CN101469276A - 一种含油碱液分离装置及方法 - Google Patents
一种含油碱液分离装置及方法 Download PDFInfo
- Publication number
- CN101469276A CN101469276A CN 200710308071 CN200710308071A CN101469276A CN 101469276 A CN101469276 A CN 101469276A CN 200710308071 CN200710308071 CN 200710308071 CN 200710308071 A CN200710308071 A CN 200710308071A CN 101469276 A CN101469276 A CN 101469276A
- Authority
- CN
- China
- Prior art keywords
- gas
- alkali
- disengaging zone
- oil
- lye
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003513 alkali Substances 0.000 title claims abstract description 235
- 238000000926 separation method Methods 0.000 title claims abstract description 50
- 238000000034 method Methods 0.000 title claims abstract description 36
- 230000008929 regeneration Effects 0.000 claims abstract description 28
- 238000011069 regeneration method Methods 0.000 claims abstract description 28
- 230000008569 process Effects 0.000 claims abstract description 20
- 238000004220 aggregation Methods 0.000 claims abstract description 11
- 230000002776 aggregation Effects 0.000 claims abstract description 11
- 239000007789 gas Substances 0.000 claims description 157
- 230000003647 oxidation Effects 0.000 claims description 27
- 238000007254 oxidation reaction Methods 0.000 claims description 27
- 238000009826 distribution Methods 0.000 claims description 23
- 239000012530 fluid Substances 0.000 claims description 18
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 claims description 10
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 10
- 239000001301 oxygen Substances 0.000 claims description 10
- 229910052760 oxygen Inorganic materials 0.000 claims description 10
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 4
- 229910052757 nitrogen Inorganic materials 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 9
- 230000008901 benefit Effects 0.000 abstract description 4
- 230000003749 cleanliness Effects 0.000 abstract description 2
- 230000006641 stabilisation Effects 0.000 abstract 1
- 238000011105 stabilization Methods 0.000 abstract 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 241
- 239000012071 phase Substances 0.000 description 17
- WQOXQRCZOLPYPM-UHFFFAOYSA-N dimethyl disulfide Chemical compound CSSC WQOXQRCZOLPYPM-UHFFFAOYSA-N 0.000 description 16
- 239000007788 liquid Substances 0.000 description 13
- 238000006243 chemical reaction Methods 0.000 description 12
- 238000005516 engineering process Methods 0.000 description 11
- 230000004907 flux Effects 0.000 description 8
- AFVFQIVMOAPDHO-UHFFFAOYSA-N Methanesulfonic acid Chemical compound CS(O)(=O)=O AFVFQIVMOAPDHO-UHFFFAOYSA-N 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 7
- 239000002994 raw material Substances 0.000 description 6
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 5
- 239000006227 byproduct Substances 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- YWHLKYXPLRWGSE-UHFFFAOYSA-N Dimethyl trisulfide Chemical compound CSSSC YWHLKYXPLRWGSE-UHFFFAOYSA-N 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 230000001590 oxidative effect Effects 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 229910052717 sulfur Inorganic materials 0.000 description 4
- 239000011593 sulfur Substances 0.000 description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 238000006477 desulfuration reaction Methods 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 230000006872 improvement Effects 0.000 description 3
- JZMJDSHXVKJFKW-UHFFFAOYSA-M methyl sulfate(1-) Chemical compound COS([O-])(=O)=O JZMJDSHXVKJFKW-UHFFFAOYSA-M 0.000 description 3
- 238000012856 packing Methods 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 238000004064 recycling Methods 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- PQUCIEFHOVEZAU-UHFFFAOYSA-N Diammonium sulfite Chemical compound [NH4+].[NH4+].[O-]S([O-])=O PQUCIEFHOVEZAU-UHFFFAOYSA-N 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- QHYIGPGWXQQZSA-UHFFFAOYSA-N azane;methanesulfonic acid Chemical compound [NH4+].CS([O-])(=O)=O QHYIGPGWXQQZSA-UHFFFAOYSA-N 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- KWUXWMAPDYIJDD-UHFFFAOYSA-N calcium;methanesulfonic acid Chemical compound [Ca].CS(O)(=O)=O KWUXWMAPDYIJDD-UHFFFAOYSA-N 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 239000012043 crude product Substances 0.000 description 2
- 239000008151 electrolyte solution Substances 0.000 description 2
- 238000003912 environmental pollution Methods 0.000 description 2
- 230000005484 gravity Effects 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 238000005984 hydrogenation reaction Methods 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 230000001172 regenerating effect Effects 0.000 description 2
- 230000000630 rising effect Effects 0.000 description 2
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 150000007944 thiolates Chemical class 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- AOSFMYBATFLTAQ-UHFFFAOYSA-N 1-amino-3-(benzimidazol-1-yl)propan-2-ol Chemical compound C1=CC=C2N(CC(O)CN)C=NC2=C1 AOSFMYBATFLTAQ-UHFFFAOYSA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- COVZYZSDYWQREU-UHFFFAOYSA-N Busulfan Chemical compound CS(=O)(=O)OCCCCOS(C)(=O)=O COVZYZSDYWQREU-UHFFFAOYSA-N 0.000 description 1
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- 241000282326 Felis catus Species 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 239000004902 Softening Agent Substances 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000010306 acid treatment Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000003905 agrochemical Substances 0.000 description 1
- 239000000908 ammonium hydroxide Substances 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 229910001424 calcium ion Inorganic materials 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000004517 catalytic hydrocracking Methods 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000006114 decarboxylation reaction Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 125000002228 disulfide group Chemical group 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000003502 gasoline Substances 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 125000001997 phenyl group Chemical class [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000004663 powder metallurgy Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 235000010265 sodium sulphite Nutrition 0.000 description 1
- 239000008247 solid mixture Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Images
Landscapes
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
Description
Claims (9)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 200710308071 CN101469276B (zh) | 2007-12-26 | 2007-12-26 | 一种含油碱液分离装置及方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 200710308071 CN101469276B (zh) | 2007-12-26 | 2007-12-26 | 一种含油碱液分离装置及方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN101469276A true CN101469276A (zh) | 2009-07-01 |
CN101469276B CN101469276B (zh) | 2012-12-26 |
Family
ID=40827085
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN 200710308071 Active CN101469276B (zh) | 2007-12-26 | 2007-12-26 | 一种含油碱液分离装置及方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN101469276B (zh) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102671912A (zh) * | 2012-04-20 | 2012-09-19 | 宁波中一石化科技有限公司 | 一种含硫醇钠碱渣的氧化再生装置及方法 |
CN102757809A (zh) * | 2012-08-03 | 2012-10-31 | 宁波中一石化科技有限公司 | 一种汽油轻馏分脱硫醇及碱液再生的装置及方法 |
CN105038850A (zh) * | 2015-08-24 | 2015-11-11 | 宁波中一石化科技股份有限公司 | 一种凝析油脱硫醇及碱液再生回收二硫化物的装置及方法 |
CN110013758A (zh) * | 2018-01-09 | 2019-07-16 | 中国石油化工股份有限公司 | 氢化反应装置中氢化尾气安全回用与处理方法 |
CN115400591A (zh) * | 2022-10-08 | 2022-11-29 | 山东高端化工研究院有限公司 | 一种气液喷射混合强化传质的脱硫醇碱液再生装置 |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1224679C (zh) * | 2002-06-27 | 2005-10-26 | 中国石油化工股份有限公司 | 一种生产低硫汽油的方法 |
CN100335589C (zh) * | 2002-07-22 | 2007-09-05 | 李大民 | 一种含油废液的处理装置 |
CN200957308Y (zh) * | 2006-10-11 | 2007-10-10 | 宁波中一石化科技有限公司 | 聚结式分离器 |
-
2007
- 2007-12-26 CN CN 200710308071 patent/CN101469276B/zh active Active
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102671912A (zh) * | 2012-04-20 | 2012-09-19 | 宁波中一石化科技有限公司 | 一种含硫醇钠碱渣的氧化再生装置及方法 |
CN102671912B (zh) * | 2012-04-20 | 2014-05-14 | 宁波中一石化科技有限公司 | 一种含硫醇钠碱渣的氧化再生装置及方法 |
CN102757809A (zh) * | 2012-08-03 | 2012-10-31 | 宁波中一石化科技有限公司 | 一种汽油轻馏分脱硫醇及碱液再生的装置及方法 |
CN102757809B (zh) * | 2012-08-03 | 2015-03-18 | 宁波中一石化科技有限公司 | 一种汽油轻馏分脱硫醇及碱液再生的装置及方法 |
CN105038850A (zh) * | 2015-08-24 | 2015-11-11 | 宁波中一石化科技股份有限公司 | 一种凝析油脱硫醇及碱液再生回收二硫化物的装置及方法 |
CN110013758A (zh) * | 2018-01-09 | 2019-07-16 | 中国石油化工股份有限公司 | 氢化反应装置中氢化尾气安全回用与处理方法 |
CN115400591A (zh) * | 2022-10-08 | 2022-11-29 | 山东高端化工研究院有限公司 | 一种气液喷射混合强化传质的脱硫醇碱液再生装置 |
Also Published As
Publication number | Publication date |
---|---|
CN101469276B (zh) | 2012-12-26 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US7223332B1 (en) | Reactor and process for mercaptan oxidation and separation in the same vessel | |
CN101371967B (zh) | 液化气脱硫醇碱液氧化再生方法及装置 | |
US4675100A (en) | Treatment of sour hydrocarbon distillate | |
CN103189117A (zh) | 分离方法 | |
CN101469276B (zh) | 一种含油碱液分离装置及方法 | |
CN86108658A (zh) | 用于从高烯烃料液中萃取硫醇的连续工艺 | |
CN205676426U (zh) | 一种液态烃精脱硫的装置 | |
CN107043636B (zh) | 一种轻烃脱硫碱液的三相再生的装置及方法 | |
CN101712888A (zh) | 一种重苯的加氢精制工艺 | |
CN108686474A (zh) | 一种利用悬浮床的高效脱硫及再生一体化系统 | |
CN104711023A (zh) | 液化气脱硫醇尾气及碱渣治理方法及其专用设备 | |
CN108686488A (zh) | 一种悬浮床湿法脱硫及再生一体化系统 | |
CN105228724B (zh) | 减少cos和cs2的方法 | |
CN108686485A (zh) | 一种可再生的高效悬浮床脱硫工艺 | |
CN101077981A (zh) | 一种再生含有硫醇钠碱液的方法 | |
CN106861401B (zh) | 液化石油气脱硫净化系统及净化方法 | |
CN103911177A (zh) | 一种饱和液态烃深度脱硫方法 | |
CN105175296A (zh) | 一种甲硫醇盐溶液氧化生产二甲基二硫的方法及装置 | |
CN104403688A (zh) | 一种石油液化气深度脱硫精制组合工艺 | |
CN108059975A (zh) | 液化气脱硫装置及其工艺 | |
CN105731497B (zh) | 一种利用酸性气生产碳酸氢钠的方法及装置 | |
CN204211485U (zh) | 双氧水生产系统 | |
CN203238197U (zh) | 一种低含硫mtbe的生产装置 | |
CN109420417B (zh) | 一种水合法分离酸性气工艺及装置 | |
CN212396335U (zh) | 一种含硫工艺气湿法脱硫装置 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
ASS | Succession or assignment of patent right |
Owner name: NINGBO ZHONGYI PETROCHEMICAL TECHNOLOGY CO., LTD. Free format text: FORMER OWNER: NIE TONGYUAN Effective date: 20140307 Free format text: FORMER OWNER: WANG MING Effective date: 20140307 |
|
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20140307 Address after: 315040, Zhejiang, Ningbo province National hi tech Zone Lingyun road 1177 Lingyun Industrial Park, building 10, north 2 floor Patentee after: Ningbo Zhongyi Petrochemical Technology Co., Ltd. Address before: 315040, Zhejiang, Ningbo (hi tech Industrial Development Zone) Jiangnan Road 1558, room 9018, Ningbo first Petrochemical Technology Co., Ltd. Patentee before: Nie Tongyuan Patentee before: Wang Ming |
|
C56 | Change in the name or address of the patentee | ||
CP01 | Change in the name or title of a patent holder |
Address after: 315040, Zhejiang, Ningbo province National hi tech Zone Lingyun road 1177 Lingyun Industrial Park, building 10, north 2 floor Patentee after: NINGBO ZHONGYI PETROCHEMICAL TECHNOLOGY CO., LTD. Address before: 315040, Zhejiang, Ningbo province National hi tech Zone Lingyun road 1177 Lingyun Industrial Park, building 10, north 2 floor Patentee before: Ningbo Zhongyi Petrochemical Technology Co., Ltd. |
|
TR01 | Transfer of patent right |
Effective date of registration: 20210918 Address after: 300350 506-11, area a, 8 Gaoying Road, National Independent Innovation Demonstration Zone, beizhakou Town, Jinnan District, Tianjin Patentee after: SOUTH-VENTURE (TIANJIN) TECHNOLOGY DEVELOPMENT Co.,Ltd. Address before: 315040 2, North 10, Lingyun Industrial Park, Lingyun Road, 1177, national hi tech Zone, Ningbo, Zhejiang. Patentee before: NINGBO ZHONGYI PETROCHEMICAL TECHNOLOGY Co.,Ltd. |
|
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20220401 Address after: 315000 north area, 1st and 2nd floor, building 10, 1177 Lingyun Road, high tech Zone, Ningbo City, Zhejiang Province Patentee after: NINGBO ZHONGYI PETROCHEMICAL TECHNOLOGY Co.,Ltd. Address before: 300350 506-11, area a, 8 Gaoying Road, National Independent Innovation Demonstration Zone, beizhakou Town, Jinnan District, Tianjin Patentee before: SOUTH-VENTURE (TIANJIN) TECHNOLOGY DEVELOPMENT Co.,Ltd. |
|
TR01 | Transfer of patent right |