CN101445687A - Alcohol solution printing ink for wrapping paper of intaglio plate cigarette and preparation method thereof - Google Patents

Alcohol solution printing ink for wrapping paper of intaglio plate cigarette and preparation method thereof Download PDF

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Publication number
CN101445687A
CN101445687A CN 200810243277 CN200810243277A CN101445687A CN 101445687 A CN101445687 A CN 101445687A CN 200810243277 CN200810243277 CN 200810243277 CN 200810243277 A CN200810243277 A CN 200810243277A CN 101445687 A CN101445687 A CN 101445687A
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China
Prior art keywords
printing ink
alcohol
intaglio plate
cigarette package
pure molten
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CN 200810243277
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CN101445687B (en
Inventor
周贤永
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JIANGSU TIGER INK CO Ltd
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Individual
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Abstract

The invention discloses an alcohol-soluble printing ink for wrapping paper of an intaglio plate cigarette, which is characterized in that the alcohol-soluble printing ink is prepared from the following raw materials by the weight percentage: 1 to 10 percent of polyvinyl butyal, 15 to 85 percent of alcohol and 5 to 75 percent of paints and/or fillers. 1 to 15 percent of solid resin and/or 0.1 to 5 percent of auxiliary agents can be added to the alcohol-soluble printing ink. The invention further discloses a method for preparing the alcohol-soluble printing ink for the intaglio wrapping paper of the plate cigarette. Compared with the traditional alcohol-soluble printing ink for the filter tip of the intaglio plate cigarette, the invention has the advantages of stable quality, high color depth of the printing ink, good printing adaptability, no harmful residue after printed products are dried, clear and bright printing patterns, bright color, good brightness, strong adhesive degree, fading prevention and falling-off prevention of the printing products, good water resistance and excellent friction resistance.

Description

The intaglio plate cigarette package paper is with pure molten printing ink and preparation method thereof
Technical field
The present invention relates to a kind of printing ink, particularly a kind of intaglio plate cigarette package paper is with pure molten printing ink; The invention also discloses the preparation method of above-mentioned printing ink.
Background technology
The intaglio plate cigarette package paper has been widely used in the cigarette pack industry with pure molten printing ink.But existing tipping paper is single with pure molten ink performance, the print quality instability, and the printing ink China ink is difficult for adjusting.In recent years, to diversified development, the content of cigarette filter outward appearance, pattern, cigarette, technology of the package also was colourful to cigarette brand by simplification.Therefore, the intaglio plate cigarette package paper with pure molten printing ink new requirement has been proposed.
Summary of the invention
Technical problem to be solved by this invention is at the deficiencies in the prior art, provides that a kind of China ink is good, the intaglio plate cigarette package paper of stable performance is with pure molten printing ink.
Another technical problem to be solved by this invention provides the preparation method of a kind of aforesaid intaglio plate cigarette package paper with pure molten printing ink.
Technical problem to be solved by this invention is to realize by following technical scheme.The present invention be a kind of intaglio plate cigarette package paper with pure molten printing ink, be characterized in that it is made by following raw materials by weight percent, polyvinyl butyral acetal 1-10%; Alcohol 15-85%;
Pigment and filler 5-75%.
Technical problem to be solved by this invention can also further realize by following technical scheme.Above-described intaglio plate cigarette package paper is characterized in that with pure molten printing ink it has also added following raw materials by weight percent, solid resin 1-15%.
Technical problem to be solved by this invention can also further realize by following technical scheme.Above-described intaglio plate cigarette package paper is characterized in that with pure molten printing ink it has also added following raw materials by weight percent,
Auxiliary agent 0.1-5%.
Technical problem to be solved by this invention can also further realize by following technical scheme.Above-described intaglio plate cigarette package paper is characterized in pure molten printing ink, and the weight percent of each raw material is,
Polyvinyl butyral acetal 4%; Solid resin 10%;
Pigment 20%; Filler 30%;
Alcohol 34%; Auxiliary agent 2%.
In above-described technical solution of the present invention:
Described solid resin can be disclosed any solid resin that is applicable to that printing ink is produced in the prior art, preferred polyketone resin, aldehyde ketone resin or rosin;
Described raw material alcohol generally selects for use concentration to be not less than 95% alcohol, and preferred concentration is not less than 99% alcohol;
Described auxiliary agent can be disclosed any auxiliary agent that is applicable to that printing ink is produced in the prior art, comprises in softening agent, drying retardant, flow agent, the dispersion agent one or more;
Described pigment can be disclosed any pigment that is applicable to that printing ink is produced in the prior art, one or more in preferred iron oxide yellow, red iron oxide, carbon black, the titanium dioxide; Described filler can be disclosed any filler that is applicable to that printing ink is produced in the prior art, one or more in preferred fine particle calcium carbonate, talcum powder, the kaolin;
Described pigment and filler can only use pigment in use, also can only use filler, can also use pigment and filler the two by arbitrary proportion blended mixture.
Each raw material described in the present invention all can refer to disclosed any described raw material, the perhaps described raw material that makes by disclosed method in the prior art in the prior art if no special instructions.
Technical problem to be solved by this invention can also further realize by following technical scheme.The invention also discloses a kind of as described intaglio plate cigarette package paper of above technical scheme preparation method, be characterized in that its step is as follows with pure molten printing ink,
(1) 10%-40% with polyvinyl butyral acetal, solid resin and alcohol total amount disperses to dissolve fully until solid resin in the material cylinder, gets resin liquid;
(2) with the 60%-90% of resin liquid, pigment with/or filler, auxiliary agent mix with the 20%-50% of alcohol total amount, be uniformly dispersed;
(3) scattered material is transferred in the sand mill grinds, reach requirement, resin liquid, the alcohol of remainder are successively crossed sand mill, once more all materials are uniformly dispersed, promptly until fineness.
Compared with prior art, the molten ink quality of intaglio plate cigarette filter alcohol that the present invention is more traditional is stable, printing ink depth of shade height, printing adaptability are good, no hazard residue thing after the printed matter drying, clear lucid and lively, bright-colored, the good luster of printed patterns, attachment fastness is strong, and printing is difficult for fading, difficult drop-off, water resisting property are good, and scratch-resistant performance is good.
Embodiment
Below further describe concrete technical scheme of the present invention,, and do not constitute restriction its right so that those skilled in the art understands the present invention further.
Embodiment 1.A kind of intaglio plate cigarette package paper is with pure molten printing ink, and it is made by following raw materials by weight percent, polyvinyl butyral acetal 1%; Alcohol 24%;
Pigment or filler 75%.
The production technique of printing ink preparation routinely.
Embodiment 2.A kind of intaglio plate cigarette package paper is with pure molten printing ink, and it is made by following raw materials by weight percent, polyvinyl butyral acetal 10%; Alcohol 85%;
Pigment or filler 5%.
Embodiment 3.A kind of intaglio plate cigarette package paper is with pure molten printing ink, and it is made by following raw materials by weight percent, polyvinyl butyral acetal 5%; Alcohol 30%;
Pigment or filler 65%.
Embodiment 4.A kind of intaglio plate cigarette package paper is with pure molten printing ink, and it is made by following raw materials by weight percent, polyvinyl butyral acetal 10%; Alcohol 15%;
Pigment or filler 75%.
Embodiment 5.A kind of intaglio plate cigarette package paper is with pure molten printing ink, and it is made by following raw materials by weight percent, polyvinyl butyral acetal 10%; Alcohol 85%;
Pigment or filler 5%.
Embodiment 6.A kind of intaglio plate cigarette package paper is with pure molten printing ink, and it is made by following raw materials by weight percent, polyvinyl butyral acetal 8%; Alcohol 52%;
Pigment 20%; Filler 20%.
Embodiment 7.A kind of intaglio plate cigarette package paper is with pure molten printing ink, and it is made by following raw materials by weight percent, polyvinyl butyral acetal 2%; Alcohol 30%;
Pigment 30%; Filler 38%.
Embodiment 8.A kind of intaglio plate cigarette package paper is with pure molten printing ink, and it is made by following raw materials by weight percent, polyvinyl butyral acetal 10%; Alcohol 79%;
Pigment or filler 20%; Solid resin 1%;
The production technique of printing ink preparation routinely.
Embodiment 9.A kind of intaglio plate cigarette package paper is with pure molten printing ink, and it is made by following raw materials by weight percent, polyvinyl butyral acetal 1%; Alcohol 79%;
Pigment or filler 5%; Solid resin 15%.
Embodiment 10.A kind of intaglio plate cigarette package paper is with pure molten printing ink, and it is made by following raw materials by weight percent, polyvinyl butyral acetal 5%; Alcohol 40%;
Pigment or filler 45%; Solid resin 10%.
Embodiment 11.A kind of intaglio plate cigarette package paper is with pure molten printing ink, and it is made by following raw materials by weight percent, polyvinyl butyral acetal 8%; Alcohol 20%;
Pigment 10%; Filler 50%;
Solid resin 12%.
Embodiment 12.A kind of intaglio plate cigarette package paper is with pure molten printing ink, and it is made by following raw materials by weight percent, polyvinyl butyral acetal 6%; Alcohol 60%;
Pigment 5%; Filler 25%;
Solid resin 4%.
Embodiment 13.A kind of intaglio plate cigarette package paper is with pure molten printing ink, and it is made by following raw materials by weight percent, polyvinyl butyral acetal 3.9%; Alcohol 56%;
Pigment or filler 40%; Auxiliary agent 0.1%;
The production technique of printing ink preparation routinely.
Embodiment 14.A kind of intaglio plate cigarette package paper is with pure molten printing ink, and it is made by following raw materials by weight percent, polyvinyl butyral acetal 7%; Alcohol 28%;
Pigment or filler 60%; Auxiliary agent 5%.
Embodiment 15.A kind of intaglio plate cigarette package paper is with pure molten printing ink, and it is made by following raw materials by weight percent, polyvinyl butyral acetal 3%; Alcohol 55%;
Pigment or filler 40%; Auxiliary agent 2%.
Embodiment 16.A kind of intaglio plate cigarette package paper is with pure molten printing ink, and it is made by following raw materials by weight percent, polyvinyl butyral acetal 6%; Alcohol 15%;
Pigment 5%; Filler 70%;
Auxiliary agent 4%.
Embodiment 17.A kind of intaglio plate cigarette package paper is with pure molten printing ink, and it is made by following raw materials by weight percent, polyvinyl butyral acetal 2%; Alcohol 27%;
Pigment 60%; Filler 10%;
Auxiliary agent 1%;
Embodiment 18.A kind of intaglio plate cigarette package paper is with pure molten printing ink, and it is made by following raw materials by weight percent, polyvinyl butyral acetal 7%; Alcohol 25%;
Pigment 15%; Filler 50%;
Auxiliary agent 3%;
Embodiment 19.A kind of intaglio plate cigarette package paper is with pure molten printing ink, and it is made by following raw materials by weight percent, polyvinyl butyral acetal 1%; Alcohol 83%;
Pigment or filler 5%; Solid resin 10%;
Auxiliary agent 1%;
The production technique of printing ink preparation routinely.
Embodiment 20.A kind of intaglio plate cigarette package paper is with pure molten printing ink, and it is made by following raw materials by weight percent, polyvinyl butyral acetal 10%; Alcohol 65%;
Pigment or filler 5%; Solid resin 15%;
Auxiliary agent 5%.
Its preparation methods steps is as follows,
(1) 10% of polyvinyl butyral acetal, solid resin and alcohol total amount disperseed to dissolve fully until solid resin in the material cylinder, get resin liquid;
(2) with resin liquid 60%, pigment with/or filler, auxiliary agent mix with 20% of alcohol total amount, be uniformly dispersed;
(3) scattered material is transferred in the sand mill grinds, reach requirement, resin liquid, the alcohol of remainder are successively crossed sand mill, once more all materials are uniformly dispersed, promptly until fineness.。
Embodiment 21.A kind of intaglio plate cigarette package paper is with pure molten printing ink, and it is made by following raw materials by weight percent, polyvinyl butyral acetal 5%; Alcohol 18.9%;
Pigment or filler 75%; Solid resin 1%;
Auxiliary agent 0.1%.
Its preparation methods steps is as follows,
(1) 40% of polyvinyl butyral acetal, solid resin and alcohol total amount disperseed to dissolve fully until solid resin in the material cylinder, get resin liquid;
(2) with resin liquid 90%, pigment with/or filler, auxiliary agent mix with 50% of alcohol total amount, be uniformly dispersed;
(3) scattered material is transferred in the sand mill grinds, reach requirement, resin liquid, the alcohol of remainder are successively crossed sand mill, once more all materials are uniformly dispersed, promptly until fineness.。
Embodiment 22.A kind of intaglio plate cigarette package paper is with pure molten printing ink, and it is made by following raw materials by weight percent, polyvinyl butyral acetal 8%; Alcohol 15%;
Pigment or filler 70%; Solid resin 5%;
Auxiliary agent 2%.
Its preparation methods steps is as follows,
(1) 25% of polyvinyl butyral acetal, solid resin and alcohol total amount disperseed to dissolve fully until solid resin in the material cylinder, get resin liquid;
(2) with resin liquid 75%, pigment with/or filler, auxiliary agent mix with 35% of alcohol total amount, be uniformly dispersed;
(3) scattered material is transferred in the sand mill grinds, reach requirement, resin liquid, the alcohol of remainder are successively crossed sand mill, once more all materials are uniformly dispersed, promptly until fineness.
Embodiment 23.A kind of intaglio plate cigarette package paper is with pure molten printing ink, and it is made by following raw materials by weight percent, polyvinyl butyral acetal 1%; Alcohol 70%;
Pigment 5%; Filler 5%;
Solid resin 15%; Auxiliary agent 4%.
Its preparation methods steps is as follows,
(1) 10% of polyvinyl butyral acetal, solid resin and alcohol total amount disperseed to dissolve fully until solid resin in the material cylinder, get resin liquid;
(2) with resin liquid 60%%, pigment with/or filler, auxiliary agent mix with 20% of alcohol total amount, be uniformly dispersed;
(3) scattered material is transferred in the sand mill grinds, reach requirement, resin liquid, the alcohol of remainder are successively crossed sand mill, once more all materials are uniformly dispersed, promptly until fineness.
Embodiment 24.A kind of intaglio plate cigarette package paper is with pure molten printing ink, and it is made by following raw materials by weight percent, polyvinyl butyral acetal 10%; Alcohol 25%;
Pigment 30%; Filler 20%;
Solid resin 12%; Auxiliary agent 3%.
Its preparation methods steps is as follows,
(1) 20% of polyvinyl butyral acetal, solid resin and alcohol total amount disperseed to dissolve fully until solid resin in the material cylinder, get resin liquid;
(2) with resin liquid 80%, pigment with/or filler, auxiliary agent mix with 30% of alcohol total amount, be uniformly dispersed;
(3) scattered material is transferred in the sand mill grinds, reach requirement, resin liquid, the alcohol of remainder are successively crossed sand mill, once more all materials are uniformly dispersed, promptly until fineness.
Embodiment 25.A kind of intaglio plate cigarette package paper is with pure molten printing ink, and it is made by following raw materials by weight percent, polyvinyl butyral acetal 4%; Solid resin 10%;
Pigment 20%; Filler 30%;
Alcohol 34%; Auxiliary agent 2%.
Its preparation methods steps is as follows,
(1) 30% of polyvinyl butyral acetal, solid resin and alcohol total amount disperseed to dissolve fully until solid resin in the material cylinder, get resin liquid;
(2) with resin liquid 70%, pigment with/or filler, auxiliary agent mix with 400% of alcohol total amount, be uniformly dispersed;
(3) scattered material is transferred in the sand mill grinds, reach requirement, resin liquid, the alcohol of remainder are successively crossed sand mill, once more all materials are uniformly dispersed, promptly until fineness.
Embodiment 26.Any one described intaglio plate cigarette package paper is with in the pure molten printing ink among the embodiment 8-12, and described solid resin is the polyketone resin.
Embodiment 27.Any one described intaglio plate cigarette package paper is with in the pure molten printing ink among the embodiment 19-25, and described solid resin is aldehyde ketone resin or rosin.
Embodiment 28.Any one described intaglio plate cigarette package paper is with in the pure molten printing ink among the embodiment 13-25, and described auxiliary agent is any one in softening agent, drying retardant, flow agent, the dispersion agent.
Embodiment 29.Any one described intaglio plate cigarette package paper is with in the pure molten printing ink among the embodiment 13-25, and described auxiliary agent is any two kinds in softening agent, drying retardant, flow agent, the dispersion agent.
Embodiment 30.Any one described intaglio plate cigarette package paper is with in the pure molten printing ink among the embodiment 13-25, and described auxiliary agent is any three kinds in softening agent, drying retardant, flow agent, the dispersion agent.
Embodiment 31.Any one described intaglio plate cigarette package paper is with in the pure molten printing ink among the embodiment 13-25, and described auxiliary agent is softening agent, drying retardant, flow agent and dispersion agent.
Embodiment 32.Any one described intaglio plate cigarette package paper is with in the pure molten printing ink among the embodiment 1-25, and described pigment is any one in iron oxide yellow, red iron oxide, carbon black, the titanium dioxide; Described filler is any one in fine particle calcium carbonate, talcum powder, the kaolin.
Embodiment 33.Any one described intaglio plate cigarette package paper is with in the pure molten printing ink among the embodiment 1-25, and described pigment is any two kinds in iron oxide yellow, red iron oxide, carbon black, the titanium dioxide; Described filler is any two kinds in fine particle calcium carbonate, talcum powder, the kaolin.
Embodiment 34.Any one described intaglio plate cigarette package paper is with in the pure molten printing ink among the embodiment 1-25, and described pigment is any three kinds in iron oxide yellow, red iron oxide, carbon black, the titanium dioxide; Described filler is fine particle calcium carbonate, talcum powder and kaolin.
Embodiment 35.Any one described intaglio plate cigarette package paper is with in the pure molten printing ink among the embodiment 1-25, and described pigment is iron oxide yellow, red iron oxide, carbon black and titanium dioxide; Described filler is any one in fine particle calcium carbonate, talcum powder, the kaolin.

Claims (10)

1, a kind of intaglio plate cigarette package paper is characterized in that with pure molten printing ink, and it is made by following raw materials by weight percent,
Polyvinyl butyral acetal 1-10%; Alcohol 15-85%;
Pigment and filler 5-75%.
2, intaglio plate cigarette package paper according to claim 1 is characterized in that with pure molten printing ink, and described raw material alcohol is that concentration is not less than 99% alcohol.
3, intaglio plate cigarette package paper according to claim 1 is characterized in that with pure molten printing ink, and it has also added following raw materials by weight percent,
Solid resin 1-15%.
4, intaglio plate cigarette package paper according to claim 3 is characterized in that with pure molten printing ink, and described solid resin is selected from polyketone resin, aldehyde ketone resin or rosin.
5, intaglio plate cigarette package paper according to claim 3 is characterized in that with pure molten printing ink, and it has also added following raw materials by weight percent,
Auxiliary agent 0.1-5%.
6, intaglio plate cigarette package paper according to claim 5 is characterized in that with pure molten printing ink, and described auxiliary agent is at least a in softening agent, drying retardant, flow agent, the dispersion agent.
7, intaglio plate cigarette package paper according to claim 5 is characterized in that with pure molten printing ink, and the weight percent of each raw material is,
Polyvinyl butyral acetal 4%; Solid resin 10%;
Pigment 20%; Filler 30%;
Alcohol 34%; Auxiliary agent 2%.
8, intaglio plate cigarette package paper according to claim 1 is characterized in that with pure molten printing ink, and described pigment is at least a in iron oxide yellow, red iron oxide, carbon black, the titanium dioxide; Described filler is at least a in fine particle calcium carbonate, talcum powder, the kaolin.
9, intaglio plate cigarette package paper according to claim 1 is characterized in that with pure molten printing ink, and it has also added following raw materials by weight percent,
Auxiliary agent 0.1-5%.
10, a kind of as right 5 or 7 described intaglio plate cigarette package papers with the preparation method of pure molten printing ink, it is characterized in that its step is as follows,
(1) 10%-40% with polyvinyl butyral acetal, solid resin and alcohol total amount disperses to dissolve fully until solid resin in the material cylinder, gets resin liquid;
(2) with the 60%-90% of resin liquid, pigment with/or filler, auxiliary agent mix with the 20%-50% of alcohol total amount, be uniformly dispersed;
(3) scattered material is transferred in the sand mill grinds, reach requirement, resin liquid, the alcohol of remainder are successively crossed sand mill, once more all materials are uniformly dispersed, promptly until fineness.
CN 200810243277 2008-12-23 2008-12-23 Alcohol solution printing ink for wrapping paper of intaglio plate cigarette and preparation method thereof Active CN101445687B (en)

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CN102250507A (en) * 2011-08-15 2011-11-23 高邮市卫星卷烟材料有限公司 Antistatic foaming tipping paper printing ink
CN102896922A (en) * 2011-07-25 2013-01-30 大亚科技股份有限公司 Production method of tipping paper with water-based ink
CN103073952A (en) * 2013-02-03 2013-05-01 云南彩丰油墨有限公司 Alcohol ester-soluble ink for cast coating cardboard intaglio printing and preparation method of alcohol ester-soluble ink
CN103483509A (en) * 2013-09-18 2014-01-01 江苏泰格油墨有限公司 Method for preparing alcohol-sol-resin for tipping paper printing ink
CN103666090A (en) * 2012-08-30 2014-03-26 广东广乐包装材料股份有限公司 Alcohol-soluble environment-friendly printing ink for tipping paper and preparation method thereof
CN103694780A (en) * 2013-12-11 2014-04-02 苏州谊恒印务有限公司 Alcohol-soluble silk-screen printing ink
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CN104479452A (en) * 2015-01-17 2015-04-01 曲靖麒麟福牌印刷有限公司 Black printing ink for printing cigarette tipping paper and preparing method
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CN110643220A (en) * 2019-09-26 2020-01-03 安徽集友纸业包装有限公司 Printing ink, tipping paper for cigarettes and cigarettes
CN110698913A (en) * 2019-09-25 2020-01-17 云南中烟工业有限责任公司 Lip adhesion-preventing alcohol-soluble ink for tipping paper for cigarettes
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CN102896922A (en) * 2011-07-25 2013-01-30 大亚科技股份有限公司 Production method of tipping paper with water-based ink
CN102250507A (en) * 2011-08-15 2011-11-23 高邮市卫星卷烟材料有限公司 Antistatic foaming tipping paper printing ink
CN102250507B (en) * 2011-08-15 2013-07-10 高邮市卫星卷烟材料有限公司 Antistatic foaming tipping paper printing ink
CN103666090A (en) * 2012-08-30 2014-03-26 广东广乐包装材料股份有限公司 Alcohol-soluble environment-friendly printing ink for tipping paper and preparation method thereof
CN103666090B (en) * 2012-08-30 2015-01-28 广东广乐包装材料股份有限公司 Alcohol-soluble environment-friendly printing ink for tipping paper and preparation method thereof
CN103073952A (en) * 2013-02-03 2013-05-01 云南彩丰油墨有限公司 Alcohol ester-soluble ink for cast coating cardboard intaglio printing and preparation method of alcohol ester-soluble ink
CN103483509A (en) * 2013-09-18 2014-01-01 江苏泰格油墨有限公司 Method for preparing alcohol-sol-resin for tipping paper printing ink
CN103709820A (en) * 2013-11-25 2014-04-09 龙游特美纸制品有限公司 White ink
CN103694780A (en) * 2013-12-11 2014-04-02 苏州谊恒印务有限公司 Alcohol-soluble silk-screen printing ink
CN104479452A (en) * 2015-01-17 2015-04-01 曲靖麒麟福牌印刷有限公司 Black printing ink for printing cigarette tipping paper and preparing method
CN104449032A (en) * 2015-01-17 2015-03-25 曲靖麒麟福牌印刷有限公司 White printing ink for printing tipping paper for cigarettes and preparation method
CN104479451A (en) * 2015-01-17 2015-04-01 曲靖麒麟福牌印刷有限公司 Connected substance of printing cigarette tipping paper
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CN110698913A (en) * 2019-09-25 2020-01-17 云南中烟工业有限责任公司 Lip adhesion-preventing alcohol-soluble ink for tipping paper for cigarettes
CN110643220A (en) * 2019-09-26 2020-01-03 安徽集友纸业包装有限公司 Printing ink, tipping paper for cigarettes and cigarettes
CN111395035A (en) * 2020-04-20 2020-07-10 玉溪思润印刷有限公司 Special lip lubricating and anti-sticking protective adhesive and application thereof to tipping paper
CN111395035B (en) * 2020-04-20 2022-04-05 玉溪思润印刷有限公司 Special lip lubricating and anti-sticking protective adhesive and application thereof to tipping paper
CN116751478A (en) * 2023-06-16 2023-09-15 江苏云合新材料科技有限公司 Environment-friendly antibacterial printing ink for tipping paper for cigarettes and preparation method thereof
CN116751478B (en) * 2023-06-16 2023-12-15 江苏云合新材料科技有限公司 Environment-friendly antibacterial printing ink for tipping paper for cigarettes and preparation method thereof

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