CN103113931A - Novel alcohol-based household fuel with auxiliary - Google Patents
Novel alcohol-based household fuel with auxiliary Download PDFInfo
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- CN103113931A CN103113931A CN2013100345356A CN201310034535A CN103113931A CN 103113931 A CN103113931 A CN 103113931A CN 2013100345356 A CN2013100345356 A CN 2013100345356A CN 201310034535 A CN201310034535 A CN 201310034535A CN 103113931 A CN103113931 A CN 103113931A
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Abstract
The invention relates to a novel alcohol-based household fuel which is prepared by taking industrial methanol as a main body and adding constant synergist, trace synergist, an ignition accelerant, a cosolvent, a corrosion inhibitor, a metal deactivator, a flame coloring agent and a smell agent. By adding the performance modifier, the novel alcohol-based household fuel can obtain the advantages of high efficiency, energy conservation, convenience in use, mutual solubility guarantee, corrosion inhibition, safety and reliability and cleanness and environmental protection.
Description
Technical field
The present invention relates to a kind of New Alcohol Based domestic fuel with auxiliary agent that is mixed with take industrial methyl alcohol as main body.
Background technology
When " alcohol radical liquid fuel " of GB16663---1996 regulation uses as domestic fuel, having certain problem and shortcoming, is not very high as its fuel efficiency, has corrodibility, light a fire more difficult, and the colourless burning accident that easily causes of flame, smell is thin etc.
Add some performance improvers can make its have advantages of energy-efficient, easy to use, guarantee to dissolve each other, suppress the safe and reliable and clean environment firendly of burn into.The one, synergistic agent can help to overcome the low shortcoming of methyl alcohol calorific value, the 2nd, ignition improver can overcome the more difficult shortcoming of methanol fuel igniting, the 3rd, corrosion inhibitor can overcome the methyl alcohol acidifying and produce corrosive shortcoming, the 4th, the flame tinting material can overcome the colourless shortcoming that easily causes burning accident of methyl alcohol flame, and the 5th, smell the flavor agent and can prevent from methyl alcohol being leaked when ethanol uses with in time discovery by mistake.
Summary of the invention
The object of the invention is to overcome the shortcoming that existing alcohol radical liquid fuel exists and a kind of energy-efficient, safe ready with auxiliary agent is provided, guarantees to dissolve each other, suppress the New Alcohol Based domestic fuel of the safe and reliable and clean environment firendly of burn into.
In order to achieve the above object, the technical solution used in the present invention is:
Take industrial methyl alcohol as main body, add constant synergistic agent, micro-synergistic agent, ignition improver, solubility promoter, corrosion inhibitor, metal passivator, flame tinting material and smell the flavor agent.
China has standard GB/T 16663----1996 " alcohol radical liquid fuel "; when it is used as domestic fuel; at aspects such as its fuel efficiency height, igniting difficulty or ease, corrodibility size, flame visibility, odor characteristics and mutual solubilities, add above-mentioned performance improver can make its have advantages of energy-efficient, easy to use, guarantee to dissolve each other, suppress the safe and reliable and clean environment firendly of burn into.The one, synergistic agent can help to overcome the low shortcoming of methyl alcohol calorific value, the 2nd, ignition improver can overcome the more difficult shortcoming of methanol fuel igniting, the 3rd, corrosion inhibitor can overcome the methyl alcohol acidifying and produce corrosive shortcoming, the 4th, the flame tinting material can overcome the colourless shortcoming that easily causes burning accident of methyl alcohol flame, and the 5th, smell the flavor agent and can prevent from methyl alcohol being leaked when ethanol uses with in time discovery by mistake.
Embodiment
A kind of New Alcohol Based domestic fuel with auxiliary agent, with industrial methyl alcohol (GB/T338, mass content 〉=99.9%) be main body, add 1～30% constant synergistic agent of methanol quality, the micro-synergistic agent of 0.01-0.2%, the ignition improver of 0.05-1%, 1～5% solubility promoter; And add corrosion inhibitor, metal passivator, flame tinting material and smell the flavor agent.The add-on of described corrosion inhibitor is to make the pH value of feed liquid at 7-8, and the add-on of metal passivator is the copper corrosion index that makes feed liquid≤1 grade, the adding of flame tinting material feed liquid flame is had and easily sees color, smelling flavor and making feed liquid have characteristic odor adding of agent; The flame tinting material and smell the flavor agent add-on be respectively≤methanol quality 0.0001%.
Described constant synergistic agent refers to calorific value higher than the liquid fuel of methyl alcohol calorific value, such as hydro carbons, higher alcohols, ethers or ester class etc.
Described micro-synergistic agent refers to ferrocene or nitrate esters.
Described ignition improver, refer to Reid Vapour Pressure higher than the Reid Vapour Pressure (13kpa) of methyl alcohol the low boiling point hydrocarbon more than three times or ethers etc.
Described solubility promoter refers to the material that can guarantee that hydrophilic methyl alcohol and oil loving additive dissolve each other, such as higher alcohols, aromatic hydrocarbons or ethers etc.
Described corrosion inhibitor refers to thanomin, polyene amine, phenylenediamine or other amine weakly alkaline organic compound, it be can in and produce acid of methyl alcohol acidifying or the passivation of material have to(for) metallic substance.
Described metal passivator is the metal passivators such as benzotriazole, and addition is 5～15ppm of methanol quality, makes the copper corrosion index of feed liquid≤1 grade.
Described flame tinting material refers to produce under the higher carbon compounds of clear flame or high temperature and produces characteristic color trace metal compound, and for example, sodium is yellow, and potassium is purple, and rubidium is purple, and calcium is brick-red, and strontium is carmetta, and barium is yellow-green colour, and copper is green.
Describedly smell the flavor agent, refer to have the material of characteristic odor, for example, aminated compounds.
A kind of compound method of the New Alcohol Based domestic fuel with auxiliary agent: adding in the time of need to being in a liquid state below its boiling point-249 ℃ except constant synergistic agent dme, other at room temperature adds, and stirs to get final product.
Embodiment 1: get and meet 1000 liters of GB/T338---2004 " industrial methyl alcohol ", add 0.5 liter of liquid dimethyl ether below constant synergistic agent dme boiling point-24.9 ℃, get final product smooth ignition at 0 ℃; At room temperature add corrosion inhibitor alkylphosphonic acid carboxylic acid amine salt solution, regulating pH value is 7～8, adds simultaneously the ethanolic soln of metal passivator benzotriazole, by metal passivator benzotriazole 5 grams, namely have significant preservative activity, guarantee that the copper corrosion index is not more than 1 grade; At room temperature add 10 milliliters of flame tinting material ethylenediamine tetraacetic acid(EDTA) sodium saturated solutions, can make flame be yellow clearly; Smell flavor agent alkylphosphonic acid carboxylic acid amine salt owing to having added, the amine flavor of feed liquid has been covered the methyl alcohol smell, can prevent that people from misapplying and leaking, thereby needn't add other smell conditioning agent again.
Embodiment 2: get and meet 1000 liters of GB/T338----2004 " industrial methyl alcohol ", at room temperature add 1 liter of constant synergistic agent ether to get final product smooth ignition; At room temperature add corrosion inhibitor alkylphosphonic acid carboxylic acid amine salt solution, regulating pH value is 7～8, adds simultaneously the ethanolic soln of metal passivator benzotriazole, by metal passivator benzotriazole 5 grams, namely have significant preservative activity, guarantee that the copper corrosion index is not more than 1 grade; At room temperature add 10 milliliters of flame tinting material copper sulfate saturated solutions, can make flame be green clearly; Smell flavor agent alkylphosphonic acid carboxylic acid amine salt owing to having added, the amine flavor of feed liquid has been covered the methyl alcohol smell, can prevent that people from misapplying and leaking, thereby needn't add other smell conditioning agent again.
Embodiment 3: get and meet 1000 liters of GB/T338----2004 " industrial methyl alcohol ", at room temperature add 5 liters of constant synergistic agent lightweight oils to get final product smooth ignition; At room temperature add corrosion inhibitor alkylphosphonic acid carboxylic acid amine salt solution, regulating pH value is 7～8, adds simultaneously the ethanolic soln of metal passivator benzotriazole, by metal passivator benzotriazole 5 grams, namely have significant preservative activity, guarantee that the copper corrosion index is not more than 1 grade; At room temperature add 10 liters of flame tinting material illuminating kerosenes, can send bright flame; Smell flavor agent alkylphosphonic acid carboxylic acid amine salt owing to having added, the amine flavor of feed liquid has been covered the methyl alcohol smell, can prevent that people from misapplying and leaking, thereby needn't add other smell conditioning agent again.
Described alkylphosphonic acid carboxylic acid amine salt solution simultaneously as corrosion inhibitor, smell the flavor agent.
Claims (10)
1. the New Alcohol Based domestic fuel with auxiliary agent, take industrial methyl alcohol as main body, is characterized in that: add constant synergistic agent, micro-synergistic agent, ignition improver, solubility promoter, corrosion inhibitor, metal passivator, flame tinting material and smell the flavor agent.
2. fuel according to claim 1 is specially: take industrial methyl alcohol as main body, add 1～30% constant synergistic agent of methanol quality, the micro-synergistic agent of 0.01-0.2%, the ignition improver of 0.05-1%, 1～5% solubility promoter; And add corrosion inhibitor, metal passivator, flame tinting material and smell the flavor agent; The add-on of described corrosion inhibitor is to make the pH value of feed liquid at 7-8; The add-on of metal passivator is the copper corrosion index that makes feed liquid≤1 grade; The adding of flame tinting material feed liquid flame is had and easily sees color, smelling flavor and making feed liquid have characteristic odor adding of agent, flame tinting material and the add-on of smelling the flavor agent be respectively≤methanol quality 0.0001%.
3. fuel according to claim 1 and 2, it is characterized in that: described constant synergistic agent refers to calorific value higher than the liquid fuel of methyl alcohol calorific value, such as hydro carbons, higher alcohols, ethers or ester class etc.
4. fuel according to claim 1 and 2, it is characterized in that: described micro-synergistic agent refers to ferrocene or nitrate esters.
5. fuel according to claim 1 and 2 is characterized in that: described ignition improver, refer to Reid Vapour Pressure higher than the Reid Vapour Pressure of methyl alcohol the low boiling point hydrocarbon more than three times or ethers etc.
6. fuel according to claim 1 and 2 is characterized in that: described solubility promoter refers to the material that can guarantee that hydrophilic methyl alcohol and oil loving additive dissolve each other, such as higher alcohols, aromatic hydrocarbons or ethers etc.
7. fuel according to claim 1 and 2, it is characterized in that: described corrosion inhibitor, refer to thanomin, polyene amine, phenylenediamine or other amine weakly alkaline organic compound, it be can in and produce acid of methyl alcohol acidifying or the passivation of material have to(for) metallic substance.
8. fuel according to claim 1 and 2, it is characterized in that: described metal passivator is the metal passivators such as benzotriazole, addition is 5～15ppm of methanol quality, makes the copper corrosion index of feed liquid≤1 grade.
9. fuel according to claim 1 and 2, it is characterized in that: described flame tinting material, produce characteristic color trace metal compound under the higher carbon compounds of finger generation clear flame or high temperature, for example, sodium is yellow, potassium is purple, rubidium is purple, and calcium is brick-red, and strontium is carmetta, barium is yellow-green colour, and copper is green.
10. fuel according to claim 1 and 2 is characterized in that: describedly smells the flavor agent, refers to have the material of characteristic odor, for example, aminated compounds.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013100345356A CN103113931A (en) | 2013-01-30 | 2013-01-30 | Novel alcohol-based household fuel with auxiliary |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013100345356A CN103113931A (en) | 2013-01-30 | 2013-01-30 | Novel alcohol-based household fuel with auxiliary |
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| CN103113931A true CN103113931A (en) | 2013-05-22 |
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| CN2013100345356A Pending CN103113931A (en) | 2013-01-30 | 2013-01-30 | Novel alcohol-based household fuel with auxiliary |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103525478A (en) * | 2013-10-15 | 2014-01-22 | 常州市梧桐树环保科技有限公司 | Water-based liquid fuel applied to industrial atomization diffusive combustion and synthesis method thereof |
| CN107325849A (en) * | 2017-06-26 | 2017-11-07 | 贵州黔晟新能源实业有限公司 | A kind of high-vapor-pressure value alcohol-based fuel and preparation method thereof |
| CN108485726A (en) * | 2018-02-05 | 2018-09-04 | 河南云牛网络技术有限公司 | A kind of high heating value methanol fuel |
| CN109207209A (en) * | 2018-03-31 | 2019-01-15 | 黄晓磊 | Based on the methanol fuel oil additive of yeast grease and its methanol fuel oil of preparation |
| CN114106894A (en) * | 2021-11-24 | 2022-03-01 | 西安交通大学 | Imidazole borane adduct self-combustion type liquid fuel with ignition delay time regulated and controlled by ferrocene and application thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1821368A (en) * | 2006-03-17 | 2006-08-23 | 冯向法 | Alcohol civil fuel with aid and its preparing method |
-
2013
- 2013-01-30 CN CN2013100345356A patent/CN103113931A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1821368A (en) * | 2006-03-17 | 2006-08-23 | 冯向法 | Alcohol civil fuel with aid and its preparing method |
Non-Patent Citations (1)
| Title |
|---|
| 吴域琦等: "甲醇燃料——最具竞争力的可替代能源", 《中外能源》 * |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103525478A (en) * | 2013-10-15 | 2014-01-22 | 常州市梧桐树环保科技有限公司 | Water-based liquid fuel applied to industrial atomization diffusive combustion and synthesis method thereof |
| CN107325849A (en) * | 2017-06-26 | 2017-11-07 | 贵州黔晟新能源实业有限公司 | A kind of high-vapor-pressure value alcohol-based fuel and preparation method thereof |
| CN108485726A (en) * | 2018-02-05 | 2018-09-04 | 河南云牛网络技术有限公司 | A kind of high heating value methanol fuel |
| CN109207209A (en) * | 2018-03-31 | 2019-01-15 | 黄晓磊 | Based on the methanol fuel oil additive of yeast grease and its methanol fuel oil of preparation |
| CN109207209B (en) * | 2018-03-31 | 2022-09-30 | 广西金源生物化工实业有限公司 | Methanol fuel oil additive based on yeast grease and methanol fuel oil prepared by same |
| CN114106894A (en) * | 2021-11-24 | 2022-03-01 | 西安交通大学 | Imidazole borane adduct self-combustion type liquid fuel with ignition delay time regulated and controlled by ferrocene and application thereof |
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Application publication date: 20130522 |