CN101476174A - Enhanced artificial lawn fibre and preparation thereof - Google Patents
Enhanced artificial lawn fibre and preparation thereof Download PDFInfo
- Publication number
- CN101476174A CN101476174A CNA2009100284356A CN200910028435A CN101476174A CN 101476174 A CN101476174 A CN 101476174A CN A2009100284356 A CNA2009100284356 A CN A2009100284356A CN 200910028435 A CN200910028435 A CN 200910028435A CN 101476174 A CN101476174 A CN 101476174A
- Authority
- CN
- China
- Prior art keywords
- fibre
- artificial lawn
- nano
- particle
- enhanced artificial
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Images
Landscapes
- Artificial Filaments (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses an enhancing type artificial turf fibre and a preparing method thereof which belongs to the artificial turf technique field. Fibre intension and flexible of the enhancing type artificial turf fibre are increased greatly and is suitable for occasion with great intensity movement and vehement that can reduce probability of influencing movement caused by turf fibre hurting. The enhancing type artificial turf fibre is composed of matrix resin, enhancing master batch and functional material that each component has weight percentage as follows: 60-94% matrix resin, 5-30% enhancing master batch and 0.1-10% functional material.
Description
Technical field
The present invention relates to a kind of fiber and preparation method thereof,, belong to the chinampa technical field more specifically to a kind of enhanced artificial lawn fibre and preparation method thereof.
Background technology
Natural lawn is the first-selected place of large-scale international tournament, can satisfy motor function and defencive function, but it is poor to exist the durability weatherability, administrative expenses height, the shortcoming of the incompatible big stream of people, high density motion.Compare with natural lawn, chinampa except that on serviceability near the natural lawn, tangible advantage is also arranged: used in round-the-clock 24 hours, and be subjected to rain, snow weather effect little; Safeguard that simply maintenance costs is low etc.
The nylon of the first generation has been experienced in the development of artificial grass fibre, the polypropylene of the second generation, the developing stage that the polyethylene of the third generation is such, the durability of nylon is relatively good, but can change when having its mechanical property of suction back with drying, thereby change the inherent characteristic on lawn, the polypropylene weatherability is relatively poor, the fibrillation phenomenon appears easily, and its skin-friction coefficient is bigger, easily athletic sliding damaged, though the polyethylene of the third generation has improvement greatly than the exercise performance on earlier generations lawn, but high-intensity motion for fierceness, artificial grass fibre still presents certain deficiency: split on this direction in that lawn fiber behind the axial tension is easier, the dehiscence part of fiber will fracture soon, form to tangle or exposed sharp movement speckle in artificial turf playing field, this is to the exercise performance such as the shock absorbing on lawn, right sphere bounce-back etc. has a negative impact, and sportsman Yi Zaocheng is damaged etc.
Find by patent retrieval, research to artificial grass fibre at present mainly concentrates on two aspects, the one, the blending and modifying of polyvinyl addresses the above problem by the angle of first synthetic compound and the second synthetic compound blend as patent EP02077589.6.The 2nd, from the profile aspect of grass silk, improve the deflection of grass fiber, as patent WO2006085751, and nanometer inorganic filler is used for artificial lawn fiber, the patent that improves fibre strength yet there are no report.
Inorganic nano-particle can produce strong materialization effect with macromolecule himself to have special nature such as unique skin effect, small-size effect, quantum size effect and macro quanta tunnel effect, reaches polymer is strengthened toughness reinforcing effect.At present, be filler with the inorganic nano-particle, the technology of preparation nano composite material has been widely used in a plurality of technical fields such as space flight, engineering plastics, packing.
Summary of the invention
The invention solves above-mentioned the deficiencies in the prior art and problem, a kind of enhanced artificial lawn fibre is provided, this kind artificial lawn fiber is applicable to school, swimming pool non-slip floor, golf course aisle, is particularly useful for relatively more frequent, the relatively fiercer place of motions such as football field, tennis court, Rugby field.
The present invention also provides the preparation method of this enhanced artificial lawn fibre.
The present invention is achieved by the following technical solutions:
Enhanced artificial lawn fibre of the present invention is made up of matrix resin, enhancing master batch and functional material, and each weight percentages of components is as follows:
Matrix resin 60～94%
Strengthen master batch 5～30%
Functional material 0.1～10%.
The further technical scheme of enhanced artificial lawn fibre of the present invention is that described enhancing masterbatch is made up of inorganic nano-particle, vector resin and dispersant, and its each component percentage by weight is as follows:
Vector resin 40～79.5%
Inorganic nano-particle 20～59.5%
Dispersant 0.1～5%.
The further again technical scheme of enhanced artificial lawn fibre of the present invention is that described vector resin is one or more in linear low density polyethylene, low density polyethylene (LDPE), the high density polyethylene (HDPE), its melt index is 0.2～30g/10min, is preferably 1～20g/10min.
Further technical scheme can also be that described inorganic nano-particle is one or more mixtures in nano-calcium carbonate, nanomete talc powder, nano silicon, nano diatomite, the nano-silicon lime stone again, the particle diameter of inorganic nano-particle is 10～200nm, is preferably 10～100nm.
Further technical scheme can also be that described dispersant is one or more of coupling agent, atoleine, silicone oil again.
The further technical scheme of enhanced artificial lawn fibre of the present invention can also be that described matrix resin is a TPO, is preferably polyethylene kind; Described functional material is one or more the composition in Masterbatch, light stabilizer, ultra-violet absorber, antioxidant, antistatic additive, the lubricant.
For realizing above purpose, the preparation method of enhanced artificial lawn fibre of the present invention comprises two steps: one, strengthen the preparation of master batch; Two, the preparation of enhancement mode artificial grass fibre, its concrete operation is:
● strengthen the preparation of master batch:
(1) inorganic nano-particle, dispersant, vector resin are mixed the back and mix in high-speed mixer, the temperature of mixing is 50～150 ℃, and the time of mixing is 10～60 minutes;
(2) the above-mentioned material that mixes is passed through single screw rod or double screw extruder extruding pelletization, extruder temperature is controlled to be 100～200 ℃, and screw speed is 200～500r/min;
● the preparation of enhancement mode artificial grass fibre:
(1) strengthening master batch, matrix resin and functional material blend, the fusion under 150～300 ℃ temperature through single screw rod or twin-screw is squeezed into film, or the technology by melt spinning, extrudes the formation monfil;
(2), cut into the fillet of thick 50～300 μ m, wide 2～30mm with this film or filament cooling curing; Monfil does not then need cutting;
(3) draw direction at 80-150 ℃ temperature lower edge fillet makes 4～8 times of this fillet drawing-offs;
(4) with baking oven the fillet of this drawing-off is carried out 1～10% lax heat treatment under 80～150 ℃ temperature.
The present invention compared with prior art has following beneficial effect:
Enhanced artificial lawn fibre intensity of the present invention and pliability have had and have increased substantially, and are applicable to the occasion that exercise intensity is bigger, relatively fiercer, and reducing influences exercise performance because of grass fiber is impaired.Preparation method of the present invention is simple, and cost is low.
Description of drawings
Fig. 1 is the artificial wear testing schematic diagram of simulation, and wherein 1 is the roller of wear device, and 2 is the nylon footwear fourth on the roller, and 3 is artificial grass fibre of the present invention, and 4 is the basalis of chinampa.
Roller is done the motion of horizontal and vertical both direction at chinampa during use, nylon footwear fourth random distribution on roller, and the motion of skimulated motion person's football boot on artificial turf playing field, this device has obtained the approval of International Football Union.
The specific embodiment
Below by specific embodiment explanation the present invention, but the present invention not merely is defined in these embodiment.
Embodiment 1:
Raw material: (1) nano-calcium carbonate 50kg (particle diameter is 10nm), silane coupler 2kg, LLDPE50kg (melt index is 2g/10min); (2) strengthen master batch 5kg, LLDPE resin 89kg, Masterbatch 5kg, antioxidant 0.5kg, light stabilizer 0.5kg.
● strengthen the preparation of master batch
(1) nano-calcium carbonate, silane coupler and vector resin LLDPE are mixed in high-speed mixer, mixing temperature is 150 ℃, and incorporation time is 10 minutes;
(2) with above-mentioned material extruding pelletization in double screw extruder, the extruder temperature scope is 100-150 ℃, and screw speed is 200r/min.
● the preparation of enhancement mode artificial grass fibre
Use fusion under 230 ℃ temperature such as the single screw extrusion machine of the φ 110mm enhancing master batch that blend is uniform, LLDPE, Masterbatch, antioxidant, light stabilizer to be extruded into membranaceous from T pattern head, speed with 15m/min stretches, while cooling curing film forming, film is cut into narrow strip, 5 times of 90 ℃ temperature lower edge draw direction drawing-offs, in 90 ℃ heated air circulation type baking oven, carry out loose formula heat treatment afterwards, produce the enhancement mode artificial grass fibre of wide about 10mm, about 8000 DENIER of the about 100 μ m of thickness.
The measurement result of TENSILE STRENGTH, elongation at break, percent thermal shrinkage and the mar proof of the enhancement mode artificial grass fibre of preparation sees Table 1, wherein, the mensuration of TENSILE STRENGTH and elongation at break is carried out according to GB/T1040, adopts rate of extension 100mm/min, gauge length 100mm.Shrinkage factor is to be determined at the shrinkage factor of soaking 10 minutes longitudinal directions in 130 ℃ the silicone oil.Wearability test is the chinampa that earlier artificial grass fibre is made into certain specification, by experimental rig shown in Figure 1 the grass fiber of chinampa is simulated the test of artificial wear then, by taking pictures, behind 12200 cycles that relatively wear and tear, the variation of artificial grass fibre outward appearance.
Embodiment 2
Raw material: (1) nano-calcium carbonate 50kg (particle diameter is 10nm), silane coupler 2kg, LLDPE50kg (melt index is 2g/10min); (2) strengthen master batch 15kg, LLDPE resin 74kg, Masterbatch 5kg, antioxidant 0.5kg, light stabilizer 0.5kg.
Strengthen the preparation of master batch
(1) nano-calcium carbonate, silane coupler and vector resin LLDPE are mixed in high-speed mixer, mixing temperature is 90 ℃, and incorporation time is 30 minutes;
(2) with above-mentioned material extruding pelletization in double screw extruder, the extruder temperature scope is 100-150 ℃, and screw speed is 200r/min.
● the preparation of enhancement mode artificial grass fibre
Use fusion under 230 ℃ temperature such as the single screw extrusion machine of the φ 110mm enhancing master batch that blend is uniform, LLDPE, Masterbatch, antioxidant, light stabilizer to be extruded into membranaceous from T pattern head, speed with 15m/min stretches, while cooling curing film forming, film is cut into narrow strip, 5 times of 90 ℃ temperature lower edge draw direction drawing-offs, in 90 ℃ heated air circulation type baking oven, carry out loose formula heat treatment afterwards, produce the enhancement mode artificial grass fibre of wide about 10mm, about 8000 DENIER of the about 100 μ m of thickness.
Test its TENSILE STRENGTH, elongation at break, shrinkage factor, abrasion resistance properties, the results are shown in Table 1.
Raw material: (1) nano-calcium carbonate 50kg (particle diameter is 10nm), silane coupler 2kg, LLDPE50kg (melt index is 2g/10min); (2) strengthen master batch 30kg, LLDPE resin 64kg, Masterbatch 5kg, antioxidant 0.5kg, light stabilizer 0.5kg.
● strengthen the preparation of master batch
(1) nano-calcium carbonate, silane coupler and vector resin LLDPE are mixed in high-speed mixer, mixing temperature is 50 ℃, and incorporation time is 60 minutes;
(2) with above-mentioned material extruding pelletization in double screw extruder, the extruder temperature scope is 100-150 ℃, and screw speed is 200r/min.
● the preparation of enhancement mode artificial grass fibre
Use fusions under 230 ℃ temperature such as the single screw extrusion machine of the φ 110mm enhancing master batch that blend is uniform, LLDPE, Masterbatch, antioxidant, light stabilizer, be extruded into membranaceous from T pattern head, speed with 15m/min stretches, while cooling curing film forming, film is cut into narrow strip, 5 times of 90 ℃ temperature lower edge draw direction drawing-offs, in 90 ℃ heated air circulation type baking oven, carry out loose formula heat treatment afterwards, produce the enhancement mode artificial grass fibre of wide about 10mm, about 8000 DENIER of the about 100 μ m of thickness.
Test its TENSILE STRENGTH, elongation at break, shrinkage factor, abrasion resistance properties, the results are shown in Table 1.
Embodiment 4
Raw material: (1) nano-calcium carbonate 50kg (particle diameter is 100nm), aluminate coupling agent 2kg, LLDPE50kg (melt index is 2g/10min); (2) strengthen master batch 5kg, LLDPE resin 89kg, Masterbatch 5kg, antioxidant 0.5kg, light stabilizer 0.5kg.
● strengthen the preparation of master batch
(3) nano-calcium carbonate, silane coupler and vector resin LLDPE are mixed in high-speed mixer, mixing temperature is 90 ℃, and incorporation time is 30 minutes;
(4) with above-mentioned material extruding pelletization in double screw extruder, the extruder temperature scope is 100-150 ℃, and screw speed is 200r/min.
● the preparation of enhancement mode artificial grass fibre
Use fusion under 230 ℃ temperature such as the single screw extrusion machine of the φ 110mm enhancing master batch that blend is uniform, LLDPE, Masterbatch, antioxidant, light stabilizer to be extruded into membranaceous from T pattern head, speed with 15m/min stretches, while cooling curing film forming, film is cut into narrow strip, 5 times of 90 ℃ temperature lower edge draw direction drawing-offs, in 90 ℃ heated air circulation type baking oven, carry out loose formula heat treatment afterwards, produce the enhancement mode artificial grass fibre of wide about 10mm, about 8000 DENIER of the about 100 μ m of thickness.
Test its TENSILE STRENGTH, elongation at break, shrinkage factor, abrasion resistance properties, the results are shown in Table 1.
Embodiment 5
Raw material: (1) nano-calcium carbonate 50kg (particle diameter is 20nm), silicone oil 2kg, LDPE50kg (melt index is 7g/10min); (2) strengthen master batch 5kg, LLDPE resin 89kg, Masterbatch 5kg, antioxidant 0.5kg, light stabilizer 0.5kg.
● strengthen the preparation of master batch
(5) nano-calcium carbonate, silicone oil and vector resin LLDPE are mixed in high-speed mixer, mixing temperature is 90 ℃, and incorporation time is 30 minutes;
(6) with above-mentioned material extruding pelletization in double screw extruder, the extruder temperature scope is 100-150 ℃, and screw speed is 200r/min.
● the preparation of enhancement mode artificial grass fibre
Use fusions under 230 ℃ of degree temperature such as the single screw extrusion machine of the φ 90mm enhancing master batch that blend is uniform, LLDPE, Masterbatch, antioxidant, light stabilizer, processing aid, extrude via the spinning die head, form filament, speed with 20m/min stretches, the while cooling curing, 4 times of 90 ℃ temperature lower edge draw direction drawing-offs, in 90 ℃ heated air circulation type baking oven, carry out loose formula heat treatment afterwards, produce the enhancement mode artificial grass fibre of wide about 1mm, about 1250 DENIER of the about 200 μ m of thickness.
Test its TENSILE STRENGTH, elongation at break, shrinkage factor, abrasion resistance properties, the results are shown in Table 1.
Embodiment 6
Raw material: (1) nano-calcium carbonate 50kg (particle diameter is 50nm), silicone oil 2kg, LDPE50kg (melt index is 7g/10min); (2) strengthen master batch 5kg, LLDPE resin 89kg, Masterbatch 5kg, antioxidant 0.5kg, light stabilizer 0.5kg.
● strengthen the preparation of master batch
(7) nano-calcium carbonate, silicone oil and vector resin LLDPE are mixed in high-speed mixer, mixing temperature is 90 ℃, and incorporation time is 30 minutes;
(8) with above-mentioned material extruding pelletization in double screw extruder, the extruder temperature scope is 100-150 ℃, and screw speed is 200r/min.
● the preparation of enhancement mode artificial grass fibre
Use fusions under 230 ℃ temperature such as the single screw extrusion machine of the φ 90mm enhancing master batch that blend is uniform, LLDPE, Masterbatch, antioxidant, light stabilizer, processing aid, extrude via the spinning die head, form filament, speed with 20m/min stretches, the while cooling curing, 4 times of 90 ℃ temperature lower edge draw direction drawing-offs, in 90 ℃ heated air circulation type baking oven, carry out loose formula heat treatment afterwards, produce the enhancement mode artificial grass fibre of wide about 1mm, about 1250 DENIER of the about 200 μ m of thickness.
Test its TENSILE STRENGTH, elongation at break, shrinkage factor, abrasion resistance properties, the results are shown in Table 1.
Comparative example 1,2 for adopt with embodiment 1,5 in the preparation technology of identical artificial grass fibre, but do not add the enhancing master batch, the artificial grass fibre of preparation same size as a comparative example, test TENSILE STRENGTH, elongation at break, shrinkage factor and the abrasion resistance properties of fiber in the comparative example respectively, test result sees Table 1.
Table 1: embodiment and comparative example fiber test result comparison sheet
| Scheme | TENSILE STRENGTH (cN/tex) | Elongation at break (%) | Percent thermal shrinkage (%) | Anti-wear performance |
| Comparative example 1 | 11 | 25 | 10 | Longitudinal cracking is obvious |
| Embodiment 1 | 14 | 50 | 4 | Substantially there is not longitudinal cracking |
| Embodiment 2 | 13.5 | 45 | 3.6 | A small amount of longitudinal cracking |
| |
12 | 40 | 3 | A small amount of longitudinal cracking |
| Embodiment 4 | 11.5 | 30 | 3.3 | A small amount of longitudinal cracking |
| Comparative example 2 | 14.3 | 40 | 8 | Longitudinal cracking is obvious |
| Embodiment 5 | 19.2 | 80 | 4 | Substantially there is not longitudinal cracking |
| Embodiment 6 | 18.8 | 75 | 4.3 | Substantially there is not longitudinal cracking |
It is big that enhancement mode artificial grass fibre of the present invention as can be seen from the table has TENSILE STRENGTH, and percent thermal shrinkage is little, is difficult for longitudinal cracking, the characteristics that anti-wear performance is good.
Claims (10)
1, a kind of enhanced artificial lawn fibre is characterized in that being made by following raw materials by weight percent:
Matrix resin 60～94%
Strengthen master batch 5～30%
Functional material 0.1～10%.
2, enhanced artificial lawn fibre according to claim 1 is characterized in that described enhancing masterbatch is made up of inorganic nano-particle, vector resin and dispersant, and its each component percentage by weight is as follows:
Vector resin 40～79.5%
Inorganic nano-particle 20～59.5%
Dispersant 0.1～5%.
3, enhanced artificial lawn fibre according to claim 2 is characterized in that described vector resin is one or more in linear low density polyethylene, low density polyethylene (LDPE), the high density polyethylene (HDPE), and its melt index is 0.2～30g/10min.
4, enhanced artificial lawn fibre according to claim 3, the melt index that it is characterized in that described vector resin is 5～20g/10min.
5, enhanced artificial lawn fibre according to claim 2, it is characterized in that described inorganic nano-particle is one or more mixtures in nano-calcium carbonate, nanomete talc powder, nano silicon, nano diatomite, the nano-silicon lime stone, the particle diameter of inorganic nano-particle is 10～200nm.
6, enhanced artificial lawn fibre according to claim 5, the particle diameter that it is characterized in that described inorganic nano-particle is 10～100nm.
7, enhanced artificial lawn fibre according to claim 2 is characterized in that described dispersant is one or more of coupling agent, atoleine, silicone oil.
8, enhanced artificial lawn fibre according to claim 1 is characterized in that described matrix resin is a TPO; Described functional material is one or more the composition in Masterbatch, light stabilizer, ultra-violet absorber, antioxidant, antistatic additive, the lubricant.
9, enhanced artificial lawn fibre according to claim 8 is characterized in that described TPO matrix resin is a polyethylene kind.
10, a kind of preparation method as the arbitrary described enhanced artificial lawn fibre of claim 1～9 is characterized in that may further comprise the steps:
● strengthen the preparation of master batch:
(1) inorganic nano-particle, dispersant, vector resin are mixed the back and mix in high-speed mixer, the temperature of mixing is 50～150 ℃, and the time of mixing is 10～60 minutes;
(2) the above-mentioned material that mixes is passed through single screw rod or double screw extruder extruding pelletization, extruder temperature is controlled to be 100～200 ℃, and screw speed is 200～500r/min;
● the preparation of enhancement mode artificial grass fibre:
(1) strengthening master batch, matrix resin and functional material blend, the fusion under 150～300 ℃ temperature through single screw rod or twin-screw is squeezed into film, or the technology by melt spinning, extrudes the formation monfil;
(2), cut into the fillet of thick 50～300 μ m, wide 2～30mm with this film or filament cooling curing; Monfil does not then need cutting;
(3) draw direction at 80-150 ℃ temperature lower edge fillet makes 4～8 times of this fillet drawing-offs;
(4) with baking oven the fillet of this drawing-off is carried out 1～10% lax heat treatment under 80～150 ℃ temperature.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009100284356A CN101476174B (en) | 2009-01-20 | 2009-01-20 | Enhanced artificial lawn fibre and preparation thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009100284356A CN101476174B (en) | 2009-01-20 | 2009-01-20 | Enhanced artificial lawn fibre and preparation thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101476174A true CN101476174A (en) | 2009-07-08 |
| CN101476174B CN101476174B (en) | 2011-11-30 |
Family
ID=40836952
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2009100284356A Active CN101476174B (en) | 2009-01-20 | 2009-01-20 | Enhanced artificial lawn fibre and preparation thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101476174B (en) |
Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102493011A (en) * | 2011-11-14 | 2012-06-13 | 泰山体育产业集团有限公司 | Wear-resistant artificial turf fiber |
| CN103397526A (en) * | 2013-08-02 | 2013-11-20 | 泰山体育产业集团有限公司 | Airport-use instantaneous-high-temperature-resistant man-made grass filament fiber and preparation technology thereof |
| CN103465452A (en) * | 2012-06-07 | 2013-12-25 | 常州市永明机械制造有限公司 | Plastic extrusion lawn monofilament set |
| EP2940212A1 (en) * | 2014-05-02 | 2015-11-04 | Polytex Sportbeläge Produktions-GmbH | Artificial Turf production using a nucleating agent |
| CN105061877A (en) * | 2015-08-12 | 2015-11-18 | 宜兴市联创塑业有限公司 | Wear-resisting artificial turf with high stress release and preparation process of wear-resisting artificial turf |
| CN105178138A (en) * | 2015-08-12 | 2015-12-23 | 宜兴市联创塑业有限公司 | Semi-gloss artificial grass and preparation method thereof |
| CN106498530A (en) * | 2016-10-14 | 2017-03-15 | 袁春华 | A kind of preparation method of selfreparing wear-resistant man-made grass silk |
| CN107313120A (en) * | 2017-06-30 | 2017-11-03 | 广州傲胜人造草股份有限公司 | A kind of artificial grass filaments manufacture device |
| CN108977916A (en) * | 2018-08-07 | 2018-12-11 | 江苏联创人造草坪股份有限公司 | A kind of high temperature resistant chinampa and preparation method thereof |
| CN109811618A (en) * | 2019-01-28 | 2019-05-28 | 江苏共创人造草坪股份有限公司 | A kind of chinampa and preparation method thereof with antibacterial and mouldproof |
| CN109943910A (en) * | 2019-03-11 | 2019-06-28 | 张家港市金立纳米高弹材料有限公司 | A kind of wear-resisting artificial lawn filament and preparation method thereof |
| CN110924266A (en) * | 2019-11-16 | 2020-03-27 | 江苏文明人造草坪有限公司 | Artificial lawn and manufacturing method thereof |
| CN111235685A (en) * | 2020-03-10 | 2020-06-05 | 云南孚道体育设施科技有限公司 | High-performance artificial grass filaments and preparation method thereof |
| CN111395102A (en) * | 2020-02-24 | 2020-07-10 | 广州傲胜人造草股份有限公司 | Hydrophobic sports artificial turf |
| CN115323519A (en) * | 2022-08-09 | 2022-11-11 | 江苏文明人造草坪有限公司 | Preparation method of matte artificial turf |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1210345C (en) * | 2003-03-18 | 2005-07-13 | 四川大学 | Polyvinyl chloride reinforcing and tougheness improving modifier and preparation and application thereof |
| NL1026239C2 (en) * | 2004-05-19 | 2005-11-22 | Ten Cate Thiolon Bv | Method for manufacturing a plastic fiber for use in an artificial grass sports field as well as such a plastic fiber. |
| CN100497770C (en) * | 2007-04-25 | 2009-06-10 | 华东理工大学 | Monofilament fiber in polyolefin class and its preparation method |
-
2009
- 2009-01-20 CN CN2009100284356A patent/CN101476174B/en active Active
Cited By (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102493011A (en) * | 2011-11-14 | 2012-06-13 | 泰山体育产业集团有限公司 | Wear-resistant artificial turf fiber |
| CN102493011B (en) * | 2011-11-14 | 2013-12-11 | 泰山体育产业集团有限公司 | Wear-resistant artificial turf fiber |
| CN103465452A (en) * | 2012-06-07 | 2013-12-25 | 常州市永明机械制造有限公司 | Plastic extrusion lawn monofilament set |
| CN103397526A (en) * | 2013-08-02 | 2013-11-20 | 泰山体育产业集团有限公司 | Airport-use instantaneous-high-temperature-resistant man-made grass filament fiber and preparation technology thereof |
| CN103397526B (en) * | 2013-08-02 | 2015-08-19 | 泰山体育产业集团有限公司 | One the airport artificial turf fiber of resistance to TRANSIENT HIGH TEMPERATURE and preparation technology thereof |
| JP2017516000A (en) * | 2014-05-02 | 2017-06-15 | ポリテックス・シュポルトベレーゲ・プロドゥクシオンス・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツングＰｏｌｙｔｅｘ Ｓｐｏｒｔｂｅｌａｅｇｅ Ｐｒｏｄｕｋｔｉｏｎｓ ＧｍｂＨ | Artificial lawn production using nucleating agents |
| CN105040552B (en) * | 2014-05-02 | 2020-11-10 | 普利特运动产品有限责任公司 | Artificial turf production using nucleating agents |
| WO2015165739A3 (en) * | 2014-05-02 | 2016-01-07 | Polytex Sportbeläge Produktions-Gmbh | Artificial turf production using a nucleating agent |
| EP2940212A1 (en) * | 2014-05-02 | 2015-11-04 | Polytex Sportbeläge Produktions-GmbH | Artificial Turf production using a nucleating agent |
| AU2015252273B2 (en) * | 2014-05-02 | 2017-08-31 | Polytex Sportbelage Produktions-Gmbh | Artificial turf production using a nucleating agent |
| AU2015252273B9 (en) * | 2014-05-02 | 2017-11-16 | Polytex Sportbelage Produktions-Gmbh | Artificial turf production using a nucleating agent |
| CN105040552A (en) * | 2014-05-02 | 2015-11-11 | 普利特运动产品有限责任公司 | Artificial Turf production using a nucleating agent |
| US10968565B2 (en) * | 2014-05-02 | 2021-04-06 | Polytex Sportbeläge Produktions GmbH | Artificial turf production using a nucleating agent |
| CN105061877A (en) * | 2015-08-12 | 2015-11-18 | 宜兴市联创塑业有限公司 | Wear-resisting artificial turf with high stress release and preparation process of wear-resisting artificial turf |
| CN105178138A (en) * | 2015-08-12 | 2015-12-23 | 宜兴市联创塑业有限公司 | Semi-gloss artificial grass and preparation method thereof |
| CN105178138B (en) * | 2015-08-12 | 2017-05-31 | 江苏联创人造草坪股份有限公司 | A kind of chinampa with matt and preparation method thereof |
| CN106498530A (en) * | 2016-10-14 | 2017-03-15 | 袁春华 | A kind of preparation method of selfreparing wear-resistant man-made grass silk |
| CN107313120A (en) * | 2017-06-30 | 2017-11-03 | 广州傲胜人造草股份有限公司 | A kind of artificial grass filaments manufacture device |
| CN108977916A (en) * | 2018-08-07 | 2018-12-11 | 江苏联创人造草坪股份有限公司 | A kind of high temperature resistant chinampa and preparation method thereof |
| CN109811618A (en) * | 2019-01-28 | 2019-05-28 | 江苏共创人造草坪股份有限公司 | A kind of chinampa and preparation method thereof with antibacterial and mouldproof |
| CN109943910A (en) * | 2019-03-11 | 2019-06-28 | 张家港市金立纳米高弹材料有限公司 | A kind of wear-resisting artificial lawn filament and preparation method thereof |
| CN110924266A (en) * | 2019-11-16 | 2020-03-27 | 江苏文明人造草坪有限公司 | Artificial lawn and manufacturing method thereof |
| CN111395102A (en) * | 2020-02-24 | 2020-07-10 | 广州傲胜人造草股份有限公司 | Hydrophobic sports artificial turf |
| CN111395102B (en) * | 2020-02-24 | 2022-06-10 | 广州傲胜人造草股份有限公司 | Hydrophobic sports artificial turf |
| CN111235685A (en) * | 2020-03-10 | 2020-06-05 | 云南孚道体育设施科技有限公司 | High-performance artificial grass filaments and preparation method thereof |
| CN115323519A (en) * | 2022-08-09 | 2022-11-11 | 江苏文明人造草坪有限公司 | Preparation method of matte artificial turf |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101476174B (en) | 2011-11-30 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101476174B (en) | Enhanced artificial lawn fibre and preparation thereof | |
| CN104004253B (en) | Heavy polymer nucleater modified super-high molecular weight polythene blending material | |
| CN108660535B (en) | Special fiber forming material for modified ultrahigh molecular weight polyethylene, preparation method thereof and melt spinning fiber forming method | |
| CN106192213B (en) | A kind of flexible nonwoven cloth and preparation method thereof | |
| Zhang et al. | Properties comparison of high density polyethylene composites filled with three kinds of shell fibers | |
| CN102558664B (en) | High-performance polypropylene nano composite material and preparation method thereof | |
| CN102493011B (en) | Wear-resistant artificial turf fiber | |
| CN103627088B (en) | Activeness and quietness Antibacterial polypropylene composition and preparation method thereof | |
| CN106750992B (en) | A kind of low gloss, low-odor polypropylene ene compositions and preparation method thereof | |
| CN106221165A (en) | A kind of whole life cycle design of high-barrier and preparation method thereof | |
| CN107459793B (en) | Ultra-tough polylactic acid based nano composite material of strong and unyielding equilibrium and preparation method thereof | |
| CN106608997B (en) | The preparation method of plastic pipe PP Pipe Compound and continuous tow reinforced plastics tubing | |
| CN108164820A (en) | A kind of plant fiber/PP composite materials and preparation method thereof | |
| CN102516663A (en) | Polypropylene nanocomposite material with high intensity and super high toughness as well as its preparation method | |
| CN105504769A (en) | High-flowability elastic powder for 3D printing and preparation method of high-flowability elastic powder | |
| CN102952336A (en) | Active basic magnesium sulfate whisker modified polypropylene composite material and preparation method thereof | |
| CN105647137A (en) | 3D printing polylactic acid /leather powder composite materials and preparation method thereof | |
| CN107022190B (en) | A kind of graphene microchip masterbatch and preparation method for engineering plastics enhancing | |
| CN103374166A (en) | High-strength bamboo-plastic micro-foaming composite material and preparation method thereof | |
| CN109333897B (en) | Compact serial-crystal superstrong super-wear-resistant polyethylene composite material and preparation method thereof | |
| CN1944512A (en) | In-site micro fibrous composite with micro fiber of controllable flexibility and its preparing method | |
| CN106750959A (en) | A kind of resistance to scratching, anti-tacky PP composite material and preparation method thereof | |
| CN107099864B (en) | A kind of drawing process of flexible wear-resistant artificial lawn filament | |
| CN107955344A (en) | Micropore lightweight polyester（PET）Plastics Geogrids and its manufacture method | |
| CN102532704A (en) | Liquid crystalline polymer reinforced polypropylene composite material and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CP03 | Change of name, title or address | ||
| CP03 | Change of name, title or address |
Address after: 223229 Guangzhou East Road, Huaian Economic Development Zone, Huaian, Jiangsu 66 Patentee after: Jiangsu created artificial lawn Limited by Share Ltd Address before: 223229 Shihe Industrial Park, Chuzhou, Huaian, Jiangsu Patentee before: Jiangsu Co-creation Grass Co., Ltd. |