CN101463284B - Environment protection coal-saving synergistic agent - Google Patents
Environment protection coal-saving synergistic agent Download PDFInfo
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- CN101463284B CN101463284B CN 200910076922 CN200910076922A CN101463284B CN 101463284 B CN101463284 B CN 101463284B CN 200910076922 CN200910076922 CN 200910076922 CN 200910076922 A CN200910076922 A CN 200910076922A CN 101463284 B CN101463284 B CN 101463284B
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Abstract
The invention discloses an environmental-friendly coal-saving synergistic agent. The synergistic agent is prepared by the following raw materials by weight portion: 2-3 portions of benzoperoxide, 3-4 portions of isopropanol, 2-4 portions of ethyl acetate, 2-4 portions of normal butanol, 3-5 portions of sodium chloride, 4-6 portions of methanol, 3-4 portions of a cooperative synergistic agent LE-01, 5-6 portions of ethanol, 3-5 portions of calcium chloride, 4-5 portions of diethylene glycol and butyl ether, 4-5 portions of sodium sulfate, 3-5 portions of toluene, 2-4 portions of methenamine, 2-4 portions of sodium castor oil sulfate, 3-5 portions of Quick T, 3-4 portions of potassium permanganate, 1-2 portions of dicyclopentadienyl iron, 4-6 portions of tween-60, 5-7 portions of span-60, and 20-30 portions of distilled water. The environmental-friendly coal-saving synergistic agent can bulk a coal layer and improve combusting condition so as to lead combustible components of coal to be sufficiently combusted, thereby achieving the effects of saving coal, improving thermal efficiency of fire coal, and reducing discharge of smoke and dust.
Description
Technical field
The present invention relates to a kind of coal additive, particularly a kind of environment protection coal-saving synergistic agent.
Background technology
The Energy resources of China are mainly coals, and during present primary energy source consists of, coal accounts for 75%, do not have very large change within quite long from now on period.Expect 2010, the ratio of coal in China's primary energy source consumption might drop to 65%, namely still accounts for main share.But with regard to the consumption of coal total amount, will from present approximately 1,200,000,000 tons rise to 1,800,000,000 tons (being equivalent to 12.9 hundred million tons of standard coals).The energy expenditure of China accounts for 8%～9% of the world, but SO
2Discharging account for 15.1% of the world, the SO that coal combustion discharges
2Account for again 87% of national total release.SO
2Approximately 2,000 ten thousand tons at present of annual emissions, expect 2010, if do not take effective measure of control, the quantity discharged of SO2 will reach 3,000 ten thousand tons.Burning of coal is the greatest contamination source of causing China's topsoil, and has become an important factor in order of restriction Chinese national economy and social sustainable development, has already become in the world, particularly the focus of neighboring countries and regions to China's concern.As not taking strong control measures, this situation will be accelerated to worsen, and directly affects the state plans in China's 1,200,000,000 population health and 1,600,000,000 mu of arable lands of protection.
How solving burning of coal and utilize resource exhaustion and the problem of environmental pollution that causes, is the common difficulty that the whole world faces.
Summary of the invention
The technical issues that need to address of the present invention just are to provide a kind of environment protection coal-saving synergistic agent, and it can make the coal seam bulk, improves combustion conditions, and coal combustibles is fully burnt, thereby reach the effect of economizing on coal, improving coal fuel heating efficient, reduce smoke discharge amount.
For solving the problems of the technologies described above, the present invention adopts following technical scheme:
a kind of environment protection coal-saving synergistic agent of the present invention, described synergistic agent is equipped with raw material by following weight part and is prepared from: benzoyl peroxide 2-3 part, Virahol 3-4 part, ethyl acetate 2-4 part, propyl carbinol 2-4 part, sodium-chlor 3-5 part, methyl alcohol 4-6 part, synergism synergistic agent LE-01 3-4 part, ethanol 5-6 part, calcium chloride 3-5 part, Diethylene Glycol-butyl ether 4-5 part, sodium sulfate 4-5 part, toluene 3-5 part, urotropine 2-4 part, Sulfonated castor oil 2-4 part, fast T 3-5 part, potassium permanganate 3-4 part, ferrocene 1-2 part, Tween-60 4-6 part, Arlacel-60 5-7 part, distilled water 20-30 part.
Preferably, synergistic agent of the present invention is prepared from by following weight part outfit raw material: 2.5 parts of benzoyl peroxides, 3.5 parts of Virahols, 3 parts of ethyl acetate, 3 parts of propyl carbinols, 4 parts, sodium-chlor, 5 parts of methyl alcohol, 3.5 parts of synergism synergistic agent LE-01,5.5 parts of ethanol, 4 parts, calcium chloride, 4.5 parts of Diethylene Glycol-butyl ether, 4.5 parts, sodium sulfate, 4 parts of toluene, 3 parts of urotropines, 3 parts of Sulfonated castor oils, 4 parts of fast T, 3.5 parts, potassium permanganate, 1.5 parts of ferrocene, 5 parts of Tween-60s, 6 parts of Arlacel-60s, 27 parts of distilled water.
Benzoyl peroxide has another name called the methanoyl compound, and colourless or white crystals is tasteless without all.Molten some 103-106 ℃ (decomposition) is dissolved in benzene, second alcohol and water.Be used as oxygenant in the present invention.
Virahol has another name called dimethylcarbinol, second-propyl alcohol, and colourless transparent liquid, 82.5 ℃ of boiling points can be imitative miscible with water, alcohol, ether and oxygen.
Be used as storage stabilizer in the present invention.
Ethyl acetate has another name called acetic acid, colourless flammable liquid, and 73 ℃ of boiling points have fruit fragrance, easily catch fire, and are slightly soluble in water, are dissolved in ethanol, ether, benzene etc.Be used as ignition dope in the present invention.
Propyl carbinol, colourless liquid has smells of wine, 117.7 ℃ of boiling points, water-soluble can be miscible with ethanol, ether etc., its steam and air can form explosive mixture.Be used as ignition dope in the present invention.
Sodium-chlor, i.e. Household salt gauge, white or colourless translucent work is imitated crystal, is used as ignition dope in the present invention.
Methyl alcohol has another name called another name for, another name for, the water white transparency inflammable liquid, and 64.65 ℃ of boiling points, 464 ℃ of spontaneous ignition temperatures can be miscible with water, benzene, ethanol etc., and its steam and air form explosive mixture.Be used as ignition dope in the present invention.
Synergism synergistic agent LE-01, colourless transparent liquid has little fragrance flavor, can be dissolved in most organic solvents.Be used as synergistic agent in this product.
Ethanol is commonly called as alcohol, and the water white transparency inflammable liquid is volatile, is dissolved in the organic solvents such as benzene, methyl alcohol, ether, and is also water-soluble, is used as synergistic agent in the present invention.
Calcium chloride has another name called ice calcium, Calcium Chloride Powder Anhydrous be colourless or the canescence porosu solid block or granular, easy deliquescence in air, two water things are white porous hygroscopic matters, and are soluble in water and emit a large amount of heats.Be used as initiator in the present invention.
Diethylene Glycol-butyl ether, colourless liquid, little tool butanols smell, 230 ℃ of boiling points are with water, oils and other immiscible organic solvents.Be used as initiator in the present invention.
Sodium sulfate has another name called Sodium Sulphide, and the prismatic crystal of colourless or little purple water-solublely is the highly basic reaction, is dissolved in ethanol, decomposes in acid and produces hydrogen sulfide, and oxygenizement occurs simultaneously deliquescence gradually in air.Be used as scale remover in the present invention.
Toluene, colourless volatile liquid has aromatic odour, and 110.8 ℃ of boiling points are dissolved in alcohol, ether and acetone.Steam can form explosive mixture with air.Be used as solvent in the present invention.
Urotropine another name vulkacit H, white crystalline powder or colourless glossy crystal, water-soluble, ethanol, the aqueous solution is weakly alkaline, and meeting flame can burn, and is used as promotor in the present invention.
Sulfonated castor oil has another name called and accounts for very much oil, turkey red oil, and outward appearance is brown color liquid, and the emulsion that forms soluble in water is flammable, and oxidation in air has good perviousness, is used as permeate agent in the present invention.
Fast T white or colourless liquid without special odor, are used as quickly penetrating agent in this product.
Potassium permanganate, intense violet color or bronze-colored crystallization, stable in the air, decompose when being heated to 240 ℃, aerobic overflows, and meets ethanol and the decomposition of other organic solvents.Be used as catalyzer in the present invention.
Ferrocene formal name used at school dicyclopentadienyl iron, molten some 172-174 ℃, 100 ℃ of distillations slightly are dissolved in alcohol, are dissolved in the catenanes organic solvent, are soluble in aromatic hydrocarbons, and are stable to general strong acid-base, 400 ℃ of decomposition temperatures.Be used as catalyzer in the present invention.
Tween-60 ℃, amber half gluey liquid has fatty smell, and proportion 1.05-1.10 is water-soluble, diluted acid, diluted alkaline and most organic solvent, belongs to non-ionic type wheat surface-active agent.Be used as emulsifying agent in the present invention.
Arlacel-60, white or light yellow wax, little have a fatty smell, decompose in hot water milk sap, proportion 0.98-1.03 is dissolved in ethanol, in the benzene equal solvent, has emulsification, dispersion, the performance such as wetting.Be used as emulsifying agent in the present invention.
Be used as solvent in distilled water the present invention.
The present invention has the coal-saving synergist of oxidation, katalysis by interpolation, can make the coal seam bulk, improves combustion conditions, and coal combustibles is fully burnt, thereby reaches the effect of economizing on coal, improving coal fuel heating efficient, reduce smoke discharge amount.Show according to energy-conservation department examining report, use the present invention on Industrial Boiler, coal saving rate reaches 20%, and thermo-efficiency improves 15%, and the cinder carbon content descends 50%, and cigarette sulphur emissions amount reduces 30%-60%.Add effect of the present invention in low grade coal better, take year 10000 tons, consumption coal enterprise as example, use 16 tons of coal-saving synergists of the present invention, can save 300,000 yuan of funds.Not only for enterprise has reduced cost, and can reduce pollution to environment, have obvious Social benefit and economic benefit.
Embodiment
For making the purpose, technical solutions and advantages of the present invention clearer, below embodiment of the present invention is described further in detail.
Synergistic agent of the present invention is equipped with raw material by following weight part and is prepared from: 2.5 parts of benzoyl peroxides, 3.5 parts of Virahols, 3 parts of ethyl acetate, 3 parts of propyl carbinols, 4 parts, sodium-chlor, 5 parts of methyl alcohol, 3.5 parts of synergism synergistic agent LE-01,5.5 parts of ethanol, 4 parts, calcium chloride, 4.5 parts of Diethylene Glycol-butyl ether, 4.5 parts, sodium sulfate, 4 parts of toluene, 3 parts of urotropines, 3 parts of Sulfonated castor oils, 4 parts of fast T, 3.5 parts, potassium permanganate, 1.5 parts of ferrocene, 5 parts of Tween-60s, 6 parts of Arlacel-60s, 27 parts of distilled water.
The above is only preferred embodiment of the present invention, and is in order to limit the present invention, within the spirit and principles in the present invention not all, any modification of doing, is equal to replacement, improvement etc., within all should being included in protection scope of the present invention.
Claims (2)
1. environment protection coal-saving synergistic agent, it is characterized in that: described synergistic agent is equipped with raw material by following weight part and is prepared from: benzoyl peroxide 2-3 part, Virahol 3-4 part, ethyl acetate 2-4 part, propyl carbinol 2-4 part, sodium-chlor 3-5 part, methyl alcohol 4-6 part, synergism synergistic agent LE-01 3-4 part, ethanol 5-6 part, calcium chloride 3-5 part, Diethylene Glycol-butyl ether 4-5 part, sodium sulfate 4-5 part, toluene 3-5 part, urotropine 2-4 part, Sulfonated castor oil 2-4 part, fast T 3-5 part, potassium permanganate 3-4 part, ferrocene 1-2 part, Tween-60 4-6 part, Arlacel-60 5-7 part, distilled water 20-30 part.
2. environment protection coal-saving synergistic agent as claimed in claim 1, it is characterized in that: described synergistic agent is equipped with raw material by following weight part and is prepared from: 2.5 parts of benzoyl peroxides, 3.5 parts of Virahols, 3 parts of ethyl acetate, 3 parts of propyl carbinols, 4 parts, sodium-chlor, 5 parts of methyl alcohol, 3.5 parts of synergism synergistic agent LE-01, 5.5 parts of ethanol, 4 parts, calcium chloride, 4.5 parts of Diethylene Glycol-butyl ether, 4.5 parts, sodium sulfate, 4 parts of toluene, 3 parts of urotropines, 3 parts of Sulfonated castor oils, 4 parts of fast T, 3.5 parts, potassium permanganate, 1.5 parts of ferrocene, 5 parts of Tween-60s, 6 parts of Arlacel-60s, 27 parts of distilled water.
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| Application Number | Priority Date | Filing Date | Title |
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| CN 200910076922 CN101463284B (en) | 2009-01-14 | 2009-01-14 | Environment protection coal-saving synergistic agent |
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| CN 200910076922 CN101463284B (en) | 2009-01-14 | 2009-01-14 | Environment protection coal-saving synergistic agent |
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| CN101463284A CN101463284A (en) | 2009-06-24 |
| CN101463284B true CN101463284B (en) | 2013-06-19 |
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Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102191108A (en) * | 2011-03-23 | 2011-09-21 | 王东生 | Micro-explosion catalytic combustion-supporting environmentally-friendly coal saving agent |
| CN103103006B (en) * | 2013-01-25 | 2014-04-30 | 乌鲁木齐赛蒙德尔环保科技有限公司 | Coal burning catalyst as well as preparation and use method thereof |
| CN104388145B (en) * | 2014-11-21 | 2017-01-11 | 桂林融通科技有限公司 | High-efficiency environment-friendly synergistic agent for coal |
| CN104711063B (en) * | 2015-03-24 | 2017-07-21 | 湖州科达化工燃料有限公司 | A kind of NEW TYPE OF COMPOSITE solid fuel and preparation method thereof |
| CN106190404A (en) * | 2016-08-12 | 2016-12-07 | 安徽昌信生物质能源有限公司 | A kind of preparation method of biomass fuel |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1718699A (en) * | 2005-04-06 | 2006-01-11 | 尹小林 | Catalytic combustion adjuvant for coal |
| CN1730629A (en) * | 2005-08-26 | 2006-02-08 | 张冰青 | Highly effective environment protectional catalytic agent for coal saving , its preparation method and uses |
| CN101269339A (en) * | 2008-05-14 | 2008-09-24 | 袁柏安 | High-efficiency fire coal catalyst |
| CN101302456A (en) * | 2007-07-30 | 2008-11-12 | 陈睿红 | Highly effective coal combustion improver and preparation thereof |
-
2009
- 2009-01-14 CN CN 200910076922 patent/CN101463284B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1718699A (en) * | 2005-04-06 | 2006-01-11 | 尹小林 | Catalytic combustion adjuvant for coal |
| CN1730629A (en) * | 2005-08-26 | 2006-02-08 | 张冰青 | Highly effective environment protectional catalytic agent for coal saving , its preparation method and uses |
| CN101302456A (en) * | 2007-07-30 | 2008-11-12 | 陈睿红 | Highly effective coal combustion improver and preparation thereof |
| CN101269339A (en) * | 2008-05-14 | 2008-09-24 | 袁柏安 | High-efficiency fire coal catalyst |
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