior art, a kind of Noctilucent type artificial turf and preparation thereof are provided, luminous energy can be stored storage after absorbing sun visible ray by this Noctilucent type artificial turf, luminous in the dark state, the demand that its by force ornamental and applicable people move evening.
For achieving the above object, the present invention adopts following technical scheme:
A kind of Noctilucent type artificial turf, it comprises base fabric and is woven in the fiber grass on base fabric, and described fiber grass comprises following component by weight percentage:
Described noctilucence masterbatch comprises following component by weight percentage:
RE luminous point of loose powder 30-85%
Polyethylene or polypropylene or nylon 10-50%
Dispersing agent 1-20%;
Described RE luminous point of loose powder comprises following component by weight percentage:
Rare-earth Long Persistence Luminescent Phosphor powder 70-98%
Surfactant 1-15%
Dispersing agent 1-15%.
Preferably, described processing aid is the mixture of light stabilizer, antioxidant, spin finish aid, and described surfactant is cationic surface active agent, and described dispersing agent is cationic polyvinyl wax.
A kind of Noctilucent type artificial turf, it fiber grass comprising the end back of the body and be woven in end back, fiber grass sprays noctilucence masterbatch, and described noctilucence masterbatch comprises following component by weight percentage:
RE luminous point of loose powder 10-50%
Solvent 45-75%
Processing aid 5-20%
Described RE luminous point of loose powder comprises following component by weight percentage:
Rare-earth Long Persistence Luminescent Phosphor powder 70-98%
Surfactant 1-15%
Dispersing agent 1-15%.
Preferably, described dispersing agent is cationic polyvinyl wax, and described surfactant is cationic surface active agent, and described processing aid is the mixture of light stabilizer, antioxidant, spin finish aid.
A preparation method for Noctilucent type artificial turf, it comprises the following steps:
(1) preparation of RE luminous point of loose powder: the Rare-earth Long Persistence Luminescent Phosphor powder of formula ratio, surfactant, dispersing agent are added on grinder and grinds, then mediated by high-speed kneading machine;
(2) preparation of noctilucence masterbatch: add RE luminous point of loose powder, polyethylene or polypropylene of formula ratio in double screw extruder, dispersing agent carries out mixing, extrude, draw bar, pelletizing, obtains noctilucence masterbatch;
(3) in spinning screw extruder, add the polyethylene of formula ratio or polypropylene, noctilucence masterbatch, color concentrate, processing aid carry out mixing, extrude, stretch, shape, doff, twisting, obtain luminous type artificial fiber straw;
(4) by tufting machine, luminous type artificial fiber straw, base fabric are woven into turf, finally by gum forming machine gluing, are processed into Noctilucent type artificial turf.
Preferably, in step (1), the time of grinding is 5-100min, and rotating speed is that 100-500 turns/min; The time of mediating is 1-10min, and rotating speed is that 500-3000 turns/min.
A preparation method for Noctilucent type artificial turf, it comprises the following steps:
(1) fiber grass is provided;
(2) preparation of RE luminous point of loose powder: the Rare-earth Long Persistence Luminescent Phosphor powder of formula ratio, surfactant, dispersing agent are added on grinder and grinds, then mediated by high-speed kneading machine;
(3) preparation of noctilucence masterbatch: RE luminous point of loose powder of formula ratio and processing aid are added on grinder and grinds, then transfer in mixer, add solvent and stir in mixer;
(4) spray thrower is used to be sprayed on fiber grass by noctilucence masterbatch.
Preferably, in step (2), the time of grinding is 5-100min, and rotating speed is that 100-500 turns/min; The time of mediating is 1-10min, and rotating speed is that 500-3000 turns/min.
Preferably, in step (3), the time of grinding is 60-180min, and rotating speed is that 100-500 turns/min.
Preferably, the viscosity of the noctilucence masterbatch that step (3) is obtained is less than 600pas.
Compared with prior art, the invention has the beneficial effects as follows:
1, Noctilucent type artificial turf of the present invention can absorb sun visible ray, and energy stores, fluorescent effect can be sent in the dark state, and persistence reaches 10 hours, various coloured light can be sent in the dark, as ruddiness, gold-tinted, blue light, green glow etc., lucuriant in design needs again dyes, product very environmental protection;
2, preparation technology of the present invention is simple, and existing equipment can be adopted to have gone;
3, luminous type artificial fiber straw of the present invention utilizes speed lapping kneader to the further refinement of Rare-earth Long Persistence Luminescent Phosphor powder, and add surfactant and solve the problem that Rare-earth Long Persistence Luminescent Phosphor powder refinement re-unites, prepare luminous type artificial fiber straw for utilizing Rare-earth Long Persistence Luminescent Phosphor powder and create favorable conditions.
Detailed description of the invention
Below by specific embodiment, the present invention is described in further detail.In following embodiment, light stabilizer selects be obstructed ammonium class light stabilizer and ultra-violet absorber UV-9, antioxidant 1010 selected by antioxidant, and spin finish aid uses polyvinyl alcohol, and dispersing agent selects cationic polyvinyl wax, cationic surface active agent selected by surfactant, and solvent is water.
Embodiment 1
A kind of Noctilucent type artificial turf, it comprises base fabric and is woven in the fiber grass on base fabric, and described fiber grass comprises following component by weight percentage: polyethylene 90%, noctilucence masterbatch 7%, color concentrate 2%, light stabilizer 0.5%, antioxidant 0.2%, spin finish aid 0.3%.Wherein, noctilucence masterbatch comprises following component by weight percentage: RE luminous point of loose powder 30%, polyethylene 50%, dispersing agent 20%.Described RE luminous point of loose powder comprises following component by weight percentage: Rare-earth Long Persistence Luminescent Phosphor powder 98%, surfactant 1%, dispersing agent 1%.
The preparation method of above-mentioned Noctilucent type artificial turf, comprises the following steps:
(1) preparation of RE luminous point of loose powder: the Rare-earth Long Persistence Luminescent Phosphor powder of formula ratio, surfactant, dispersing agent are added on grinder and grinds, then mediated by high-speed kneading machine; Wherein, the time of grinding is 5-100min, and rotating speed is that 100-500 turns/min; The time of mediating is 1-10min, and rotating speed is that 500-3000 turns/min.
(2) preparation of noctilucence masterbatch: add RE luminous point of loose powder of formula ratio in double screw extruder, polyethylene, dispersing agent carry out mixing, extrude, draw bar, pelletizing, obtain noctilucence masterbatch;
(3) in spinning screw extruder, add the polyethylene of formula ratio, noctilucence masterbatch, color concentrate, processing aid carry out mixing, extrude, stretch, shape, doff, twisting, obtain luminous type artificial fiber straw;
(4) by tufting machine, luminous type artificial fiber straw, base fabric are woven into turf, finally by gum forming machine gluing, are processed into Noctilucent type artificial turf.
Embodiment 2
The difference of the present embodiment and embodiment 1 is: polyethylene polypropylene replaces.
Embodiment 3
The difference of the present embodiment and embodiment 1 is: polyethylene nylon replaces.
Embodiment 4
A kind of Noctilucent type artificial turf, it comprises base fabric and is woven in the fiber grass on base fabric, and described fiber grass comprises following component by weight percentage: polyethylene 79%, noctilucence masterbatch 1%, color concentrate 10%, light stabilizer 5%, antioxidant 3%, spin finish aid 21%.Wherein, noctilucence masterbatch comprises following component by weight percentage: RE luminous point of loose powder 85%, polyethylene 10%, dispersing agent 5%.Described RE luminous point of loose powder comprises following component by weight percentage: Rare-earth Long Persistence Luminescent Phosphor powder 70%, surfactant 15%, dispersing agent 15%.
The preparation method of above-mentioned Noctilucent type artificial turf, comprises the following steps:
(1) preparation of RE luminous point of loose powder: the Rare-earth Long Persistence Luminescent Phosphor powder of formula ratio, surfactant, dispersing agent are added on grinder and grinds, then mediated by high-speed kneading machine; Wherein, the time of grinding is 5-100min, and rotating speed is that 100-500 turns/min; The time of mediating is 1-10min, and rotating speed is that 500-3000 turns/min.
(2) preparation of noctilucence masterbatch: add RE luminous point of loose powder of formula ratio in double screw extruder, polyethylene, dispersing agent carry out mixing, extrude, draw bar, pelletizing, obtain noctilucence masterbatch;
(3) in spinning screw extruder, add the polyethylene of formula ratio, noctilucence masterbatch, color concentrate, processing aid carry out mixing, extrude, stretch, shape, doff, twisting, obtain luminous type artificial fiber straw;
(4) by tufting machine, luminous type artificial fiber straw, base fabric are woven into turf, finally by gum forming machine gluing, are processed into Noctilucent type artificial turf.
Embodiment 5
The difference of the present embodiment and embodiment 4 is: replace polyethylene with polypropylene.
Embodiment 6
The difference of the present embodiment and embodiment 4 is: replace polyethylene with nylon.
Embodiment 7
A kind of Noctilucent type artificial turf, it comprises base fabric and is woven in the fiber grass on base fabric, and described fiber grass comprises following component by weight percentage: polyethylene 40%, noctilucence masterbatch 50%, color concentrate 5%, light stabilizer 3%, antioxidant 1%, spin finish aid 1%.Wherein, noctilucence masterbatch comprises following component by weight percentage: RE luminous point of loose powder 55%, polyethylene 44%, dispersing agent 1%.Described RE luminous point of loose powder comprises following component by weight percentage: Rare-earth Long Persistence Luminescent Phosphor powder 86%, surfactant 7%, dispersing agent 7%.
The preparation method of above-mentioned Noctilucent type artificial turf, comprises the following steps:
(1) preparation of RE luminous point of loose powder: the Rare-earth Long Persistence Luminescent Phosphor powder of formula ratio, surfactant, dispersing agent are added on grinder and grinds, then mediated by high-speed kneading machine; Wherein, the time of grinding is 5-100min, and rotating speed is that 100-500 turns/min; The time of mediating is 1-10min, and rotating speed is that 500-3000 turns/min.
(2) preparation of noctilucence masterbatch: add RE luminous point of loose powder of formula ratio in double screw extruder, polyethylene, dispersing agent carry out mixing, extrude, draw bar, pelletizing, obtain noctilucence masterbatch;
(3) in spinning screw extruder, add the polyethylene of formula ratio, noctilucence masterbatch, color concentrate, processing aid carry out mixing, extrude, stretch, shape, doff, twisting, obtain luminous type artificial fiber straw;
(4) by tufting machine, luminous type artificial fiber straw, base fabric are woven into turf, finally by gum forming machine gluing, are processed into Noctilucent type artificial turf.
Embodiment 8
The difference of the present embodiment and embodiment 7 is: adopt polypropylene to replace polyethylene.
Embodiment 9
The difference of the present embodiment and embodiment 7 is: adopt nylon to replace polyethylene.
Embodiment 10
A kind of Noctilucent type artificial turf, it fiber grass comprising the end back of the body and be woven in end back, fiber grass sprays noctilucence masterbatch, and described noctilucence masterbatch comprises following component by weight percentage: RE luminous point of loose powder 10%, solvent 70%, light stabilizer 10%, antioxidant 5%, spin finish aid 5%.Wherein, RE luminous point of loose powder comprises following component by weight percentage: Rare-earth Long Persistence Luminescent Phosphor powder 98%, surfactant 1%, dispersing agent 1%.
The preparation method of above-mentioned Noctilucent type artificial turf, it comprises the following steps:
(1) fiber grass is provided;
(2) preparation of RE luminous point of loose powder: the Rare-earth Long Persistence Luminescent Phosphor powder of formula ratio, surfactant, dispersing agent are added on grinder and grinds, then mediated by high-speed kneading machine; Wherein, in step (2), the time of grinding is 5-100min, and rotating speed is that 100-500 turns/min; The time of mediating is 1-10min, and rotating speed is that 500-3000 turns/min;
(3) preparation of noctilucence masterbatch: RE luminous point of loose powder of formula ratio and processing aid are added on grinder and grinds, then transfer in mixer, add solvent and stir in mixer; Wherein, the time of grinding is 60-180min, and rotating speed is that 100-500 turns/min, and the viscosity of obtained noctilucence masterbatch is less than 600pas;
(4) spray thrower is used to be sprayed on fiber grass by noctilucence masterbatch.
Embodiment 11
A kind of Noctilucent type artificial turf, it fiber grass comprising the end back of the body and be woven in end back, fiber grass sprays noctilucence masterbatch, and described noctilucence masterbatch comprises following component by weight percentage: RE luminous point of loose powder 35%, solvent 50%, light stabilizer 5%, antioxidant 5%, spin finish aid 5%.Wherein, RE luminous point of loose powder comprises following component by weight percentage: Rare-earth Long Persistence Luminescent Phosphor powder 70%, surfactant 15%, dispersing agent 15%.
The preparation method of above-mentioned Noctilucent type artificial turf, it comprises the following steps:
(1) fiber grass is provided;
(2) preparation of RE luminous point of loose powder: the Rare-earth Long Persistence Luminescent Phosphor powder of formula ratio, surfactant, dispersing agent are added on grinder and grinds, then mediated by high-speed kneading machine; Wherein, in step (2), the time of grinding is 5-100min, and rotating speed is that 100-500 turns/min; The time of mediating is 1-10min, and rotating speed is that 500-3000 turns/min;
(3) preparation of noctilucence masterbatch: RE luminous point of loose powder of formula ratio and processing aid are added on grinder and grinds, then transfer in mixer, add solvent and stir in mixer; Wherein, the time of grinding is 60-180min, and rotating speed is that 100-500 turns/min, and the viscosity of obtained noctilucence masterbatch is less than 600pas;
(4) spray thrower is used to be sprayed on fiber grass by noctilucence masterbatch.
Embodiment 12
A kind of Noctilucent type artificial turf, it fiber grass comprising the end back of the body and be woven in end back, fiber grass sprays noctilucence masterbatch, and described noctilucence masterbatch comprises following component by weight percentage: RE luminous point of loose powder 50%, solvent 45%, light stabilizer 3%, antioxidant 2%, spin finish aid 1%.Wherein, RE luminous point of loose powder comprises following component by weight percentage: Rare-earth Long Persistence Luminescent Phosphor powder 86%, surfactant 7%, dispersing agent 7%.
The preparation method of above-mentioned Noctilucent type artificial turf, it comprises the following steps:
(1) fiber grass is provided;
(2) preparation of RE luminous point of loose powder: the Rare-earth Long Persistence Luminescent Phosphor powder of formula ratio, surfactant, dispersing agent are added on grinder and grinds, then mediated by high-speed kneading machine; Wherein, in step (2), the time of grinding is 5-100min, and rotating speed is that 100-500 turns/min; The time of mediating is 1-10min, and rotating speed is that 500-3000 turns/min;
(3) preparation of noctilucence masterbatch: RE luminous point of loose powder of formula ratio and processing aid are added on grinder and grinds, then transfer in mixer, add solvent and stir in mixer; Wherein, the time of grinding is 60-180min, and rotating speed is that 100-500 turns/min, and the viscosity of obtained noctilucence masterbatch is less than 600pas;
(4) spray thrower is used to be sprayed on fiber grass by noctilucence masterbatch.
Above-described embodiment is only the preferred embodiment of the present invention, can not limit protection scope of the present invention with this, and change and the replacement of any unsubstantiality that those skilled in the art does on basis of the present invention all belong to protection scope of the present invention.