CN103555267B - Tectorial paper overlapping glue of a kind of firework, packaging industry and preparation method thereof - Google Patents
Tectorial paper overlapping glue of a kind of firework, packaging industry and preparation method thereof Download PDFInfo
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- CN103555267B CN103555267B CN201310547056.4A CN201310547056A CN103555267B CN 103555267 B CN103555267 B CN 103555267B CN 201310547056 A CN201310547056 A CN 201310547056A CN 103555267 B CN103555267 B CN 103555267B
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- firework
- wetting agents
- packaging industry
- substrate wetting
- overlapping glue
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- 239000003292 glue Substances 0.000 title claims abstract description 14
- 238000004806 packaging method and process Methods 0.000 title claims abstract description 13
- 238000002360 preparation method Methods 0.000 title claims description 10
- 239000011347 resin Substances 0.000 claims abstract description 21
- 229920005989 resin Polymers 0.000 claims abstract description 21
- 239000000080 wetting agent Substances 0.000 claims abstract description 19
- 239000000758 substrate Substances 0.000 claims abstract description 15
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 14
- 239000000463 material Substances 0.000 claims abstract description 10
- 239000002904 solvent Substances 0.000 claims abstract description 9
- 239000004902 Softening Agent Substances 0.000 claims abstract description 8
- 239000003112 inhibitor Substances 0.000 claims abstract description 8
- 230000003647 oxidation Effects 0.000 claims abstract description 8
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 8
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 18
- 238000003756 stirring Methods 0.000 claims description 15
- 239000000203 mixture Substances 0.000 claims description 10
- 239000012046 mixed solvent Substances 0.000 claims description 8
- NKDDWNXOKDWJAK-UHFFFAOYSA-N dimethoxymethane Chemical compound COCOC NKDDWNXOKDWJAK-UHFFFAOYSA-N 0.000 claims description 6
- 238000001914 filtration Methods 0.000 claims description 6
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 6
- 238000012360 testing method Methods 0.000 claims description 6
- 239000003208 petroleum Substances 0.000 claims description 5
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 claims description 4
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims description 3
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims description 3
- 238000005070 sampling Methods 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims description 3
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims description 3
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 claims description 2
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 claims description 2
- 238000007789 sealing Methods 0.000 abstract description 5
- 239000004721 Polyphenylene oxide Substances 0.000 abstract description 3
- 150000001875 compounds Chemical class 0.000 abstract description 3
- 229920001577 copolymer Polymers 0.000 abstract description 3
- 229920000570 polyether Polymers 0.000 abstract description 3
- 239000004744 fabric Substances 0.000 abstract description 2
- 239000006260 foam Substances 0.000 abstract description 2
- 239000002649 leather substitute Substances 0.000 abstract description 2
- 238000007639 printing Methods 0.000 abstract description 2
- 239000000123 paper Substances 0.000 description 12
- 239000007788 liquid Substances 0.000 description 6
- 230000000694 effects Effects 0.000 description 4
- 239000004568 cement Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 239000002344 surface layer Substances 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000002655 kraft paper Substances 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
Landscapes
- Adhesives Or Adhesive Processes (AREA)
Abstract
The present invention relates to the tectorial paper overlapping glue of a kind of firework, packaging industry, its each component and weight ratio as follows: caking agent? 12-18%, tackifying resin 20-40%, solvent 45-65%, oxidation inhibitor? 0.1-0.5%, softening agent 0-2%, substrate wetting agents 1%-5%, by selecting the polyether siloxane copolymer of 100% active matter content as substrate wetting agents, the present invention is made to have possessed good penetrability in paper material, be easy to smear, adeciduate feature; It is good that the preferred formula of combination simultaneously makes product of the present invention possess tack, tack time is long, strong adhesion, good penetrability, be easy to smear, the features such as bonding strength is high, high-low temperature resistant, are applicable to the craft sealing of firework industry, packages printing industry overlay film poster paper, overlay film carton, overlay film carton, can be widely used in the material such as compound, timber, sponge, foam bonding of case and bag, clothing artificial leather PVC/ cloth.
Description
Technical field
The present invention relates to the tectorial paper overlapping glue and preparation method thereof of a kind of firework, packaging industry, belong to adhesive area.
Background technology
Firework, packaging industry use papery all in a large number, especially the kraft paper thickeied, the display shell ball coating of firework industry, between hemisphere and hemisphere, between lead-in wire pipe core and hemisphere, to organize the tackiness agent that potted flower big gun paper web and base etc. need to use very high to infiltrative requirement, otherwise due to thickness and the fragility of papery, normally used tackiness agent, after paper surface layer attachment, is difficult to go deep into papery nexine, easily causes top layer to tear bonding unstable situation.For head it off, the domestic solvent cement also seeing promising increase dispersiveness interpolation dispersion agent or common wetting agent, quoting of wetting agent, uses extensively in paint field, normally in order to solve the layering of tackiness agent self and activity etc. in solvent cement.As CN101979453B discloses a kind of display shell spreading-ball sealing glue and preparation method thereof, the invention provides a kind of specially for the sealing compound of firework industry display shell ball coating sealing, but owing to employing mass filler, when utilization and brushing, be not easy to smear, mobility and perviousness bad.
Summary of the invention
For solving the problems of the technologies described above, the present invention relates to the tectorial paper overlapping glue and preparation method thereof of a kind of firework, packaging industry, it is good that this tackiness agent possesses tack, tack time is long, strong adhesion, good penetrability, be easy to smear, bonding strength be high, the feature such as high-low temperature resistant.
The present invention adopts following technical scheme:
A tectorial paper overlapping glue for firework, packaging industry, each component and weight ratio as follows: caking agent 12-18%, tackifying resin 20-40%, solvent 45-65%, oxidation inhibitor 0.1-0.5%, softening agent 0-2%, substrate wetting agents 1%-5%;
The weight percentage sum of each component is 100%;
Described caking agent is selected: elastomeric a kind of or their mixture of SBS elastomerics, styrene-butadiene rubber(SBR), SIS;
Described tackifying resin is selected: Gum Rosin, terpine resin, C5 petroleum resin, C9 petroleum resin, modified rosin resin a kind of or their mixture;
Ethyl acetate that what described solvent was selected is, methylal, 120# industrial naptha a kind of or their mixture; What described oxidation inhibitor was selected is antioxidant 264, antioxidant 1010 a kind of or their mixture; What described softening agent was selected is dibutyl phthalate, naphthenic oil a kind of or their mixture;
The polyether siloxane copolymer of what described substrate wetting agents was selected is 100% active matter content, transparent liquid, what specifically select is the efficient ground wetting agent that German goldschmidt chemical corporation is produced, the one that model is enlightening height TEGOWetKL245 substrate wetting agents, model is TEGO Wet 265 substrate wetting agents.
The preparation method of described a kind of firework, the tectorial paper overlapping glue of packaging industry is as follows:
The first step: the preparation of mixed solvent: first add in reactor in the ratio being 1:1:2 according to weight ratio by ethyl acetate, methylal, 120# industrial naptha, temperature controls, at 20 DEG C-40 DEG C, to be mixed with mixed solvent for subsequent use;
Second step: the mixed solvent that upper step is prepared is added in reactor, start stirring, add tackifying resin while stirring, stir 1 hour, add SBS elastomerics or styrene-butadiene rubber(SBR) or SIS elastomerics again, stir 5-8 hour, then add softening agent, oxidation inhibitor, substrate wetting agents by weight, stir 3-4 hour;
3rd step: sampling and testing viscosity, in the scope of 1600-2600mpa.s, adopts 60 object filtering nets that material filtering is finished product.
Positively effect of the present invention is: the model that 1, this tectorial paper overlapping glue selects the former German goldschmidt chemical corporation for paint field to produce is the efficient ground wetting agent of enlightening height TEGOWetKL245, and model is the substrate wetting agents of TEGO Wet 265, the polyether siloxane copolymer of 100% active matter content, transparent liquid.Wet KL 245 and Wet 265 is a kind of very effective molecular structures, it can reduce material surface tension force and be free from side effects, they reduce capillary Performance Ratio hydrocarbon polymer promoting agent and will get well, and more effective than the silicone surfactant of higher molecular weight.Utilization in the present invention, makes to invention achieves unforeseeable technique effect, especially shows tackiness agent good penetrability in paper material, is easy to smear, and can not cause cracking because paper surface layer comes off; 2, selected good toughness, bonding strength is high, and the synthetic rubber of high-low temperature resistant does caking agent, selects the resin that viscosity is good, cohesive strength is high, thermotolerance is good to be tackifying resin, selects volatile and toxicity is low material is solvent; Therefore to possess tack good for product of the present invention, and tack time is long, strong adhesion, good penetrability, be easy to smear, bonding strength be high, the feature such as high-low temperature resistant, be applicable to the craft sealing of firework industry, packages printing industry overlay film poster paper, overlay film carton, overlay film carton.This tackiness agent can be widely used in the material such as compound, timber, sponge, foam, papery bonding of case and bag, clothing artificial leather PVC/ cloth.
Embodiment
For further describing the present invention, with specific embodiment, technical scheme of the present invention is described below, but protection scope of the present invention is not limited only to this;
Embodiment 1
First add in reactor in the ratio being 1:1:2 according to weight ratio by ethyl acetate, methylal, 120# industrial naptha, temperature controls, at 20 DEG C-40 DEG C, to be mixed with mixed solvent for subsequent use.；
The mixed solvent that upper step is prepared is added in reactor, starts stirring, add tackifying resin while stirring, stir 1 hour, then add SBS elastomerics or styrene-butadiene rubber(SBR) or SIS elastomerics, stir 5-8 hour, add softening agent, oxidation inhibitor, substrate wetting agents by weight again, stir 3-4 hour.Sampling and testing viscosity, in the scope of 1600-2600mpa.s, adopts 60 object filtering nets that material filtering is finished product.
Embodiment 2, embodiment 3, reference example preparation method are with embodiment 1;
Embodiment, reference example each component parts by weight are see table 1:
Table 1
| Material name | Embodiment 1 | Embodiment 2 | Embodiment 3 | Reference example |
| Ethyl acetate | 13 | 13 | 13 | 13 |
| Methylal | 13 | 13 | 13 | 13 |
| Solvent oil | 26 | 26 | 26 | 26 |
| Styrene-butadiene rubber(SBR) | 3 | 3 | 3 | 3 |
| SBS | 10 | 11 | 12 | 11 |
| Gum Rosin | 12 | 12 | 12 | 12 |
| Terpine resin | 5 | 5 | 5 | 5 |
| Petroleum resin | 6 | 6 | 6 | 6 |
| Modified rosin resin | 8 | 7 | 6 | 10 |
| Naphthenic oil | 2 | 1 | 0 | 1 |
| 264 | 0.1 | 0.1 | 0.1 | 0.1 |
| Substrate wetting agents | 2 | 3 | 4 | 0 |
| Add up to | 100.1 | 100.1 | 100.1 | 100.1 |
The performance testing index of embodiment, reference example with reference to relevant criterion (test environment: temperature: 25 DEG C, humidity: 70%) as table 2:
Table 2 embodiment, reference example performance testing index
| Index | Embodiment 1 | Embodiment 2 | Embodiment 3 | Reference example |
| Outward appearance | Yellow viscous liquid | Yellow viscous liquid | Yellow viscous liquid | Yellow viscous liquid |
| Solid content | 48.22% | 48.35% | 48.17% | 48.25% |
| Viscosity | 2100mpa.s | 2250mpa.s | 2360mpa.s | 2200 mpa.s |
| Initial bonding strength (steel ball number) | 24 | 26 | 28 | 24 |
| The tectorial paper open hour | 40 minutes | 60 minutes | 80 minutes | 30 minutes |
| Stripping strength (canvas-canvas, 48h) | 2.82KN/m | 3.45 KN/m | 3.88 KN/m | 2.65 KN/m |
| Environmental protection index | Meet GB 18583-2008 | Meet GB 18583-2008 | Meet GB 18583-2008 | Meet GB 18583-2008 |
Claims (5)
1. a tectorial paper overlapping glue for firework, packaging industry, it is characterized in that each component and weight ratio as follows: caking agent 12-18%, tackifying resin 20-40%, solvent 45-65%, oxidation inhibitor 0.1-0.5%, softening agent 0-2%, substrate wetting agents 1%-5%; The weight percentage sum of each component is 100%;
What described substrate wetting agents was selected is the one that the model that German goldschmidt chemical corporation is produced is enlightening height TEGOWetKL245 substrate wetting agents, model is TEGO Wet 265 substrate wetting agents;
Described caking agent is selected: elastomeric a kind of or their mixture of SBS elastomerics, styrene-butadiene rubber(SBR), SIS;
Ethyl acetate that what described solvent was selected is, methylal, 120# industrial naptha a kind of or their mixture.
2. the tectorial paper overlapping glue of a kind of firework as claimed in claim 1, packaging industry, is characterized in that described tackifying resin is selected: Gum Rosin, terpine resin, C5 petroleum resin, C9 petroleum resin, modified rosin resin a kind of or their mixture.
3. the tectorial paper overlapping glue of a kind of firework as claimed in claim 1, packaging industry, what it is characterized in that described oxidation inhibitor selects is antioxidant 264, antioxidant 1010 a kind of or their mixture.
4. the tectorial paper overlapping glue of a kind of firework as claimed in claim 1, packaging industry, what it is characterized in that described softening agent selects is dibutyl phthalate, naphthenic oil a kind of or their mixture.
5. the tectorial paper overlapping glue of a kind of firework as claimed in claim 1, packaging industry, is characterized in that preparation method is as follows:
The first step: the preparation of mixed solvent: first add in reactor in the ratio being 1:1:2 according to weight ratio by ethyl acetate, methylal, 120# industrial naptha, temperature controls, at 20 DEG C-40 DEG C, to be mixed with mixed solvent for subsequent use;
Second step: the mixed solvent that upper step is prepared is added in reactor, start stirring, add tackifying resin while stirring, stir 1 hour, add SBS elastomerics or styrene-butadiene rubber(SBR) or SIS elastomerics again, stir 5-8 hour, then add softening agent, oxidation inhibitor, substrate wetting agents by weight, stir 3-4 hour;
3rd step: sampling and testing viscosity, in the scope of 1600-2600mPas, adopts 60 object filtering nets that material filtering is finished product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310547056.4A CN103555267B (en) | 2013-11-07 | 2013-11-07 | Tectorial paper overlapping glue of a kind of firework, packaging industry and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310547056.4A CN103555267B (en) | 2013-11-07 | 2013-11-07 | Tectorial paper overlapping glue of a kind of firework, packaging industry and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN103555267A CN103555267A (en) | 2014-02-05 |
| CN103555267B true CN103555267B (en) | 2015-10-28 |
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| CN201310547056.4A Active CN103555267B (en) | 2013-11-07 | 2013-11-07 | Tectorial paper overlapping glue of a kind of firework, packaging industry and preparation method thereof |
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Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105623563A (en) * | 2016-03-30 | 2016-06-01 | 光山县博正树脂有限公司 | Environment-friendly film mulching glue and preparation method thereof |
| CN106047286A (en) * | 2016-05-30 | 2016-10-26 | 广东泰强化工实业有限公司 | Spray adhesive with stable performance and preparation method thereof |
| CN110157365A (en) * | 2019-04-15 | 2019-08-23 | 安徽绿谷新材料有限公司 | A kind of rubber glue and preparation method thereof that volatility is low |
| CN115627152B (en) * | 2022-10-09 | 2024-05-07 | 浙江伟星实业发展股份有限公司 | Adhesive material for film-covered rainbow shellfish effect button and preparation method and application thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102295912A (en) * | 2010-06-25 | 2011-12-28 | 东莞市大洋化工有限公司 | Multifunctional spray glue formula and process |
| CN102775938A (en) * | 2011-05-11 | 2012-11-14 | 深圳市顾康力化工有限公司 | Environment-friendly solvent universal glue and preparation method thereof |
-
2013
- 2013-11-07 CN CN201310547056.4A patent/CN103555267B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102295912A (en) * | 2010-06-25 | 2011-12-28 | 东莞市大洋化工有限公司 | Multifunctional spray glue formula and process |
| CN102775938A (en) * | 2011-05-11 | 2012-11-14 | 深圳市顾康力化工有限公司 | Environment-friendly solvent universal glue and preparation method thereof |
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| Publication number | Publication date |
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| CN103555267A (en) | 2014-02-05 |
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| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Laminated paper sealing adhesive used in fireworks and packaging industries and preparation method thereof Effective date of registration: 20170504 Granted publication date: 20151028 Pledgee: Bank of Changsha Limited by Share Ltd. Liuyang branch Pledgor: Hunan Magpow Adhesive Manufacture Co.,Ltd. Registration number: 2017430000026 |
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Date of cancellation: 20210621 Granted publication date: 20151028 Pledgee: Bank of Changsha Limited by Share Ltd. Liuyang branch Pledgor: Hunan Magpow Adhesive Manufacture Co.,Ltd. Registration number: 2017430000026 |
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Denomination of invention: The invention relates to a laminating paper lap adhesive for fireworks and packaging industry and a preparation method thereof Effective date of registration: 20210624 Granted publication date: 20151028 Pledgee: Bank of Changsha Limited by Share Ltd. Liuyang branch Pledgor: Hunan Magpow Adhesive Manufacture Co.,Ltd. Registration number: Y2021430000022 |
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Granted publication date: 20151028 Pledgee: Bank of Changsha Limited by Share Ltd. Liuyang branch Pledgor: Hunan Magpow Adhesive Manufacture Co.,Ltd. Registration number: Y2021430000022 |