CN101421813A - Manufacturing method of sealed panel, and plasma display panel - Google Patents

Manufacturing method of sealed panel, and plasma display panel Download PDF

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Publication number
CN101421813A
CN101421813A CNA2007800127176A CN200780012717A CN101421813A CN 101421813 A CN101421813 A CN 101421813A CN A2007800127176 A CNA2007800127176 A CN A2007800127176A CN 200780012717 A CN200780012717 A CN 200780012717A CN 101421813 A CN101421813 A CN 101421813A
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China
Prior art keywords
substrate
sealing
sealing material
plasma display
wall
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CNA2007800127176A
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CN101421813B (en
Inventor
仓内利春
饭岛荣一
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Ulvac Inc
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Ulvac Inc
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J9/00Apparatus or processes specially adapted for the manufacture, installation, removal, maintenance of electric discharge tubes, discharge lamps, or parts thereof; Recovery of material from discharge tubes or lamps
    • H01J9/24Manufacture or joining of vessels, leading-in conductors or bases
    • H01J9/26Sealing together parts of vessels
    • H01J9/261Sealing together parts of vessels the vessel being for a flat panel display
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J11/00Gas-filled discharge tubes with alternating current induction of the discharge, e.g. alternating current plasma display panels [AC-PDP]; Gas-filled discharge tubes without any main electrode inside the vessel; Gas-filled discharge tubes with at least one main electrode outside the vessel
    • H01J11/20Constructional details
    • H01J11/48Sealing, e.g. seals specially adapted for leading-in conductors
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J11/00Gas-filled discharge tubes with alternating current induction of the discharge, e.g. alternating current plasma display panels [AC-PDP]; Gas-filled discharge tubes without any main electrode inside the vessel; Gas-filled discharge tubes with at least one main electrode outside the vessel
    • H01J11/10AC-PDPs with at least one main electrode being out of contact with the plasma
    • H01J11/12AC-PDPs with at least one main electrode being out of contact with the plasma with main electrodes provided on both sides of the discharge space
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J11/00Gas-filled discharge tubes with alternating current induction of the discharge, e.g. alternating current plasma display panels [AC-PDP]; Gas-filled discharge tubes without any main electrode inside the vessel; Gas-filled discharge tubes with at least one main electrode outside the vessel
    • H01J11/20Constructional details
    • H01J11/52Means for absorbing or adsorbing the gas mixture, e.g. by gettering
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J9/00Apparatus or processes specially adapted for the manufacture, installation, removal, maintenance of electric discharge tubes, discharge lamps, or parts thereof; Recovery of material from discharge tubes or lamps
    • H01J9/38Exhausting, degassing, filling, or cleaning vessels
    • H01J9/39Degassing vessels

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • Manufacturing & Machinery (AREA)
  • Gas-Filled Discharge Tubes (AREA)
  • Common Detailed Techniques For Electron Tubes Or Discharge Tubes (AREA)

Abstract

This invention provides a sealing panel (100) that can suppress a rise in discharge voltage. The sealing panel (100) comprises a resin material-containing sealing material (20) disposed on the whole periphery in a part between a pair of substrates (1,2). A getter (22), which adsorbs an impurity gas released from the sealing material (20) and an impurity gas passed through the sealing material (20), is formed continuously or intermittently along the inner periphery of the sealing material (20). Further, an ultraviolet shielding wall (24) for preventing ultraviolet light generated within the sealing panel (100) from being incident to the sealing material (20) is formed continuously along the inner periphery of the sealing material (20).

Description

The manufacture method of sealing panel and plasma display
Technical field
The present invention relates to the manufacture method of sealing panel and plasma display.
The application based on April 10th, 2006 spy in Japanese publication be willing to advocate priority for 2006-107547 number, quote its content at this.
Background technology
Plasma display comprises and is formed with the front substrate of keeping electrode and scan electrode and is formed with addressing electrode and the back substrate of fluorophor.Two substrates is configured in the sealing material of circumference and fixes, and enclosing between two substrates has discharge gas.
If apply voltage between each electrode, then discharge gas forms plasma and radiation ultraviolet ray.Excited fluophor in the fluorophor is incided in this ultraviolet ray, penetrates visible light.
Sealing material as two substrates adopted low-melting glass in the past, but had proposed to adopt the technology (for example, with reference to patent documentation 1) of resin material recently.If adopt resin material, then because heating condition and cooling condition can relax panel sealing the time can significantly shorten the panel manufacturing time.
Patent documentation 1: TOHKEMY 2002-75197 communique
But if adopt resin material as the sealing material, then foreign gas (moisture, carbon dioxide etc.) might be discharged into panel inside from resin material when panel sealing.And, when the use of sealing material mixes the sealing material that obtains as the resin material of adhesive in low-melting glass, also might when panel sealing, foreign gas be discharged into panel inside.In addition, even behind panel sealing, foreign gas also might see through the sealing material and invade inside from the panel outside.Further, if incide in the sealing material in the inner ultraviolet ray that produces of panel, then resin material might decompose and impurity (CH class etc.) gas is released to panel inside.Because these foreign gases, the purity that is enclosed in the discharge gas of panel inside reduces, the problem that exists discharge voltage to raise.Along with the rising of discharge voltage, the power consumption of plasma display increases.
In addition, the foreign gas that is discharged into panel inside from the sealing material when panel sealing is adsorbed on the tunicle that is formed on substrate surface.Thus, the secondary electron yield of substrate surface reduces, and discharge voltage raises.And if the voltage (initial aging (ageing) handles) to applying the stipulated time between substrate, then owing to break away from from substrate surface by discharge foreign gas, discharge voltage is stable.But because the foreign gas that breaks away from is trapped between substrate, the second cosmic velocity of foreign gas reduces, so be necessary to carry out for a long time initial burin-in process.
Summary of the invention
The present invention proposes in order to address the above problem, and its purpose is, provides to suppress the sealing panel that discharge voltage raises and the manufacture method of plasma display.
In order to reach above-mentioned purpose, sealing panel of the present invention comprises the sealing material that is configured in the entire circumference between a pair of substrate and contains resin material, and be sealing into discharge gas between described a pair of substrate by described sealing material, it is characterized in that, interior all continuously or intermittentlies along described sealing material are formed with adsorption material, and this adsorption material is used to adsorb the foreign gas that is discharged by described sealing material and sees through the foreign gas that described sealing material is invaded.
And, the sealing material that described sealing material also can obtain for the resin material that mixes in glass material as adhesive.
According to this structure, owing to can suppressing to be sealing into the purity reduction of the discharge gas between a pair of substrate by adsorption material absorption by the foreign gas that seals material release and through sealing the foreign gas that material is invaded.In addition, can prevent that foreign gas is adsorbed onto on the substrate surface.Therefore, can suppress the rising of discharge voltage.
And, initial ageing treatment time can be shortened or initial burin-in process can be do not carried out.
In addition, described adsorption material also can be provided with multi-turn with concentric shape.
According to this structure, can adsorb foreign gas effectively.
In addition, the described adsorption material of a part in the adsorption material of described multi-turn can be assemblied on the described substrate in the described a pair of substrate, and the described adsorption material of the remainder in the adsorption material of described multi-turn is assemblied on another described substrate in the described a pair of substrate.
According to this structure, invade the path configurations adsorption material along this when the intrusion path of foreign gas is elongated, so can improve the adsorption efficiency of foreign gas.
In addition, can be formed with the ultraviolet screener wall continuously along the interior week of described sealing material, this ultraviolet screener wall is used to shield the ultraviolet ray that produces in the inside of described sealing panel and incides described sealing material.
According to this structure, can prevent that the ultraviolet ray of the inside generation of sealing panel from inciding the sealing material.Thus, foreign gas can be suppressed, thereby the rising of discharge voltage can be suppressed from the release of sealing material.
In addition, the top of the described ultraviolet screener wall on the upright described substrate that is located in the described a pair of substrate can connect with another the described substrate in the described a pair of substrate.
According to this structure, can tackle the foreign gas that discharges by the sealing material and see through the foreign gas that seals the material intrusion by the ultraviolet screener wall, thereby the purity that can suppress discharge gas reduces.
In addition, described adsorption material preferred disposition is between described sealing material and described ultraviolet screener wall.
According to this structure, can adsorb the foreign gas of being tackled effectively by adsorption material by the ultraviolet screener wall.
In addition, preferred described sealing panel is a plasma display, described ultraviolet screener wall by and the spaced walls identical materials that is provided between the pixel of described plasma display constitute.
According to this structure, can form the ultraviolet screener wall simultaneously with spaced walls, thereby can simplify manufacturing process, reduction manufacturing cost.
On the other hand, the manufacture method of the plasma display that the present invention relates to is to comprising the sealing material that is configured in the entire circumference between a pair of substrate and contains resin material, and be sealing into the method that the plasma display of the discharge gas between described a pair of substrate is made by described sealing material, it is characterized in that, and the spaced walls that is provided between the pixel of described plasma display forms the ultraviolet screener wall simultaneously, and this ultraviolet screener wall is used to shield the ultraviolet ray that produces in the inside of described plasma display and incides described sealing material.
The spaced walls of plasma display is used to prevent the electricity that misplaces between pixel adjacent, forms the height identical with the interval of a pair of substrate.By forming this spaced walls and ultraviolet screener wall simultaneously, can form ultraviolet screener wall with the interval equal height of a pair of substrate.
Thus, can prevent effectively that the ultraviolet ray that the inside of plasma display produces from inciding the sealing material.Thus, foreign gas can be suppressed, thereby the rising of discharge voltage can be suppressed from the release of sealing material.
According to the manufacture method of sealing panel of the present invention and plasma display, can suppress to be sealing into the purity reduction of the discharge gas between a pair of substrate.In addition, can prevent that foreign gas is adsorbed onto on the substrate surface.Therefore, can suppress the rising of discharge voltage.And, ageing treatment time can be shortened or initial burin-in process can be do not carried out.
Description of drawings
Fig. 1 is the exploded perspective view of three electrode A C type plasma displays.
Fig. 2 is the sectional view of the circumference of plasma display.
Fig. 3 A is the plane graph with plasma display of getter.
Fig. 3 B is the plane graph with plasma display of getter.
Fig. 3 C is the plane graph with plasma display of getter.
Fig. 4 A is the key diagram with plasma display of a plurality of getters.
Fig. 4 B is the key diagram with plasma display of a plurality of getters.
Fig. 4 C is the key diagram with plasma display of a plurality of getters.
Fig. 5 is the flow chart of the manufacture method of plasma display.
Fig. 6 A is the fuchsin(e)test result's of plasma display a curve chart.
Fig. 6 B is the fuchsin(e)test result's of plasma display a curve chart.
Fig. 7 A is the ageing test result's of plasma display a curve chart.
Fig. 7 B is the ageing test result's of plasma display a curve chart.
Symbol description
1... back substrate
2... front substrate
15... spaced walls
16... arc chamber
20... sealing material
22... getter (adsorption material)
24... ultraviolet screener wall
100... plasma display (sealing panel)
Embodiment
Followingly embodiments of the present invention are described with reference to accompanying drawing.And, in the following description in each accompanying drawing of Shi Yonging, in order to make the size of each parts, the reduced scale of each parts is carried out appropriate change for discerning.
And in this manual, " inner surface " of substrate refers in two surfaces of this substrate, with the surface of this substrate opposing substrates side.
(plasma display)
Fig. 1 is the exploded perspective view of three electrode A C type plasma displays.This plasma display floater is (hereinafter referred to as " PDP ".) 100 comprise the back substrate 1 and the front substrate 2 of subtend configuration, and be formed on a plurality of arc chambers 16 between the two substrates 1,2.
The inner surface of substrate 1 is formed with strip addressing electrode 11 with the interval of stipulating overleaf.To cover this addressing electrode 11, be formed with dielectric layer 19.In addition, the upper surface of the dielectric layer 19 between the addressing electrode 11 of adjacency is formed with the spaced walls (rib) 15 parallel with addressing electrode 11.Further, the side of the upper surface of the dielectric layer 19 between the spaced walls 15 of adjacency and spaced walls 15 is equipped with fluorophor 17.This fluorophor 17 sends any one fluorescence in the red, green, blue.
On the other hand, the inner surface of substrate 2 in front is formed with the show electrode 12 (scan electrode 12a and keep electrode 12b) of strip with the interval of regulation.This show electrode 12 constitutes by transparent conductivity materials such as ITO, is configured on the direction with above-mentioned addressing electrode 11 quadratures.The intersection point of this addressing electrode 11 and show electrode 12 forms the pixel of PDP100.In addition, be formed with dielectric layer 13, be formed with diaphragm 14 to cover this dielectric layer 13 to cover this show electrode 12.This diaphragm 14 is by the cation protection dielectric layer 13 of the plasma generation of passing through discharge gas, by the oxide formation of alkaline-earth metals such as MgO, SrO.
Above-mentioned back substrate 1 and front substrate 2 are fitted, between the spaced walls 15 of adjacency, be formed with arc chamber 16.The discharge gass such as mist that Ne and Xe are arranged are enclosed in inside at this arc chamber 16.
Then, between addressing electrode 11 and scan electrode 12a, apply direct voltage and produce the subtend discharge, further apply alternating voltage generation surface discharge between the electrode 12b with keeping at scan electrode 12a.So the discharge gas that is sealing in the arc chamber 16 forms plasma, the radiation vacuum ultraviolet.By this ultraviolet ray excited fluorophor 17, visible light penetrates from front substrate 2.
(sealing material)
Fig. 2 is the sectional view of the circumference of plasma display.The circumference of substrate 1 is formed with projection 21 with the frame shape overleaf.Between the top end face of this projection 21 and front substrate 2, dispose the sealing material 20 that contains resin material, sealing two substrates 1,2.As sealing material 20, specifically adopt heat-curing resin or uv curing resins such as epoxy resin, acrylic resin.So, if adopt the sealing material 20 contain resin material, then compare with the situation that employing contains the existing sealing material of low-melting glass, heating condition and cooling condition during sealing are relaxed.Therefore, can significantly shorten the panel manufacturing time.And, also can adopt in low-melting glass and to mix the sealing material that the resin as adhesive obtains.
(adsorption material)
When two substrates 1,2 sealings, discharge foreign gas by the sealing material 20 that contains resin material.For example, by the sealing material 20 that contains epoxy resin or acrylic resin, except discharging H 2O and CO 2Outside, also discharge CO, H 2, CH class gas etc.In addition, in low-melting glass, mixing the sealing material that acrylic resin obtains, discharge CO by low-melting glass 2, O 2Gas etc. discharge H by acrylic resin 2O, CO 2, CO gas etc.In addition, H 2The sealing material 20 that foreign gases such as O might see through after the sealing invades inside from the outside of PDP.
Therefore, along the getter (adsorption material) 22 that is provided with absorption foreign gas interior week that seals material 20.This getter 22 adsorption moisture (H 2O) or oxygen (O 2), CO or CO 2Deng appropriate hydrocarbon gas of carbonic acid gas, CH class etc.As getter 22, specifically can adopt the SrO that is shaped to the sheet about thickness 150 μ m.In addition,, can adopt the material of thickness 5~10 μ m that use Ba, Ca, the formation of Sr isoreactivity metal, also can adopt Zr-V-Fe-Ti class material as getter 22.
Fig. 3 A~Fig. 3 C is the plane graph with plasma display of getter.As shown in Figure 3A, getter 22 preferably is formed on the inboard entire circumference of sealing material 20 continuously.And, shown in Fig. 3 B or Fig. 3 C, also can be formed on the inboard entire circumference of sealing material 20 discontinuously.
And getter 22 can be configured on the surface of back substrate 1 of inboard of sealing material 20 as shown in Figure 2, also can be configured on the surface of front substrate 2.In addition, the thickness of getter 22 can be thinner than the interval of two substrates 1,2 as shown in Figure 2, also can be equal with the interval of two substrates 1,2.
Fig. 4 A and Fig. 4 B are the plane graph with plasma display of a plurality of getters.Shown in Fig. 4 A, can along the sealing material 20 interior week dispose multi-turn getter 22a, 22b with concentric shape.A plurality of getter 22a, 22b can form shown in Fig. 4 A continuously, also can form discontinuously shown in Fig. 4 B.In addition, the part in also can a plurality of getters forms continuously, remainder forms discontinuously.So, by multi-turn getter 22a, 22b are configured to concentric shape, can adsorb foreign gas effectively.
Fig. 4 C is the sectional view of the A-A line of Fig. 4 A.Shown in Fig. 4 C, also a part of getter 22a among multi-turn getter 22a, the 22b can be assemblied on the back substrate 1, the getter 22b of remainder is assembled on the front substrate 2.Thus, invade path configurations getter 22a, 22b along this when the intrusion path of foreign gas is elongated, so can improve the adsorption efficiency of foreign gas.And a plurality of getter 22a, 22b can be assemblied on the back substrate 1, also can all be assemblied on the front substrate 2.
(ultraviolet screener wall)
Get back to Fig. 2, interior week be provided with ultraviolet screener wall 24 continuously along above-mentioned getter 22.This ultraviolet screener wall 24 prevents in the arc chamber 16 that the ultraviolet ray that produces incides sealing material 20, passes through PbOB 2O 3SiO 2Form 1mm left and right sides width Deng ultraviolet absorption material.Ultraviolet screener wall 24 can stand as shown in Figure 2 and be located on the back substrate 1, also can stand to be located on the front substrate 2.
The height of ultraviolet screener wall 24 forms with the interval of a pair of substrate 1,2 and equates.Therefore, the upright top that is located at the ultraviolet screener wall 24 on the back substrate 1 abuts against front substrate 2.According to this structure, can be by the interception of ultraviolet screener wall by the foreign gas of sealing material 20 releases and the foreign gas of invading through sealing material 20.And above-mentioned getter 22 preferably is provided between sealing material 20 and the ultraviolet screener wall 24.
According to this structure,, not only can tackle, and can adsorb effectively by getter 22 by ultraviolet screener wall 24 for the foreign gas that discharges by sealing material 20.
Ultraviolet screener wall 24 preferably is made of the ultraviolet absorption material identical with spaced walls 15, is located on the back substrate 1 with spaced walls 15 is upright in the same manner.Thus, can as described belowly form ultraviolet screener wall 24 simultaneously, thereby can simplify manufacturing process, reduce manufacturing cost with spaced walls 15.
The spaced walls 15 of PDP is used to prevent the electricity that misplaces between the arc chamber 16 of adjacency, forms the identical height in interval with back substrate 1 and front substrate 2.By forming this spaced walls 15 and ultraviolet screener wall 24 simultaneously, can form ultraviolet screener wall 24 with the interval equal height of two substrates 1,2.Thus, can prevent effectively in the arc chamber 16 that the ultraviolet ray that produces incides sealing material 20.
(manufacture method of plasma display)
Then, use Fig. 2 and Fig. 5 that the manufacture method of the plasma display in the present embodiment is described.Fig. 5 is the flow chart of the manufacture method of the plasma display in the present embodiment.
At first, as shown in Figure 2, the inner surface of substrate 2 forms show electrode 12 and dielectric layer 13 (step 32) in front.In addition, the inner surface of substrate 1 forms addressing electrode 11 and dielectric layer 19 (step 42) overleaf.
Then, form spaced walls 15 and ultraviolet screener wall 24 (step 44) simultaneously on the surface of the dielectric layer 19 of substrate 1 overleaf.The inner surface that its concrete method is a substrate 1 at first overleaf forms the tunicle of ultraviolet absorption material.Specifically, the pasty state ultraviolet absorption material is coated with into 200 μ m left and right thicknesses, dryly forms above-mentioned tunicle by print process etc.Then, laminating film resist (DFR) on the surface of above-mentioned tunicle.Then, with this DFR exposure and development, with the shape formation pattern of spaced walls 15 and ultraviolet screener wall 24.Then, implement sand-blast as mask, with the shape formation pattern of above-mentioned tunicle with spaced walls 15 and ultraviolet screener wall 24 with this DFR pattern.Then, peel off and remove DFR, back substrate 1 is put in the sintering furnace, spaced walls 15 and ultraviolet screener wall 24 are carried out sintering.Thus, form spaced walls 15 and ultraviolet screener wall 24 on the inner surface of substrate 1 overleaf.
In addition, as other method that forms simultaneously, can be before forming addressing electrode 11 and dielectric layer 19, lamination DFR on the inner surface of substrate 1 overleaf.Then with this DFR exposure and development, with the shape formation pattern of spaced walls 15 and ultraviolet screener wall 24.Then, implement sand-blast with this DFR pattern as mask, the back substrate 1 that will contain ultraviolet absorption materials such as glass digs to the 150 μ m left and right sides degree of depth.Then, peel off and remove DFR.Thus, be directly formed to spaced walls 15 and ultraviolet screener wall 24 on the inner surface of substrate 1 overleaf.After this, forming addressing electrode 11 grades gets final product.And, also can form spaced walls 15 and ultraviolet screener wall 24 simultaneously by the method beyond above-mentioned.
Then, at the inboard of the spaced walls of adjacency coating fluorophor 17.
Then, the configuration of the entire circumference of substrate 1 seals material 20 and getter 22 (step 46) overleaf.The configuration of sealing material 20 is undertaken by the encapsulant of coating pasty state.The coating of encapsulant can utilize drops such as distribution (dispenser) method or ink-jet method spue method or print process etc.In addition, the configuration of getter 22 is undertaken by the SrO material piece of pasting about width 3~10mm, about thickness 150 μ m.This SrO material piece can followingly form: join the SrO powder in the mould and at 200~400kgf/cm 2Forming under the pressure, further at N 2In about 30 minutes of about 1200 ℃ of following sintering, form above-mentioned SrO material piece in the atmosphere.
Then, front substrate 2 and back substrate 1 are put in the vacuum apparatus for continous treatment 50, two substrates 1,2 is not exposed to and proceeds to following sealing process under the atmosphere.
At first, in a vacuum back substrate 1 is heated, carry out from the degassing processing and the pump-down process (step 48) of the sealing material 20 that contains resin material.By this heating, can be in the activation processing of carrying out when the degassing of sealing material 20 is handled, carrying out getter 22.In addition, in a vacuum front substrate 2 is heated, carry out handling (step 34) from the degassing of dielectric layer 13 grades.Then, form diaphragm 14 (step 36) by EB vapour deposition process etc. on the inner surface of substrate 2 in front.
And, in order to reduce the power consumption of PDP, the MgO that adopts SrO class materials such as (SrCa) O to substitute is in the past studied as the constituent material of diaphragm 14 recently.This SrO class material is compared with MgO, and moisture absorption is high and have because moisture absorption and the character of variable color.For this problem; by in vacuum apparatus for continous treatment 50 from the degassing treatment process of two substrates 1,2 through the formation operation of over-protective film 14 sealing process until two substrates 1,2, can prevent diaphragm 14 because the variable color that moisture absorption causes and the rising of discharge voltage.
Then, sealing two substrates 1,2 (step 52).Specifically, at first in chamber (chamber), drop into two substrates 1,2, in this chamber, import discharge gas.Then, aim at (contraposition) two substrates 1,2 and carry out temporary fixed.Then, two substrates 1,2 is applied the voltage discharge of wearing out.Further, the electrode of two substrates 1,2 is applied driving voltage and carry out luminescent inspection.Its result removes the back substrate 1 or the front substrate 2 that note abnormalities, fixes between the normal luminous two substrates 1,2 confirming.Specifically, when constituting sealing material 20 by uv curing resin,, when constituting sealing material 20 by heat-curing resin, sealing material 20 is solidified by sealing material 20 is heated by to sealing material 20 irradiation ultraviolet radiations.Thus, under the state in the inside that discharge gas is sealing into two substrates 1,2, sealing two substrates 1,2.
(fuchsin(e)test, ageing test)
The present inventor carries out the fluctuation that discharge voltage is measured in fuchsin(e)test for PDP in the above-mentioned present embodiment and PDP of the prior art.PDP in the present embodiment comprises getter 22 and ultraviolet screener wall 24 as shown in Figure 2.Specifically, as getter 22, adopt at N 2The sheet getter that sintering SrO obtains in the gas.In addition, as the constituent material of ultraviolet screener wall 24, adopt the PbOB identical with spaced walls 15 2O 3SiO 2, form ultraviolet screener wall 24 simultaneously with spaced walls 15.And sealing material 20 adopts uv curing resin.In addition, as diaphragm 14, form the thickness 8000 that contains SrO20mol%CaO by the EB vapour deposition process
Figure A200780012717D0013113513QIETU
Tunicle.In addition, as discharge gas, enclose Ne4%Xe gas with 400Torr.
Therewith relatively, PDP of the prior art is for removing the PDP of getter 22 and ultraviolet screener wall 24 among the PDP from present embodiment.
Fuchsin(e)test is studied the standing time and the relation of discharge sustaining voltage by carrying out placing PDP under 85 ℃ in the thermostat of humidity 95%.
Fig. 6 A and Fig. 6 B are the fuchsin(e)test result curve figure of PDP, and Fig. 6 A is the situation of the PDP in the present embodiment, and Fig. 6 B is the situation of PDP of the prior art.And in the following curve chart, in the PDP that contains 300 two-dimensional matrix discharge cells (cell), making whole discharge cells necessary driving voltage that begins to discharge is final discharge cell point modulating voltage.In addition, when the state that whole discharge cells are lit a lamp slowly reduced driving voltage, the voltage that initial discharge cell is turned off the light was the first discharge cell light-off voltage.
Under the situation of PDP of the prior art shown in Fig. 6 B, the first discharge cell light-off voltage and final discharge cell point modulating voltage significantly increase under the placement of short time.Think that this is because the moisture in the thermostat sees through the inside that the sealing material invades PDP, has reduced the purity of discharge gas.
Therewith relatively, under the situation of the PDP in the present embodiment shown in Fig. 6 A, even obtained increasing standing time voltage fluctuation also in 5V, can problematic result in practicality.Think that this is that the purity that has suppressed discharge gas reduces owing to the moisture that invades the inside of PDP through the sealing material is adsorbed by getter.
In addition, the present inventor carries out ageing test for the PDP in the present embodiment and PDP of the prior art the fluctuation of discharge voltage is measured.As the PDP in the present embodiment,, adopt the PDP that removes getter in order to confirm the effect of ultraviolet screener wall.In addition, as PDP of the prior art, adopt the PDP that removes ultraviolet screener wall and getter.
Ageing test is undertaken by at room temperature in the atmosphere of humidity 50% PDP being applied long-time voltage, and the ageing time and the relation of discharge sustaining voltage are investigated.
Fig. 7 A and Fig. 7 B are the ageing test result curve figure of PDP, and Fig. 7 A is the situation of the PDP in the present embodiment, and Fig. 7 B is the situation of PDP of the prior art.
Under the situation of PDP of the prior art shown in Fig. 7 B, the discharge sustaining voltage raise when ageing time increased, and final discharge cell point modulating voltage increases 30V approximately after 2000 hours the burin-in process.Think that this is because the sealing material is incided in the ultraviolet ray of the discharge generation by PDP for a long time, the resin material that the sealing material contains is decomposed, the foreign gas of CH class is released to PDP inside, has reduced the purity of discharge gas.
Therewith relatively, under the situation of the PDP in the present embodiment shown in Fig. 7 A, even after carrying out 2000 hours aging, voltage raises also below 10V.Think that this is because the ultraviolet ray of the discharge generation by PDP is absorbed by the ultraviolet screener wall, prevent that thus foreign gas from discharging from the sealing material, thereby the purity that has suppressed discharge gas reduces.
As mentioned above, the PDP in the present embodiment has the structure that forms getter along interior all continuously or intermittentlies of sealing material.According to this structure, owing to can suppressing to be sealing into the purity reduction of the discharge gas between a pair of substrate by getter absorption by the foreign gas that seals material release and through sealing the foreign gas that material is invaded.Therefore, can suppress the rising of discharge voltage.
In addition, owing to can adsorb foreign gas, can prevent that foreign gas is had hygroscopic diaphragm absorption by getter.Thus, the reduction of the secondary electron yield of substrate surface can be suppressed, the rising of discharge voltage can be suppressed.Further, can not be trapped between substrate from the foreign gas of diaphragm disengaging, can be adsorbed by getter at the voltage that applies the stipulated time between substrate (initial burin-in process).Thus, the disengaging of foreign gas can be promptly finished, initial ageing treatment time can be shortened.
In addition, the PDP in the present embodiment has the structure that forms the ultraviolet screener wall along the interior week of above-mentioned sealing material continuously.According to this structure,, can prevent to incide the sealing material because the ultraviolet ray that produces in the inside of sealing panel is absorbed by the ultraviolet screener wall.Thus, can suppress foreign gas and discharge, can suppress the rising of discharge voltage from the sealing material.
And technical scope of the present invention is not limited by the respective embodiments described above, comprises the mode of the respective embodiments described above being carried out various changes without departing from the spirit and scope of the present invention yet.
That is, concrete material of enumerating in each execution mode or structure etc. only are an example, can carry out appropriate change.
For example, in the above-described embodiment, the present invention is applicable to plasma display, but also the present invention can be applicable to the field emission display floater.In the field emission display floater,, itself and fluorophor are collided and luminous from electron emission source (emitter) emitting electrons to vacuum that is configured in each pixel.As concrete field emission display floater, can enumerate field-emitter display (FED, Field Emission Display) with convex electronic emission element or surface-conduction-electron emission display (SED, Surface-Conduction Electron-EmitterDisplay) etc. with surface conductive type electronic emission element.Even when the present invention is applicable to this field emission display floater, also can suppress the rising of discharge voltage.
Utilizability on the industry
The present invention goes in the manufacture method of sealing panel and plasma display.

Claims (9)

1, a kind of sealing panel comprises the sealing material that is configured in the entire circumference between a pair of substrate and contains resin material, and is sealing into discharge gas between described a pair of substrate by described sealing material, it is characterized in that,
Interior all continuously or intermittentlies along described sealing material are formed with adsorption material, and this adsorption material is used to adsorb the foreign gas that is discharged by described sealing material and sees through the foreign gas that described sealing material is invaded.
2, sealing panel according to claim 1 is characterized in that, the sealing material that described sealing material obtains for the resin material that mixes in glass material as adhesive.
3, sealing panel according to claim 1 is characterized in that, described adsorption material is provided with multi-turn with concentric shape.
4, sealing panel according to claim 3 is characterized in that, the described adsorption material of the part in the adsorption material of described multi-turn is assemblied on the described substrate in the described a pair of substrate,
The described adsorption material of remainder in the adsorption material of described multi-turn is assemblied on another described substrate in the described a pair of substrate.
5, according to any described sealing panel in the claim 1~4, it is characterized in that, interior week along described sealing material is formed with the ultraviolet screener wall continuously, and this ultraviolet screener wall is used to shield the ultraviolet ray that produces in the inside of described sealing panel and incides described sealing material.
6, sealing panel according to claim 5 is characterized in that, founds the top of the described ultraviolet screener wall that is located at a described substrate in the described a pair of substrate and another the described substrate in the described a pair of substrate and connects.
According to claim 5 or 6 described sealing panels, it is characterized in that 7, described adsorption material is configured between described sealing material and the described ultraviolet screener wall.
8, according to any described sealing panel in the claim 5~7, it is characterized in that, described sealing panel is a plasma display, described ultraviolet screener wall by and the spaced walls identical materials that is provided between the pixel of described plasma display constitute.
9, a kind of manufacture method of plasma display, described manufacture method is to comprising the sealing material that is configured in the entire circumference between a pair of substrate and contains resin material, and be sealing into the method that the plasma display of the discharge gas between described a pair of substrate is made by described sealing material, it is characterized in that
And the spaced walls that is provided between the pixel of described plasma display forms the ultraviolet screener wall simultaneously, and this ultraviolet screener wall is used to shield the ultraviolet ray that produces in the inside of described plasma display and incides described sealing material.
CN2007800127176A 2006-04-10 2007-04-04 Manufacturing method of sealed panel, and plasma display panel Expired - Fee Related CN101421813B (en)

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PCT/JP2007/057561 WO2007119676A1 (en) 2006-04-10 2007-04-04 Method for manufacturing sealing panel and plasma display panel

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JP4787054B2 (en) 2011-10-05
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RU2395863C2 (en) 2010-07-27
WO2007119676A1 (en) 2007-10-25
EP2009667A1 (en) 2008-12-31
EP2009667B1 (en) 2012-06-13
KR20100116716A (en) 2010-11-01
KR20080110612A (en) 2008-12-18
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CN101421813B (en) 2012-05-30
KR101042036B1 (en) 2011-06-16

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