CN101462904B - Production and use methods of organic high protein selenium-rich fertilizer - Google Patents
Production and use methods of organic high protein selenium-rich fertilizer Download PDFInfo
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- CN101462904B CN101462904B CN2009100138152A CN200910013815A CN101462904B CN 101462904 B CN101462904 B CN 101462904B CN 2009100138152 A CN2009100138152 A CN 2009100138152A CN 200910013815 A CN200910013815 A CN 200910013815A CN 101462904 B CN101462904 B CN 101462904B
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Abstract
The invention relates to a fertilizer and a production method and a usage thereof, specifically provides an organic high-protein selenium-rich fertilizer, and the fertilizer is sprayed on the leaf surfaces of fruits and vegetables of root vegetables at different growing periods to achieve the purpose of allowing the fruits and vegetables of the root vegetables to be selenium-rich by utilizing the absorption and transformation of various elements contained in the organic high-protein selenium-rich fertilizer by the fruits and vegetables of the root vegetables, thus being capable of producing the fruits and vegetables of the selenium-rich root vegetables.
Description
Technical field
The present invention relates to a kind of fertilizer and production application process thereof, specifically a kind of production of organic high protein selenium-rich fertilizer and using method.
Background technology
Selenium is the indispensable trace element of humans and animals vital movement, and it has the effect of five aspects: 1, antimutagenic effect; 2, antioxygenation; 3, promote the deactivation of carcinogen in vivo; 4, inhibition of cell proliferation effect; 5, enhancing body immunity.But the content of selenium in the earth's crust only is 1/100000000th, there are 70% scarce selenium of regional soil and even poor selenium in the whole world, crowd more than 2/3rds lives in and lacks the selenium area, the scarce selenium present situation of China is even more serious, 2/3rds the scarce selenium area of area for generally acknowledging in the world arranged approximately, wherein, one of nearly three parts is again the serious selenium area that lacks.There is 70% population in the whole nation in the area life of scarce selenium.Existing studies show that selenium deficiency serious harm the health of human body.Scarce selenium will cause the many vitals functions of human body to descend, and significantly reduce body immunity, and some endemic illness and cardiovascular and cerebrovascular disease easily take place.
Medical research in recent years shows that selenium also has significantly anti-ageing and anti-cancer function, and the selenium content in cancer patients's blood is than the low 3-6 of normal people times, and therefore the World Health Organization announce that also selenium is described as " anticancer king ".Therefore many experts also appeal, develop selenium-enriched food as early as possible, grab benefit selenium as paying attention to enriching the iodine.But be difficult to see the food of supplement selenium element in daily life, the approach of the effective supplement selenium element of people is also very limited.
Summary of the invention
The purpose of this invention is to provide a kind of organic high protein selenium-rich fertilizer, by being carried out the blade face, sprays the earth vegetable type fruits and vegetables that is in different growing stages, and utilize earth vegetable type fruits and vegetables self that the absorption of each element in the organic high protein selenium-rich fertilizer and conversion are reached to make the rich selenium purpose of earth vegetable type fruits and vegetables, thereby can produce rich selenium earth vegetable type fruits and vegetables.
Organic high protein selenium-rich fertilizer of the present invention, various compositions that it adopts and proportioning be by weight:
Selenium element 2-9 part, each 1-5 part of zinc, magnesium, calcium, molybdenum, boron, manganese element and tensio-active agent, each 4-100 part of nitrogen, phosphorus and potassium element, the amino acid of 90-180 part.
In order to reach best effect, can be with the ratio optimization of above-mentioned each material:
Selenium element 4-8 part, each 2-4 part of zinc, magnesium, calcium, molybdenum, boron, manganese element and tensio-active agent, each 10-60 part of nitrogen, phosphorus and potassium element, 100-120 part amino acid.
Various elements in the said ratio can derive from following material: described selenium element is taken from sodium selenate or Sodium Selenite; Zinc element is taken from zinc nitrate or zinc sulfate; Magnesium elements is taken from magnesium dichloride or sal epsom; Calcium constituent is taken from calcium oxide or nitrocalcite or U-Ramin MC; Boron is taken from boric acid or sodium tetraborate; Manganese element is taken from potassium permanganate or manganous sulfate or Manganse Dioxide; The nitrogen element is taken from urea or ammonium hydrogencarbonate or primary ammonium phosphate; Phosphoric and potassium element are taken from potassium primary phosphate or saltpetre or Repone K or vitriolate of tartar.Wherein both can adopt single source by every kind of element, also can adopt multiple source, decide on production environment.And described amino acid is high protein amino acid, as: the high material of protein contents such as offal of soybean, soybean cake, peanut cake, woolen tankage, oil expression, the amino acid that generates through enzymolysis all belongs to high protein amino acid; The tensio-active agent that is adopted is a tensio-active agent commonly used on the market, as washing powder etc.
In organic high protein selenium-rich fertilizer, not only increased the content of selenium element, nitrogen, phosphorus, potassium have also been added simultaneously, because these three kinds of elements are the essential important elements of plant-growth, potassium element particularly, in the quality of improving fruit and mouthfeel, play important effect, boron and manganese element belong to trace element, except the resistance against diseases that can strengthen crop, they are the same with potassium element to play a part to improve and optimize fruit quality, mouthfeel.The interpolation of other various elements also has same or analogous effect, has improved the resistance against diseases of crop and the quality of raising fruit.
The technology for preparing above-mentioned organic high protein selenium-rich fertilizer, concrete technology is as follows: the compound at a plurality of elements place is joined in the water that weight part is 800-1100 part according to proportioning, add amino acid according to proportioning after stirring all, under 30-120 ℃ of condition, carry out getting final product in complex reaction 1-6 hour; Preferably adopt and under 40-90 ℃ of condition, carried out complex reaction 1-2.5 hour. after adopting this preparation method, following benefit is arranged: one: be to allow various elements be dissolved in fully uniformly in the aqueous solution mix fully with amino acid, its two: this temperature is the optimum temps of amino-acid complex reaction, it is just complete only to prolong the complex reaction of certain reaction time under this temperature, its three: evidence repeatedly is only under this reaction conditions, generate new complex compound, the easiest being absorbed on plant, effect is best.
Use the method for this organic high protein selenium-rich fertilizer, concrete steps are: when earth vegetable type fruits and vegetables grows 5-6 sheet leaf and the young fruit period or the expanding stage of fruit tree fruit or expand and carry out foliage spray later stage to stationary phase; Fertilizer dilute with water during sprinkling, dilution ratio are 1: 120-1: 180; The timed interval of carrying out foliage spray is 7-15 days.In order to reach better effect, the timed interval that foliage spray is carried out in general control is 10 days.
Use other precaution in the sprinkling process to be: execute to good with 4 calm rainy day gas blowouts later in afternoon, spraying back 6 hours chance rain should fill spray; Forbade spraying in preceding about 20 days gathering; Spray machinery and require cleaning, for well, can not mix with agricultural chemicals that contains phosphorus, copper or fertilizer and execute with special equipment.
This organic high protein selenium-rich fertilizer is compared with the inorganic selenium preparation of present use, and the inorganic selenium preparation that uses is to absorb inorganic selenium by plant at growth and development stage at present, changes into human body beneficial's organoselenium; Therefore in use as weather when arid, must be behind sprinkling inorganic selenium preparation in 5 days to the plant irrigation of watering, otherwise inorganic selenium can cause dunsiekte; And the present invention by inorganic selenium and high protein complex reaction after, the organic high protein selenium-rich fertilizer of making aspect the absorption of plant, has same effect with soil ulmin organophilic clay miscellaneous fertilizers, can not cause the dunsiekte phenomenon, has guaranteed the normal growth of crop.
The organic high protein selenium-rich fertilizer that adopts above-mentioned prescription and technology to make at high temperature reacts by adopting inorganic selenium and multiple inorganic elements and high protein amino acid, has generated selenium and amino acid whose complex compound, makes inorganic selenium be converted into organoselenium.Fruits and vegetables, crop absorb selenium at growth and development stage, reach the purpose that selenium is mended in the edible back of people.The organic high protein selenium-rich fertilizer of this invention is compared with the rich selenium preparation of present multielement: 1, rich selenium preparation is to adopt the compound at inorganic elements place and the inorganic selenium-enriched fertilizer that water is mixed and forms, and organic high protein selenium-rich fertilizer is the multiple amino acids that adopts inorganic elements and high protein to become by enzymolysis, carry out under the pyritous condition that complex reaction makes, it is the organic Se-rich fertilizer that the form with amino acid and inorganic elements complex compound exists; 2, selenium-enriched organic fertilizer is than the multiple element preparation of present inorganic selenium, easilier absorbed by crop, is difficult for causing the crop intoxicating phenomenon; Adopt fruits and vegetables, the crop of the rich selenium of selenium-enriched organic fertilizer material production, the content height of selenium not only, and can increase the content of multiple nutritional components such as calcium, zinc, VC, SOD, sugar, not only satisfied the requirement of human body to various trace elements, and local flavor and the mouthfeel of fruits and vegetables, crop have been improved, because the selenium element has antioxygenation, reduce putrefactive phenomenon simultaneously, had the excellent popularization using value.This organic high protein selenium-rich fertilizer is suitable for plurality of vegetables and fruit and other crops.
Embodiment
Embodiment 1
A kind of organic high protein selenium-rich fertilizer composition and proportioning are as follows:
Sodium Selenite 12.5g, zinc nitrate 8g, sal epsom 8g, calcium oxide 8g, ammonium molybdate 5g, boric acid 8g, potassium permanganate 0.6g, tensio-active agent 5g, urea or ammonium hydrogencarbonate 100g, primary ammonium phosphate 200g, saltpetre 200g; High protein amino acid 280g;
The method for making of this organic high protein selenium-rich fertilizer is as follows:
Above-mentioned various materials are joined stir in the water of 1000g after, in reaction under 100 ℃ the condition after 1.5 hours, the organic high protein selenium-rich fertilizer of making.
When earth vegetable type fruits and vegetables grows to 5-6 sheet leaf or the young fruit period behind the fruit tree fallen flowers, the organic high protein selenium-rich fertilizer for preparing is diluted with water to the flushing liquor of organic high protein selenium-rich fertilizer by 1: 130 multiplying power, carries out foliage spray with the flushing liquor of this organic high protein selenium-rich fertilizer;
The earth vegetable type fruits and vegetables root at expanding stage, carries out second time foliage spray with above-mentioned organic high protein selenium-rich fertilizer flushing liquor with concentration at the fruit of expanding stage or fruit tree;
Expand expanding later stage to stationary phase of earth vegetable type fruits and vegetables and various crop or fruit tree of later stage or fruit tree fruit at the earth vegetable type fruits and vegetables root, adopt above-mentioned organic high protein selenium-rich fertilizer flushing liquor to carry out foliage spray for the third time with concentration;
Spraying the timed interval for three times is 15 days;
The fruit selenium content of bright earth vegetable type fruits and vegetables and fruit tree reaches 0.85mg/kg.
Embodiment 2
A kind of organic high protein selenium-rich fertilizer composition and proportioning are as follows:
Sodium selenate 10g, zinc sulfate 6g, magnesium dichloride 15g, nitrocalcite 5g, ammonium molybdate 8g, boric acid 15g, potassium permanganate 0.1g, tensio-active agent 5g, urea or ammonium hydrogencarbonate 200g, primary ammonium phosphate 250g, saltpetre 200g, high protein amino acid 220g;
The method for making of this organic high protein selenium-rich fertilizer is as follows:
Above-mentioned various materials are joined stir in the water of 1000g after, in reaction under 90 ℃ the condition after 2 hours, the organic high protein selenium-rich fertilizer of making.
When earth vegetable type fruits and vegetables grows to 5-6 sheet leaf or the young fruit period behind the fruit tree fallen flowers, the organic high protein selenium-rich fertilizer for preparing is diluted with water to the flushing liquor of organic high protein selenium-rich fertilizer by 1: 120 multiplying power, carries out foliage spray with the flushing liquor of this organic high protein selenium-rich fertilizer;
The earth vegetable type fruits and vegetables root at expanding stage, carries out second time foliage spray with above-mentioned organic high protein selenium-rich fertilizer flushing liquor with concentration at the fruit of expanding stage or fruit tree;
Expand expanding later stage to stationary phase of earth vegetable type fruits and vegetables and various crop or fruit tree of later stage or fruit tree fruit at the earth vegetable type fruits and vegetables root, adopt above-mentioned organic high protein selenium-rich fertilizer flushing liquor to carry out foliage spray for the third time with concentration;
Spraying the timed interval for three times is 8 days;
The fruit selenium content of bright earth vegetable type fruits and vegetables and fruit tree reaches 0.84mg/kg.
Embodiment 3
A kind of organic high protein selenium-rich fertilizer composition and proportioning are as follows:
Sodium Selenite 18g, zinc nitrate 5g, sal epsom 4g, calcium chloride 6g, ammonium molybdate 5g, borax 8g, ammonium hydrogencarbonate 180g, Secondary ammonium phosphate 400g, Repone K 200g, high protein amino acid 320g;
The method for making of this organic high protein selenium-rich fertilizer is as follows:
Above-mentioned various materials are joined stir in the water of 1000g after, in reaction under 120 ℃ the condition after 1 hour, the organic high protein selenium-rich fertilizer of making.
When earth vegetable type fruits and vegetables grows to 5-6 sheet leaf or the young fruit period behind the fruit tree fallen flowers, the organic high protein selenium-rich fertilizer for preparing is diluted with water to the flushing liquor of organic high protein selenium-rich fertilizer by 1: 120 multiplying power, carries out foliage spray with the flushing liquor of this organic high protein selenium-rich fertilizer;
The earth vegetable type fruits and vegetables root at expanding stage, carries out second time foliage spray with above-mentioned organic high protein selenium-rich fertilizer flushing liquor with concentration at the fruit of expanding stage or fruit tree;
Expand expanding later stage to stationary phase of earth vegetable type fruits and vegetables and various crop or fruit tree of later stage or fruit tree fruit at the earth vegetable type fruits and vegetables root, adopt above-mentioned organic high protein selenium-rich fertilizer flushing liquor to carry out foliage spray for the third time with concentration;
Spraying the timed interval for three times is 8 days;
The fruit selenium content of bright earth vegetable type fruits and vegetables and fruit tree reaches 0.80mg/kg.
Embodiment 4
A kind of organic high protein selenium-rich fertilizer composition and proportioning are as follows:
Sodium Selenite 5g, zinc acetate 10g, magnesium dichloride 10g, calcium oxide 4g, ammonium molybdate 6g, boric acid 15g, potassium permanganate 0.3g, ammonium hydrogencarbonate 200g, primary ammonium phosphate 250g, saltpetre 250g, high protein amino acid/11 80g;
The method for making of this organic high protein selenium-rich fertilizer is as follows:
Above-mentioned various materials are joined stir in the water of 800g after, in reaction under 80 ℃ the condition after 1 hour, the organic high protein selenium-rich fertilizer of making.
When earth vegetable type fruits and vegetables grows to 5-6 sheet leaf or the young fruit period behind the fruit tree fallen flowers, the organic high protein selenium-rich fertilizer for preparing is diluted with water to the flushing liquor of organic high protein selenium-rich fertilizer by 1: 160 multiplying power, carries out foliage spray with the flushing liquor of this organic high protein selenium-rich fertilizer;
The earth vegetable type fruits and vegetables root at expanding stage, carries out second time foliage spray with above-mentioned organic high protein selenium-rich fertilizer flushing liquor with concentration at the fruit of expanding stage or fruit tree;
Expand expanding later stage to stationary phase of earth vegetable type fruits and vegetables and various crop or fruit tree of later stage or fruit tree fruit at the earth vegetable type fruits and vegetables root, adopt above-mentioned organic high protein selenium-rich fertilizer flushing liquor to carry out foliage spray for the third time with concentration;
Spraying the timed interval for three times is 7 days;
The fruit selenium content of bright earth vegetable type fruits and vegetables and fruit tree reaches 0.85mg/kg.
Embodiment 5:
A kind of organic high protein selenium-rich fertilizer composition and proportioning are as follows:
Sodium Selenite 37g, zinc sulfate 12g, sal epsom 9g, calcium oxide 6g, ammonium molybdate 8g, sodium tetraborate 15g, manganous chloride 3g, sulfate of ammoniac 280g, ammonium phosphate 400g, vitriolate of tartar potassium 500g, high protein amino acid 850g;
The method for making of this organic high protein selenium-rich fertilizer is as follows:
Above-mentioned various materials are joined stir in the water of 1200g after, in reaction under 40 ℃ the condition after 90 minutes, the organic high protein selenium-rich fertilizer of making.
Grow to 5-6 sheet leaf or the young fruit period behind the fruit tree fallen flowers at earth vegetable type fruits and vegetables, the organic high protein selenium-rich fertilizer for preparing is diluted with water to the flushing liquor of organic high protein selenium-rich fertilizer by 1: 180 multiplying power, carries out foliage spray with the flushing liquor of this organic high protein selenium-rich fertilizer;
The earth vegetable type fruits and vegetables root at expanding stage, carries out second time foliage spray with above-mentioned organic high protein selenium-rich fertilizer flushing liquor with concentration at the fruit of expanding stage or fruit tree;
Expand expanding later stage to stationary phase of earth vegetable type fruits and vegetables and various crop or fruit tree of later stage or fruit tree fruit at the earth vegetable type fruits and vegetables root, adopt above-mentioned organic high protein selenium-rich fertilizer flushing liquor to carry out foliage spray for the third time with concentration;
Spraying the timed interval for three times is 5 days;
The fruit selenium content of bright earth vegetable type fruits and vegetables and fruit tree reaches 0.88mg/kg.
The test example
The contriver adopts the Weihe River county radish in Shandong to carry out simultaneous test, what experimental group adopted is prepared organic high protein selenium-rich fertilizer among the embodiment 3, and disclosed processing using method, the Weihe River county radish that produces, control group is respectively the inorganic selenium preparation that adopts present people to use always, and does not adopt selenium-enriched fertilizer; Using method is the conventional supply of sowing, test period is the complete growth cycle of radish, the Weihe River county radish of production, the Weihe River county radish of not spraying selenium fertilizer, national standard detection method according to the up-to-date issue of country detects its nutritive ingredient, activeconstituents respectively.Detected result sees Table 1:
Table 1: rich selenium Weihe River county radish and the nutritive ingredient of Weihe River county radish, the measurement result of activeconstituents
By data in the table as can be known: organic high protein selenium-rich fertilizer is easier to be absorbed by crop, is difficult for causing the crop intoxicating phenomenon.With the Weihe River county radish of its output, the content height of selenium not only, and can increase the content of calcium, zinc, VC, SOD sugar etc., and the mouthfeel that Weihe River county radish is become is better.Than adopting inorganic selenium preparation as fertilizer sources, various content and mouthfeel all are greatly improved.
Claims (7)
1. organic high protein selenium-rich fertilizer is characterized in that: various compositions that it adopts and proportioning by weight:
Selenium element 2-9 part, each 1-5 part of zinc, magnesium, calcium, molybdenum, boron, manganese element and tensio-active agent, each 4-100 part of nitrogen, phosphorus and potassium element, the amino acid of 90-180 part;
Its preparation method is as follows:
The compound at each element place is joined in the water that weight part is 800-1100 part according to proportioning, add amino acid according to proportioning after the stirring all, under 30-120 ℃ of condition, carry out getting final product in complex reaction 1-6 hour;
Described selenium element is taken from sodium selenate or Sodium Selenite; Zinc element is taken from zinc nitrate or zinc acetate or zinc sulfate; Magnesium elements is taken from magnesium dichloride or sal epsom; Calcium constituent is taken from calcium oxide or nitrocalcite or U-Ramin MC; Boron is taken from boric acid or sodium tetraborate; Manganese element is taken from potassium permanganate or manganous sulfate or Manganse Dioxide; The nitrogen element is taken from urea, ammonium hydrogencarbonate or ammonium sulfate or primary ammonium phosphate; Phosphoric and potassium element are taken from potassium primary phosphate or saltpetre or Repone K or vitriolate of tartar; Molybdenum element is from ammonium molybdate.
2. organic high protein selenium-rich fertilizer according to claim 1, it is characterized in that: various compositions that it adopts and proportioning by weight: selenium element 4-8 part, each 2-4 part of zinc, magnesium, calcium, molybdenum, boron, manganese element and tensio-active agent, each 10-60 part of nitrogen, phosphorus and potassium element, 100-120 part amino acid.
3. organic high protein selenium-rich fertilizer according to claim 1 is characterized in that: described amino acid is the amino acid that the high protein material forms by enzymolysis.
4. the technology for preparing organic high protein selenium-rich fertilizer as claimed in claim 1, concrete technology is as follows: the compound at each element place is joined in the water that weight part is 800-1100 part according to proportioning, add amino acid according to proportioning after stirring all, under 30-120 ℃ of condition, carry out getting final product in complex reaction 1-6 hour;
Described selenium element is taken from sodium selenate or Sodium Selenite; Zinc element is taken from zinc nitrate or zinc acetate or zinc sulfate; Magnesium elements is taken from magnesium dichloride or sal epsom; Calcium constituent is taken from calcium oxide or nitrocalcite or U-Ramin MC; Boron is taken from boric acid or sodium tetraborate; Manganese element is taken from potassium permanganate or manganous sulfate or Manganse Dioxide; The nitrogen element is taken from urea, ammonium hydrogencarbonate or ammonium sulfate or primary ammonium phosphate; Phosphoric and potassium element are taken from potassium primary phosphate or saltpetre or Repone K or vitriolate of tartar; Molybdenum element is from ammonium molybdate.
5. organic high protein selenium-rich fertilizer technology according to claim 4 is characterized in that: carry out getting final product in complex reaction 1-2.5 hour under 40-90 ℃ of condition.
6. use the method for the described organic high protein selenium-rich fertilizer of claim 1, it is characterized in that: when earth vegetable type fruits and vegetables grows 5-6 sheet leaf and the young fruit period or the expanding stage of fruit tree fruit or expand and carry out foliage spray later stage to stationary phase; Fertilizer dilute with water during sprinkling, dilution ratio are 1: 120-1: 180; The timed interval of carrying out foliage spray is 7-15 days.
7. the using method of organic high protein selenium-rich fertilizer according to claim 6 is characterized in that:, the timed interval of carrying out foliage spray is 10 days.
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| CN109485505A (en) * | 2018-12-25 | 2019-03-19 | 李勇 | A kind of poly- semicarbazide element compound fertilizer |
| CN111108993A (en) * | 2019-12-25 | 2020-05-08 | 南京绿宙薄壳山核桃科技有限公司 | Selenium-rich fertilizer for apocarya, preparation method and application thereof, and selenium-rich cultivation method for apocarya |
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