CN109811618A - A kind of chinampa and preparation method thereof with antibacterial and mouldproof - Google Patents

A kind of chinampa and preparation method thereof with antibacterial and mouldproof Download PDF

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Publication number
CN109811618A
CN109811618A CN201910081875.1A CN201910081875A CN109811618A CN 109811618 A CN109811618 A CN 109811618A CN 201910081875 A CN201910081875 A CN 201910081875A CN 109811618 A CN109811618 A CN 109811618A
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CN
China
Prior art keywords
antibacterial
mouldproof
chinampa
agent
inhibitor
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Pending
Application number
CN201910081875.1A
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Chinese (zh)
Inventor
王辉
赵春贵
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Jiangsu Created Artificial Lawn Ltd By Share Ltd
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Jiangsu Created Artificial Lawn Ltd By Share Ltd
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Priority to CN201910081875.1A priority Critical patent/CN109811618A/en
Priority to CN202311212311.XA priority patent/CN117211130A/en
Publication of CN109811618A publication Critical patent/CN109811618A/en
Pending legal-status Critical Current

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Abstract

The invention discloses a kind of chinampas with antibacterial and mouldproof, it includes antibacterial and mouldproof artificial silk, the combination of base fabric and antibacterial and mouldproof latex, the main characteristic of the invention lies in that chinampa plastic wire and bottom surface all have antibacterial and mouldproof, antibiosis is to antibiotic rates such as staphylococcus aureus, Escherichia coli, streptococcus albus up to 99%, to the mould proof grade such as Aspergillus flavus, black-koji mould, Penicillium notatum, rhizopus up to 1 grade or more in terms of mildew resistance, and antibacterial mildew inhibitor can further improve artificial silk and glue film tensile strength, heat resistance.

Description

A kind of chinampa and preparation method thereof with antibacterial and mouldproof
Technical field
The present invention relates to synthetic plastic lawns, and in particular to a kind of with the chinampa of antibacterial and mouldproof and its preparation side Method.
Background technique
Chinampa is increasingly liked by people, first is that having and supporting because it has unique advantage than natural lawn Shield is simple, and the four seasons are available, attractive and durable etc., second is that will be used wider and wider, including basic football, tennis, rugby etc. Athletic ground is generalized to garden leisure now, children pet is played place, landscape place etc..With the needs of people increasingly Extensively, also higher and higher to chinampa performance requirement.It plays place using more and more children pets at present, there is an urgent need to Chinampa has antibacterial and fungicidal properties, and common chinampa is in contact pet and its excreta, or is placed in long-term dark and damp It is also easy to produce bacterial fungus etc. in environment, damages the health of user.
Summary of the invention
It is directed to where problem above, the chinampa combination with antibacterial and mouldproof that the present invention relates to a kind of can Bacterium and mould is effectively inhibited to increase simultaneously.
To achieve the goals above, the present invention adopts the following technical scheme:
A kind of chinampa with antibacterial and mouldproof, including antibacterial and mouldproof artificial grass filaments, bottom cloth layer and antibacterial and mouldproof Emulsion layer, for antibacterial and mouldproof artificial grass filaments tufting on bottom cloth layer, antibacterial and mouldproof emulsion layer is bonded in bottom cloth layer far from antibacterial and mouldproof The one side of artificial grass filaments.
Of the invention is mainly characterized in that:
1. chinampa artificial grass filaments and antibacterial and mouldproof emulsion layer have antibacterial and mould proof two kinds of characteristics;
2. antibacterial and mouldproof chinampa low manufacture cost, additive amount is few, and timeliness is long.
Further, antibacterial and mouldproof artificial grass filaments are prepared by the raw material of following mass percent: the load of 60%-80% Body, the nano-sized filler component of 1%-10% mass parts, the antibacterial mildew inhibitor component of 1%-5%, the Masterbatch group of 1%-10% Point and 0.5%-5% adjuvant component.
Be using above-mentioned further beneficial effect, mixed raw material with above-mentioned mass percent, be kneaded wire drawing at The effect of type is good, antibacterial and mouldproof significant effect.
Further, antibacterial and mouldproof emulsion layer is prepared by the raw material of following mass percent: the base-material of 40%-80%, The filler of 40%-70%, the mill base of 0.1%-5%, the auxiliary agent of 0%-5% and the antibacterial mildew inhibitor component of 1%-10%.
It is using above-mentioned further beneficial effect, selects the raw material of above-mentioned mass percent, can guaranteeing latex Under performance, make antibacterial and mouldproof emulsion layer that there is optimal antibacterial and mouldproof.
Further, above-mentioned antibacterial mildew inhibitor group is divided into composite bactericidal mould inhibitor or single type antibacterial mildew inhibitor, wherein Composite bactericidal mould inhibitor is pyridine silver/zinc inorganic salts antibacterial mildew inhibitor, it is any in silver/zinc system quaternary ammonium salt antibacterial mildew inhibitor or Two kinds of mixing;
Single type antibacterial mildew inhibitor is the mixture that antibacterial agent and mould inhibitor are mixed with mass ratio 0.2-5:1, and antibacterial agent is Any in liquid or solid inorganic nano-silver ion series antibacterial agent, zinc ion series antibacterial agent or Inorganic Copper ion series antibacterial agent Kind or several mixing;Mould inhibitor is organosilicon-quaternary ammonium salt composite mildew inhibitor, phenol system compound mould inhibitor, material of organic ethers chemical combination Object mould inhibitor, triazine series mould inhibitor, polyguanidine inorganic acid salt mould inhibitor, any one or several of acylate mould inhibitor mix It closes.
It is using above-mentioned further beneficial effect, the antibacterial and mouldproof component effect obtained with the adding manner of said ratio Fruit is optimal, and the antibacterial and mouldproof effect embodied is best.
Further, in antibacterial and mouldproof artificial grass filaments, adjuvant component is light stabilizer, antioxidant, antistatic agent, dispersing agent, Any one or several mixing of lubricant etc.;
Carrier is polypropylene, polyethylene, any one or several mixing of polyamide;
Nano-sized filler group is divided into nanometer grade calcium carbonate, mixing any one or two kinds of in nanoscale talcum powder;
Masterbatch group is divided into using polyethylene or polypropylene as the organic pigment toner masterbatch mix of carrier.
Using above-mentioned further beneficial effect be the above raw material can under the premise of guaranteeing careless silk basic mechanical performance, It is sufficiently mixed with antibacterial mildew inhibitor component, prepared careless silk can embody excellent antibacterial and mouldproof performance.
Further, the filler of antibacterial and mouldproof emulsion layer be kaolin, calcium carbonate, talcum powder or aluminium hydroxide any or Several mixing;
Auxiliary agent is any one or several mixing of anti-settling agent, plasticizer;
Base-material carboxylic styrene butadiene latex, any one or several mixing of polyurethane PU;
Mill base is aqueous or oil pastes.
Be using above-mentioned further beneficial effect, above raw material mix obtained antibacterial and mouldproof emulsion layer viscosity compared with Good, intensity is higher.
The present invention also provides the preparation methods of the above-mentioned chinampa with antibacterial and mouldproof, comprising the following steps:
(1) by carrier, nano-sized filler component, Masterbatch component, antibacterial mildew inhibitor component and adjuvant component, high-speed stirring Mixing is mixed, then carries out melting mixing with screw extruder, extrusion, wire drawing, sizing obtain antibacterial and mouldproof artificial grass filaments, by antibacterial Mould proof artificial grass filaments are processed into chinampa semi-finished product by tufting machine tufting on bottom cloth layer;
(2) base-material, filler, mill base, auxiliary agent and antibacterial mildew inhibitor component are obtained into antibacterial and mouldproof emulsion layer after mixing, The bottom of chinampa semi-finished product, coated weight 500-1000g/m are coated in by back-gluing machine2
The beneficial effect of preparation method of the present invention is: preparation method simple process, cost of material is low, is easy to extensive work Industry production.
Detailed description of the invention
Fig. 1 is the chinampa sectional view that the present invention has antibacterial and mouldproof.
In attached drawing, parts list represented by the reference numerals are as follows:
1, antibacterial and mouldproof artificial grass filaments, 2, bottom cloth layer, 3, antibacterial and mouldproof emulsion layer.
Specific embodiment
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete Site preparation description, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.It is based on Embodiment in the present invention, it is obtained by those of ordinary skill in the art without making creative efforts every other Embodiment shall fall within the protection scope of the present invention.
Embodiment 1
Chinampa with antibacterial and mouldproof is prepared by raw material in following table:
The preparation method comprises the following steps:
(1) each raw material is weighed by upper table antibacterial and mouldproof artificial grass filaments raw material additional amount, is stirred, then uses Screw Extrusion Machine progress melting mixing, extrusion, wire drawing, sizing obtain antibacterial and mouldproof artificial grass filaments, and antibacterial and mouldproof artificial grass filaments pass through tufting Machine tufting is processed into chinampa semi-finished product on bottom cloth layer;
(2) each raw material is weighed by upper table antibacterial and mouldproof emulsion layer raw material additional amount, obtains antibacterial and mouldproof cream after mixing Then glue-line is coated in the bottom of chinampa semi-finished product, coated weight 800g/m by back-gluing machine2, heated by oven heat Curing molding is to get the chinampa with antibacterial and mouldproof.
Embodiment 2
Chinampa with antibacterial and mouldproof is prepared by raw material in following table:
The preparation method comprises the following steps:
(1) each raw material is weighed by upper table antibacterial and mouldproof artificial grass filaments raw material additional amount, is stirred, then uses Screw Extrusion Machine progress melting mixing, extrusion, wire drawing, sizing obtain antibacterial and mouldproof artificial grass filaments, and antibacterial and mouldproof artificial grass filaments pass through tufting Machine tufting is processed into chinampa semi-finished product on bottom cloth layer;
(2) each raw material is weighed by upper table antibacterial and mouldproof emulsion layer raw material additional amount, obtains antibacterial and mouldproof cream after mixing Then glue-line is coated in the bottom of chinampa semi-finished product, coated weight 900g/m by back-gluing machine2, heated by oven heat Curing molding is to get the chinampa with antibacterial and mouldproof.
Embodiment 3
Chinampa with antibacterial and mouldproof is prepared by raw material in following table:
The preparation method comprises the following steps:
(1) each raw material is weighed by upper table antibacterial and mouldproof artificial grass filaments raw material additional amount, is stirred, then uses Screw Extrusion Machine progress melting mixing, extrusion, wire drawing, sizing obtain antibacterial and mouldproof artificial grass filaments, and antibacterial and mouldproof artificial grass filaments pass through tufting Machine tufting is processed into chinampa semi-finished product on bottom cloth layer;
(2) each raw material is weighed by upper table antibacterial and mouldproof emulsion layer raw material additional amount, obtains antibacterial and mouldproof cream after mixing Then glue-line is coated in the bottom of chinampa semi-finished product, coated weight 950g/m by back-gluing machine2, heated by oven heat Curing molding is to get the chinampa with antibacterial and mouldproof.
Embodiment 4
Chinampa with antibacterial and mouldproof is prepared by raw material in following table:
The preparation method comprises the following steps:
(1) each raw material is weighed by upper table antibacterial and mouldproof artificial grass filaments raw material additional amount, is stirred, then uses Screw Extrusion Machine progress melting mixing, extrusion, wire drawing, sizing obtain antibacterial and mouldproof artificial grass filaments, and antibacterial and mouldproof artificial grass filaments pass through tufting Machine tufting is processed into chinampa semi-finished product on bottom cloth layer;
(2) each raw material is weighed by upper table antibacterial and mouldproof emulsion layer raw material additional amount, obtains antibacterial and mouldproof cream after mixing Then glue-line is coated in the bottom of chinampa semi-finished product, coated weight 850g/m by back-gluing machine2, heated by oven heat Curing molding is to get the chinampa with antibacterial and mouldproof.
Embodiment 5
Chinampa with antibacterial and mouldproof is prepared by raw material in following table:
The preparation method comprises the following steps:
(1) each raw material is weighed by upper table antibacterial and mouldproof artificial grass filaments raw material additional amount, is stirred, then uses Screw Extrusion Machine progress melting mixing, extrusion, wire drawing, sizing obtain antibacterial and mouldproof artificial grass filaments, and antibacterial and mouldproof artificial grass filaments pass through tufting Machine tufting is processed into chinampa semi-finished product on bottom cloth layer;
(2) each raw material is weighed by upper table antibacterial and mouldproof emulsion layer raw material additional amount, obtains antibacterial and mouldproof cream after mixing Then glue-line is coated in the bottom of chinampa semi-finished product, coated weight 750g/m by back-gluing machine2, heated by oven heat Curing molding is to get the chinampa with antibacterial and mouldproof.
Performance test
Chinampa prepared by above-described embodiment 1-5 with antibacterial and mouldproof is tested for the property, antibacterial test Method uses the test method of the antibacterial agent determination of activity under ASTME2149-10 dynamic condition, the specified golden yellow Portugal of test sample bacterium Grape coccus;Mildew resistance test method uses the measurement of ASTMG21-2002 synthesising macromolecule copolymer material fungicidal properties, test Inoculation is black-koji mould, G virens, Chaetomium globosum, penicillium funiculosum mixed-culture medium, and antibacterial and fungus-proof test result are respectively such as The following table 1-2:
1 anti-microbial property test result of table
Antibiotic property/% Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4 Embodiment 5
Antibacterial and mouldproof artificial grass filaments 99.25 99.89 99.96 99.72 99.78
Antibacterial and mouldproof emulsion layer 99.57 99.34 99.23 99.85 99.58
2 fungicidal properties test result of table
Mould proof grade Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4 Embodiment 5
Antibacterial and mouldproof artificial grass filaments 1 1 0 1 1
Antibacterial and mouldproof emulsion layer 1 0 0 0 1
By upper table 1-2 it is found that the present invention have antibacterial and mouldproof chinampa pass through antibacterial test, antibiotic rate >= 99%;1 grade of mould proof grade or more, antibacterial and mouldproof excellent effect.

Claims (10)

1. a kind of chinampa with antibacterial and mouldproof, which is characterized in that including antibacterial and mouldproof artificial grass filaments (1), bottom cloth layer (2) and antibacterial and mouldproof emulsion layer (3), antibacterial and mouldproof artificial grass filaments (1) tufting are described anti-on the bottom cloth layer (2) The mould proof emulsion layer of bacterium (3) is bonded in the one side of the bottom cloth layer (2) far from the antibacterial and mouldproof artificial grass filaments (1).
2. a kind of chinampa with antibacterial and mouldproof according to claim 1, which is characterized in that the antibacterial and mouldproof Artificial grass filaments (1) are prepared by the raw material of following mass percent: the carrier of 60%-80%, 1%-10% mass parts are received Scaled fillers component, the antibacterial mildew inhibitor component of 1%-5%, the Masterbatch component of 1%-10% and the auxiliary agent of 0.5%-5% Component.
3. a kind of chinampa with antibacterial and mouldproof according to claim 1, which is characterized in that the antibacterial and mouldproof Emulsion layer (3) is prepared by the raw material of following mass percent: the base-material of 40%-80%, the filler of 40%-70%, The mill base of 0.1%-5%, the auxiliary agent of 0%-5% and the antibacterial mildew inhibitor component of 1%-10%.
4. a kind of chinampa with antibacterial and mouldproof according to claim 2 or 3, which is characterized in that the antibacterial Mould inhibitor group is divided into composite bactericidal mould inhibitor or single type antibacterial mildew inhibitor.
5. a kind of chinampa with antibacterial and mouldproof according to claim 4, which is characterized in that described compound anti- Bacterium mould inhibitor is pyridine silver/zinc inorganic salts antibacterial mildew inhibitor, any one or two kinds of mixed in silver/zinc system quaternary ammonium salt antibacterial mildew inhibitor It closes.
6. a kind of chinampa with antibacterial and mouldproof according to claim 4, which is characterized in that the single type is anti- Bacterium mould inhibitor is the mixture that antibacterial agent and mould inhibitor are mixed with mass ratio 0.2-5:1,
The antibacterial agent is liquid or solid inorganic nano-silver ion series antibacterial agent, zinc ion series antibacterial agent or inorganic copper ion The mixing of any one or more of series antibacterial agent;
The mould inhibitor is that organosilicon-quaternary ammonium salt composite mildew inhibitor, phenol system compound mould inhibitor, material of organic ethers compound are mould proof Agent, any one or several mixing of triazine series mould inhibitor, polyguanidine inorganic acid salt mould inhibitor, acylate mould inhibitor.
7. a kind of chinampa with antibacterial and mouldproof according to claim 2, which is characterized in that the antibacterial and mouldproof In artificial grass filaments (1), the adjuvant component be light stabilizer, antioxidant, antistatic agent, dispersing agent, lubricant etc. it is any Or several mixing;
The carrier is polypropylene, polyethylene, any one or several mixing of polyamide;
The nano-sized filler group is divided into nanometer grade calcium carbonate, mixing any one or two kinds of in nanoscale talcum powder;
The Masterbatch group is divided into using polyethylene or polypropylene as the organic pigment toner masterbatch mix of carrier.
8. a kind of chinampa with antibacterial and mouldproof according to claim 3, which is characterized in that the antibacterial and mouldproof In emulsion layer (3), the filler is any one or several mixing of kaolin, calcium carbonate, talcum powder or aluminium hydroxide;
The auxiliary agent is any one or several mixing of anti-settling agent, plasticizer;
The base-material carboxylic styrene butadiene latex, any one or several mixing of polyurethane PU.
9. a kind of preparation method of the chinampa with antibacterial and mouldproof, which comprises the following steps:
(1) antibacterial and mouldproof artificial grass filaments are processed into chinampa semi-finished product by tufting machine tufting on bottom cloth layer;
(2) bottom that antibacterial and mouldproof emulsion layer is coated in chinampa semi-finished product is obtained into the pedaline with antibacterial and mouldproof Level ground.
10. a kind of preparation method of chinampa with antibacterial and mouldproof according to claim 9, which is characterized in that The amount of coating described in step (2) is 500-1000g/m2
CN201910081875.1A 2019-01-28 2019-01-28 A kind of chinampa and preparation method thereof with antibacterial and mouldproof Pending CN109811618A (en)

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CN202311212311.XA CN117211130A (en) 2019-01-28 2019-01-28 Artificial turf with antibacterial and mildew-proof properties and preparation method thereof

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CN114032624A (en) * 2021-12-28 2022-02-11 江苏纵横优仪人造草坪有限公司 Antibacterial artificial lawn and preparation method thereof
CN115850836A (en) * 2022-12-07 2023-03-28 江苏共创人造草坪股份有限公司 Simulated plant with antibacterial and mildew-proof properties and preparation method thereof

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Application publication date: 20190528