CN101422416A - Use of residual liquid in producing daily chemical product after extracting d-borneol from borneol camphor - Google Patents
Use of residual liquid in producing daily chemical product after extracting d-borneol from borneol camphor Download PDFInfo
- Publication number
- CN101422416A CN101422416A CNA2008101439171A CN200810143917A CN101422416A CN 101422416 A CN101422416 A CN 101422416A CN A2008101439171 A CNA2008101439171 A CN A2008101439171A CN 200810143917 A CN200810143917 A CN 200810143917A CN 101422416 A CN101422416 A CN 101422416A
- Authority
- CN
- China
- Prior art keywords
- borneolum syntheticum
- borneol
- camphor tree
- camphora
- chemical products
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- DTGKSKDOIYIVQL-WEDXCCLWSA-N (+)-borneol Chemical compound C1C[C@@]2(C)[C@@H](O)C[C@@H]1C2(C)C DTGKSKDOIYIVQL-WEDXCCLWSA-N 0.000 title claims abstract description 112
- 239000007788 liquid Substances 0.000 title claims abstract description 47
- 239000000126 substance Substances 0.000 title claims abstract description 30
- 241000723346 Cinnamomum camphora Species 0.000 title claims description 66
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 title abstract description 9
- REPVLJRCJUVQFA-UHFFFAOYSA-N (-)-isopinocampheol Natural products C1C(O)C(C)C2C(C)(C)C1C2 REPVLJRCJUVQFA-UHFFFAOYSA-N 0.000 title abstract 9
- CKDOCTFBFTVPSN-UHFFFAOYSA-N borneol Natural products C1CC2(C)C(C)CC1C2(C)C CKDOCTFBFTVPSN-UHFFFAOYSA-N 0.000 title abstract 9
- 229940116229 borneol Drugs 0.000 title abstract 9
- DTGKSKDOIYIVQL-UHFFFAOYSA-N dl-isoborneol Natural products C1CC2(C)C(O)CC1C2(C)C DTGKSKDOIYIVQL-UHFFFAOYSA-N 0.000 title abstract 9
- DTGKSKDOIYIVQL-NQMVMOMDSA-N (+)-Borneol Natural products C1C[C@]2(C)[C@H](O)C[C@@H]1C2(C)C DTGKSKDOIYIVQL-NQMVMOMDSA-N 0.000 title abstract 4
- 229930008380 camphor Natural products 0.000 title 1
- 229960000846 camphor Drugs 0.000 title 1
- 239000000344 soap Substances 0.000 claims abstract description 11
- 239000013078 crystal Substances 0.000 claims abstract description 8
- 239000000077 insect repellent Substances 0.000 claims abstract description 5
- 239000002453 shampoo Substances 0.000 claims abstract description 5
- 239000000606 toothpaste Substances 0.000 claims abstract description 5
- 229940034610 toothpaste Drugs 0.000 claims abstract description 5
- 238000009833 condensation Methods 0.000 claims description 28
- 230000005494 condensation Effects 0.000 claims description 28
- 239000000284 extract Substances 0.000 claims description 15
- 238000001256 steam distillation Methods 0.000 claims description 11
- 239000003599 detergent Substances 0.000 claims description 9
- 239000006071 cream Substances 0.000 claims description 5
- 239000003974 emollient agent Substances 0.000 claims description 4
- 239000002304 perfume Substances 0.000 claims description 4
- 235000013399 edible fruits Nutrition 0.000 claims description 3
- 239000012530 fluid Substances 0.000 claims description 2
- 239000000499 gel Substances 0.000 claims description 2
- 210000000056 organ Anatomy 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 32
- 230000000694 effects Effects 0.000 abstract description 15
- -1 borneol camphora series Chemical class 0.000 abstract description 12
- 229940025250 camphora Drugs 0.000 abstract description 8
- 239000010238 camphora Substances 0.000 abstract description 8
- 239000002699 waste material Substances 0.000 abstract description 5
- 238000005406 washing Methods 0.000 abstract description 4
- 239000000843 powder Substances 0.000 abstract description 3
- 239000004909 Moisturizer Substances 0.000 abstract 1
- 230000001333 moisturizer Effects 0.000 abstract 1
- 239000002324 mouth wash Substances 0.000 abstract 1
- 229940051866 mouthwash Drugs 0.000 abstract 1
- 239000000047 product Substances 0.000 description 34
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 19
- 238000004821 distillation Methods 0.000 description 18
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 13
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 12
- 238000002156 mixing Methods 0.000 description 12
- 239000000470 constituent Substances 0.000 description 11
- 238000002360 preparation method Methods 0.000 description 11
- 239000004094 surface-active agent Substances 0.000 description 11
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 9
- 239000012153 distilled water Substances 0.000 description 9
- 239000000203 mixture Substances 0.000 description 9
- 102000004190 Enzymes Human genes 0.000 description 8
- 108090000790 Enzymes Proteins 0.000 description 8
- LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical compound COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 description 8
- 230000000844 anti-bacterial effect Effects 0.000 description 7
- 235000011187 glycerol Nutrition 0.000 description 7
- GVJHHUAWPYXKBD-UHFFFAOYSA-N (±)-α-Tocopherol Chemical compound OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 6
- 238000000605 extraction Methods 0.000 description 6
- 239000011734 sodium Substances 0.000 description 6
- 244000179970 Monarda didyma Species 0.000 description 5
- 235000010672 Monarda didyma Nutrition 0.000 description 5
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 5
- 239000007789 gas Substances 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 239000003921 oil Substances 0.000 description 5
- 235000019198 oils Nutrition 0.000 description 5
- 208000003251 Pruritus Diseases 0.000 description 4
- 230000003385 bacteriostatic effect Effects 0.000 description 4
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 4
- 235000019864 coconut oil Nutrition 0.000 description 4
- 239000003240 coconut oil Substances 0.000 description 4
- 238000001816 cooling Methods 0.000 description 4
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 4
- 238000012856 packing Methods 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- 230000001954 sterilising effect Effects 0.000 description 4
- 239000000080 wetting agent Substances 0.000 description 4
- XKZQKPRCPNGNFR-UHFFFAOYSA-N 2-(3-hydroxyphenyl)phenol Chemical compound OC1=CC=CC(C=2C(=CC=CC=2)O)=C1 XKZQKPRCPNGNFR-UHFFFAOYSA-N 0.000 description 3
- SNPLKNRPJHDVJA-ZETCQYMHSA-N D-panthenol Chemical compound OCC(C)(C)[C@@H](O)C(=O)NCCCO SNPLKNRPJHDVJA-ZETCQYMHSA-N 0.000 description 3
- 239000011703 D-panthenol Substances 0.000 description 3
- 235000004866 D-panthenol Nutrition 0.000 description 3
- 208000001840 Dandruff Diseases 0.000 description 3
- 229930003427 Vitamin E Natural products 0.000 description 3
- 238000002835 absorbance Methods 0.000 description 3
- 210000001367 artery Anatomy 0.000 description 3
- 229960003949 dexpanthenol Drugs 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 230000001408 fungistatic effect Effects 0.000 description 3
- WIGCFUFOHFEKBI-UHFFFAOYSA-N gamma-tocopherol Natural products CC(C)CCCC(C)CCCC(C)CCCC1CCC2C(C)C(O)C(C)C(C)C2O1 WIGCFUFOHFEKBI-UHFFFAOYSA-N 0.000 description 3
- 229940051841 polyoxyethylene ether Drugs 0.000 description 3
- 229920000056 polyoxyethylene ether Polymers 0.000 description 3
- 239000008213 purified water Substances 0.000 description 3
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 3
- 235000010234 sodium benzoate Nutrition 0.000 description 3
- 239000004299 sodium benzoate Substances 0.000 description 3
- 239000011780 sodium chloride Substances 0.000 description 3
- JHJUUEHSAZXEEO-UHFFFAOYSA-M sodium;4-dodecylbenzenesulfonate Chemical compound [Na+].CCCCCCCCCCCCC1=CC=C(S([O-])(=O)=O)C=C1 JHJUUEHSAZXEEO-UHFFFAOYSA-M 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 210000003462 vein Anatomy 0.000 description 3
- 235000019165 vitamin E Nutrition 0.000 description 3
- 229940046009 vitamin E Drugs 0.000 description 3
- 239000011709 vitamin E Substances 0.000 description 3
- NOOLISFMXDJSKH-UTLUCORTSA-N (+)-Neomenthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@@H]1O NOOLISFMXDJSKH-UTLUCORTSA-N 0.000 description 2
- OPFTUNCRGUEPRZ-QLFBSQMISA-N (-)-beta-elemene Chemical compound CC(=C)[C@@H]1CC[C@@](C)(C=C)[C@H](C(C)=C)C1 OPFTUNCRGUEPRZ-QLFBSQMISA-N 0.000 description 2
- FTLYMKDSHNWQKD-UHFFFAOYSA-N (2,4,5-trichlorophenyl)boronic acid Chemical compound OB(O)C1=CC(Cl)=C(Cl)C=C1Cl FTLYMKDSHNWQKD-UHFFFAOYSA-N 0.000 description 2
- QMMJWQMCMRUYTG-UHFFFAOYSA-N 1,2,4,5-tetrachloro-3-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=C(Cl)C(Cl)=CC(Cl)=C1Cl QMMJWQMCMRUYTG-UHFFFAOYSA-N 0.000 description 2
- OWEGWHBOCFMBLP-UHFFFAOYSA-N 1-(4-chlorophenoxy)-1-(1H-imidazol-1-yl)-3,3-dimethylbutan-2-one Chemical compound C1=CN=CN1C(C(=O)C(C)(C)C)OC1=CC=C(Cl)C=C1 OWEGWHBOCFMBLP-UHFFFAOYSA-N 0.000 description 2
- FPIPGXGPPPQFEQ-UHFFFAOYSA-N 13-cis retinol Natural products OCC=C(C)C=CC=C(C)C=CC1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-UHFFFAOYSA-N 0.000 description 2
- RZRILSWMGXWSJY-UHFFFAOYSA-N 2-[bis(2-hydroxyethyl)amino]ethanol;sulfuric acid Chemical compound OS(O)(=O)=O.OCCN(CCO)CCO RZRILSWMGXWSJY-UHFFFAOYSA-N 0.000 description 2
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- 239000005711 Benzoic acid Substances 0.000 description 2
- NOOLISFMXDJSKH-UHFFFAOYSA-N DL-menthol Natural products CC(C)C1CCC(C)CC1O NOOLISFMXDJSKH-UHFFFAOYSA-N 0.000 description 2
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical class [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 2
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 2
- 241000208152 Geranium Species 0.000 description 2
- HSRJKNPTNIJEKV-UHFFFAOYSA-N Guaifenesin Chemical compound COC1=CC=CC=C1OCC(O)CO HSRJKNPTNIJEKV-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- HPEUJPJOZXNMSJ-UHFFFAOYSA-N Methyl stearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC HPEUJPJOZXNMSJ-UHFFFAOYSA-N 0.000 description 2
- CWNSVVHTTQBGQB-UHFFFAOYSA-N N,N-Diethyldodecanamide Chemical compound CCCCCCCCCCCC(=O)N(CC)CC CWNSVVHTTQBGQB-UHFFFAOYSA-N 0.000 description 2
- OTGQIQQTPXJQRG-UHFFFAOYSA-N N-(octadecanoyl)ethanolamine Chemical compound CCCCCCCCCCCCCCCCCC(=O)NCCO OTGQIQQTPXJQRG-UHFFFAOYSA-N 0.000 description 2
- 229910000503 Na-aluminosilicate Inorganic materials 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 2
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- FPIPGXGPPPQFEQ-OVSJKPMPSA-N all-trans-retinol Chemical compound OC\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-OVSJKPMPSA-N 0.000 description 2
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- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
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- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
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- PXRCIOIWVGAZEP-UHFFFAOYSA-N Primaeres Camphenhydrat Natural products C1CC2C(O)(C)C(C)(C)C1C2 PXRCIOIWVGAZEP-UHFFFAOYSA-N 0.000 description 1
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- 150000001408 amides Chemical class 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 230000003110 anti-inflammatory effect Effects 0.000 description 1
- 239000010692 aromatic oil Substances 0.000 description 1
- NPNUFJAVOOONJE-UHFFFAOYSA-N beta-cariophyllene Natural products C1CC(C)=CCCC(=C)C2CC(C)(C)C21 NPNUFJAVOOONJE-UHFFFAOYSA-N 0.000 description 1
- 229930006722 beta-pinene Natural products 0.000 description 1
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- 229930006974 beta-terpinene Natural products 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 229930006739 camphene Natural products 0.000 description 1
- ZYPYEBYNXWUCEA-UHFFFAOYSA-N camphenilone Natural products C1CC2C(=O)C(C)(C)C1C2 ZYPYEBYNXWUCEA-UHFFFAOYSA-N 0.000 description 1
- 229940095731 candida albicans Drugs 0.000 description 1
- 229940117948 caryophyllene Drugs 0.000 description 1
- NPNUFJAVOOONJE-UONOGXRCSA-N caryophyllene Natural products C1CC(C)=CCCC(=C)[C@@H]2CC(C)(C)[C@@H]21 NPNUFJAVOOONJE-UONOGXRCSA-N 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 230000001413 cellular effect Effects 0.000 description 1
- 229960005233 cineole Drugs 0.000 description 1
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- 239000003814 drug Substances 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 230000002255 enzymatic effect Effects 0.000 description 1
- CAMHHLOGFDZBBG-UHFFFAOYSA-N epoxidized methyl oleate Natural products CCCCCCCCC1OC1CCCCCCCC(=O)OC CAMHHLOGFDZBBG-UHFFFAOYSA-N 0.000 description 1
- 235000019197 fats Nutrition 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- HIGQPQRQIQDZMP-UHFFFAOYSA-N geranil acetate Natural products CC(C)=CCCC(C)=CCOC(C)=O HIGQPQRQIQDZMP-UHFFFAOYSA-N 0.000 description 1
- 210000004907 gland Anatomy 0.000 description 1
- 210000004209 hair Anatomy 0.000 description 1
- 239000007943 implant Substances 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- 235000018219 lavender Nutrition 0.000 description 1
- 229940087305 limonene Drugs 0.000 description 1
- 235000001510 limonene Nutrition 0.000 description 1
- 229930007744 linalool Natural products 0.000 description 1
- 239000013521 mastic Substances 0.000 description 1
- HIGQPQRQIQDZMP-FLIBITNWSA-N neryl acetate Chemical compound CC(C)=CCC\C(C)=C/COC(C)=O HIGQPQRQIQDZMP-FLIBITNWSA-N 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
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- 229920001223 polyethylene glycol Polymers 0.000 description 1
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- QJVXKWHHAMZTBY-GCPOEHJPSA-N syringin Chemical compound COC1=CC(\C=C\CO)=CC(OC)=C1O[C@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 QJVXKWHHAMZTBY-GCPOEHJPSA-N 0.000 description 1
- 229940126680 traditional chinese medicines Drugs 0.000 description 1
- XJPBRODHZKDRCB-UHFFFAOYSA-N trans-alpha-ocimene Natural products CC(=C)CCC=C(C)C=C XJPBRODHZKDRCB-UHFFFAOYSA-N 0.000 description 1
- NPNUFJAVOOONJE-ZIAGYGMSSA-N trans-caryophyllene Natural products C1CC(C)=CCCC(=C)[C@H]2CC(C)(C)[C@@H]21 NPNUFJAVOOONJE-ZIAGYGMSSA-N 0.000 description 1
- OUYCCCASQSFEME-UHFFFAOYSA-N tyrosine Natural products OC(=O)C(N)CC1=CC=C(O)C=C1 OUYCCCASQSFEME-UHFFFAOYSA-N 0.000 description 1
- 235000019154 vitamin C Nutrition 0.000 description 1
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- WTARULDDTDQWMU-UHFFFAOYSA-N β-pinene Chemical compound C1C2C(C)(C)C1CCC2=C WTARULDDTDQWMU-UHFFFAOYSA-N 0.000 description 1
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Abstract
The invention discloses an application of a residual liquid generated after d-Borneol from borneol camphora is extracted in a daily use chemical product. In the invention, the residual liquid generated after d-Borneol is extracted from borneol camphora, i.e., the rest liquid generated after the branches and leaves of the borneol camphora are distilled and condensed by vapor to separate out a crystal (the d-Borneol) is used for the daily use chemical products of borneol camphora series like borneol camphora nourishing moisturizer, shower bath, washing-powder, toothpaste, fancy soap, shampoo, washing liquid, mosquito-repellent toilet water, camphora liquid soap, astringent, mouthwash, and the like. The prepared daily use chemical products of borneol camphora series are the products which have the advantages of pure savageness, non-pollution, specific effect and remarkable function. The invention leads the borneol camphora resources to be fully used and developed, leads the liquid which used to be abandoned after the water of the borneol camphora is distilled and condensed to be fully used, changes waste into valuable and has huge economic benefits.
Description
Technical field
The present invention relates to the application in daily chemical products, especially from Borneolum Syntheticum Camphor tree plant, extract behind the dextro Borneolum Syntheticum residual solution in daily chemical products, use.
Background technology
Borneolum Syntheticum Camphor tree Cinnamomum camphora (L.) presl has another name called Lignum cinnamomi camphorae, aiphyllium, height of tree 30m, leaf keratin, alternate, ellipse or ovum shape ellipse, the anxious point of tip, the base portion wedge, full edge, leaf margin is wavy, top green or yellow green, glossy, below yellow green or celadon, dark and gloomy, normal attached stain, tool goes out arteries and veins from base three, in the arteries and veins axil body of gland is arranged, below the two sides do not have hair or back side when children by little pubescence, tool goes out arteries and veins from base three.4 ~ May of florescence, 8 ~ November of fructescence.Mainly be distributed in north latitude 10 degree-34 degree areass to the south, the Changjiang river, particularly Jiujiang, the western Hunan, Hunan. the Lignum cinnamomi camphorae in mountain area, the southeast, Guizhou is the most famous, quantity then with Taiwan for; Vertical distribution is generally at height above sea level below 600 meters, and the western Hunan and the southeast, Guizhou can reach 1000 meters, Taiwan middle part height above sea level mountain area well-grown below 1500 meters, and wildwood then can grow in height above sea level more than 1800 meters; Also there are distribution in Korea, Japan, North Vietnam, India, Malaysia.
The fruit of Borneolum Syntheticum Camphor tree, leaf, mainly contain Borneolum Syntheticum in bark and the trunk, Camphora, linalool, terpinolene, β-terpinene, ocimene, limonene, eucalyptol, to P-cymene, α-phellandrene, α-myrcene, nopinene, camphene, australene, α-thujene, β-terpineol, alpha-terpineol, neryl acetate, α-different safrene, borneol acetate, beta-elemene, cis Flos Caryophylli alkene, α-Flos Caryophylli alkene, gima ethylenic D, chemical constituents such as caryophyllene oxygen compound.Quintessence oil that from the Borneolum Syntheticum Camphor tree, extracts or aromatic oil, mainly contain Borneolum Syntheticum, it is separated can be used for preparing Herba Rosmarini Officinalis, type essence and medicine such as Garden lavender, some traditional Chinese medicines of China particularly. the Borneolum Syntheticum Camphor tree is as the main raw material(s) that extracts natural dextro Borneolum Syntheticum at present, its technology is mainly from Borneolum Syntheticum leaf of Lignum cinnamomi camphorae, branch and uses steam distillation, separates out the dextro Borneolum Syntheticum crystal by condensing tube condensation, and other remaining liqs etc. are used as waste liquid and are discarded.
The inventor has done a lot of researchs to Borneolum Syntheticum Camphor tree plant and chemical constituent, discovery has good bactericidal and skin care effect with steam distillation from the condensation residual liquid that Borneolum Syntheticum Camphor tree branch and leaf extract behind the dextro Borneolum Syntheticum, has the potential quality that well is developed to the pure natural daily chemical products.Never there is its relevant waste liquid of report to be applied in the daily chemical products at present, raising day by day along with China's living standards of the people, the people strengthen year by year to the demand of pure natural daily use chemicals health product and environment-friendly type daily chemical products, and the research and development and the application of Borneolum Syntheticum Camphor tree daily chemical products have wide future.
Summary of the invention
The present invention makes full use of the Borneolum Syntheticum Camphor tree resource of Hunan establishing in large scale and applicant's correlational study; propose a kind of from Borneolum Syntheticum Camphor tree plant, extract dextro Borneolum Syntheticum after debris (being the condensation of residual liquid after the dextro Borneolum Syntheticum crystallization is separated out in the condensation of steam distillation Borneolum Syntheticum Camphor tree) in daily chemical products, use; this class daily chemical products has good sterilizing and itch-relieving; can beautify and improve the people's quality of life, will play crucial effect for the protection of human health, ecological environment.For people provide a kind of efficient, safe Borneolum Syntheticum Camphor tree series daily chemical products, its preparation method is simple and easy to do, safe and efficient simultaneously.
Debris is used in daily chemical products extract dextro Borneolum Syntheticum from the Borneolum Syntheticum Camphor tree after, is that debris extract dextro Borneolum Syntheticum from the Borneolum Syntheticum Camphor tree after is used to prepare daily chemical products; Describedly extract from the Borneolum Syntheticum Camphor tree that debris is that finger Borneolum Syntheticum Camphor tree is used steam distillation behind the dextro Borneolum Syntheticum, the remaining condensed fluid behind the crystal is separated out in the retort gas condensation.
Described Borneolum Syntheticum Camphor tree is from the one or more combination in Borneolum Syntheticum leaf of Lignum cinnamomi camphorae, branch, the fruit organ.
Extracting debris is used to prepare behind the dextro Borneolum Syntheticum daily chemical products from the Borneolum Syntheticum Camphor tree comprises and nourishes emollient cream, bath gel, detergent, toothpaste, fancy soap, shampoo, detergent liquid, mosquito-repellent perfume, handwashing liquid, astringent or collutory.
The present invention has been for people provide a kind of high-quality, efficient, safe Borneolum Syntheticum Camphor tree active component series daily chemical products, belong to pure natural, pollution-free, effect is unique, the tangible serial daily chemical products of effect.Simultaneously, because the exploitation of this series products utilization, make Borneolum Syntheticum Camphor tree resource be fully utilized and develop.Original Borneolum Syntheticum Camphor tree mainly was to be used to extract dextro Borneolum Syntheticum, generally adopted steam distillation Borneolum Syntheticum Camphor tree, and dextro Borneolum Syntheticum is separated out in the distillate condensation, and other remaining liq is taken as the refuse waste liquid and gives up.The present invention makes the Borneolum Syntheticum Camphor tree that originally was rejected distill condensed liquid and has obtained utilization, turns waste into wealth.Can promote simultaneously the implant mass of Borneolum Syntheticum Camphor tree plant again, the energy planting trees on barren hills are shaken off poverty and set out on the road to prosperity for the flat Royal Park that is stranded, and significantly improve ecological benefits.
The preparation of debris behind the extraction dextro Borneolum Syntheticum in the Borneolum Syntheticum Camphor tree
Get Borneolum Syntheticum leaf of Lignum cinnamomi camphorae, branch 2kg pulverized the 10-20 mesh sieve, adopted 20 times steam distillation, through 10 ℃ of condenser condenses, its distillate is separated out crystallization (dextro Borneolum Syntheticum) through being condensate on the condenser, the residual remaining liq of distillation condensation that obtains.
Debris efficacy test behind the extraction dextro Borneolum Syntheticum from the Borneolum Syntheticum Camphor tree
One, antibacterial bacteriostatic effect measuring
Get the evaluating and measuring of the fungistatic effect that above-mentioned resulting debris carries out, carry out bacteriostatic test according to QB/T 2738 " daily chemical products antibacterial bacteriostatic Evaluation on effect method ", test strain is pressed regulation selection in QB/T 2738 " daily chemical products antibacterial bacteriostatic Evaluation on effect method " 6.3 chapters: gold-coloured staphylococci, escherichia coli, Candida albicans, bacillus pyocyaneus.Fungistatic effect is evaluated as B
1Level higher level (bacteriostasis rate 〉=90%)
Fungistatic effect is estimated
Two, white-skinned face function research
Measure the activity of cultured cell restraint of tyrosinase, measure white-skinned face function from cellular level.
Enzymatic oxidation product-dopachrome (dopachrome) that the mensuration of enzyme activity determination method tryrosinase vigor is based on L one tyrosine and L-DOPA has absorption maximum at 475nm wavelength place, and its specific absorbance is ￡=3700 (mol/L/cm).The definition of tryrosinase reactivity: is enzyme activity unit, i.e. a 1U/min with the per minute dopachrome in the absorbance increase by 0.001 of 475nm wavelength.Therefore, by measuring the 475nm absorbance growth straight line in time of enzymic catalytic reaction system, can try to achieve enzyme activity from straight slope.Wherein measure single phenolase vigor, the whole mass concentration of enzyme is 20mg/L.Measure the diphenol enzyme activity, the whole mass concentration of enzyme is 6mg/L.Measure the process curve of the residual liquid of variable concentrations to tryrosinase list phenol, diphenol enzyme inhibition.The result shows single phenolase suppression ratio IC
500.40ml/ml, diphenol enzyme inhibition rate IC
500.50ml/ml.
Below be applied in the preparation explanation of daily chemical products for debris behind the extraction dextro Borneolum Syntheticum in the Borneolum Syntheticum Camphor tree of the present invention
One, nourishes emollient cream
Weight is formed (%) and is distilled residual liquid 5-20 after the condensation, high-carbon alcohols 4-8, esters 1-15, surfactant 2-6 for the Borneolum Syntheticum Camphor tree, wetting agent 1-6, D-panthenol 0.5-2, vitamins 0.1-1, antiseptic 0.2-0.5, essence 0.1-0.6, all the other are water, final component summation is 100%.
Component medium high carbon alcohol is: spermol, stearyl alcohol, lauryl alcohol; Esters is: methyl stearate, butyl stearate; Surfactant is: aliphatic alcohol polyethenoxy (25) ether, tween 80, Tween-60; Wetting agent: glycerol, propylene glycol; Vitamins: vitamin A, vitamin E, vitamin C; Antiseptic: methyl hydroxybenzoate, sodium benzoate.
Two, shampoo
Weight is formed (%) and is distilled residual liquid 2-4 after the condensation for the Borneolum Syntheticum Camphor tree, surfactant 20-40, and anti-dandruff dose of 1-4, conditioner 0.5-2.5, natural essence 0.1-2, methyl hydroxybenzoate 0.1-0.5, distilled water 20-50, each component summation is 100%.
Surfactant in the component: lauryl alcohol polyethylene glycol oxide sulfosuccinic acid monoesters disodium salt, cocamido propyl betaine, month silicic acid diethanol acyl amine, stearic acid monoethanolamide, lauryl alcohol sulphuric acid three ethanol etc.; Anti-dandruff dose: Zinc Pyrithione, active climbazole, hydroxymethylpyridine ketone ethanolamine salt.
Three, bath gel
It is residual liquid 6-10 after the Borneolum Syntheticum Camphor tree water distillation condensation that weight is formed (%), surfactant 20-50, wetting agent 2-10, lanoline (water solublity) 2-5, methyl hydroxybenzoate 0.1-0.5, orange bergamot essence 0.5-4, other are Purified Water, and final component summation is 100%
Surfactant in the component: lauryl alcohol sulphuric acid triethanolamine salt, ether alcohol sulfate what is said or talked about, lauroyl diethanolamine etc.Wetting agent: glycerol palmitate, glycerol, propylene glycol.
Four, detergent liquid
Weight is formed (%) surfactant 20-60, residual liquid 2-5 after the Borneolum Syntheticum Camphor tree water distillation condensation, and sodium chloride 2-5, essence 0.5-1.5, citric acid 3-8, other water, final component summation is 100%
Surfactant: dodecylbenzene sodium sulfonate, dodecyl polyoxyethylene ether sulphuric acid amine, sodium xylene sulfonate, fatty diglycollic amide etc.
Five, fancy soap
Residual liquid/coconut oil soap (3:10) 5-15 after weight composition (%) Borneolum Syntheticum Camphor tree distillation condensation, stearic acid 1-5, fatty acid distribution of coconut oil 2-9, residual liquid 1-2 after the Borneolum Syntheticum Camphor tree distillation condensation, surfactant 20-70, sodium oxide 2-5, titanium white 0.5-1, orange bergamot essence 0.5-1, distilled water 1-4, each component summation is 100%
Surfactant in the component: octyl group glycerin ether sodium sulfonate, sodium isethionate.
Six, toothpaste
Components by weight percent (%) is dibastic sodium phosphate 25-50, propylene glycol 10-26, residual liquid 0.5-1.5 after the Borneolum Syntheticum Camphor tree water distillation condensation, sodium lauryl sulfate 2-10, methyl hydroxybenzoate 0.1-0.5, menthol and natural essence 0.1-0.5, saccharin sodium 0.1-0.5, water 10-25, each component summation is 100%.
Seven, detergent
Weight is formed (%) and is distilled residual liquid 1-4 after the condensation, sodium alkyl benzene sulfonate 20-40, sodium aluminosilicate 4-7, soda 15-35, aliphatic acid polyethenoxy ether 8-10, EDTA-Na for the Borneolum Syntheticum Camphor tree
44-10, fluorescent whitening agent 1-2, essence 0.1-0.8, water content 3-9, each component summation is 100%.
Eight, mosquito-repellent perfume
Components by weight percent (%) for Borneolum Syntheticum Camphor tree distillation condensation after residual liquid 0.5-2, orange blossom oil 2-3, Fructus Citri Limoniae oil 0.3-1, oleum bergamottae 0.8-1.3, geranium absolute 0.2-0.4, benzoic acid 0.2-0.5, ethanol (75%) 50-95%, each component summation is 100%.
The specific embodiment
The present invention will be further described below in conjunction with several embodiment.
Get fresh Borneolum Syntheticum Camphor tree plant leaf of 1kg and branch and rub, place in the distillating still, use steam distillation, retort gas is separated out crystal (dextro Borneolum Syntheticum) by condenser.Condensed liquid collecting gets up to be concentrated to 1000ml.Obtain Borneolum Syntheticum Camphor tree water and distill condensed residual solution.Standby.
Embodiment 1: nourish emollient cream preparation
Constituent content (%) is
A organizes spermol 3, stearyl alcohol 4, and butyl stearate 10, glycerol 5, fatty pure polyoxyethylene (25) ether 3, wool grease 4, D-panthenol 1, Borneolum Syntheticum Camphor tree water distills condensed residual solution 10
B organizes vitamin A 0.1, vitamin E 0.2, natural essence 0.2, sodium benzoate 0.3, Buddhist nun's ripple tortoise beetle ester 0.2, distilled water 59
Make: (1) slowly is heated to 80 ℃ with the A group in the rustless steel jacketed pan, make it miscible.(2) under constantly stirring, with the sodium benzoate in the B group, methyl hydroxybenzoate and distilled water evenly add in the jacketed pan and mix, after making it emulsifying evenly, be cooled to 35 ℃, (3) more respectively will B in the group vitamin E and essence add in the jacketed pan and mix, obtain good mastic after the homogenize and can divide and be filled in the bottle.
This product has good sterilization, itching-relieving action, and has the effect of nutrition Glycerin preferably, is high-grade skin moistening skin care good product, is applicable to various skin.
Embodiment 2: the preparation of shampoo
Each component content (%) is polyoxyethylene lauryl ether sulfosuccinic acid monoesters disodium salt (30%) 25, cocamido propyl betaine (30%) 15, lauric acid diethyl amide 3, stearic acid monoethanolamide 3, residual liquid 3 after the Borneolum Syntheticum Camphor tree distillation condensation, active climbazole 2, D-panthenol 1, natural essence 0.7, methyl hydroxybenzoate 0.3, distilled water 47.
Make: when (1) is heated to 60 ℃ with distilled water, successively each material is slowly added in the entry, after mixing, cooling gradually.When (2) temperature is reduced to below 40 ℃, add essence, after mixing, be cooled to packing behind the room temperature.
Embodiment 3: the preparation of bath gel
Each constituent content (%) is a lauryl alcohol sulphuric acid triethanolamine salt 40, ether alcohol sulfate (30% water dissolution) 20, lauric acid diethyl amide 5, glycerol palmitin 1, lanoline (water solublity) 2, glycerol 4, residual liquid 10 after the Borneolum Syntheticum Camphor tree water distillation condensation, orange bergamot essence 1, methyl hydroxybenzoate 1, distilled water 16.
Make: when (1) is heated to 50 ℃ with distilled water, successively with behind the mix homogeneously in each component adding container, cooling.When (2) temperature is reduced to below 40 ℃, add orange bergamot essence, after mixing, be cooled to packing behind the room temperature.
This product has good clean effect and the good sterilizing and itch-relieving effect of washing, and it is soft and smooth pleasant to wash clean back skin.
Embodiment 4: the preparation of detergent liquid
Each constituent content (%) is a dodecylbenzene sodium sulfonate (60%) 28, dodecyl polyoxyethylene ether ammonium sulfate (60%) 18.3, fatty diglycollic amide 4, sodium xylene sulfonate (40%) 8.5, sodium chloride 3, residual liquid 2 after the Borneolum Syntheticum Camphor tree water distillation condensation, essence 0.5, Purified Water 33.7, citric acid 2.
Make: when (1) is heated to 45 ℃ with Purified Water, successively with behind the mix homogeneously in each component adding container, cooling.(2), add essence, after mixing, the reuse citric acid transfers pH value to 6.5-7.0, packing behind the mixing.
Embodiment 5: the preparation of fancy soap
Each constituent content (%) for Borneolum Syntheticum Camphor tree distillation condensation after residual liquid/coconut oil soap (3:97) 8, stearic acid 1, fatty acid distribution of coconut oil 8, residual liquid 1 after the Borneolum Syntheticum Camphor tree water distillation condensation, octyl group glycerin ether sodium sulfonate 68, sodium isethionate 5, sodium chloride 4, titanium white 0.5, orange bergamot essence 1. distilled water 3.5.
Make: (1) is heated to molten condition and mix homogeneously with mixing of materials; (2) obtain soap powder (3) after the spray drying essence is added in the soap powder, behind the spice, grind evenly; (4) printing shaping behind the vacuum press strip, cooling gets product.
This product belongs to the senior fancy soap of mild, has good degerming itching-relieving efficacies, and can Glycerin.
Embodiment 6: the preparation of toothpaste
Each constituent content (%) dibastic sodium phosphate 49, propylene glycol 25, residual liquid 1 after the Borneolum Syntheticum Camphor tree water distillation condensation, sodium lauryl sulfate 2, methyl hydroxybenzoate 0.1, menthol and natural essence 0.1, saccharin sodium 0.5, water 22.3
Make: liquid joins mixing in the liquid material after (1) Borneolum Syntheticum Camphor tree distillation condensation; (2) granular material is sieved respectively join mixing in the mixing and blending machine after the weighing; (3) under stirring, blended liquid material is slowly joined mixing in the granular material; (4) through colloid mill mill cream; (5) after the vacuum outgas, be delivered to the filling machine tubulature and seal.
Use this product breath freshening, the oral cavity is comfortable.
Embodiment 7: the preparation of detergent
Each constituent content (%) for Borneolum Syntheticum Camphor tree distillation condensation after residual liquid 3, sodium alkyl benzene sulfonate 35.5, sodium aluminosilicate 5, soda 30, fat is calculated polyoxyethylene ether 10, EDTA-Na
410, fluorescent whitening agent 1.5, essence 0.5, water content 5.
Method for making: residual liquid and essence liquid components add mixing after (1) usefulness Borneolum Syntheticum Camphor tree distillation condensation; (2) with after the solid constituent premixing evenly, liquid components is pressurizeed even spraying to solid constituent, and mix strongly; (3) after the cylinder drying drying, the packing of sieving gets final product.
This product has stronger bactericidal action, can be used as the first-selected detergent of underwear washing machine washing
Embodiment 8: the preparation of mosquito-repellent perfume
Each constituent content (%) for Borneolum Syntheticum Camphor tree distillation condensation after residual liquid 1, orange blossom oil 3, Fructus Citri Limoniae oil 0.6, oleum bergamottae 1.2, geranium absolute 0.25, benzoic acid 0.4 ethanol (75%) 93.55
Make: (1) is got 75% ethanol and is added in the rustless steel container, residual liquid after the adding Borneolum Syntheticum Camphor tree distillation condensation, and stirring is dissolved it fully: (2) under agitation add various essence according to this, and mix homogeneously get final product.
This product fragrance gracefulness is pleasant, flight class insecticides such as the mosquito around expelling after the use.
Embodiment 9: handwashing liquid
Get fresh Borneolum Syntheticum Camphor tree plant leaf of 1kg and branch and rub, place in the distillating still, use steam distillation, retort gas is separated out crystal (dextro Borneolum Syntheticum) by condenser, and condensed liquid is from the Borneolum Syntheticum Camphor tree debris behind the extraction dextro Borneolum Syntheticum.With itself and surfactant dodecylbenzene sodium sulfonate and the bottling of Oleum menthae (12:12:1) mix homogeneously.
This product has good antibacterial sterilization functions.Use this product can guarantee Personal hygiene.
Embodiment 9: collutory
Get fresh Borneolum Syntheticum Camphor tree plant leaf of 1kg and branch and rub, place in the distillating still, use steam distillation, retort gas is separated out crystal (dextro Borneolum Syntheticum) by condenser, and condensed liquid is from the Borneolum Syntheticum Camphor tree debris behind the extraction dextro Borneolum Syntheticum.Collutory is made in its direct bottling.
This product has good oral cavity antiinflammatory and bactericidal action, uses this product can guarantee Personal hygiene.
Embodiment 10: astringent
Get fresh Borneolum Syntheticum Camphor tree plant leaf of 1kg and branch and rub, place in the distillating still, use steam distillation, retort gas is separated out crystal (dextro Borneolum Syntheticum) by condenser, and condensed liquid is from the Borneolum Syntheticum Camphor tree debris behind the extraction dextro Borneolum Syntheticum.Astringent is made in its direct bottling.
This product has good bacteriostasis, uses this product can keep skin clean.
Claims (3)
1, from the Borneolum Syntheticum Camphor tree, extract dextro Borneolum Syntheticum after debris in daily chemical products, use, it is characterized in that: debris is used to prepare daily chemical products extract dextro Borneolum Syntheticum from the Borneolum Syntheticum Camphor tree after; Describedly extract from the Borneolum Syntheticum Camphor tree that debris is that the Borneolum Syntheticum Camphor tree is referred to use steam distillation behind the dextro Borneolum Syntheticum, the remaining condensed fluid behind the crystal is separated out in the retort gas condensation.
2, according to claim 2 from the Borneolum Syntheticum Camphor tree, extract dextro Borneolum Syntheticum after debris in daily chemical products, use, it is characterized in that: described Borneolum Syntheticum Camphor tree is from the one or more combination in Borneolum Syntheticum leaf of Lignum cinnamomi camphorae, branch, the fruit organ.
3, according to claim 1 from the Borneolum Syntheticum Camphor tree, extract dextro Borneolum Syntheticum after debris in daily chemical products, use, it is characterized in that: from the Borneolum Syntheticum Camphor tree, extract the daily chemical products that debris is used to prepare behind the dextro Borneolum Syntheticum and comprise: nourish emollient cream, bath gel, detergent, toothpaste, fancy soap, shampoo, detergent liquid, mosquito-repellent perfume, handwashing liquid, astringent or collutory.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2008101439171A CN101422416B (en) | 2008-12-12 | 2008-12-12 | Use of residual liquid in producing daily chemical product after extracting d-borneol from borneol camphor |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2008101439171A CN101422416B (en) | 2008-12-12 | 2008-12-12 | Use of residual liquid in producing daily chemical product after extracting d-borneol from borneol camphor |
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| Publication Number | Publication Date |
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| CN101422416A true CN101422416A (en) | 2009-05-06 |
| CN101422416B CN101422416B (en) | 2011-04-06 |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102784200A (en) * | 2012-07-04 | 2012-11-21 | 厦门牡丹香化实业有限公司 | Method for extracting lignans from camphor tree leaves |
| CN105753648A (en) * | 2016-03-03 | 2016-07-13 | 陈爱华 | Method for extracting borneol from camphorwood branches and leaves |
| CN106635513A (en) * | 2016-08-26 | 2017-05-10 | 广州市博林机械设备有限公司 | Application of Lauraceae plant extract serving as detergent |
| CN109566661A (en) * | 2018-12-11 | 2019-04-05 | 怀化五零三侗医药科技开发有限公司 | Expelling parasite bacteriostatic gel and preparation method thereof |
| CN109908059A (en) * | 2019-04-16 | 2019-06-21 | 王云轲 | A kind of borneol Essence of plant extract and preparation method thereof |
-
2008
- 2008-12-12 CN CN2008101439171A patent/CN101422416B/en not_active Expired - Fee Related
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102784200A (en) * | 2012-07-04 | 2012-11-21 | 厦门牡丹香化实业有限公司 | Method for extracting lignans from camphor tree leaves |
| CN105753648A (en) * | 2016-03-03 | 2016-07-13 | 陈爱华 | Method for extracting borneol from camphorwood branches and leaves |
| CN106635513A (en) * | 2016-08-26 | 2017-05-10 | 广州市博林机械设备有限公司 | Application of Lauraceae plant extract serving as detergent |
| CN109566661A (en) * | 2018-12-11 | 2019-04-05 | 怀化五零三侗医药科技开发有限公司 | Expelling parasite bacteriostatic gel and preparation method thereof |
| CN109908059A (en) * | 2019-04-16 | 2019-06-21 | 王云轲 | A kind of borneol Essence of plant extract and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101422416B (en) | 2011-04-06 |
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