CN107722926A - Transparent glue spraying of a kind of net taste of environmental protection and preparation method thereof - Google Patents

Transparent glue spraying of a kind of net taste of environmental protection and preparation method thereof Download PDF

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Publication number
CN107722926A
CN107722926A CN201710892528.8A CN201710892528A CN107722926A CN 107722926 A CN107722926 A CN 107722926A CN 201710892528 A CN201710892528 A CN 201710892528A CN 107722926 A CN107722926 A CN 107722926A
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CN
China
Prior art keywords
glue spraying
environmental protection
transparent glue
net taste
preparation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710892528.8A
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Chinese (zh)
Inventor
肖高军
蔡伟阳
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Foshan City Gaoming District Deligao Coating Co Ltd
Original Assignee
Foshan City Gaoming District Deligao Coating Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Foshan City Gaoming District Deligao Coating Co Ltd filed Critical Foshan City Gaoming District Deligao Coating Co Ltd
Priority to CN201710892528.8A priority Critical patent/CN107722926A/en
Publication of CN107722926A publication Critical patent/CN107722926A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J193/00Adhesives based on natural resins; Adhesives based on derivatives thereof
    • C09J193/04Rosin
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/08Macromolecular additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/10Transparent films; Clear coatings; Transparent materials
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

The invention discloses a kind of transparent glue spraying of net taste of environmental protection, include the following component of weight percentage:Thiacyclohexane 20 30%, No. 6 solvent naphthas 25 35%, SBS792 9.5 11.5%, terpenes tackifying resin 3 7%, superfine rosin 18 23%, hydrogenated petroleum resin 5 11%;The percentage by weight sum of said components is 100%.The invention also discloses a kind of preparation method of the transparent glue spraying of net taste of environmental protection.The glue spraying of the present invention have bonding force it is good, without benzene, smell it is small and the characteristics of color is transparent.

Description

Transparent glue spraying of a kind of net taste of environmental protection and preparation method thereof
Technical field
The present invention relates to a kind of glue spraying, and in particular to transparent glue spraying of a kind of net taste of environmental protection and preparation method thereof.
Background technology
Glue spraying be it is a kind of there is suitable viscosity, be suitable for spray gun as construction tool spraying application, it is different by two kinds Material interface closely connects, and plays the adhesive for transmitting application effect;Spraying application is often than traditional brushing construction party Formula can more reach time saving, laborsaving, save the effect such as glue, synergy, play a multiplier effect, glue spraying has been widely used in thickness Bonding between the materials such as skin, corium, imitation leather, regenerated bark, sponge, cloth, timber, metal, stone material, footwear material.Glue spraying includes solvent Type glue spraying (oiliness glue spraying) and water-soluble spraying glue,
At present, still based on low and middle-end solvent-borne type glue spraying, a large amount of organic solvents include poisonous glue spraying of the prior art Halogenated hydrocarbons and triphen (benzene,toluene,xylene) solvent got into the air in construction, viscous force difference be present and smell be big lacks Point, the petroleum oil resource being becoming tight a large amount of days was both consumed, has had a strong impact on people's lives environment and health again.
The content of the invention
For overcome the deficiencies in the prior art, an object of the present invention is to provide a kind of net taste of environmental protection transparent glue spraying, The glue spraying have bonding force it is good, without benzene, smell it is small and the characteristics of color is transparent.
The second object of the present invention is to provide a kind of preparation method of the transparent glue spraying of net taste of environmental protection, have it is easy to operate, The characteristics of safety and environmental protection, high stability.
An object of the present invention adopts the following technical scheme that realization:
A kind of transparent glue spraying of net taste of environmental protection, it is characterised in that the following component including weight percentage:
The percentage by weight sum of said components is 100%.
Further, the net transparent glue spraying of taste of the environmental protection includes the following component of weight percentage:Thiacyclohexane 20- 30%, No. 6 solvent naphtha 25-35%, SBS792 10.5-11.5%, terpenes tackifying resin 3-7%, superfine rosin 18-23%, hydrogen Fossil oleoresin 5-11%.
Further, the net transparent glue spraying of taste of the environmental protection includes the following component of weight percentage:Thiacyclohexane 20- 30%, No. 6 solvent naphtha 25-35%, SBS792 11%, terpenes tackifying resin 3-7%, superfine rosin 18-23%, non-hydrogenated petroleum Resin 5-11%.
Further, the net transparent glue spraying of taste of the environmental protection includes the following component of weight percentage:Thiacyclohexane 25%, No. 6 solvent naphthas 31%, SBS792 11%, terpenes tackifying resin 5%, superfine rosin 20%, hydrogenated petroleum resin 8%.
Further, the viscosity of the transparent glue spraying of the net taste of environmental protection is 80-120cps.
Further, solid the containing for 44% of the transparent glue spraying of the net taste of environmental protection.
The second object of the present invention adopts the following technical scheme that realization:
A kind of preparation method of the transparent glue spraying of the net taste of environmental protection, it is characterised in that including:
Material preparation step:Each raw material is weighed according to Formulations Formula, it is standby;
First time blend step:The thiacyclohexane of formula ratio is put into agitating device, then the SBS792 of formula ratio is put into In agitating device, after being warming up to 45-55 DEG C, stir, obtain the first mixture;
Second of blend step:No. 6 solvent naphthas, terpenes tackifying resin, superfine of formula ratio are added into the first mixture Rosin, hydrogenated petroleum resin, insulated and stirred is uniform, obtains the second mixture;
Detecting step:The second mixture is taken, viscosity is detected, after qualified, is packaged to be finished product.
Further, in first time blend step, mixing speed is 800-1200 revs/min, mixing time 0.5-1.5 Hour.
Further, in second of blend step, mixing speed is 800-1200 revs/min, mixing time 2.5-3.5 Hour.
Further, in detecting step, viscosity is detected using rotation viscometer.
Compared with prior art, the beneficial effects of the present invention are:
1st, the present invention is by optimization of C/C composites, develop with bonding force it is good, without the small glue spraying of benzene, smell, the product be Clear homogeneous thick liquid, no suspended substance, without visible mechanical admixture and phenomenon of phase separation.T peel strengths are detected, by adhesive material Tear fracture, in dry heat resistance energy (60 DEG C, 7d) splicing face without phenomenon of coming unglued.The initial bonding strength of glue spraying can reach 1.1KN.m-1, sponge with 180 DEG C of peel strengths of sponge can reach 3.9KN.m-1.The product of the present invention is applied to high-grade sponge, leather and has the viscous of moulding Close and use.
2nd, method of the invention, by Optimizing Process Parameters, there is the advantages of easy to operate, safety and environmental protection, high stability.
Embodiment
Below, with reference to embodiment, the present invention is described further, it is necessary to which explanation is, what is do not collided Under the premise of, new embodiment can be formed between various embodiments described below or between each technical characteristic in any combination.This reality Apply employed in example to material be commercially available.
A kind of transparent glue spraying of net taste of environmental protection, include the following component of weight percentage:Thiacyclohexane 20-30%, No. 6 Solvent naphtha 25-35%, SBS792 9.5-11.5%, terpenes tackifying resin 3-7%, superfine rosin 18-23%, non-hydrogenated petroleum tree Fat 5-11%;The percentage by weight sum of said components is 100%.
As preferred embodiment, the net transparent glue spraying of taste of environmental protection include weight percentage such as the following group Point:Thiacyclohexane 20-30%, No. 6 solvent naphthas 25-35%, SBS792 10.5-11.5%, terpenes tackifying resin 3-7%, superfine pine Fragrant 18-23%, hydrogenated petroleum resin 5-11%.
As preferred embodiment, the net transparent glue spraying of taste of environmental protection include weight percentage such as the following group Point:Thiacyclohexane 20-30%, No. 6 solvent naphtha 25-35%, SBS792 11%, terpenes tackifying resin 3-7%, superfine rosin 18- 23%, hydrogenated petroleum resin 5-11%.
As preferred embodiment, the net transparent glue spraying of taste of environmental protection include weight percentage such as the following group Point:Thiacyclohexane 25%, No. 6 solvent naphthas 31%, SBS792 11%, terpenes tackifying resin 5%, superfine rosin 20%, non-hydrogenated petroleum Resin 8%.
As preferred embodiment, the viscosity of the transparent glue spraying of the net taste of environmental protection is 80-120cps.
As preferred embodiment, solid the containing for 44% of the transparent glue spraying of the net taste of environmental protection.
As preferred embodiment, the superfine rosin is superfine galbanum.
A kind of preparation method of the transparent glue spraying of the net taste of environmental protection, including:
Material preparation step:Each raw material is weighed according to Formulations Formula, it is standby;
First time blend step:The thiacyclohexane of formula ratio is put into agitating device, then the SBS792 of formula ratio is put into In agitating device, after being warming up to 45-55 DEG C, stir, obtain the first mixture;
Second of blend step:No. 6 solvent naphthas, terpenes tackifying resin, superfine of formula ratio are added into the first mixture Rosin, hydrogenated petroleum resin, insulated and stirred is uniform, obtains the second mixture;
Detecting step:The second mixture is taken, viscosity is detected, after qualified, is packaged to be finished product.
As preferred embodiment, in first time blend step, mixing speed is 800-1200 revs/min, during stirring Between be 0.5-1.5 hours.
As preferred embodiment, in second of blend step, mixing speed is 800-1200 revs/min, during stirring Between be 2.5-3.5 hours.
As preferred embodiment, in detecting step, viscosity is detected using rotation viscometer, it is 80- to control viscosity 120cps。
Embodiment 1:
A kind of transparent glue spraying of net taste of environmental protection, include the following component of weight percentage:
Thiacyclohexane 25%, No. 6 solvent naphthas 31%, SBS792 11%, terpenes tackifying resin 5%, superfine rosin 20%, hydrogen Fossil oleoresin 8%.
A kind of preparation method of the transparent glue spraying of the net taste of environmental protection, including:
Material preparation step:Each raw material is weighed according to Formulations Formula, it is standby;
First time blend step:The thiacyclohexane of formula ratio is put into agitating device, then the SBS792 of formula ratio is put into In agitating device, after being warming up to 45-55 DEG C, stir, mixing speed is 1000 revs/min, and mixing time is 1 hour, is obtained To the first mixture;
Second of blend step:No. 6 solvent naphthas of formula ratio, terpenes tackifying resin, superfine pine are added into the first mixture Fragrant, hydrogenated petroleum resin, insulated and stirred is uniform, and mixing speed is 1000 revs/min, and mixing time is 3 hours, and it is mixed to obtain second Compound;
Detecting step:The second mixture is taken, detects viscosity using rotation viscometer, it is 80-120cps to control viscosity, qualified Afterwards, it is packaged to be finished product.
Embodiment 2:
A kind of transparent glue spraying of net taste of environmental protection, include the following component of weight percentage:Thiacyclohexane 30%, No. 6 molten Agent oil 25%, SBS792 10%, terpenes tackifying resin 7%, superfine rosin 18%, hydrogenated petroleum resin 10%.
The preparation method of the transparent glue spraying of environmentally friendly net taste is same as Example 1.
Embodiment 3:
A kind of transparent glue spraying of net taste of environmental protection, include the following component of weight percentage:
Thiacyclohexane 20%, No. 6 solvent naphthas 35%, SBS792 11.5%, terpenes tackifying resin 5.5%, superfine rosin 23%, hydrogenated petroleum resin 5%.
The preparation method of the transparent glue spraying of environmentally friendly net taste is same as Example 1.
Embodiment 4:
A kind of transparent glue spraying of net taste of environmental protection, include the following component of weight percentage:
Thiacyclohexane 24.5%, No. 6 solvent naphthas 30%, SBS792 11.5%, terpenes tackifying resin 3%, superfine rosin 20%, hydrogenated petroleum resin 11%;.
The preparation method of the transparent glue spraying of environmentally friendly net taste is same as Example 1.
Comparative example 1:
A kind of glue spraying, include the following component of weight percentage:
Thiacyclohexane 25%, No. 6 solvent naphthas 35%, SBS792 7%, terpenes tackifying resin 5%, superfine rosin 20%, hydrogenation Petropols 8%.
The preparation method of glue spraying is same as Example 1.
Comparative example 2:
A kind of glue spraying, include the following component of weight percentage:
Thiacyclohexane 25%, No. 6 solvent naphthas 33%, SBS792 9%, terpenes tackifying resin 5%, superfine rosin 20%, hydrogenation Petropols 8%.
The preparation method of glue spraying is same as Example 1.
Comparative example 3:
A kind of glue spraying, include the following component of weight percentage:
Thiacyclohexane 25%, No. 6 solvent naphthas 30%, SBS792 12%, terpenes tackifying resin 5%, superfine rosin 20%, hydrogen Fossil oleoresin 8%.
The preparation method of glue spraying is same as Example 1.
Performance test:
Embodiment 1-4 and comparative example 1-3 glue spraying are tested respectively, test result is shown in Table 1:
Table 1
The present invention passes through lot of experiments, as a result proves:11% SBS792 is optimum addition, when addition is optimal When, the initial bonding strength of glue spraying is 1.1KN.m-1, sponge and 180 DEG C of peel strengths of sponge are 3.9KN.m-1, material rupture, exceed The performance of like product, cementability is substantially increased, and meet environmental protection requirement.
Above-mentioned embodiment is only the preferred embodiment of the present invention, it is impossible to the scope of protection of the invention is limited with this, The change and replacement for any unsubstantiality that those skilled in the art is done on the basis of the present invention belong to institute of the present invention Claimed scope.

Claims (10)

  1. A kind of 1. transparent glue spraying of net taste of environmental protection, it is characterised in that the following component including weight percentage:
    The percentage by weight sum of said components is 100%.
  2. 2. the transparent glue spraying of the net taste of environmental protection as claimed in claim 1, it is characterised in that including the as follows of weight percentage Component:Thiacyclohexane 20-30%, No. 6 solvent naphthas 25-35%, SBS792 10.5-11.5%, terpenes tackifying resin 3-7%, it is superfine Rosin 18-23%, hydrogenated petroleum resin 5-11%.
  3. 3. the transparent glue spraying of the net taste of environmental protection as claimed in claim 1, it is characterised in that including the as follows of weight percentage Component:Thiacyclohexane 20-30%, No. 6 solvent naphtha 25-35%, SBS792 11%, terpenes tackifying resin 3-7%, superfine rosin 18- 23%, hydrogenated petroleum resin 5-11%.
  4. 4. the transparent glue spraying of the net taste of environmental protection as claimed in claim 1, it is characterised in that including the as follows of weight percentage Component:Thiacyclohexane 25%, No. 6 solvent naphthas 31%, SBS792 11%, terpenes tackifying resin 5%, superfine rosin 20%, hydrogenate stone Oleoresin 8%.
  5. 5. the transparent glue spraying of the net taste of environmental protection as claimed in claim 1, it is characterised in that the viscosity of the transparent glue spraying of the net taste of environmental protection For 80-120cps.
  6. 6. the transparent glue spraying of the net taste of environmental protection as claimed in claim 1, it is characterised in that consolidating for the transparent glue spraying of the net taste of environmental protection contains For 44%.
  7. A kind of 7. preparation method of the transparent glue spraying of the net taste of environmental protection as claimed in any one of claims 1 to 6, it is characterised in that bag Include:
    Material preparation step:Each raw material is weighed according to Formulations Formula, it is standby;
    First time blend step:By the SBS792 input stirrings in the thiacyclohexane input agitating device of formula ratio, then by formula ratio In device, after being warming up to 45-55 DEG C, stir, obtain the first mixture;
    Second of blend step:Added into the first mixture No. 6 solvent naphthas of formula ratio, terpenes tackifying resin, superfine rosin, Hydrogenated petroleum resin, insulated and stirred is uniform, obtains the second mixture;
    Detecting step:The second mixture is taken, viscosity is detected, after qualified, is packaged to be finished product.
  8. 8. the preparation method of the transparent glue spraying of the net taste of environmental protection as claimed in claim 7, it is characterised in that first time blend step In, mixing speed is 800-1200 revs/min, and mixing time is 0.5-1.5 hours.
  9. 9. the preparation method of the transparent glue spraying of the net taste of environmental protection as claimed in claim 7, it is characterised in that second of blend step In, mixing speed is 800-1200 revs/min, and mixing time is 2.5-3.5 hours.
  10. 10. the preparation method of the transparent glue spraying of the net taste of environmental protection as claimed in claim 7, it is characterised in that in detecting step, use Rotation viscometer detects viscosity.
CN201710892528.8A 2017-09-27 2017-09-27 Transparent glue spraying of a kind of net taste of environmental protection and preparation method thereof Pending CN107722926A (en)

Priority Applications (1)

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CN201710892528.8A CN107722926A (en) 2017-09-27 2017-09-27 Transparent glue spraying of a kind of net taste of environmental protection and preparation method thereof

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Application Number Priority Date Filing Date Title
CN201710892528.8A CN107722926A (en) 2017-09-27 2017-09-27 Transparent glue spraying of a kind of net taste of environmental protection and preparation method thereof

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CN107722926A true CN107722926A (en) 2018-02-23

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109021846A (en) * 2018-08-01 2018-12-18 佛山市高明区德力高涂料有限公司 A kind of environmental protection ordor removing foam glue and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1035188A1 (en) * 1996-04-15 2000-09-13 Hercules Incorporated Viscosity modifier for hot-melt adhesives
CN1451708A (en) * 2003-04-21 2003-10-29 黄楚填 Environment protection spray universal adhesive, and preparation and use method thereof
CN105567156A (en) * 2016-02-29 2016-05-11 广东泰强化工实业有限公司 SBS-type nano deodorization spray adhesive

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1035188A1 (en) * 1996-04-15 2000-09-13 Hercules Incorporated Viscosity modifier for hot-melt adhesives
CN1451708A (en) * 2003-04-21 2003-10-29 黄楚填 Environment protection spray universal adhesive, and preparation and use method thereof
CN105567156A (en) * 2016-02-29 2016-05-11 广东泰强化工实业有限公司 SBS-type nano deodorization spray adhesive

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109021846A (en) * 2018-08-01 2018-12-18 佛山市高明区德力高涂料有限公司 A kind of environmental protection ordor removing foam glue and preparation method thereof
CN109021846B (en) * 2018-08-01 2022-04-22 佛山市高明区德力高涂料有限公司 Environment-friendly odor-free foam adhesive and preparation method thereof

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Application publication date: 20180223