CN106757468A - A kind of chinampa with antibiotic property and preparation method thereof - Google Patents

A kind of chinampa with antibiotic property and preparation method thereof Download PDF

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Publication number
CN106757468A
CN106757468A CN201611061334.5A CN201611061334A CN106757468A CN 106757468 A CN106757468 A CN 106757468A CN 201611061334 A CN201611061334 A CN 201611061334A CN 106757468 A CN106757468 A CN 106757468A
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China
Prior art keywords
chinampa
antiseptic
antibiotic property
lawn
antibacterial
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Granted
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CN201611061334.5A
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CN106757468B (en
Inventor
王辉
赵春贵
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JIANGSU CO-CREATION GRASS Co Ltd
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JIANGSU CO-CREATION GRASS Co Ltd
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    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/44—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds
    • D01F6/46—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds of polyolefins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/02—Organic and inorganic ingredients
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
    • C08K3/015—Biocides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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    • C08K3/02—Elements
    • C08K3/08—Metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C08K3/346—Clay
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/0058—Biocides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00—Use of pretreated ingredients
    • C08K9/12—Adsorbed ingredients, e.g. ingredients on carriers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/04—Non-macromolecular additives inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/06—Non-macromolecular additives organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J113/00—Adhesives based on rubbers containing carboxyl groups
    • C09J113/02—Latex
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
    • C09J175/04—Polyurethanes
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00—General methods for the manufacture of artificial filaments or the like
    • D01F1/02—Addition of substances to the spinning solution or to the melt
    • D01F1/09—Addition of substances to the spinning solution or to the melt for making electroconductive or anti-static filaments
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00—General methods for the manufacture of artificial filaments or the like
    • D01F1/02—Addition of substances to the spinning solution or to the melt
    • D01F1/10—Other agents for modifying properties
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00—General methods for the manufacture of artificial filaments or the like
    • D01F1/02—Addition of substances to the spinning solution or to the melt
    • D01F1/10—Other agents for modifying properties
    • D01F1/103—Agents inhibiting growth of microorganisms
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/88—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
    • D01F6/90—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyamides
    • E—FIXED CONSTRUCTIONS
    • E01—CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
    • E01C—CONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
    • E01C13/00—Pavings or foundations specially adapted for playgrounds or sports grounds; Drainage, irrigation or heating of sports grounds
    • E01C13/08—Surfaces simulating grass ; Grass-grown sports grounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/08—Metals
    • C08K2003/0806—Silver
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/08—Metals
    • C08K2003/0893—Zinc
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    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2227—Oxides; Hydroxides of metals of aluminium
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    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C08K2003/265—Calcium, strontium or barium carbonate

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  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Textile Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Civil Engineering (AREA)
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  • Life Sciences & Earth Sciences (AREA)
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Abstract

The invention discloses a kind of chinampa with antibiotic property; the chinampa is respectively provided with antibiotic property in lawn two sides (careless silk and primer); if lawn is in dark and damp or ponding environment; generation bacterium, mould, fungi, the damp worm of growth are easiest at the back of the body of lawn bottom (near ground); antibacterial lawn of the invention can effectively suppress the generation of these harmful substances; antibacterial timeliness is long, and addition is few, protects the health of user.Chinampa with antibiotic property of the invention, includes base fabric, artificial grass filaments and primer, and the artificial grass filaments described in it are antibacterial artificial grass silk, are made up than raw material of following weight：60 90 parts of carrier, careless 0.1 10 parts of silk antiseptic, 1 20 parts of Masterbatch, 0 10 parts of auxiliary agent；Described primer is antibacterial primer, is made up of than raw material following weight：Carboxylic styrene butadiene latex or 30 60 parts of polyurethane, 40 100 parts of filler, 0.1 5 parts of primer antiseptic.

Description

A kind of chinampa with antibiotic property and preparation method thereof
Technical field
The present invention relates to a kind of chinampa, more particularly to a kind of chinampa and its system with antibiotic property Preparation Method.
Background technology
Chinampa is made up of the primer of careless silk, base fabric and fixed grass silk, and nowadays chinampa increasingly receives people Welcome, not only on athletic ground, be also applied to place of lying fallow, Household courtyard and landscape place etc. contrast natural lawn, Chinampa has the advantages that attractive and durable, maintaining low cost and all-season, however, common chinampa with it is natural It is careless the same, without anti-microbial property, lawn be placed in dark and damp environment especially near the back on ground easily produce bacterium, Mould, fungi etc., or animal contact can also produce bacterial micro-organism.User's especially easy bacterial infection of child, to strong Health threatens.Add suitable antimicrobial moiety in chinampa combination, refer to make microorganism (bacterium, fungi, mould, Virus etc.) growth or breeding be maintained at necessary below horizontal so that chinampa turns into the product with antibacterial and bactericidal property Product.
The Chinese patent of publication number CN 102995153A discloses a kind of antibacterial artificial turf and preparation method thereof, and it is not It one is that antiseptic species used is narrow that foot part is, antiseptic is expensive；Two is that no antibacterial ability is carried on the back at lawn bottom, On the ground of moist or ponding, lawn bottom is easiest to produce bacterium, mould and grows damp worm, causes very big potential danger Evil.Therefore need to develop a kind of more preferable chinampa of anti-microbial property.
The content of the invention
The present invention solves above-mentioned problems of the prior art with deficiency, there is provided a kind of pedaline with antibiotic property Level ground, the chinampa is respectively provided with antibiotic property in lawn two sides (careless silk and primer), if lawn is in dark and damp or ponding environment, Generation bacterium, mould, fungi, the damp worm of growth are easiest at the back of the body of lawn bottom (near ground), antibacterial lawn of the invention can have The generation for suppressing these harmful substances of effect, antibacterial timeliness is long, and addition is few, protects the health of user.
The present invention also provides the preparation method of the chinampa with antibiotic property simultaneously.
The present invention is achieved by the following technical solutions：
Chinampa with antibiotic property of the invention, includes base fabric, artificial grass filaments and primer, the pedaline described in it Silk is antibacterial artificial grass silk, is made up than raw material of following weight：
Described primer is antibacterial primer, is made up of than raw material following weight：
Carboxylic styrene butadiene latex or polyurethane 30-60 parts
Filler 40-100 parts
0.1-5 parts of primer antiseptic.
The above-mentioned chinampa with antibiotic property of the present invention, its further technical scheme is described careless silk antiseptic It is solid-state organic antibacterial agent, inorganic nano silver-series antibacterial agent, inorganic nano zinc series antibacterial agent or its combination；Described primer antibacterial Agent is inorganic antiseptic, high temperature resistant organic antibacterial agent or its combination.Further technical scheme is described inorganic antiseptic For the inorganic nano silver-series antibacterial agent of liquid or solid-state powdery, inorganic nano copper system antiseptic, inorganic nano zinc series antibacterial agent or Its combination；The high temperature resistant organic antibacterial agent is anilid class, vanilla aldehydes, ethyl vanillin aldehydes or material of organic ethers antibacterial Agent.Antiseptic has fire resistant water resistant solution characteristic, and wherein inorganic nano antiseptic passes through silicate or zeolite-loaded silver, copper, zinc Inorganic mineral and oxide one or more composition, antibiotic rate >=98%.
The above-mentioned chinampa with antibiotic property of the present invention, its further technical scheme can also be described carrier It is polypropylene, polyethylene or polyamide.
The above-mentioned chinampa with antibiotic property of the present invention, its further technical scheme can also be described filler For kaolin, calcium carbonate, talcum powder, aluminium hydroxide one or more.
The above-mentioned chinampa with antibiotic property of the present invention, its further technical scheme can also be described auxiliary agent For in light stabilizer, antioxidant, antistatic additive, dispersant, lubricant one or more, auxiliary dosage be 0.5-5 parts.
Wherein light stabilizer is light stabilizer 770, light stabilizer 622, ultraviolet absorbent UV-531, ultra-violet absorber One or more of UV-P, light stabilizer 783, light stabilizer 944；Antioxidant is antioxidant 1010, irgasfos 168, antioxidant 1076th, one or more of antioxidant CA；Dispersant is cationic polyvinyl wax or low molecular weight silicone oil.
The preparation method of the above-mentioned chinampa with antibiotic property of the present invention, comprises the following steps：
(1) preparation of antibacterial artificial grass silk：The carrier of formula ratio, Masterbatch, antiseptic and auxiliary agent are squeezed for screw rod Go out machine mixed, extruded, wire drawing, sizing, twisting, be processed into antibiotic property artificial grass filaments；
(2) by antibacterial artificial grass silk, chinampa is machined to by tufting together with base fabric；
(3) preparation of antibiosis rubber：The carboxylic styrene butadiene latex or polyurethane component of formula ratio, filler and antiseptic are mixed After uniform, the bottom of chinampa is uniformly coated in, and obtain with antibacterial by after oven post-cure infrared or long shaping The chinampa of property.
The present invention has following beneficial effect compared with prior art：
1. lawn two sides (careless silk and bottom are carried on the back) is respectively provided with antibiotic property, because lawn is in dark and damp or ponding environment, lawn Generation bacterium, mould, fungi, the damp worm of growth are easiest at the back of the body of bottom (near ground), antibacterial lawn of the invention can be effective Suppress the generation of these harmful substances, protect the health of user.
2. antibacterial artificial turf has the growth for effectively suppressing bacterium, mould and fungi, and antibacterial timeliness is long, can prevent Transmission of disease, and antiseptic addition is few, and selectable antiseptic species is more, low cost.
Specific embodiment
The present invention is illustrated below by way of specific embodiment, but the present invention is not merely defined in these embodiments, wherein Antibacterial test method uses the test method of the antiseptic determination of activity under ASTM E 2149-10 dynamic conditions, in dynamic Contact Under the conditions of determine the antibacterial behavior of stable state antiseptic sample, test sample bacterium specifies staphylococcus aureus, and time of contact is small for 24 When, each lawn species test sample size is 5*5cm, the number of the final staphylococcus aureus living of test, and based on without The blank sample number of bacteria for the treatment of, calculates antibiotic rate.
Embodiment 1 [0027]
(1) according to the mass fraction of B component in batch mixer batch mixing, be subsequently used for double screw extruder melting extrusion, draw Silk, sizing, then by twisting, are processed into antibiotic property artificial grass filaments；
(2) by upper described antibacterial artificial grass silk, chinampa is machined to by tufting together with base fabric；
(3) preparation of antibiosis rubber：According to the mass fraction of component A, by the carboxylic styrene butadiene latex of formula ratio, filler and anti- After microbial inoculum is well mixed, the bottom of chinampa is uniformly coated in, gum amount is in 900g/m2, and by baking oven infrared or long The chinampa with antibiotic property is obtained after solidify afterwards shaping.
Anti-bacteria test result is as follows：
According to the preparation scheme of embodiment 1, wherein the chinampa for being not added with antiseptic preparation completely is denoted as lawn A, latex In be not added with antiseptic preparation lawn be denoted as lawn B, be not added with careless silk antiseptic preparation lawn be denoted as lawn C, careless silk and the back of the body Glue adds chinampa prepared by antiseptic to be denoted as lawn D, and anti-bacteria test result is as follows
Lawn species A B C D
Antibiotic rate (%) 0.02 78.12 49.65 98.49
Embodiment 2
(1) according to the mass fraction of B component in batch mixer batch mixing, be subsequently used for double screw extruder melting extrusion, draw Silk, sizing, then by twisting, are processed into antibiotic property artificial grass filaments
(2) by upper described antibacterial artificial grass silk, chinampa is machined to by tufting together with base fabric
(3) preparation of antibiosis rubber, according to the mass fraction of component A, by the polyurethane PU component of formula ratio, filler and anti- After microbial inoculum is well mixed, the bottom of chinampa is uniformly coated in, gum amount is in 800g/m2, and by baking oven infrared or long The chinampa with antibiotic property is obtained after solidify afterwards shaping.
Anti-bacteria test result is as follows：
According to the preparation scheme of embodiment 2, wherein the chinampa for being not added with antiseptic preparation completely is denoted as lawn A, latex In be not added with antiseptic preparation lawn be denoted as lawn B, be not added with careless silk antiseptic preparation lawn be denoted as lawn C, careless silk and the back of the body Glue adds chinampa prepared by antiseptic to be denoted as lawn D, and anti-bacteria test result is as follows
Lawn species A B C D
Antibiotic rate (%) 0 81.36 51.32 99.45
Embodiment 3
(1) according to the mass fraction of B component in batch mixer batch mixing, be subsequently used for double screw extruder melting extrusion, wire drawing, fixed Type, then by twisting, is processed into antibiotic property artificial grass filaments
(2) by upper described antibacterial artificial grass silk, chinampa is machined to by tufting together with base fabric
(3) preparation of antibiosis rubber, according to the mass fraction of component A, by the carboxylic styrene butadiene latex of formula ratio, filler and anti- After microbial inoculum is well mixed, be uniformly coated in the bottom of chinampa, gum amount in 1100g/m2, and by baking oven infrared or long The chinampa with antibiotic property is obtained after solidify afterwards shaping.
Anti-bacteria test result is as follows：
According to the preparation scheme of embodiment 3, wherein the chinampa for being not added with antiseptic preparation completely is denoted as lawn A, latex In be not added with antiseptic preparation lawn be denoted as lawn B, be not added with careless silk antiseptic preparation lawn be denoted as lawn C, careless silk and the back of the body Glue adds chinampa prepared by antiseptic to be denoted as lawn D, and anti-bacteria test result is as follows
Lawn species A B C D
Antibiotic rate (%) 0 75.66 48.98 99.73
Embodiment 4
(1) according to the mass fraction of B component in batch mixer batch mixing, be subsequently used for double screw extruder melting extrusion, draw Silk, sizing, then by twisting, are processed into antibiotic property artificial grass filaments
(2) by upper described antibacterial artificial grass silk, chinampa is machined to by tufting together with base fabric
(3) preparation of antibiosis rubber, according to the mass fraction of component A, by the polyurethane PU component of formula ratio, filler and anti- After microbial inoculum is well mixed, be uniformly coated in the bottom of chinampa, gum amount in 1000g/m2, and by baking oven infrared or long The chinampa with antibiotic property is obtained after solidify afterwards shaping.
Anti-bacteria test result is as follows：
According to the preparation scheme of embodiment 4, wherein the chinampa for being not added with antiseptic preparation completely is denoted as lawn A, latex In be not added with antiseptic preparation lawn be denoted as lawn B, be not added with careless silk antiseptic preparation lawn be denoted as lawn C, careless silk and the back of the body Glue adds chinampa prepared by antiseptic to be denoted as lawn D, and anti-bacteria test result is as follows
Lawn species A B C D
Antibiotic rate (%) 0.03 66.33 45.65 98.32
Embodiment 5
(1) according to the mass fraction of B component in batch mixer batch mixing, be subsequently used for double screw extruder melting extrusion, draw Silk, sizing, then by twisting, are processed into antibiotic property artificial grass filaments
(2) by upper described antibacterial artificial grass silk, chinampa is machined to by tufting together with base fabric
(3) preparation of antibiosis rubber, according to the mass fraction of component A, by the carboxylic styrene butadiene latex of formula ratio, filler and anti- After microbial inoculum is well mixed, be uniformly coated in the bottom of chinampa, gum amount in 1500g/m2, and by baking oven infrared or long The chinampa with antibiotic property is obtained after solidify afterwards shaping.
Anti-bacteria test result is as follows：
According to the preparation scheme of embodiment 5, wherein the chinampa for being not added with antiseptic preparation completely is denoted as lawn A, latex In be not added with antiseptic preparation lawn be denoted as lawn B, be not added with careless silk antiseptic preparation lawn be denoted as lawn C, careless silk and the back of the body Glue adds chinampa prepared by antiseptic to be denoted as lawn D, and anti-bacteria test result is as follows
Lawn species A B C D
Antibiotic rate (%) 0.01 78.66 52.69 99.62
Embodiment 6
(1) according to the mass fraction of B component in batch mixer batch mixing, be subsequently used for double screw extruder melting extrusion, draw Silk, sizing, then by twisting, are processed into antibiotic property artificial grass filaments
(2) by upper described antibacterial artificial grass silk, chinampa is machined to by tufting together with base fabric
(3) preparation of antibiosis rubber, according to the mass fraction of component A, by the carboxylic styrene butadiene latex of formula ratio, filler and anti- After microbial inoculum is well mixed, be uniformly coated in the bottom of chinampa, gum amount in 1300g/m2, and by baking oven infrared or long The chinampa with antibiotic property is obtained after solidify afterwards shaping.
Anti-bacteria test result is as follows：
According to the preparation scheme of embodiment 6, wherein the chinampa for being not added with antiseptic preparation completely is denoted as lawn A, latex In be not added with antiseptic preparation lawn be denoted as lawn B, be not added with careless silk antiseptic preparation lawn be denoted as lawn C, careless silk and the back of the body Glue adds chinampa prepared by antiseptic to be denoted as lawn D, and anti-bacteria test result is as follows
Lawn species A B C D
Antibiotic rate (%) 0 65.38 48.52 98.69
Embodiment 7
(1) according to the mass fraction of B component in batch mixer batch mixing, be subsequently used for double screw extruder melting extrusion, draw Silk, sizing, then by twisting, are processed into antibiotic property artificial grass filaments
(2) by upper described antibacterial artificial grass silk, chinampa is machined to by tufting together with base fabric
(3) preparation of antibiosis rubber, according to the mass fraction of component A, by the polyurethane PU component of formula ratio, filler and anti- After microbial inoculum is well mixed, be uniformly coated in the bottom of chinampa, gum amount in 900g/m2, and by baking oven infrared or long The chinampa with antibiotic property is obtained after solidify afterwards shaping.
Anti-bacteria test result is as follows：
According to the preparation scheme of embodiment 7, wherein the chinampa for being not added with antiseptic preparation completely is denoted as lawn A, latex In be not added with antiseptic preparation lawn be denoted as lawn B, be not added with careless silk antiseptic preparation lawn be denoted as lawn C, careless silk and the back of the body Glue adds chinampa prepared by antiseptic to be denoted as lawn D, and anti-bacteria test result is as follows
Lawn species A B C D
Antibiotic rate (%) 0 75.62 51.36 99.78

Claims (7)

1. a kind of chinampa with antibiotic property, includes base fabric, artificial grass filaments and primer, it is characterised in that described is artificial Careless silk is antibacterial artificial grass silk, is made up than raw material of following weight：
Described primer is antibacterial primer, is made up of than raw material following weight：
Carboxylic styrene butadiene latex or polyurethane 30-60 parts
Filler 40-100 parts
0.1-5 parts of primer antiseptic.
2. the chinampa with antibiotic property according to claim 1, it is characterised in that described careless silk antiseptic is solid State organic antibacterial agent, inorganic nano silver-series antibacterial agent, inorganic nano zinc series antibacterial agent or its combination；Described primer antiseptic is Inorganic antiseptic, high temperature resistant organic antibacterial agent or its combination.
3. the chinampa with antibiotic property according to claim 2, it is characterised in that described inorganic antiseptic is liquid The inorganic nano silver-series antibacterial agent of state or solid-state powdery, inorganic nano copper system antiseptic, inorganic nano zinc series antibacterial agent or its group Close；The high temperature resistant organic antibacterial agent is anilid class, vanilla aldehydes, ethyl vanillin aldehydes or material of organic ethers antiseptic.
4. the chinampa with antibiotic property according to claim 1, it is characterised in that described carrier is polypropylene, poly- Ethene or polyamide.
5. the chinampa with antibiotic property according to claim 1, it is characterised in that described filler is kaolin, carbon One or more of sour calcium, talcum powder, aluminium hydroxide.
6. the chinampa with antibiotic property according to claim 1, it is characterised in that described auxiliary agent be light stabilizer, In antioxidant, antistatic additive, dispersant, lubricant one or more, auxiliary dosage be 0.5-5 parts.
7. a kind of preparation method of chinampa with antibiotic property as described in claim 1-6 is any, it is characterised in that bag Include following steps：
(1) preparation of antibacterial artificial grass silk：The carrier of formula ratio, Masterbatch, antiseptic and auxiliary agent are used for screw extruder Mixed, extruded, wire drawing, sizing, twisting, be processed into antibiotic property artificial grass filaments；
(2) by antibacterial artificial grass silk, chinampa is machined to by tufting together with base fabric；
(3) preparation of antibiosis rubber：The carboxylic styrene butadiene latex or polyurethane component of formula ratio, filler and antiseptic are well mixed Afterwards, the bottom of chinampa is uniformly coated in, and is obtained with antibiotic property by after oven post-cure infrared or long shaping Chinampa.
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CN107287671A (en) * 2017-08-02 2017-10-24 合肥百绿盛农业科技有限公司 A kind of antibacterial environment protection type chinampa and preparation method thereof
CN109811618A (en) * 2019-01-28 2019-05-28 江苏共创人造草坪股份有限公司 A kind of chinampa and preparation method thereof with antibacterial and mouldproof
EP3566577A1 (en) * 2018-05-09 2019-11-13 Polytex Sportbeläge Produktions-GmbH An artificial turf infill material for disinfecting artificial turfs
CN110777605A (en) * 2019-11-08 2020-02-11 江苏文明人造草坪有限公司 Artificial lawn made of nylon material
CN110777604A (en) * 2019-10-25 2020-02-11 杭州宝力体育设施工程有限公司 Synthetic formula and construction method of environment-friendly artificial turf
CN111364113A (en) * 2020-02-24 2020-07-03 广州傲胜人造草股份有限公司 Heat-dissipation slow-release antibacterial artificial grass
CN111607833A (en) * 2019-02-22 2020-09-01 斯坦德瑞琪色彩（苏州）有限公司 Artificial lawn with antibacterial and anti-aging functions and preparation method thereof
CN111719380A (en) * 2020-06-19 2020-09-29 江苏共创人造草坪股份有限公司 Novel artificial turf system with high water drainage
CN112226838A (en) * 2020-10-13 2021-01-15 乐陵泰山人造草坪产业有限公司 Artificial grass silk with shape memory function, preparation method and artificial lawn
CN114032624A (en) * 2021-12-28 2022-02-11 江苏纵横优仪人造草坪有限公司 Antibacterial artificial lawn and preparation method thereof
CN115160955A (en) * 2022-07-29 2022-10-11 乐陵泰山人造草坪产业有限公司 Transparent bottom-back high-water-seepage integrally-recyclable artificial lawn and preparation method thereof
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Publication number Priority date Publication date Assignee Title
CN107287671A (en) * 2017-08-02 2017-10-24 合肥百绿盛农业科技有限公司 A kind of antibacterial environment protection type chinampa and preparation method thereof
EP3566577A1 (en) * 2018-05-09 2019-11-13 Polytex Sportbeläge Produktions-GmbH An artificial turf infill material for disinfecting artificial turfs
WO2019215259A1 (en) * 2018-05-09 2019-11-14 Polytex Sportbeläge Produktions-Gmbh An artificial turf infill material for disinfecting artificial turfs
CN109811618A (en) * 2019-01-28 2019-05-28 江苏共创人造草坪股份有限公司 A kind of chinampa and preparation method thereof with antibacterial and mouldproof
CN111607833A (en) * 2019-02-22 2020-09-01 斯坦德瑞琪色彩（苏州）有限公司 Artificial lawn with antibacterial and anti-aging functions and preparation method thereof
CN110777604A (en) * 2019-10-25 2020-02-11 杭州宝力体育设施工程有限公司 Synthetic formula and construction method of environment-friendly artificial turf
CN110777605A (en) * 2019-11-08 2020-02-11 江苏文明人造草坪有限公司 Artificial lawn made of nylon material
CN111364113A (en) * 2020-02-24 2020-07-03 广州傲胜人造草股份有限公司 Heat-dissipation slow-release antibacterial artificial grass
CN111719380A (en) * 2020-06-19 2020-09-29 江苏共创人造草坪股份有限公司 Novel artificial turf system with high water drainage
CN112226838A (en) * 2020-10-13 2021-01-15 乐陵泰山人造草坪产业有限公司 Artificial grass silk with shape memory function, preparation method and artificial lawn
CN114032624A (en) * 2021-12-28 2022-02-11 江苏纵横优仪人造草坪有限公司 Antibacterial artificial lawn and preparation method thereof
EP4286580A3 (en) * 2022-05-25 2024-02-28 Synthetic Turf Resources Artificial turf comprising antimicrobial polyurethane backing
CN115160955A (en) * 2022-07-29 2022-10-11 乐陵泰山人造草坪产业有限公司 Transparent bottom-back high-water-seepage integrally-recyclable artificial lawn and preparation method thereof

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