CN109504170A - A kind of abrasion resistant fire blocking type cigarette tipping paper ink and preparation method thereof - Google Patents
A kind of abrasion resistant fire blocking type cigarette tipping paper ink and preparation method thereof Download PDFInfo
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- CN109504170A CN109504170A CN201811528300.1A CN201811528300A CN109504170A CN 109504170 A CN109504170 A CN 109504170A CN 201811528300 A CN201811528300 A CN 201811528300A CN 109504170 A CN109504170 A CN 109504170A
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- iron oxide
- tipping paper
- abrasion resistant
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
- C09D11/033—Printing inks characterised by features other than the chemical nature of the binder characterised by the solvent
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/08—Printing inks based on natural resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses a kind of abrasion resistant fire blocking type cigarette tipping paper ink, by following components by weight percent at being grouped as: 100~200 parts of ink adhesive, 180~220 parts of ink adhesive auxiliary agent, 30~70 parts of wear-resisting type filler material, 40~80 parts of colorant, 20~60 parts of flame retardant and 200~400 parts of solvent.The invention has the advantages that printing quality is high, Fit Models are extensive, can arbitrarily adjust machine in viscosity, and thermophily is wide.
Description
Technical field
The invention belongs to ink manufacture field, in particular to a kind of abrasion resistant fire blocking type cigarette tipping paper ink and its preparation side
Method.
Background technique
Cigarette tipping paper is the important materials for producing cigarette, is to be printed using base paper for tipping paper as substrate by tipping paper printing ink
Brush processing, a kind of dedicated paper that filter tip and cigarette cigarette are got up.Tipping paper is wrapped around cigarette rear portion, contacts smoker
Oral cavity, the printing of tipping paper coating ink are applied to body paper for tobacco-use tipping paper surface, formed similar fireproof coating it is the same play screen
The wear-resistant protective layer for covering effect no longer burns when smoker is drawn onto the cigarette tipping paper position for being coated with wear-resisting and fire-retardant ink,
It can ensure smoker's safety (easily burn smoking property of cigarette person's hand and lip)；When smoker's lip is dry, cigarette tipping paper surface
There is wearability not glue brokenly the lip of smoker；After stub is arbitrarily abandoned after smoking property of cigarette person sucks, to be coated with it is wear-resisting and
Fire-retardant ink cigarette position meeting self-extinguish, can reduce fire, be avoided that and cause cigarette butt public fire and forest fire thing
Therefore.
The medium-to-high grade needs of cigarette and the needs of reducing tar and reducing harm, the ink technique water of tipping paper are improved to adapt to tobacco business
Flat continuous improvement, production development go out a variety of suitable cigarettes reduce coke damages, flavoring, wear-resisting, product.Since smoking consumer sucks
When lip contacted with tipping paper, oxious component can be entered in human body by oral cavity in tipping paper, wherein heavy metal arsenic, lead, nickel,
The health of the safety and sanitation such as cadmium, mercury, fluorescent material, total plate count index is directly or indirectly related to cigarette consumption person, to tipping
Paper ink proposes high request.
Generally speaking, hygienic, safe and environment-friendly to be the development trend of tobacco package, but it is attached to Cigarette multifunctionality
Be tipping paper, and determine that the key of tipping paper function and novelty is the post-processing procedure to base paper for tipping paper, i.e. tipping paper
Coating ink.
Cigarette tipping paper: using the tipping base paper in whole wood pulp as printing element, ink is equably printed and is coated on its table
Face, process is gold stamping, cutting, punches manufactured cigarette filter dedicated paper.
Traditional tipping paper printing ink: being by chromoplast (such as pigment, dyeing), link stuff, filler material, auxiliary agent material, through letter
Homogeneous mixture made of single preparation, stirring and grinding is referred to as tipping paper printing ink.Tipping paper printing ink is used in tipping paper original
Printing becomes cigarette tipping paper on paper, and traditional ink easy firing, it is poor to be printed on abrasion resistance on tipping paper, does not have anti-flammability
Energy and abrasion resistance.
In order to prevent to burn, in the prior art, fire proofing is by being arranged inside tipping paper, and cigarette is everywhere
Ingredient is different, the oral contact of tipping paper and smoker, and cigarette easily has with generating after flue gas mixes or high temperature ignites after lighting
Harmful chemical derivative, being unfavorable for smoking property of cigarette, person is healthy.Existing tipping paper printing ink does not have high-wearing feature, easy to stick broken
Cigarette consumption person's lip.
Summary of the invention
In view of the above-mentioned problems, the object of the present invention is to provide a kind of abrasion resistant fire blocking type cigarette tipping paper ink.
To achieve the above object, the technical scheme adopted by the invention is that:
A kind of abrasion resistant fire blocking type cigarette tipping paper ink, by following components by weight percent at being grouped as: ink adhesive 100~
200 parts, 180~220 parts of ink adhesive auxiliary agent, 30~70 parts of wear-resisting type filler material, 40~80 parts of colorant, flame retardant 20~
60 parts and 200~400 parts of solvent.
The present invention has strict demand to the selection of high molecular material in ink adhesive.By to polyvinyl butyral tree
The various types of resins such as rouge, polyacrylamide resin, alkyd resin, polyurethane, polyketone carry out comprehensive test and use, obtain
Film forming, fire resistance data and the sequence of various types of resins.By the assay optimization for comparing and acting synergistically, polyethylene contracting is selected
Butyral resin, polyacrylamide resin improve wear resistence, fire resistance as macromolecule binder in ink.
Selection of the present invention to ink fire retardant: to borax, antimony oxide-chlorinated paraffin system, high molecular material schiff bases
(hydroxy benzaldehyde, diaminonaphthalene condensation product), magnesium hydroxide, mineral wool, alumina silicate fibre, vermiculite, diatomite progress are comprehensive
Test and use, have obtained fire resistance, the mobility, the data and sequence of upper machine adaptability of each analog assistant.By comparison and
The test of synergistic effect determines to select borax, antimony oxide-chlorinated paraffin system, high molecular material new material schiff bases (hydroxyl
Benzaldehyde, diaminonaphthalene condensation product), magnesium hydroxide is as ink fire retardant.
The present invention selects ink filling material raw material: sufficiently to titanium dioxide, medical talc powder, iron oxide red, iron oxide black,
The various types of filler such as white carbon black, calcium bicarbonate, kaolin carry out comprehensive test and use, have obtained the wear-resistant of various types of filler
Property, fire resistance data and sequence, discussed by comparison, done the test of the synergistic effect of various types of filler, by optimization, finally
Titanium dioxide, medical talc powder are selected, iron oxide red, iron oxide black, white carbon black are as filler.
Preferably, the ink adhesive is selected from polyvinyl butyral resin, polyacrylamide resin or modified rosin
One of or their arbitrary proportion mixture；
The ink adhesive auxiliary agent is selected from one of auxiliary agent ethyl alcohol or dibutyl ester or their arbitrary proportion mixing
Object；
The wear-resisting type filler material is selected from one of titanium dioxide, medical talc powder or white carbon black or their any ratio
Example mixture；
The colorant is selected from one of iron oxide red, iron oxide black or iron oxide yellow or their arbitrary proportion mixing
Object；
The flame retardant is in borax, antimony oxide-chlorinated paraffin system, high molecular material schiff bases or magnesium hydroxide
One kind or their arbitrary proportion mixture；
The solvent is selected from one of dissolution ethyl alcohol or water or their arbitrary proportion mixture.
Preferably, the abrasion resistant fire blocking type cigarette tipping paper ink is prepared from the following raw materials in parts by weight: polyethylene
80~120 parts of butyral resin, 30~70 parts of polyacrylamide resin, 8~12 parts of modified rosin, auxiliary agent ethyl alcohol 180~220
Part, 3~7 parts of dibutyl ester, 18~22 parts of titanium dioxide, 18~22 parts of medical talc powder, 8~12 parts of white carbon black, iron oxide red 8~12
Part, 22~28 parts of iron oxide black, 28~32 parts of iron oxide yellow, 1~3 part of borax, antimony oxide -12~18 parts of chlorinated paraffin system,
20~30 parts of high molecular material schiff bases, 3~7 parts of magnesium hydroxide, dissolution 280~320 parts of ethyl alcohol and 18~22 parts of water.
Preferably, the abrasion resistant fire blocking type cigarette tipping paper ink is prepared from the following raw materials in parts by weight: polyethylene
100 parts of butyral resin, 50 parts of polyacrylamide resin, 10 parts of modified rosin, 200 parts of ethyl alcohol of auxiliary agent, 5 parts of dibutyl ester, titanium
20 parts of white powder, 20 parts of medical talc powder, 10 parts of white carbon black, 10 parts of iron oxide red, 25 parts of iron oxide black, 30 parts of iron oxide yellow, boron
2 parts of sand, antimony oxide -15 parts of chlorinated paraffin system, 20 parts of high molecular material schiff bases, 5 parts of magnesium hydroxide, dissolution ethyl alcohol 300
Part and 20 parts of water.
Preferably, the abrasion resistant fire blocking type cigarette tipping paper ink is prepared from the following raw materials in parts by weight: polyethylene
140~160 parts of butyral resin, 13~17 parts of modified rosin, 3~7 parts of dibutyl ester, 35~45 parts of medical talc powder, white carbon black 8
~12 parts, 8~12 parts of iron oxide red, 22~28 parts of iron oxide black, 28~32 parts of iron oxide yellow, 1~3 part of borax, macromolecule material
Expect 25~35 parts of schiff bases, 8~12 parts of magnesium hydroxide, dissolution 280~330 parts of ethyl alcohol and 8~12 parts of water.
Preferably, the abrasion resistant fire blocking type cigarette tipping paper ink is prepared from the following raw materials in parts by weight: polyethylene
150 parts of butyral resin, 15 parts of modified rosin, 5 parts of dibutyl ester, 40 parts of medical talc powder, 10 parts of white carbon black, iron oxide red 10
Part, 25 parts of iron oxide black, 30 parts of iron oxide yellow, 2 parts of borax, 30 parts of high molecular material schiff bases, 10 parts of magnesium hydroxide, dissolution are used
310 parts and 10 parts of water of ethyl alcohol.
Preferably, the abrasion resistant fire blocking type cigarette tipping paper ink is prepared from the following raw materials in parts by weight: polypropylene
80~120 parts of amide resin, 18~22 parts of modified rosin, 180~220 parts of ethyl alcohol of auxiliary agent, 3~7 parts of dibutyl ester, titanium dioxide 18
~22 parts, 28~32 parts of medical talc powder, 8~12 parts of iron oxide red, 22~28 parts of iron oxide black, 28~32 parts of iron oxide yellow,
Second is used in antimony oxide -15~20 parts of chlorinated paraffin system, 18~22 parts of high molecular material schiff bases, 3~7 parts of magnesium hydroxide, dissolution
280~320 parts and 18~22 parts of water of alcohol.
Preferably, the abrasion resistant fire blocking type cigarette tipping paper ink is prepared from the following raw materials in parts by weight: polypropylene
100 parts of amide resin, 20 parts of modified rosin, 200 parts of ethyl alcohol of auxiliary agent, 5 parts of dibutyl ester, 20 parts of titanium dioxide, medical talc powder 30
Part, 10 parts of iron oxide red, 25 parts of iron oxide black, 30 parts of iron oxide yellow, antimony oxide -17 parts of chlorinated paraffin system, high molecular material
20 parts of schiff bases, 5 parts of magnesium hydroxide, dissolution 300 parts of ethyl alcohol and 20 parts of water.
The present invention also provides a kind of methods for preparing the abrasion resistant fire blocking type cigarette tipping paper ink, including following step
It is rapid:
(1) raw material is weighed according to the proportion；
(2) preparation of binder；Ink adhesive and ink adhesive auxiliary agent are put into closed reaction kettle, are heated up to
It 80 DEG C~90 DEG C, stirs 4~8 hours, then is cooled to room temperature；
(3) it mixes；Wear-resisting type filler material, colorant, flame retardant and solvent are put into the reaction kettle, are heated up to 60 DEG C
~80 DEG C, stirring is cooled to room temperature after 2~5 hours；
(4) it grinds；
(5) it filters；
(6) it packs.
In the present invention, ink adhesive, ink adhesive auxiliary agent, wear-resisting type filler material, colorant, flame retardant and solvent are
Commercial product, buying is in the producer with legal qualification.
The invention has the following advantages:
The present invention uses ink adhesive, ink adhesive auxiliary agent, wear-resisting type filler material, colorant, flame retardant and solvent
Scientific matching, each component interaction, obtained ink can greatly improve printing quality.Its printing effect are as follows: 1, printing machine
100-250 ms/min, Fit Models are extensive；2, this ink is diluted using 95% ethyl alcohol, water 1:0.5 by weight ratio, can be any
Adjust machine in viscosity；3, printing dry heat temperature is 50 DEG C -85 DEG C, and thermophily is wide.
Specific embodiment
Specific embodiments of the present invention will be further explained below.It should be noted that for these implementations
The explanation of mode is used to help understand the present invention, but and does not constitute a limitation of the invention.In addition, invention described below
Technical characteristic involved in each embodiment can be combined with each other as long as they do not conflict with each other.
Embodiment 1
A method of preparing abrasion resistant fire blocking type cigarette tipping paper ink, comprising the following steps:
(1) raw material is weighed according to the proportion；120 parts of polyvinyl butyral resin, 70 parts of polyacrylamide resin, modified rosin
12 parts, 220 parts of ethyl alcohol of auxiliary agent, 7 parts of dibutyl ester, 22 parts of titanium dioxide, 22 parts of medical talc powder, 12 parts of white carbon black, iron oxide red
12 parts, 28 parts of iron oxide black, 32 parts of iron oxide yellow, 3 parts of borax, antimony oxide -18 parts of chlorinated paraffin system, high molecular material Schiff
30 parts of alkali, 7 parts of magnesium hydroxide, dissolution 320 parts of ethyl alcohol and 22 parts of water.
(2) preparation of binder；Ink adhesive and ink adhesive auxiliary agent are put into closed reaction kettle, are heated up to
It 90 DEG C, stirs 8 hours, then is cooled to room temperature；
(3) it mixes；Wear-resisting type filler material, colorant, flame retardant and solvent are put into the reaction kettle, are heated up to 80
DEG C, stirring is cooled to room temperature after 5 hours；
(4) it grinds；It is carried out circular grinding 3 times in horizontal mill.
(5) it filters；It is filtered with the sieve device of 300 mesh.
(6) it packs.
Embodiment 2
A method of preparing abrasion resistant fire blocking type cigarette tipping paper ink, comprising the following steps:
(1) raw material is weighed according to the proportion；80 parts of polyvinyl butyral resin, 30 parts of polyacrylamide resin, modified rosin 8
Part, 180 parts of ethyl alcohol of auxiliary agent, 3 parts of dibutyl ester, 18 parts of titanium dioxide, 18 parts of medical talc powder, 8 parts of white carbon black, 8 parts of iron oxide red,
22 parts of iron oxide black, 28 parts of iron oxide yellow, 1 part of borax, antimony oxide -12 parts of chlorinated paraffin system, high molecular material schiff bases 20
Part, 3 parts of magnesium hydroxide, dissolution 280 parts of ethyl alcohol and 18 parts of water.
(2) preparation of binder；Ink adhesive and ink adhesive auxiliary agent are put into closed reaction kettle, are heated up to
It 80 DEG C, stirs 4 hours, then is cooled to room temperature；
(3) it mixes；Wear-resisting type filler material, colorant, flame retardant and solvent are put into the reaction kettle, are heated up to 60
DEG C, stirring is cooled to room temperature after 2 hours；
(4) it grinds；It is carried out circular grinding 3 times in horizontal mill.
(5) it filters；It is filtered with the sieve device of 300 mesh.
(6) it packs.
Embodiment 3
A method of preparing abrasion resistant fire blocking type cigarette tipping paper ink, comprising the following steps:
(1) raw material is weighed according to the proportion；100 parts of polyvinyl butyral resin, 50 parts of polyacrylamide resin, modified rosin
10 parts, 200 parts of ethyl alcohol of auxiliary agent, 5 parts of dibutyl ester, 20 parts of titanium dioxide, 20 parts of medical talc powder, 10 parts of white carbon black, iron oxide red
10 parts, 25 parts of iron oxide black, 30 parts of iron oxide yellow, 2 parts of borax, antimony oxide -15 parts of chlorinated paraffin system, high molecular material Schiff
20 parts of alkali, 5 parts of magnesium hydroxide, dissolution 300 parts of ethyl alcohol and 20 parts of water.
(2) preparation of binder；Ink adhesive and ink adhesive auxiliary agent are put into closed reaction kettle, are heated up to
It 85 DEG C, stirs 6 hours, then is cooled to room temperature；
(3) it mixes；Wear-resisting type filler material, colorant, flame retardant and solvent are put into the reaction kettle, are heated up to 70
DEG C, stirring is cooled to room temperature after 3 hours；
(4) it grinds；It is carried out circular grinding 3 times in horizontal mill.
(5) it filters；It is filtered with the sieve device of 300 mesh.
(6) it packs.
Embodiment 4
A method of preparing abrasion resistant fire blocking type cigarette tipping paper ink, comprising the following steps:
(1) raw material is weighed according to the proportion；It is 160 parts of polyvinyl butyral resin, 17 parts of modified rosin, 7 parts of dibutyl ester, medical
45 parts of talcum powder, 12 parts of white carbon black, 12 parts of iron oxide red, 28 parts of iron oxide black, 32 parts of iron oxide yellow, 3 parts of borax, macromolecule material
Expect 35 parts of schiff bases, 12 parts of magnesium hydroxide, dissolution 330 parts of ethyl alcohol and 12 parts of water.
(2) preparation of binder；Ink adhesive and ink adhesive auxiliary agent are put into closed reaction kettle, are heated up to
It 90 DEG C, stirs 8 hours, then is cooled to room temperature；
(3) it mixes；Wear-resisting type filler material, colorant, flame retardant and solvent are put into the reaction kettle, are heated up to 60
DEG C, stirring is cooled to room temperature after 5 hours；
(4) it grinds；It is carried out circular grinding 3 times in horizontal mill.
(5) it filters；It is filtered with the sieve device of 300 mesh.
(6) it packs.
Embodiment 5
A method of preparing abrasion resistant fire blocking type cigarette tipping paper ink, comprising the following steps:
(1) raw material is weighed according to the proportion；It is 140 parts of polyvinyl butyral resin, 13 parts of modified rosin, 3 parts of dibutyl ester, medical
35 parts of talcum powder, 8 parts of white carbon black, 8 parts of iron oxide red, 22 parts of iron oxide black, 28 parts of iron oxide yellow, 1 part of borax, high molecular material
25 parts of schiff bases, 8 parts of magnesium hydroxide, dissolution 280 parts of ethyl alcohol and 8 parts of water.
(2) preparation of binder；Ink adhesive and ink adhesive auxiliary agent are put into closed reaction kettle, are heated up to
It 80 DEG C, stirs 4 hours, then is cooled to room temperature；
(3) it mixes；Wear-resisting type filler material, colorant, flame retardant and solvent are put into the reaction kettle, are heated up to 60
DEG C, stirring is cooled to room temperature after 5 hours；
(4) it grinds；It is carried out circular grinding 3 times in horizontal mill.
(5) it filters；It is filtered with the sieve device of 300 mesh.
(6) it packs.
Embodiment 6
A method of preparing abrasion resistant fire blocking type cigarette tipping paper ink, comprising the following steps:
(1) raw material is weighed according to the proportion；It is 150 parts of polyvinyl butyral resin, 15 parts of modified rosin, 5 parts of dibutyl ester, medical
40 parts of talcum powder, 10 parts of white carbon black, 10 parts of iron oxide red, 25 parts of iron oxide black, 30 parts of iron oxide yellow, 2 parts of borax, macromolecule material
Expect 30 parts of schiff bases, 10 parts of magnesium hydroxide, dissolution 310 parts of ethyl alcohol and 10 parts of water.
(2) preparation of binder；Ink adhesive and ink adhesive auxiliary agent are put into closed reaction kettle, are heated up to
It 85 DEG C, stirs 7 hours, then is cooled to room temperature；
(3) it mixes；Wear-resisting type filler material, colorant, flame retardant and solvent are put into the reaction kettle, are heated up to 65
DEG C, stirring is cooled to room temperature after 4 hours；
(4) it grinds；It is carried out circular grinding 3 times in horizontal mill.
(5) it filters；It is filtered with the sieve device of 300 mesh.
(6) it packs.
Embodiment 7
A method of preparing abrasion resistant fire blocking type cigarette tipping paper ink, comprising the following steps:
(1) raw material is weighed according to the proportion；120 parts of polyacrylamide resin, 22 parts of modified rosin, 220 parts of ethyl alcohol of auxiliary agent,
7 parts of dibutyl ester, 22 parts of titanium dioxide, 32 parts of medical talc powder, 12 parts of iron oxide red, 28 parts of iron oxide black, 32 parts of iron oxide yellow, oxygen
Change antimony -20 parts of chlorinated paraffin system, 22 parts of high molecular material schiff bases, 7 parts of magnesium hydroxide, dissolution 320 parts of ethyl alcohol and water 22
Part.
(2) preparation of binder；Ink adhesive and ink adhesive auxiliary agent are put into closed reaction kettle, are heated up to
It 90 DEG C, stirs 5 hours, then is cooled to room temperature；
(3) it mixes；Wear-resisting type filler material, colorant, flame retardant and solvent are put into the reaction kettle, are heated up to 80
DEG C, stirring is cooled to room temperature after 4 hours；
(4) it grinds；It is carried out circular grinding 3 times in horizontal mill.
(5) it filters；It is filtered with the sieve device of 300 mesh.
(6) it packs.
Embodiment 8
A method of preparing abrasion resistant fire blocking type cigarette tipping paper ink, comprising the following steps:
(1) raw material is weighed according to the proportion；80 parts of polyacrylamide resin, 18 parts of modified rosin, 180 parts of ethyl alcohol of auxiliary agent,
3 parts of dibutyl ester, 18 parts of titanium dioxide, 28 parts of medical talc powder, 8 parts of iron oxide red, 22 parts of iron oxide black, 28 parts of iron oxide yellow, oxygen
Change antimony -15 parts of chlorinated paraffin system, 18 parts of high molecular material schiff bases, 3 parts of magnesium hydroxide, dissolution 280 parts of ethyl alcohol and water 18
Part.
(2) preparation of binder；Ink adhesive and ink adhesive auxiliary agent are put into closed reaction kettle, are heated up to
It 80 DEG C, stirs 7 hours, then is cooled to room temperature；
(3) it mixes；Wear-resisting type filler material, colorant, flame retardant and solvent are put into the reaction kettle, are heated up to 70
DEG C, stirring is cooled to room temperature after 3 hours；
(4) it grinds；It is carried out circular grinding 3 times in horizontal mill.
(5) it filters；It is filtered with the sieve device of 300 mesh.
(6) it packs.
Embodiment 9
A method of preparing abrasion resistant fire blocking type cigarette tipping paper ink, comprising the following steps:
(1) raw material is weighed according to the proportion；100 parts of polyacrylamide resin, 20 parts of modified rosin, 200 parts of ethyl alcohol of auxiliary agent,
5 parts of dibutyl ester, 20 parts of titanium dioxide, 30 parts of medical talc powder, 10 parts of iron oxide red, 25 parts of iron oxide black, 30 parts of iron oxide yellow, oxygen
Change antimony -17 parts of chlorinated paraffin system, 20 parts of high molecular material schiff bases, 5 parts of magnesium hydroxide, dissolution 300 parts of ethyl alcohol and water 20
Part.
(2) preparation of binder；Ink adhesive and ink adhesive auxiliary agent are put into closed reaction kettle, are heated up to
It 85 DEG C, stirs 5 hours, then is cooled to room temperature；
(3) it mixes；Wear-resisting type filler material, colorant, flame retardant and solvent are put into the reaction kettle, are heated up to 65
DEG C, stirring is cooled to room temperature after 3 hours；
(4) it grinds；It is carried out circular grinding 3 times in horizontal mill.
(5) it filters；It is filtered with the sieve device of 300 mesh.
(6) it packs.
In order to verify the technical effects of the present invention, spy makees following tests:
The resulting abrasion resistant fire blocking type cigarette tipping paper ink of the present invention, is improved during practice, is passed through
Scene printing and practical application, the printing quality of the ink are improved step by step.Its printing condition are as follows: 1, printing machine 100-250
M/min, Fit Models are extensive；2, this ink is diluted using 95% ethyl alcohol, water 1:0.5 by weight ratio, can arbitrarily be adjusted viscous
Machine on degree；3, printing dry heat temperature is 50 DEG C -85 DEG C, and thermophily is wide.
Further to verify technical effect of the invention, embodiment products obtained therefrom is subjected to following detection, the results are shown in Table 1.
The detection of 1 properties of product of table
| Performance | Data |
| Viscosity (second) | 23-28 |
| PH value | 8.5-9.0 |
| Fineness (mesh) | 50-70 |
| Color difference (E≤2.0 △) | △E≤1.2 |
| Solid content (%) | 13-17 |
| Heat resistance | ≥600℃ |
Above the embodiments of the present invention are described in detail, but the present invention is not limited to described embodiments.It is right
For those skilled in the art, in the case where not departing from the principle of the invention and spirit, these embodiments are carried out more
Kind change, modification, replacement and modification, still fall in protection scope of the present invention.
Claims (9)
1. a kind of abrasion resistant fire blocking type cigarette tipping paper ink, it is characterised in that: by following components by weight percent at being grouped as: ink connects
100~200 parts of splicing, 180~220 parts of ink adhesive auxiliary agent, 30~70 parts of wear-resisting type filler material, 40~80 parts of colorant, resistance
Fire 20~60 parts and 200~400 parts of solvent of auxiliary agent.
2. a kind of abrasion resistant fire blocking type cigarette tipping paper ink according to claim 1, it is characterised in that:
The ink adhesive be selected from one of polyvinyl butyral resin, polyacrylamide resin or modified rosin or it
Arbitrary proportion mixture；
The ink adhesive auxiliary agent is selected from one of auxiliary agent ethyl alcohol or dibutyl ester or their arbitrary proportion mixture；
The wear-resisting type filler material is selected from one of titanium dioxide, medical talc powder or white carbon black or their arbitrary proportion is mixed
Close object；
The colorant is selected from one of iron oxide red, iron oxide black or iron oxide yellow or their arbitrary proportion mixture；
The flame retardant in borax, antimony oxide-chlorinated paraffin system, high molecular material schiff bases or magnesium hydroxide one
Kind or their arbitrary proportion mixture；
The solvent is selected from one of dissolution ethyl alcohol or water or their arbitrary proportion mixture.
3. a kind of abrasion resistant fire blocking type cigarette tipping paper ink according to claim 2, it is characterised in that: the abrasion resistant fire blocking
Type cigarette tipping paper ink is prepared from the following raw materials in parts by weight: 80~120 parts of polyvinyl butyral resin, polyacrylamide
30~70 parts of resin, 8~12 parts of modified rosin, 180~220 parts of ethyl alcohol of auxiliary agent, 3~7 parts of dibutyl ester, titanium dioxide 18~22
Part, 18~22 parts of medical talc powder, 8~12 parts of white carbon black, 8~12 parts of iron oxide red, 22~28 parts of iron oxide black, iron oxide yellow
28~32 parts, 1~3 part of borax, antimony oxide -12~18 parts of chlorinated paraffin system, 20~30 parts of high molecular material schiff bases, hydrogen-oxygen
Change 3~7 parts of magnesium, dissolution 280~320 parts of ethyl alcohol and 18~22 parts of water.
4. a kind of abrasion resistant fire blocking type cigarette tipping paper ink according to claim 3, it is characterised in that: the abrasion resistant fire blocking
Type cigarette tipping paper ink is prepared from the following raw materials in parts by weight: 100 parts of polyvinyl butyral resin, polyacrylamide resin
50 parts, 10 parts of modified rosin, 200 parts of ethyl alcohol of auxiliary agent, 5 parts of dibutyl ester, 20 parts of titanium dioxide, 20 parts of medical talc powder, white carbon black
10 parts, 10 parts of iron oxide red, 25 parts of iron oxide black, 30 parts of iron oxide yellow, 2 parts of borax, antimony oxide -15 parts of chlorinated paraffin system,
20 parts of high molecular material schiff bases, 5 parts of magnesium hydroxide, dissolution 300 parts of ethyl alcohol and 20 parts of water.
5. a kind of abrasion resistant fire blocking type cigarette tipping paper ink according to claim 2, it is characterised in that: the abrasion resistant fire blocking
Type cigarette tipping paper ink is prepared from the following raw materials in parts by weight: 140~160 parts of polyvinyl butyral resin, modified rosin
13~17 parts, 3~7 parts of dibutyl ester, 35~45 parts of medical talc powder, 8~12 parts of white carbon black, 8~12 parts of iron oxide red, iron oxide
Black 22~28 parts, 28~32 parts of iron oxide yellow, 1~3 part of borax, 25~35 parts of high molecular material schiff bases, magnesium hydroxide 8~12
Part, dissolution 280~330 parts of ethyl alcohol and 8~12 parts of water.
6. a kind of abrasion resistant fire blocking type cigarette tipping paper ink according to claim 5, it is characterised in that: the abrasion resistant fire blocking
Type cigarette tipping paper ink is prepared from the following raw materials in parts by weight: 150 parts of polyvinyl butyral resin, 15 parts of modified rosin,
5 parts of dibutyl ester, 40 parts of medical talc powder, 10 parts of white carbon black, 10 parts of iron oxide red, 25 parts of iron oxide black, 30 parts of iron oxide yellow, boron
2 parts of sand, 30 parts of high molecular material schiff bases, 10 parts of magnesium hydroxide, dissolution 310 parts of ethyl alcohol and 10 parts of water.
7. a kind of abrasion resistant fire blocking type cigarette tipping paper ink according to claim 2, it is characterised in that: the abrasion resistant fire blocking
Type cigarette tipping paper ink is prepared from the following raw materials in parts by weight: 80~120 parts of polyacrylamide resin, modified rosin 18~
22 parts, 180~220 parts of ethyl alcohol of auxiliary agent, 3~7 parts of dibutyl ester, 18~22 parts of titanium dioxide, 28~32 parts of medical talc powder, oxidation
8~12 parts of iron oxide red, 22~28 parts of iron oxide black, 28~32 parts of iron oxide yellow, antimony oxide -15~20 parts of chlorinated paraffin system, height
18~22 parts of molecular material schiff bases, 3~7 parts of magnesium hydroxide, dissolution 280~320 parts of ethyl alcohol and 18~22 parts of water.
8. a kind of abrasion resistant fire blocking type cigarette tipping paper ink according to claim 7, it is characterised in that: the abrasion resistant fire blocking
Type cigarette tipping paper ink is prepared from the following raw materials in parts by weight: 100 parts of polyacrylamide resin, helps 20 parts of modified rosin
200 parts of ethyl alcohol of agent, 5 parts of dibutyl ester, 20 parts of titanium dioxide, 30 parts of medical talc powder, 10 parts of iron oxide red, 25 parts of iron oxide black,
30 parts of iron oxide yellow, antimony oxide -17 parts of chlorinated paraffin system, 20 parts of high molecular material schiff bases, 5 parts of magnesium hydroxide, dissolution are used
300 parts and 20 parts of water of ethyl alcohol.
9. a kind of method for preparing abrasion resistant fire blocking type cigarette tipping paper ink as claimed in claim 1 or 2, which is characterized in that including
Following steps:
(1) raw material is weighed according to the proportion；
(2) preparation of binder；Ink adhesive and ink adhesive auxiliary agent are put into closed reaction kettle, are heated up to 80 DEG C
It~90 DEG C, stirs 4~8 hours, then is cooled to room temperature；
(3) it mixes；Wear-resisting type filler material, colorant, flame retardant and solvent are put into the reaction kettle, are heated up to 60 DEG C~80
DEG C, stirring is cooled to room temperature after 2~5 hours；
(4) it grinds；
(5) it filters；
(6) it packs.
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| CN201811528300.1A CN109504170A (en) | 2018-12-13 | 2018-12-13 | A kind of abrasion resistant fire blocking type cigarette tipping paper ink and preparation method thereof |
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