CN102627986A - Environmental-friendly alcohol-based civil liquid fuel and preparation method thereof - Google Patents

Environmental-friendly alcohol-based civil liquid fuel and preparation method thereof Download PDF

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Publication number
CN102627986A
CN102627986A CN201210098605XA CN201210098605A CN102627986A CN 102627986 A CN102627986 A CN 102627986A CN 201210098605X A CN201210098605X A CN 201210098605XA CN 201210098605 A CN201210098605 A CN 201210098605A CN 102627986 A CN102627986 A CN 102627986A
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China
Prior art keywords
alcohol
liquid fuel
ethanol
parts
environmental
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Pending
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CN201210098605XA
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Chinese (zh)
Inventor
牛玉
王仁章
郑可利
崔国星
林明穗
罗菊香
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Sanming University
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Sanming University
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Priority to CN201210098605XA priority Critical patent/CN102627986A/en
Publication of CN102627986A publication Critical patent/CN102627986A/en
Pending legal-status Critical Current

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Abstract

The invention discloses an environmental-friendly alcohol-based civil liquid fuel and a preparation method thereof. The environmental-friendly alcohol-based civil liquid fuel comprises the following raw material components in parts by mass: 80-95 parts of methanol, 3-5 parts of ethanol, 1-3 parts of dichloromethane, 3-10 parts of dicyclopentadienyl iron and 0.1-1 part of ethanethiol. The preparation method comprises the following steps of: pouring dicyclopentadienyl iron into a mixed solution of a part of ethanol and dichloromethane, and pouring a part of methanol solution for fully dissolving the dicyclopentadienyl iron; and mixing two parts of solutions by taking a mixed solution prepared from the remaining methanol, ethanol and sulfur alcohol as a flavoring agent to obtain the product. In the method, dichloromethane and ethanol are added, so that the intersolubility of the fuel is improved, the transparency of the fuel is improved, and the production of precipitates coming out is reduced. The dicyclopentadienyl iron is taken as a smoke-eliminating energy-saving additive, so that the combustion efficiency can be increased greatly, smoke is reduced, and environmental pollution is prevented. The environmental-friendly alcohol-based civil liquid fuel can be stored, transported and used at the normal temperature and under the normal pressure without special process treatment, has low cost, and is very suitable for civil use.

Description

A kind of environmental protection alcohol-based domestic liquid fuel and preparation method thereof
Technical field
The invention belongs to the fuel field, be specifically related to a kind of environmental protection alcohol-based domestic liquid fuel and preparation method thereof.
Background technology
China's oil starvation, weak breath, rich coal, according to the world energy sources statistics, about 1,000,000,000,000 tons of coal retained reserve is wherein verified 1,145 hundred million tons of workable reserve, and explored coal reserves accounts for 33.8% of world's coal reserves.Verified in the fossil energy reserves in the whole nation, oil and natural gas only accounts for 6%, and all the other 94% are coal.Therefore, coal is the main energy sources of China, and this energy structure can not change in following one period.About 75% of the present output of coal of China directly is used for burning, the main energy is provided for national economy and people's lives, has also brought the serious environmental pollution simultaneously.Based on more than, the development and utilization of substitute energy just becomes the focus of research, invents a kind of environment friendly alcohol civil liquid fuel, not only alleviates the nervous situation that the energy uses, and also meets the longterm planning of country " 12 " energy development.Novel environment friendly fuel should be sanitation and hygiene, safe, cheap and easy to get and easy to use, convenient transportation.But at present, various alcohol civil fuel is arranged on the market, but all ubiquity that the cigarette amount is big, burning not thoroughly, unstable, the carbon distribution of combustion processes and etc. many defectives.
Summary of the invention
The object of the present invention is to provide a kind of environmental protection alcohol-based domestic liquid fuel and preparation method thereof, the present invention adds ethanol and methylene dichloride, improves the mutual solubility of fuel, improves the transparency of fuel, reduces and separates out sedimentary generation.Ferrocene as the fume-eliminating energy-saving additive, can be increased substantially efficiency of combustion, reduces smog, prevents the pollution of the environment.The present invention can store at normal temperatures and pressures, transports, use, and need not special process and handles, and each item is with low cost, is fit to very much civilian.
For realizing above-mentioned purpose, the present invention adopts following technical scheme:
A kind of feed composition of environmental protection alcohol-based domestic liquid fuel and the mass fraction of each component are methyl alcohol 80-95 part, ethanol 3-5 part, methylene dichloride 1-3 part, ferrocene 3-10 part, sulfur alcohol 0.1-1 part.
A kind of preparation method of environmental protection alcohol-based domestic liquid fuel is by each component of proportioning weighing, ferrocene is poured in the mixing solutions of part ethanol and methylene dichloride, pours the part methanol solution again into ferrocene is dissolved fully, and ie in solution becomes clear; The mixing solutions that is mixed with remaining methyl alcohol and ethanol and sulfur alcohol mixes two portions solution as odorant, promptly gets described environmental protection alcohol-based domestic liquid fuel.
Remarkable advantage of the present invention is:
(1) in the environmental protection alcohol-based domestic liquid fuel, adds ethanol, methylene dichloride mutual solvent, can improve the mutual solubility of liquid like this, improve clarity of liquor, reduce and separate out sedimentary generation.
(2) ferrocene is a kind of organometallics, also is ferrocene.It is as the fume-eliminating energy-saving additive in the present invention; Add uniform dissolution in the liquid fuel with less mass ratio; Can increase substantially efficiency of combustion, reduce smog, the positive effect that prevented the pollution of the environment, and the production cost of ferrocene is lower, be fit to extensive the use.
(3) the present invention is to be raw material with the thick methyl alcohol of cheapness, according to certain processing condition synthetic cleaning, environmental protection, high heating value liquid fuel, can store at normal temperatures and pressures, transports, use, and need not special process and handles, and each item is with low cost, is fit to very much civilian.
Embodiment
Embodiment 1
A kind of feed composition of environmental protection alcohol-based domestic liquid fuel and the mass fraction of each component are 80 parts of methyl alcohol, 5 parts of ethanol, 3 parts of methylene dichloride, 10 parts of ferrocene, 1 part of sulfur alcohol.
A kind of preparation method of environmental protection alcohol-based domestic liquid fuel is by each component of proportioning weighing, ferrocene is poured in the mixing solutions of part ethanol and methylene dichloride, pours the part methanol solution again into ferrocene is dissolved fully, and ie in solution becomes clear; The mixing solutions that is mixed with remaining methyl alcohol and ethanol and sulfur alcohol mixes two portions solution as odorant, promptly gets described environmental protection alcohol-based domestic liquid fuel.
Embodiment 2
A kind of feed composition of environmental protection alcohol-based domestic liquid fuel and the mass fraction of each component are 95 parts of methyl alcohol, 3 parts of ethanol, 1 part of methylene dichloride, 3 parts of ferrocene, 0.1 part of sulfur alcohol.
A kind of preparation method of environmental protection alcohol-based domestic liquid fuel is by each component of proportioning weighing, ferrocene is poured in the mixing solutions of part ethanol and methylene dichloride, pours the part methanol solution again into ferrocene is dissolved fully, and ie in solution becomes clear; The mixing solutions that is mixed with remaining methyl alcohol and ethanol and sulfur alcohol mixes two portions solution as odorant, promptly gets described environmental protection alcohol-based domestic liquid fuel.
Embodiment 3
A kind of feed composition of environmental protection alcohol-based domestic liquid fuel and the mass fraction of each component are 85 parts of methyl alcohol, 4 parts of ethanol, 2 parts of methylene dichloride, 5 parts of ferrocene, 0.5 part of sulfur alcohol.
A kind of preparation method of environmental protection alcohol-based domestic liquid fuel is by each component of proportioning weighing, ferrocene is poured in the mixing solutions of part ethanol and methylene dichloride, pours the part methanol solution again into ferrocene is dissolved fully, and ie in solution becomes clear; The mixing solutions that is mixed with remaining methyl alcohol and ethanol and sulfur alcohol mixes two portions solution as odorant, promptly gets described environmental protection alcohol-based domestic liquid fuel.
A kind of environmental protection alcohol-based domestic liquid fuel effect of combustion:
1. owing to fuel self structure characteristics, consume oxygen is less during burning, and fuel combustion is abundant, presents blue flame during stable burning, does not contain solid particulate in the flue gas, and products of combustion is mainly carbonic acid gas and water;
2. fuel bound nitrogen, sulphur content are very low, and nitride in the flue gas after the fuel combustion, that sulfide generates concentration is also extremely low, can obviously reduce emission of harmful substances.
3. this fuel is compared with liquefied gas stove with diesel oil, the expense that can cut down the consumption of energy, and alleviate pollution to environment.Its thermo-efficiency can reach about 60%.
The above is merely preferred embodiment of the present invention, and all equalizations of doing according to claim of the present invention change and modify, and all should belong to covering scope of the present invention.

Claims (2)

1. environmental protection alcohol-based domestic liquid fuel, it is characterized in that: the mass fraction of feed composition and each component is methyl alcohol 80-95 part, ethanol 3-5 part, methylene dichloride 1-3 part, ferrocene 3-10 part, sulfur alcohol 0.1-1 part.
2. the preparation method of an environmental protection alcohol-based domestic liquid fuel as claimed in claim 1; It is characterized in that: by each component of proportioning weighing; Ferrocene is poured in the mixing solutions of part ethanol and methylene dichloride; Pour the part methanol solution again into ferrocene is dissolved fully, ie in solution becomes clear; The mixing solutions that is mixed with remaining methyl alcohol and ethanol and sulfur alcohol mixes two portions solution as odorant, promptly gets described environmental protection alcohol-based domestic liquid fuel.
CN201210098605XA 2012-04-06 2012-04-06 Environmental-friendly alcohol-based civil liquid fuel and preparation method thereof Pending CN102627986A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201210098605XA CN102627986A (en) 2012-04-06 2012-04-06 Environmental-friendly alcohol-based civil liquid fuel and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201210098605XA CN102627986A (en) 2012-04-06 2012-04-06 Environmental-friendly alcohol-based civil liquid fuel and preparation method thereof

Publications (1)

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CN102627986A true CN102627986A (en) 2012-08-08

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103980957A (en) * 2014-04-04 2014-08-13 黄利 Novel alcohol-based liquid fuel and preparation method thereof
CN106010676A (en) * 2016-05-30 2016-10-12 贵州绿能燃料科技有限公司 Preparation method for environment-friendly alcohol-based liquid fuel and prepared fuel
CN106190357A (en) * 2016-08-25 2016-12-07 桂林浩新科技服务有限公司 A kind of efficient environment protective fuel additive and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20050160662A1 (en) * 2002-06-11 2005-07-28 Oryxe Energy International, Inc. Method and composition for using stabilized beta-carotene as cetane improver in hydrocarbonaceous diesel fuels
CN1818037A (en) * 2006-03-07 2006-08-16 路俊杰 Synthetic environmental-protective methanol fuel
CN101144037A (en) * 2006-09-14 2008-03-19 蒋维均 Nano composite alcohol group fuel
CN101619250A (en) * 2009-07-15 2010-01-06 占小玲 Methanol gasoline heat value agent

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20050160662A1 (en) * 2002-06-11 2005-07-28 Oryxe Energy International, Inc. Method and composition for using stabilized beta-carotene as cetane improver in hydrocarbonaceous diesel fuels
CN1818037A (en) * 2006-03-07 2006-08-16 路俊杰 Synthetic environmental-protective methanol fuel
CN101144037A (en) * 2006-09-14 2008-03-19 蒋维均 Nano composite alcohol group fuel
CN101619250A (en) * 2009-07-15 2010-01-06 占小玲 Methanol gasoline heat value agent

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103980957A (en) * 2014-04-04 2014-08-13 黄利 Novel alcohol-based liquid fuel and preparation method thereof
CN106010676A (en) * 2016-05-30 2016-10-12 贵州绿能燃料科技有限公司 Preparation method for environment-friendly alcohol-based liquid fuel and prepared fuel
CN106190357A (en) * 2016-08-25 2016-12-07 桂林浩新科技服务有限公司 A kind of efficient environment protective fuel additive and preparation method thereof

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Application publication date: 20120808