CN105567156A - SBS-type nano deodorization spray adhesive - Google Patents
SBS-type nano deodorization spray adhesive Download PDFInfo
- Publication number
- CN105567156A CN105567156A CN201610111061.4A CN201610111061A CN105567156A CN 105567156 A CN105567156 A CN 105567156A CN 201610111061 A CN201610111061 A CN 201610111061A CN 105567156 A CN105567156 A CN 105567156A
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- China
- Prior art keywords
- sbs
- percent
- glue spraying
- type nanometer
- clean taste
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J193/00—Adhesives based on natural resins; Adhesives based on derivatives thereof
- C09J193/04—Rosin
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses an SBS-type nano deodorization spray adhesive. The SBS-type nano deodorization spray adhesive is prepared from the following components by weight percent: 5 to 10 percent of SBS1401, 5 to 10 percent of SBS1301, 4 to 8 percent of methyl acetate, 4 to 8 percent of cyclohexane, 45 to 52 percent of solvent oil No.6, 4 to 8 percent of terpene resin, 3 to 6 percent of C5 hydrogenated petroleum resin, 13 to 18 percent of polymerized rosin, 5 to 10 percent of disproportionated rosin and 0.1 to 0.3 percent of antioxidant. The SBS-type nano deodorization spray adhesive is good in environmental protection, high in anti-aging capacity and high in stripping strength.
Description
Technical field
The present invention relates to glue spraying field, particularly the clean taste glue spraying of a kind of SBS type nanometer.
Background technology
Chinese patent application CN200910037409.X discloses a kind of SBS multi-purpose adhesive, it becomes the starting material of number to make by following quality group: environmentally friendly solvent: 60 ~ 65 parts, SBS:15 ~ 20 part, terpine resin: 3 ~ 6 parts, petroleum resin: 3 ~ 6 parts, rosin: 4 ~ 7 parts, filler: 1 ~ 3 part, frostproofer: 1 ~ 3 part, anti-aging agent: 1 ~ 3 part; The SBS multi-purpose adhesive made by this technique has that brushing area is large, environmental protection, solid content is high, initial bonding strength is strong, transparent, smell is good feature, thus can be widely used in the bonding of the materials such as aluminium-plastic panel, PLASTIC LAMINATED, wooden skin, plank.
Chinese patent application CN201510677753.0 SBS tackiness agent disclosing a kind of salt spray resistance and preparation method thereof, relate to field of adhesive technology, it comprises following component and the weight proportion of each component is: thermoplastic styrene butadiene rubber 15-25 part, tackifying resin 10-25 part, salt spray resistance auxiliary agent 0.1-5 part, silane coupling agent 0.1-5 part, anti-aging agent 0.1-5 part, solvent 45-60 part.The irritating smell amount that the SBS tackiness agent of this salt spray resistance distributes in tackiness agent when reality uses is few, and the feature of environmental protection is better, and it has very outstanding salt spray resistance simultaneously, can meet the service requirements of coastal or high salt mist environment well.
Although above-mentioned composition has certain environmental protection superiority, and viscosity is high, its Problems existing is to there is a need to further raising in ageing-resistant performance, environmental-protecting performance, intensity.
Summary of the invention
The object of this invention is to provide a kind of good environmental protection, ageing-resistant ability be strong, the clean taste glue spraying of SBS type nanometer that stripping strength is large.
Technical scheme of the present invention is: the clean taste glue spraying of a kind of SBS type nanometer, comprises following component:
In the above-mentioned clean taste glue spraying of SBS type nanometer, comprise following component:
In the above-mentioned clean taste glue spraying of SBS type nanometer, described oxidation inhibitor is antioxidant 264.
In the above-mentioned clean taste glue spraying of SBS type nanometer, the described clean taste glue spraying of SBS type nanometer is prepared by following steps:
S1: take each component in proportion;
S2: ritalin, hexanaphthene, No. 6 solvent oils are added remaining ingredient after mixing, stirs at normal temperatures and makes it abundant dissolving;
S3: mixture S2 process obtained obtains the clean taste glue spraying of SBS type nanometer after filtering.
Beneficial effect of the present invention is as follows:
The present invention adopts multi-solvents 5 to join, and improves the mixing uniformity in this formula between resin, improves ageing-resistant ability and the stripping ability of this glue spraying.The present invention simultaneously adopts SBS1401, SBS1301, C5 hydrogenated petroleum resin, terpine resin, polymerized rosin, nilox resin effectively to improve ageing-resistant performance and the stripping ability of resin compound.
Embodiment
Below in conjunction with embodiment, technical scheme of the present invention is described in further detail, but does not form any limitation of the invention.
Specific embodiment 1:
The clean taste glue spraying of a kind of SBS type nanometer, composed of the following components:
Its preparation method is as follows:
S1: take each component in proportion;
S2: ritalin, hexanaphthene, No. 6 solvent oils are added remaining ingredient after mixing, stirs and makes it abundant dissolving at 30 DEG C;
S3: mixture S2 process obtained obtains the clean taste glue spraying of SBS type nanometer after filtering.
Specific embodiment 2
The clean taste glue spraying of a kind of SBS type nanometer, composed of the following components:
Its preparation method is as follows:
S1: take each component in proportion;
S2: ritalin, hexanaphthene, No. 6 solvent oils are added remaining ingredient after mixing, stirs and makes it abundant dissolving at 30 DEG C;
S3: mixture S2 process obtained obtains the clean taste glue spraying of SBS type nanometer after filtering.
Specific embodiment 3
The clean taste glue spraying of a kind of SBS type nanometer, composed of the following components:
Its preparation method is as follows:
S1: take each component in proportion;
S2: ritalin, hexanaphthene, No. 6 solvent oils are added remaining ingredient after mixing, stirs and makes it abundant dissolving at 30 DEG C;
S3: mixture S2 process obtained obtains the clean taste glue spraying of SBS type nanometer after filtering.
Specific embodiment 4
The clean taste glue spraying of a kind of SBS type nanometer, composed of the following components:
Its preparation method is as follows:
S1: take each component in proportion;
S2: ritalin, hexanaphthene, No. 6 solvent oils are added remaining ingredient after mixing, stirs and makes it abundant dissolving at 30 DEG C;
S3: mixture S2 process obtained obtains the clean taste glue spraying of SBS type nanometer after filtering.
Specific embodiment 5
The clean taste glue spraying of a kind of SBS type nanometer, composed of the following components:
Its preparation method is as follows:
S1: take each component in proportion;
S2: ritalin, hexanaphthene, No. 6 solvent oils are added remaining ingredient after mixing, stirs and makes it abundant dissolving at 30 DEG C;
S3: mixture S2 process obtained obtains the clean taste glue spraying of SBS type nanometer after filtering.
Specific embodiment 6
The clean taste glue spraying of a kind of SBS type nanometer, composed of the following components:
Its preparation method is as follows:
S1: take each component in proportion;
S2: ritalin, hexanaphthene, No. 6 solvent oils are added remaining ingredient after mixing, stirs and makes it abundant dissolving at 30 DEG C;
S3: mixture S2 process obtained obtains the clean taste glue spraying of SBS type nanometer after filtering.
Comparative example 1
Glue spraying is filled a prescription:
Preparation method is with embodiment 6.
Application experiment:
Experiment 1 is with reference to GBT27561-2011 styrene-butadiene-styrene block copolymer (SBS) tackiness agent standard, and the mensuration of Section of 5.6 T stripping strength tests T stripping strength;
Experiment 2 is with reference to GBT27561-2011 styrene-butadiene-styrene block copolymer (SBS) tackiness agent standard, and 5.7.2 saves the dry heat resistance experiment of glue spraying.
Experiment 3 is with reference to GBT27561-2011 styrene-butadiene-styrene block copolymer (SBS) tackiness agent standard, the record of 5.6.1 prepares sample, sample is placed in 50 DEG C of thermostat container constant temperature 24h, then sample is placed in the refrigerator constant temperature 24h of-5 DEG C, repeating aforesaid operations, is a circulation with 48h, observes sample cement plane and whether produces slight crack and bubbling, as produced slight crack and bubbling then judges that this time circulates unsuccessfully, the number of times of the successful circulation of record.
Test result is as table 1
Table 1
| Experiment 1 | Experiment 2 | Test 3/ number | |
| Embodiment 1 | Qualified | Without bubbling without coming unglued | 3 |
| Embodiment 2 | Qualified | Without bubbling without coming unglued | 3 |
| Embodiment 3 | Qualified | Without bubbling without coming unglued | 2 |
| Embodiment 4 | Qualified | Without bubbling without coming unglued | 3 |
| Embodiment 5 | Qualified | Without bubbling without coming unglued | 5 |
| Embodiment 6 | Qualified | Without bubbling without coming unglued | 6 |
| Comparative example 1 | Qualified | Bubbling 2 nothings are come unglued | 1 |
Above-describedly be only preferred embodiment of the present invention, all do within the scope of the spirit and principles in the present invention any amendment, equivalently to replace and improvement etc., all should be included within protection scope of the present invention.
Claims (4)
1. the clean taste glue spraying of SBS type nanometer, is characterized in that: comprise following component:
2. the clean taste glue spraying of SBS type nanometer according to claim 1, is characterized in that: comprise following component:
3. the clean taste glue spraying of SBS type nanometer according to claim 1 and 2, is characterized in that: described oxidation inhibitor is antioxidant 264.
4. the clean taste glue spraying of SBS type nanometer according to claim 1 and 2, is characterized in that: the described clean taste glue spraying of SBS type nanometer is prepared by following steps:
S1: take each component in proportion;
S2: ritalin, hexanaphthene, No. 6 solvent oils are added remaining ingredient after mixing, stirs at normal temperatures and makes it abundant dissolving;
S3: mixture S2 process obtained obtains the clean taste glue spraying of SBS type nanometer after filtering.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610111061.4A CN105567156A (en) | 2016-02-29 | 2016-02-29 | SBS-type nano deodorization spray adhesive |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610111061.4A CN105567156A (en) | 2016-02-29 | 2016-02-29 | SBS-type nano deodorization spray adhesive |
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| Publication Number | Publication Date |
|---|---|
| CN105567156A true CN105567156A (en) | 2016-05-11 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610111061.4A Pending CN105567156A (en) | 2016-02-29 | 2016-02-29 | SBS-type nano deodorization spray adhesive |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105838269A (en) * | 2016-05-30 | 2016-08-10 | 广东泰强化工实业有限公司 | Multipurpose spray glue and preparation method thereof |
| CN107189720A (en) * | 2017-05-22 | 2017-09-22 | 广东泰强化工实业有限公司 | A kind of ageing-resistant antiscirrhous bi-component waterborne glue spraying and preparation method thereof |
| CN107722926A (en) * | 2017-09-27 | 2018-02-23 | 佛山市高明区德力高涂料有限公司 | Transparent glue spraying of a kind of net taste of environmental protection and preparation method thereof |
| CN107739591A (en) * | 2017-09-27 | 2018-02-27 | 佛山市高明区德力高涂料有限公司 | A kind of net taste strength glue spraying of environmental protection and preparation method thereof |
| CN108611054A (en) * | 2018-04-13 | 2018-10-02 | 中科广化（重庆）新材料研究院有限公司 | A kind of no triphen SBS types black glue spraying and preparation method thereof |
| CN109021846A (en) * | 2018-08-01 | 2018-12-18 | 佛山市高明区德力高涂料有限公司 | A kind of environmental protection ordor removing foam glue and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101294053A (en) * | 2008-06-25 | 2008-10-29 | 佛山市美涂士化工有限公司 | Rubber toughened SBS aldehyde removed all-purpose adhesive and preparation method thereof |
| CN102775955A (en) * | 2011-05-11 | 2012-11-14 | 深圳市顾康力化工有限公司 | Environment-friendly solvent spraying glue and preparation method thereof |
| CN105153980A (en) * | 2015-10-20 | 2015-12-16 | 湖南金化科技集团有限公司 | Salt spray resistant SBS adhesive and preparation method thereof |
-
2016
- 2016-02-29 CN CN201610111061.4A patent/CN105567156A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101294053A (en) * | 2008-06-25 | 2008-10-29 | 佛山市美涂士化工有限公司 | Rubber toughened SBS aldehyde removed all-purpose adhesive and preparation method thereof |
| CN102775955A (en) * | 2011-05-11 | 2012-11-14 | 深圳市顾康力化工有限公司 | Environment-friendly solvent spraying glue and preparation method thereof |
| CN105153980A (en) * | 2015-10-20 | 2015-12-16 | 湖南金化科技集团有限公司 | Salt spray resistant SBS adhesive and preparation method thereof |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105838269A (en) * | 2016-05-30 | 2016-08-10 | 广东泰强化工实业有限公司 | Multipurpose spray glue and preparation method thereof |
| CN105838269B (en) * | 2016-05-30 | 2017-05-24 | 广东泰强化工实业有限公司 | Multipurpose spray glue and preparation method thereof |
| CN107189720A (en) * | 2017-05-22 | 2017-09-22 | 广东泰强化工实业有限公司 | A kind of ageing-resistant antiscirrhous bi-component waterborne glue spraying and preparation method thereof |
| CN107722926A (en) * | 2017-09-27 | 2018-02-23 | 佛山市高明区德力高涂料有限公司 | Transparent glue spraying of a kind of net taste of environmental protection and preparation method thereof |
| CN107739591A (en) * | 2017-09-27 | 2018-02-27 | 佛山市高明区德力高涂料有限公司 | A kind of net taste strength glue spraying of environmental protection and preparation method thereof |
| CN108611054A (en) * | 2018-04-13 | 2018-10-02 | 中科广化（重庆）新材料研究院有限公司 | A kind of no triphen SBS types black glue spraying and preparation method thereof |
| CN109021846A (en) * | 2018-08-01 | 2018-12-18 | 佛山市高明区德力高涂料有限公司 | A kind of environmental protection ordor removing foam glue and preparation method thereof |
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Application publication date: 20160511 |
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