CN106244103B - A kind of glue spraying and preparation method thereof - Google Patents
A kind of glue spraying and preparation method thereof Download PDFInfo
- Publication number
- CN106244103B CN106244103B CN201610667741.4A CN201610667741A CN106244103B CN 106244103 B CN106244103 B CN 106244103B CN 201610667741 A CN201610667741 A CN 201610667741A CN 106244103 B CN106244103 B CN 106244103B
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- parts
- stirring
- glue spraying
- resin
- organic solvent
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J193/00—Adhesives based on natural resins; Adhesives based on derivatives thereof
- C09J193/04—Rosin
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J145/00—Adhesives based on homopolymers or copolymers of compounds having no unsaturated aliphatic radicals in a side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic or in a heterocyclic system; Adhesives based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J153/00—Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
- C09J153/02—Vinyl aromatic monomers and conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/04—Thermoplastic elastomer
Abstract
The present invention relates to a kind of glue spraying and preparation method thereof, its weight includes：10~20 parts of synthetic rubber, 30~65 parts of tackifying resin, 0.1~0.5 part of bridging agent, 20~55 parts of organic solvent, impermeable dose 0.1~5 part.Have the advantages that：1. dicyandiamide solution is environmentally friendly, low taste, quick-drying, can rapid draing after spraying；2. construction application performance is good；3. the excellent combination property such as good combination property, adhesive strength, open hour.
Description
Technical field
The present invention relates to a kind of rubber adhesive, specifically a kind of preferable glue spraying of anti-permeability, the invention further relates to
The preparation method of above-mentioned glue spraying.
Background technology
At present, common glue spraying is mainly made up of materials such as synthetic rubber, tackifying resin, organic solvent, auxiliary agents, has system
Standby the features such as technique is simple, viscosity is low, sprayability is good, applied widely, it is mainly used in sofa, furniture, sponge, case and bag, fabrics
It is deep to be favored by market Deng field.
But because by construction process requirement, glue spraying viscosity is unsuitable too high, must be entered when being formulated and designing using a large amount of solvents
Row dilution, however, in the bonding of the loose material of quality applied to such as fabrics class, glue infiltration often occurs for common glue spraying
To the viscous material back side, overall manufacturing process is had a strong impact on, or even product quality problem can be caused.
Published similar technique is a lot, such as the glue spraying and its making work that number of patent application is 200510035847.4
Skill, glue spraying of the invention is pollution-free, harmless, and stickiness is strong, fast drying, can with resistance to height, smell is small, spraying is equal
Even, just viscous ability is strong, viscous force is lasting, ageing-resistant, solid content is high, and 10-30% is saved than common like product dosage, proper use of
It is harmless；Number of patent application is 201511015563.9 water white transparency environmental protection handbag glue spraying and preparation method thereof, this hair
Bright resistance to ag(e)ing is good, baby food made of rice-flour and sugar grace, water white transparency, taste are low, uniform, impermeable, viscous without poisonous and harmful substances, spray plane contact point-like
Intensity is higher with joint efforts；Number of patent application be 201610111061.4 a kind of net taste glue spraying of SBS types nanometer, environmental-protecting performance of the present invention
Well, ageing-resistant ability is strong, peel strength is high.
Above-mentioned patent is not directed on the infiltrative disclosure illustrated with beneficial effect.Therefore, prepare a kind of anti-
The glue spraying of good penetrability is imperative.
The content of the invention
The invention aims to overcome techniques as described above defect, there is provided a kind of good glue spraying of anti-permeability,
The preparation method of the glue spraying is also provided simultaneously.
The present invention is achieved in that a kind of glue spraying, includes by weight ratio：
10~20 parts of synthetic rubber
30~65 parts of tackifying resin
0.1~0.5 part of bridging agent
20~55 parts of organic solvent
Impermeable dose 0.1~5 part.
Described synthetic rubber is at least one in SBS thermoplastic elastomer (TPE)s, SIS thermoplastic elastomer (TPE)s, neoprene A30
Kind.
Described tackifying resin be hydrogenated rosin, phenolic resin, ester gum, Petropols, in terpene resin extremely
Few one kind.
Described bridging agent is at least one of zinc stearate, zinc acrylate resin.
Described organic solvent is at least one of hexamethylene, methyl acetate, dimethyl carbonate, acetone, 6# solvent naphthas.
Described organic solvent can also be at least one of dimethoxym ethane, petroleum ether, ethanol, sec-butyl acetate.
Described impermeable dose is bentonite or inorganic crystal whisker and nanometer diatomaceous earth, the mixture of silane coupler, by weight
Measure part to match, bentonite or inorganic crystal whisker: nanometer diatomaceous earth: silane coupler=2~5: 0.5~2: 0.1~1, wherein inorganic
Whisker is calcium carbonate crystal whisker, at least one of calcium sulfate crystal whiskers, the product of nanometer diatomaceous earth preferably three woods trade Co., Ltds,
Silane coupler is at least one of KH-550, KH-560, A-171, A-172, KBM-602.
The preferable weight of described impermeable dose is 0.1~2 part.
A kind of preparation method of glue spraying of the present invention, comprises the following steps：By weight ratio, organic solvent is added,
Under stirring, tackifying resin, synthetic rubber are added, stirring is to being uniformly dissolved；Impermeable dose is added, continues to disperse after stirring evenly
10~30 minutes, bridging agent is added, stirs evenly rear cooling discharging.
The present invention contrasts with market like product, has the advantages that：
1. pass through the type selecting of solvent and the rational design of dicyandiamide solution, it is ensured that dicyandiamide solution is environmentally friendly, low taste, quick-drying, spraying
After can rapid draing, reduce time of penetration；
2. construction application performance is good, is used by bridging agent and impermeable dose of rational design and collaboration, change spraying
Afterwards glue particle substrate surface spatial arrangement mode, solvent through path distance increase, before adhesive effect is not influenceed
Put, greatly reduce infiltration, so as to reach impermeable effect；
3. the excellent combination property such as good combination property, adhesive strength, open hour.
Embodiment
The present invention will be described for following examples, but the present invention is not limited to these examples system.To the present invention's
Embodiment is modified or carries out equivalent substitution to some technical characteristics, without departing from the spirit of the present invention program,
It all should cover among the claimed technical scheme scope of the present invention.
Embodiment 1
By weight ratio, 4 parts of methyl acetate, 4 parts of acetone, 2 parts of dimethyl carbonate, 10 parts of 6# solvent naphthas are added, is being stirred
Mix under state, add 20 parts of hydrogenated rosin, 10 parts of Petropols, 20 parts of terpene resin, 10 parts of SBS thermoplastic elastomer (TPE)s, stirring
To being uniformly dissolved；0.019 part of 0.077 part, nanometer diatomaceous earth of bentonite, 0.004 part of silane resin acceptor kh-550 are added, is stirred evenly
After continue scattered 10 minutes, add 0.1 part of zinc acrylate resin, stir evenly rear cooling discharging.
Embodiment 2
By weight ratio, 3 parts of ethanol, 5 parts of sec-butyl acetate, 12 parts of dimethoxym ethane, 20 parts of petroleum ether are added, in stirring shape
Under state, 10 parts of hydrogenated rosin, 15 parts of terpene resin, 5 parts of ester gum, 15 parts of SIS thermoplastic elastomer (TPE)s are added, is stirred to molten
Solution is uniform；0.48 part of bentonite 1.29 part, nanometer diatomaceous earth, 0.23 part of silane coupling A -171 are added, is continued after stirring evenly point
Dissipate 20 minutes, add 0.3 part of zinc acrylate resin, cooling discharging after stirring.
Embodiment 3
By weight ratio, 5 parts of hexamethylene, 15 parts of methyl acetate, 5 parts of dimethyl carbonate, 10 parts of acetone, 6# solvents are added
20 parts of oil, under stirring, add 15 parts of phenolic resin, 40 parts of ester gum, 10 parts of Petropols, neoprene A30
20 parts, stirring is to being uniformly dissolved；Add 1.25 parts of 3.12 part, nanometer diatomaceous earth of calcium sulfate crystal whiskers, silane coupler KBM-602
0.63 part, continue scattered 30 minutes, 0.5 part of zinc stearate of addition, cooling discharging after stirring after stirring evenly.
Comparative example 4
By weight ratio, 5 parts of ethyl acetate, 15 parts of acetone, 20 parts of 6# solvent naphthas are added, under stirring, is added
10 parts of hydrogenated rosin, 5 parts of terpene resin, 15 parts of ester gum, 15 parts of SIS thermoplastic elastomer (TPE)s, stirring is to being uniformly dissolved；Add
Enter 1.77 parts of white carbon, 0.23 part of silane coupling A -171, cooling discharging after stirring.
Comparative example 5
By weight ratio, 5 parts of hexamethylene, 10 parts of acetone, 20 parts of methyl acetate, 20 parts of 6# solvent naphthas are added, is being stirred
Under state, 25 parts of phenolic resin, 40 parts of ester gum, 20 parts of neoprene A30 are added, stirring is to being uniformly dissolved；Regulation turns
Speed is 1500r/min, adds 4.37 parts of calcium sulfate crystal whiskers, continues to disperse 30 minutes after stirring evenly, adds 0.5 part of zinc stearate, stir
Cooling discharging after mixing uniformly.
Embodiment 1~3, a kind of correlated performance method of testing of glue spraying of comparative example 4~5 are as follows：
1. peel strength：Canvas is to canvas, with reference to GB/T 2791-1995《Adhesive T peeling strength tests method is flexible
Material is to flexible material》Tested.
2. the open hour：With reference to GB/T 27561-2011《SBS (SBS) glue
Stick》Tested.
3. permeability：Anti-permeability is characterized, from 20 × 20cm2 primary colors gauze (fine gauze) and an equal amount of blank sheet of paper,
Gauze is overlapping with blank sheet of paper, glue is sprayed in gauze one side by 200g/m2 glue-spread, observes after a period of time and is permeated on blank sheet of paper
The area of glue accounts for the ratio of the gross area, and permeability is bigger, and anti-permeability is poorer.
Embodiment 1~3, the glue spraying the performance test results of comparative example 4~5 are as shown in table 1 below.
Table 1
As can be seen from the above table, a kind of glue spraying of the present invention and prior art（Comparative example 4~5）Compare, adhesive property is good, opens
Time length is put, permeability is low, on the premise of adhesive property is not influenceed, has significant anti-permeability.
Claims (1)
1. a kind of glue spraying, its feature part is, includes by weight ratio：
10~20 parts of synthetic rubber
30~65 parts of tackifying resin
0.1~0.5 part of bridging agent
20~55 parts of organic solvent
Impermeable dose 0.1~5 part；
Synthetic rubber is at least one of SBS thermoplastic elastomer (TPE)s, SIS thermoplastic elastomer (TPE)s, neoprene A30；Thickening tree
Fat is at least one of hydrogenated rosin, phenolic resin, ester gum, Petropols, terpene resin；Bridging agent is stearic acid
At least one of zinc, zinc acrylate resin；Organic solvent is in hexamethylene, methyl acetate, dimethyl carbonate, acetone, 6# solvent naphthas
At least one；Impermeable dose is bentonite or inorganic crystal whisker and nanometer diatomaceous earth, the mixture of silane coupler, by weight
Proportioning：Bentonite or inorganic crystal whisker: nanometer diatomaceous earth: silane coupler=2~5: 0.5~2: 0.1~1, wherein inorganic crystal whisker
For at least one of calcium carbonate crystal whisker, calcium sulfate crystal whiskers, nanometer diatomaceous earth is the product of three woods trade Co., Ltds, and silane is even
It is at least one of KH-550, KH-560, A-171, A-172, KBM-602 to join agent；Preparation method comprises the following steps：By weight
Part proportioning is measured, adds organic solvent, under stirring, adds tackifying resin, synthetic rubber, stirring is to being uniformly dissolved；Add
Impermeable dose, continue to disperse 10~30 minutes after stirring evenly, add bridging agent, stir evenly rear cooling discharging.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610667741.4A CN106244103B (en) | 2016-08-15 | 2016-08-15 | A kind of glue spraying and preparation method thereof |
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|---|---|---|---|
| CN201610667741.4A CN106244103B (en) | 2016-08-15 | 2016-08-15 | A kind of glue spraying and preparation method thereof |
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| CN106244103A CN106244103A (en) | 2016-12-21 |
| CN106244103B true CN106244103B (en) | 2018-02-06 |
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Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107142055A (en) * | 2017-06-06 | 2017-09-08 | 光山县博正树脂有限公司 | PP, PE special glue and preparation method thereof |
| CN108611054A (en) * | 2018-04-13 | 2018-10-02 | 中科广化（重庆）新材料研究院有限公司 | A kind of no triphen SBS types black glue spraying and preparation method thereof |
| CN109322211B (en) * | 2018-09-28 | 2021-07-30 | 东莞市贝辉装饰材料有限公司 | Silicon sheet amine-aldehyde resin glue, odorless adhesive film paper and preparation method |
| CN110734721B (en) * | 2019-09-16 | 2022-06-28 | 深圳市力洁化工科技有限公司 | Aerosol spray glue and preparation method thereof |
| CN112759984B (en) * | 2021-01-19 | 2022-04-15 | 广东美涂士建材股份有限公司 | Water-in-oil neoprene spray adhesive and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101418197A (en) * | 2008-12-01 | 2009-04-29 | 广东三和化工科技有限公司 | Environmental protection chloroprene rubber adhesive agent and production method thereof |
| CN101659838A (en) * | 2009-09-24 | 2010-03-03 | 广东三和化工科技有限公司 | Neoprene latex adhesive and preparation method thereof |
| CN103709960A (en) * | 2013-12-21 | 2014-04-09 | 广东三和化工科技有限公司 | Nail-free rubber and preparation method thereof |
| CN105176443A (en) * | 2015-10-13 | 2015-12-23 | 广东三和化工科技有限公司 | Solvent type rubber adhesive and preparation method thereof |
-
2016
- 2016-08-15 CN CN201610667741.4A patent/CN106244103B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101418197A (en) * | 2008-12-01 | 2009-04-29 | 广东三和化工科技有限公司 | Environmental protection chloroprene rubber adhesive agent and production method thereof |
| CN101659838A (en) * | 2009-09-24 | 2010-03-03 | 广东三和化工科技有限公司 | Neoprene latex adhesive and preparation method thereof |
| CN103709960A (en) * | 2013-12-21 | 2014-04-09 | 广东三和化工科技有限公司 | Nail-free rubber and preparation method thereof |
| CN105176443A (en) * | 2015-10-13 | 2015-12-23 | 广东三和化工科技有限公司 | Solvent type rubber adhesive and preparation method thereof |
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