CN105924772A - High pullout force artificial turf and preparing method thereof - Google Patents

High pullout force artificial turf and preparing method thereof Download PDF

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Publication number
CN105924772A
CN105924772A CN201610320925.3A CN201610320925A CN105924772A CN 105924772 A CN105924772 A CN 105924772A CN 201610320925 A CN201610320925 A CN 201610320925A CN 105924772 A CN105924772 A CN 105924772A
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chinampa
withdrawal force
high withdrawal
parts
preparation
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Inventor
王祥
李翠
赵春贵
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JIANGSU CO-CREATION GRASS Co Ltd
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JIANGSU CO-CREATION GRASS Co Ltd
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Priority to CN201610320925.3A priority Critical patent/CN105924772A/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/06Polyethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • C08K3/346Clay
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • C08L23/12Polypropene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/04Non-macromolecular additives inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J113/00Adhesives based on rubbers containing carboxyl groups
    • C09J113/02Latex
    • EFIXED CONSTRUCTIONS
    • E01CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
    • E01CCONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
    • E01C13/00Pavings or foundations specially adapted for playgrounds or sports grounds; Drainage, irrigation or heating of sports grounds
    • E01C13/08Surfaces simulating grass ; Grass-grown sports grounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/002Physical properties
    • C08K2201/003Additives being defined by their diameter
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Dispersion Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Architecture (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

The invention discloses a high pullout force artificial turf and a preparing method thereof. According to the high pullout force artificial turf and the preparing method thereof, functional filler is added into a grass formula so as to change the polarity of grass, the bonding force between the grass and an adhesive is increased based on the principle of the dissolution in the similar material structure, and thus the pullout force of the grass is increased. The high pullout force artificial turf is prepared from modified artificial grass, bottom cloth and an adhesive layer, wherein the modified artificial grass is prepared from, by weight, 100 parts of basic resin, 0.1-10 parts of color masterbatch, 0.1-5 parts of a processing aid and 1-20 parts of functional masterbatch.

Description

A kind of high withdrawal force chinampa and preparation method thereof
Technical field
The present invention relates to a kind of chinampa and preparation method thereof, a kind of high withdrawal force chinampa and Preparation method.
Background technology
Chinampa is born in the U.S. of the eighties of last century sixties, and eighties of last century enters Chinese market the end of the eighties.It is to mould Material fiber product is the plan lawn that raw material manual method makes.It need to consume unlike natural lawn the required fertilizer of growth, Water, the resource such as artificial, can meet the motion needs of 24 hours high intensity of whole day, and draining rapidly, levelling of the land degree outstanding, nothing Opinion in the winter time or summer, can normally use, be affected by weather less;Good endurance, a piece of chinampa normally uses Phase, either the practicality of chinampa or economy, be superior to natural lawn up to more than 10 years.Chinampa is at present Extensively become special competition area, public's training field of the motion such as football, tennis, golf or beautify room as ground pavement Interior environment etc..
Chinampa is made up of grass silk, base fabric, adhesive three part.Regulation: whole bunch of careless silk is fixed, upwards pulls out from base fabric Go out, and in withdrawal process, record the maximal force extracted, referred to as withdrawal force.In international standard, withdrawal force is all had strict Requirement, especially move grass, and on the basis of meeting international standards, athlete to be ensured moves for a long time on chinampa Grass silk does not still fall off, and the performance on lawn is just had higher requirement by this, and in this case, grass silk is fixed by adhesive Effect is just particularly important, and is especially to ensure that the life-time service on lawn, thus present stage chinampa needs the weight of solution Wanting problem is to improve the withdrawal force of grass silk.At present, the conventional method improving grass silk withdrawal force is the consumption by increasing adhesive, Adjust the constituent content of adhesive, or the type etc. of replacing adhesive, and on the one hand these common methods can increase cost, separately On the one hand expected effect is not often reached due to factors such as technical limitations, a kind of new enhancing grass silk withdrawal force technology Breakthrough.The careless silk of chinampa is raw materials used is mostly PE, PP, PA family macromolecule polymer, and these polymer are past More weak toward polarity, and for the adhesive of fixing grass silk be mainly composed of carboxylic styrene butadiene latex, polyurethane rubber latex, styrene-butadiene latex, One or more in carboxylic acrylonitrile butadiene rubber latex, show stronger polarity, and both compatibilitys are poor, thus cause grass silk with gluing Active force between agent is not strong, does not finally reach the effect of the most fixing grass silk.
Summary of the invention
The present invention overcomes the deficiencies in the prior art, the invention provides a kind of high withdrawal force chinampa and preparation method thereof.This Bright change the polarity of grass silk by adding functional stuffing in grass silk formula, according to similar compatibility principle, enhance grass silk and glue Cohesive force between stick, thus improve the withdrawal force of grass silk.
The present invention is achieved by the following technical solutions:
The high withdrawal force chinampa of the present invention, includes modified artificial grass silk, base fabric and adhesive layer, its described modified people Make grass silk to be made up of each composition of following parts by weight:
The high withdrawal force chinampa that the present invention is above-mentioned, its further technical scheme be described basic resin be PP, PE and One in PA or a combination thereof.
The high withdrawal force chinampa that the present invention is above-mentioned, its further technical scheme can also is that described processing aid is ultraviolet One in light stabilizer, antioxidant, antistatic additive, opening agent, dispersant or a combination thereof.
The high withdrawal force chinampa that the present invention is above-mentioned, its further technical scheme can also is that described functional agglomerate is by following Each composition of parts by weight is made:
Basic resin 100 parts
Processing aid 0.1~5 parts
Functional stuffing 1~10 parts;
Further technical scheme be described basic resin be the one in PP, PE and PA or a combination thereof;Described processing Auxiliary agent is the one in UV light stabilizing agent, antioxidant, antistatic additive, opening agent, dispersant or a combination thereof.
The high withdrawal force chinampa that the present invention is above-mentioned, its further technical scheme be described functional stuffing be PE maleic acid One in acid anhydride grafted material, POE maleic anhydride grafted material, EVA maleic anhydride grafted material or a combination thereof.
The high withdrawal force chinampa that the present invention is above-mentioned, its further technical scheme can also is that described adhesive is by following One-tenth is grouped into:
Basic 100 parts of latex
Filler 100~300 parts;
Further technical scheme be described basic latex be carboxylic styrene butadiene latex;Described filler is Pulvis Talci, Kaolin, carbon The mixture of one or more in acid calcium, packing material size is 100~1000 mesh.
Further technical scheme can also is that the viscosity of described adhesive is in the range of 10000mpa.s~50000mpa.s.
The preparation method of the high withdrawal force chinampa that the present invention is above-mentioned, it comprises the following steps:
The preparation of functional agglomerate:
(1) by basic resin, functional stuffing, processing aid mix homogeneously;
(2) control temperature is at 100-200 DEG C, and functional agglomerate is prepared in pelletize on double screw extruder;
The preparation of modified artificial grass silk:
(1) by basic resin, Masterbatch, functional agglomerate, processing aid mix homogeneously;
(2) extrusion molding temperature controls at 150 DEG C~300 DEG C, total production ratio 3~10, and oven temperature controls at 50~150 DEG C, Through single screw extrusion machine extrusion, wire drawing, prepare modified artificial grass silk;
The preparation of chinampa:
(1) the modified artificial grass silk twisting that will prepare, tufting machine on by specifying needle gage and line-spacing to be woven into semi-finished product on base fabric Lawn;
(2) adhesive is uniformly coated on bottom semi-finished product lawn, solidifies through oven for drying, make chinampa.
Compared with prior art the present invention has a following beneficial effect:
In the present invention, functional stuffing is by PE maleic anhydride grafted material, POE maleic anhydride grafted material, the grafting of EVA maleic anhydride One or more compositions in material;The addition of these grafted materials so that the molecular structure symmetry of the polymer such as PP, PE, PA Being deteriorated, by original nonpolar or low pole, polarity slowly gradually strengthens, thus enhances and this Type of Collective such as Carboxy Active force between thing molecule, finally makes the cohesive force between latex and grass silk strengthen, increases the withdrawal force on lawn further.
Detailed description of the invention
Below by way of specific embodiment, the present invention is described, but the present invention is not merely defined in these embodiments.
Embodiment 1
The preparation of functional agglomerate:
By polyethylene 100kg, processing aid 1kg, (UV light stabilizing agent, antioxidant, antistatic additive, opening agent, dispersant are each 0.2kg), PE maleic anhydride grafted material 1kg mix homogeneously, double screw extruder temperature controls, at 160 DEG C, to prepare functional agglomerate.
The preparation of artificial grass filaments:
By polyethylene 100kg, Masterbatch 4kg, processing aid 1kg (UV light stabilizing agent, antioxidant, antistatic additive, opening agent, The each 0.2kg of dispersant), functional agglomerate 10kg blending extrusion molding, prepare artificial grass filaments, extrusion molding temperature is 210 DEG C, Total drawing ratio is 5-6, and oven temperature is 95 DEG C;
The preparation of high withdrawal force chinampa:
Artificial grass filaments, through tufting, makes chinampa semi-finished product, then according to the glue amount of every square of 1.5kg, is glued by butadiene-styrene rubber stick Degree is adjusted to 15000~20000mpa.s, is uniformly coated on bottom semi-finished product, makes high withdrawal force chinampa.
Withdrawal force detects:
Take the sample block of 20*20cm, uniformly take a little, use tensilon to measure the withdrawal force of each point, take its meansigma methods, with Normal lawn is compared withdrawal force and is improved 1N.
Embodiment 2
The preparation of functional agglomerate:
By polyethylene 100kg, processing aid 1kg, (UV light stabilizing agent, antioxidant, antistatic additive, opening agent, dispersant are each 0.2kg), PE maleic anhydride grafted material 4kg mix homogeneously, double screw extruder temperature controls, at 160 DEG C, to prepare functional agglomerate.
The preparation of artificial grass filaments:
By polyethylene 100kg, Masterbatch 4kg, processing aid 1kg (UV light stabilizing agent, antioxidant, antistatic additive, opening agent Each 0.1kg, dispersant 0.6kg), functional agglomerate 10kg blending extrusion molding, prepare artificial grass filaments, extrusion molding temperature is 210 DEG C, Total drawing ratio is 5-6, and oven temperature is 95 DEG C;
The preparation of high withdrawal force chinampa:
Artificial grass filaments, through tufting, makes chinampa semi-finished product, then according to the glue amount of every square of 1.5kg, is glued by butadiene-styrene rubber stick Degree is adjusted to 15000~20000mpa.s, is uniformly coated on bottom semi-finished product, makes high withdrawal force chinampa.
Withdrawal force detects:
Take the sample block of 20*20cm, uniformly take a little, use tensilon to measure the withdrawal force of each point, take its meansigma methods, with Normal lawn is compared withdrawal force and is improved 5N.
Embodiment 3
The preparation of functional agglomerate:
By polyethylene 100kg, processing aid 1kg (each 0.25kg of UV light stabilizing agent, antioxidant, opening agent, dispersant), PE maleic anhydride grafted material 8kg mix homogeneously, double screw extruder temperature controls, at 160 DEG C, to prepare functional agglomerate.
The preparation of artificial grass filaments:
By polyethylene 100kg, Masterbatch 4kg, processing aid 1kg, (UV light stabilizing agent, antioxidant, opening agent, dispersant are each 0.25kg), functional agglomerate 10kg blending extrusion molding, prepare artificial grass filaments, extrusion molding temperature is 210 DEG C, total drawing ratio For 5-6, oven temperature is 95 DEG C;
The preparation of high withdrawal force chinampa:
Artificial grass filaments, through tufting, makes chinampa semi-finished product, then according to the glue amount of every square of 1.5kg, is glued by butadiene-styrene rubber stick Degree is adjusted to 15000~20000mpa.s mpa.s, is uniformly coated on bottom semi-finished product, makes high withdrawal force chinampa.
Withdrawal force detects:
Take the sample block of 20*20cm, uniformly take a little, use tensilon to measure the withdrawal force of each point, take its meansigma methods, with Normal lawn is compared withdrawal force and is improved 3N.
Embodiment 4
The preparation of functional agglomerate:
Polyethylene 100kg, processing aid 1kg (UV light stabilizing agent 0.1kg, antioxidant 0.2kg, antistatic additive 0.1kg, are opened The mouth each 0.2kg of agent, dispersant 0.4kg), PE maleic anhydride grafted material 10kg mix homogeneously, double screw extruder temperature controls 160 DEG C, prepare functional agglomerate.
The preparation of artificial grass filaments:
By polyethylene 100kg, Masterbatch 4kg, processing aid 1kg (UV light stabilizing agent 0.1kg, antioxidant 0.2kg, antistatic The each 0.2kg of agent 0.2kg, opening agent, dispersant 0.3kg), functional agglomerate 10kg blending extrusion molding, prepare artificial grass filaments, Extrusion molding temperature is 210 DEG C, and total drawing ratio is 5-6, and oven temperature is 95 DEG C;
The preparation of high withdrawal force chinampa:
Artificial grass filaments, through tufting, makes chinampa semi-finished product, then according to the glue amount of every square of 1.5kg, is glued by butadiene-styrene rubber stick Degree is adjusted to 15000~20000mpa.s, is uniformly coated on bottom semi-finished product, makes high withdrawal force chinampa.
Withdrawal force detects:
Take the sample block of 20*20cm, uniformly take a little, use tensilon to measure the withdrawal force of each point, take its meansigma methods, with Normal lawn is compared withdrawal force and is improved 2N.
Embodiment 5
The preparation of functional agglomerate:
Polyethylene 100kg, processing aid 1kg (UV light stabilizing agent 0.1kg, antioxidant 0.1kg, antistatic additive 0.3kg, are opened The mouth each 0.2kg of agent, dispersant 0.3kg), POE maleic anhydride grafted material 1kg mix homogeneously, double screw extruder temperature controls 160 DEG C, prepare functional agglomerate.
The preparation of artificial grass filaments:
By polyethylene 100kg, Masterbatch 4kg, processing aid 1kg (UV light stabilizing agent 0.1kg, antioxidant 0.1kg, antistatic The each 0.2kg of agent 0.3kg, opening agent, dispersant 0.3kg), functional agglomerate 10kg blending extrusion molding, prepare artificial grass filaments, Extrusion molding temperature is 210 DEG C, and total drawing ratio is 5-6, and oven temperature is 95 DEG C;
The preparation of high withdrawal force chinampa:
Artificial grass filaments, through tufting, makes chinampa semi-finished product, then according to the glue amount of every square of 1.5kg, is glued by butadiene-styrene rubber stick Degree is adjusted to 15000~20000mpa.s, is uniformly coated on bottom semi-finished product, makes high withdrawal force chinampa.
Withdrawal force detects:
Take the sample block of 20*20cm, uniformly take a little, use tensilon to measure the withdrawal force of each point, take its meansigma methods, with Normal lawn is compared withdrawal force and is improved 2N.
Embodiment 6
The preparation of functional agglomerate:
By polyethylene 100kg, processing aid 1kg (antioxidant 0.2kg, antistatic additive 0.3kg, each 0.2kg of opening agent, dispersant 0.3kg), POE maleic anhydride grafted material 4kg mix homogeneously, double screw extruder temperature controls at 160 DEG C, prepares function female Grain.
The preparation of artificial grass filaments:
By polyethylene 100kg, Masterbatch 4kg, processing aid 1kg (UV light stabilizing agent 0.3kg, antistatic additive 0.2kg, opening The each 0.2kg of agent, dispersant 0.3kg), functional agglomerate 10kg blending extrusion molding, prepare artificial grass filaments, extrusion molding temperature is 210 DEG C, total drawing ratio is 5-6, and oven temperature is 95 DEG C;
The preparation of high withdrawal force chinampa:
Artificial grass filaments, through tufting, makes chinampa semi-finished product, then according to the glue amount of every square of 1.5kg, is glued by butadiene-styrene rubber stick Degree is adjusted to 15000~20000mpa.s, is uniformly coated on bottom semi-finished product, makes high withdrawal force chinampa.
Withdrawal force detects:
Take the sample block of 20*20cm, uniformly take a little, use tensilon to measure the withdrawal force of each point, take its meansigma methods, with Normal lawn is compared withdrawal force and is improved 5N.
Embodiment 7
The preparation of functional agglomerate:
By polyethylene 100kg, processing aid 1kg (UV light stabilizing agent 0.15kg, antioxidant 0.1kg, antistatic additive 0.2kg, The each 0.25kg of opening agent, dispersant 0.3kg), POE maleic anhydride grafted material 8kg mix homogeneously, double screw extruder temperature controls At 160 DEG C, prepare functional agglomerate.
The preparation of artificial grass filaments:
By polyethylene 100kg, Masterbatch 4kg, processing aid 1kg (UV light stabilizing agent 0.1kg, antioxidant 0.1kg, antistatic The each 0.3kg of agent 0.2kg, opening agent, dispersant 0.3kg), functional agglomerate 10kg blending extrusion molding, prepare artificial grass filaments, Extrusion molding temperature is 210 DEG C, and total drawing ratio is 5-6, and oven temperature is 95 DEG C;
The preparation of high withdrawal force chinampa:
Artificial grass filaments, through tufting, makes chinampa semi-finished product, then according to the glue amount of every square of 1.5kg, is glued by butadiene-styrene rubber stick Degree is adjusted to 15000~20000mpa.s, is uniformly coated on bottom semi-finished product, makes high withdrawal force chinampa.
Withdrawal force detects:
Take the sample block of 20*20cm, uniformly take a little, use tensilon to measure the withdrawal force of each point, take its meansigma methods, with Normal lawn is compared withdrawal force and is improved 4N.
Embodiment 8
The preparation of functional agglomerate:
Polyethylene 100kg, processing aid 1kg (UV light stabilizing agent 0.1kg, antioxidant 0.1kg, antistatic additive 0.1kg, are opened The mouth each 0.4kg of agent, dispersant 0.3kg), POE maleic anhydride grafted material 10kg mix homogeneously, double screw extruder temperature controls 160 DEG C, prepare functional agglomerate.
The preparation of artificial grass filaments:
By polyethylene 100kg, Masterbatch 4kg, processing aid 1kg (UV light stabilizing agent 0.2kg, antioxidant 0.1kg, antistatic The each 0.2kg of agent 0.2kg, opening agent, dispersant 0.3kg), functional agglomerate 10kg blending extrusion molding, prepare artificial grass filaments, Extrusion molding temperature is 210 DEG C, and total drawing ratio is 5-6, and oven temperature is 95 DEG C;
The preparation of high withdrawal force chinampa:
Artificial grass filaments, through tufting, makes chinampa semi-finished product, then according to the glue amount of every square of 1.5kg, is glued by butadiene-styrene rubber stick Degree is adjusted to 15000~20000mpa.s, is uniformly coated on bottom semi-finished product, makes high withdrawal force chinampa.
Withdrawal force detects:
Take the sample block of 20*20cm, uniformly take a little, use tensilon to measure the withdrawal force of each point, take its meansigma methods, with Normal lawn is compared withdrawal force and is improved 2N.

Claims (10)

1. a high withdrawal force chinampa, includes modified artificial grass silk, base fabric and adhesive layer, it is characterised in that described modification Artificial grass filaments is made up of each composition of following parts by weight:
2. according to the high withdrawal force chinampa described in claims 1, it is characterised in that described basic resin is PP, PE and PA In one or a combination thereof.
3. according to the high withdrawal force chinampa described in claims 1, it is characterised in that described processing aid be UV light stabilizing agent, One in antioxidant, antistatic additive, opening agent, dispersant or a combination thereof.
4. according to the high withdrawal force chinampa described in claims 1, it is characterised in that described functional agglomerate is by following parts by weight Each composition make:
Basic resin 100 parts
Processing aid 0.1~5 parts
Functional stuffing 1~10 parts.
5. according to the high withdrawal force chinampa described in claims 4, it is characterised in that described basic resin is PP, PE and PA In one or a combination thereof;Described processing aid is UV light stabilizing agent, antioxidant, antistatic additive, opening agent, dispersant In one or a combination thereof.
6. according to the high withdrawal force chinampa described in claims 4, it is characterised in that described functional stuffing is PE maleic anhydride One in grafted material, POE maleic anhydride grafted material, EVA maleic anhydride grafted material or a combination thereof.
7. according to the high withdrawal force chinampa described in claims 1, it is characterised in that described adhesive is grouped into by following one-tenth:
Basic 100 parts of latex
Filler 100~300 parts.
8. according to the high withdrawal force chinampa described in claims 7, it is characterised in that described basic latex is carboxylic styrene butadiene latex; Described filler is the mixture of one or more in Pulvis Talci, Kaolin, calcium carbonate, and packing material size is 100~1000 mesh.
9. according to the high withdrawal force chinampa described in claims 7, it is characterised in that the viscosity of described adhesive exists 10000mpa.s~in the range of 50000mpa.s.
10. one kind as arbitrary in claims 1-9 as described in the preparation method of high withdrawal force chinampa, it is characterised in that include following Step:
The preparation of functional agglomerate:
(1) by basic resin, functional stuffing, processing aid mix homogeneously;
(2) control temperature is at 100-200 DEG C, and functional agglomerate is prepared in pelletize on double screw extruder;
The preparation of modified artificial grass silk:
(1) by basic resin, Masterbatch, functional agglomerate, processing aid mix homogeneously;
(2) extrusion molding temperature controls at 150 DEG C~300 DEG C, total production ratio 3~10, and oven temperature controls at 50~150 DEG C, Through single screw extrusion machine extrusion, wire drawing, prepare modified artificial grass silk;
The preparation of chinampa:
(1) the modified artificial grass silk twisting that will prepare, tufting machine on by specifying needle gage and line-spacing to be woven into semi-finished product on base fabric Lawn;
(2) adhesive is uniformly coated on bottom semi-finished product lawn, solidifies through oven for drying, make chinampa.
CN201610320925.3A 2016-05-16 2016-05-16 High pullout force artificial turf and preparing method thereof Pending CN105924772A (en)

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CN106757468A (en) * 2016-11-28 2017-05-31 江苏共创人造草坪有限公司 A kind of chinampa with antibiotic property and preparation method thereof
CN106832536A (en) * 2016-09-23 2017-06-13 泰山体育产业集团有限公司 One kind leisure landscape chinampa and preparation method thereof
CN106854379A (en) * 2016-12-05 2017-06-16 钦州市钦南区生产力促进中心 A kind of chinampa and preparation method thereof
CN107165025A (en) * 2017-05-06 2017-09-15 青岛百花旺塑料科技有限公司 A kind of use PET/PBT bends the chinampa of silk
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CN109267448A (en) * 2018-11-16 2019-01-25 江苏共创人造草坪股份有限公司 A kind of reversable light sensitive discoloration chinampa and preparation method thereof
CN109722162A (en) * 2018-12-28 2019-05-07 江苏共创人造草坪股份有限公司 Anti-sticking, antifouling hydrophobic automatically cleaning chinampa of one kind and preparation method thereof
CN110511475A (en) * 2019-08-26 2019-11-29 湖北绿城体育产业有限公司 A kind of dumb light type pedaline
CN111575937A (en) * 2020-06-10 2020-08-25 江苏共创人造草坪股份有限公司 Artificial turf tufted base cloth, production method and turf produced by artificial turf tufted base cloth
CN112280496A (en) * 2020-10-21 2021-01-29 江苏共创人造草坪股份有限公司 Water-based thermoplastic adhesive and application thereof in artificial turf
CN112921445A (en) * 2021-02-26 2021-06-08 江苏威腾体育产业股份有限公司 Matte artificial grass silk for label printing and preparation method thereof
CN115323519A (en) * 2022-08-09 2022-11-11 江苏文明人造草坪有限公司 Preparation method of matte artificial turf

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Cited By (16)

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Publication number Priority date Publication date Assignee Title
CN106832536A (en) * 2016-09-23 2017-06-13 泰山体育产业集团有限公司 One kind leisure landscape chinampa and preparation method thereof
CN106757468B (en) * 2016-11-28 2019-01-15 江苏共创人造草坪股份有限公司 A kind of chinampa and preparation method thereof with antibiotic property
CN106757468A (en) * 2016-11-28 2017-05-31 江苏共创人造草坪有限公司 A kind of chinampa with antibiotic property and preparation method thereof
CN106854379A (en) * 2016-12-05 2017-06-16 钦州市钦南区生产力促进中心 A kind of chinampa and preparation method thereof
WO2018113110A1 (en) * 2016-12-19 2018-06-28 广州爱奇实业有限公司 Method for preparing simulation turf
US10774480B2 (en) 2016-12-19 2020-09-15 Guangzhou Act Industrial Co., Ltd. Method for preparing simulated lawn
CN107165025A (en) * 2017-05-06 2017-09-15 青岛百花旺塑料科技有限公司 A kind of use PET/PBT bends the chinampa of silk
CN109267448A (en) * 2018-11-16 2019-01-25 江苏共创人造草坪股份有限公司 A kind of reversable light sensitive discoloration chinampa and preparation method thereof
CN109267448B (en) * 2018-11-16 2023-12-08 江苏共创人造草坪股份有限公司 Reversible photosensitive color-changing artificial lawn and preparation method thereof
CN109722162B (en) * 2018-12-28 2021-01-01 江苏共创人造草坪股份有限公司 Anti-sticking, anti-fouling, hydrophobic and self-cleaning artificial lawn and preparation method thereof
CN109722162A (en) * 2018-12-28 2019-05-07 江苏共创人造草坪股份有限公司 Anti-sticking, antifouling hydrophobic automatically cleaning chinampa of one kind and preparation method thereof
CN110511475A (en) * 2019-08-26 2019-11-29 湖北绿城体育产业有限公司 A kind of dumb light type pedaline
CN111575937A (en) * 2020-06-10 2020-08-25 江苏共创人造草坪股份有限公司 Artificial turf tufted base cloth, production method and turf produced by artificial turf tufted base cloth
CN112280496A (en) * 2020-10-21 2021-01-29 江苏共创人造草坪股份有限公司 Water-based thermoplastic adhesive and application thereof in artificial turf
CN112921445A (en) * 2021-02-26 2021-06-08 江苏威腾体育产业股份有限公司 Matte artificial grass silk for label printing and preparation method thereof
CN115323519A (en) * 2022-08-09 2022-11-11 江苏文明人造草坪有限公司 Preparation method of matte artificial turf

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