CN101413332A - Fire-proof type exterior wall composite thermal insulation decorative board and manufacture method thereof - Google Patents

Fire-proof type exterior wall composite thermal insulation decorative board and manufacture method thereof Download PDF

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Publication number
CN101413332A
CN101413332A CNA2008101968688A CN200810196868A CN101413332A CN 101413332 A CN101413332 A CN 101413332A CN A2008101968688 A CNA2008101968688 A CN A2008101968688A CN 200810196868 A CN200810196868 A CN 200810196868A CN 101413332 A CN101413332 A CN 101413332A
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board
layer
insulation
thermal
calcium silicate
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CNA2008101968688A
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Chinese (zh)
Inventor
马保国
穆松
马玲
蹇守卫
王耀城
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武汉科华高新材料发展有限公司
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Priority to CNA2008101968688A priority Critical patent/CN101413332A/en
Publication of CN101413332A publication Critical patent/CN101413332A/en

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Abstract

The invention belongs to the technical field of building materials and particularly relates to a fireproof composite thermal-insulation decorative board for an exterior wall and a preparation method thereof. The fireproof composite thermal-insulation decorative board for the exterior wall is characterized in that the fireproof composite thermal-insulation decorative board for the exterior wall comprises a fireproof thermal insulation layer, a strengthening layer and a decoration layer. The thickness of the fireproof thermal insulation layer is between 30 and 80mm, and the fireproof thermal insulation layer consists of rock wool and a calcium silicate board, or mineral cotton and the calcium silicate board, or a rock wool board and the calcium silicate board, or a mineral cotton board and the calcium silicate board, or one of the mineral cotton board and the rock wool board, wherein the rock wool, the mineral cotton, the rock wool board, and the mineral cotton board are all subjected to hydrophobic treatment by organic silicon. The thickness of the strengthening layer is between 3 and 8mm, and the strengthening layer is polymer mortar or the calcium silicate board. The decoration layer is fluorobcarbon coating, metallic paint, stone like coating or crylic acid emulsion paint. The thermal insulation board is arranged on the wall surface through a mode with the combination of adhesion and anchorage. The invention can prevent the thermal-insulation decorative board for the exterior wall from being burnt and destroyed too early during fire hazards, protect the safety of personal life of personnel and properties in buildings during the fire hazards, and has the advantages of controllable quality of prefabricated forming, assembled construction, and integrated decoration and thermal insulation functions.

Description

Fireproofing external wall composite thermal insulation decorative board and preparation method thereof

One, technical field

The invention belongs to building material technical field, be specifically related to a kind of fireproofing external wall composite thermal insulation decorative board and preparation method thereof.

Two, background technology

At present, architectural energy consumption consumes energy side by side with industrial consumption energy, traffic, becomes three big " big power consumers " of AND ENERGY RESOURCES CONSUMPTION IN CHINA.Especially architectural energy consumption is accompanied by the lifting of the constantly soaring and residence comfort of building total amount, is the trend that sharply raises up.The former vice-minister Chou Baoxing of the Ministry of Construction just pointed out in 2005, and nearly 2,000,000,000 square metres of China's annual town and country newly constructed house building area wherein is the highly energy-consuming building more than 80%; Nearly 40,000,000,000 square metres of existing building is the high energy consumption building more than 95%.Energy consumption is 2 to 3 times in a developed country.According to the chief engineer Wang Tiehong of Ministry of Construction introduction, the energy consumption of building (comprise and build energy consumption, life energy consumption, heating air conditioning etc.) accounts for 30% of whole society's total energy consumption.Therefore, building energy conservation has been the key object in government's energy-saving and emission-reduction work.

Under construction, outwards in the total amount of heat of scattering and disappearing, residential building about 70%~80% outwards scatters and disappears by the heat transfer of space enclosing structure, and in the multi-storey building heat transfer across wall heat consumption, exterior wall accounts for 23%~27%, window 23%~25%, staircase partition wall 6%~11%, roof 7%~8%, balcony door bottom 2%~3%, family door 2%~3%, ground 2%.As seen the thermal losses of peripheral structure is bigger, body of wall has accounted for very great share again in the peripheral structure, so the construction wall reform is a most important link of energy-saving building technology with the development of body of wall power-saving technology, development External Walls Heating Insulation and energy-saving material then are the main implementations of building energy conservation.

External wall outer insulation has consequence as a kind of main External Walls Heating Insulation in new building heat preservation energy-saving and existing building reducing energy consumption.Because it is good that External Thermal Insulation Technology for External has heat preservation and energy conservation effects, do not take indoor floor space, be convenient to building is carried out decoration renovation, not only can prevent that " heat bridge " located to produce dewfall but also can eliminate advantages such as " heat bridges " substantially, so External Thermal Insulation Technology for External is used widely in China's External Walls Heating Insulation now.Yet there are the following problems in actual applications for existing External Thermal Insulation Technology for External:

1. existing external thermal insulation system adopts on-the-spot artificial construction's mode, is difficult to guarantee the heat insulation effect of external thermal insulation system, the cracking of wayward external thermal insulation system;

2. existing external thermal insulation system adopts on-the-spot artificial construction's the required long construction period of mode, and speed of application is slow;

3. having now burns when the external wall outer insulation product is less considers insulation layer organic insulation material fire causes whole external thermal insulation system to lose efficacy, and finally endangers personal life and property safety.

In sum, under existing external thermal insulation system system, exploitation has high security and durability, possess good thermal and insulating performance and decorative effect simultaneously, standardized production, quality controllable, prefabricated profiled fireproofing external wall composite thermal insulation decorative board is significant.China Patent No. is to disclose a kind of warming plate and preparation method thereof in the patent of invention manual of CN 200610053884.2; this warming plate comprises antiwear cement layer; enhancement layer and organic foam plate; but when considering breaking out of fire, this warming plate, plate surface is not decorated processing to the protection of organic foam plate.China Patent No. is manufacture method and the mounting method that discloses multilayer external wall insulation and this warming plate thereof in the patent of invention manual of CN200710023729.0, and this warming plate comprises alkaline-resisting layer, insulation layer with impervious layer.This warming plate is built-in wire with increasing the heat bridge of exterior wall, influences heat insulating effect; When considering breaking out of fire, this warming plate, plate surface is not decorated processing to the protection of organic foam plate yet.China Patent No. is to disclose a kind of rock wool sandwich PLASTIC LAMINATED in the patent of invention manual of ZL 200520122958.4, this PLASTIC LAMINATED is by protected apron, and rock wool and substrate are formed, and wherein protected apron is a color steel, substrate is glass magnesium plate or silica-magnesia panel, is mainly used in the fire prevention important place.This warming plate does not adopt expanded polystyrene foam plastics (EPS), and any one in extrusion molding polystyrene polyfoam (XPS) or the polyurethane foam plastics (PU) do not decorated processing to plate surface as insulation layer.China Patent No. is to disclose a kind of fiber composite type warming plate with fire prevention airing function in the patent of invention manual of ZL 200620200335.9, this warming plate adopts fireproof heat insulating fibrage and organic heat-insulating plate to be composited, wherein have the through hole of having placed the fireproof heat insulating fiber in the organic fiber warming plate, do not design the structure of fireprotection layer, insulation layer, enhancement layer and decorative layer.

In sum, do not consider to adopt in the above-mentioned patent specification to comprise fireproofing external wall composite thermal insulation decorative board of fireproof thermal-insulation layer, enhancement layer and decorative layer and preparation method thereof.

Three, summary of the invention

The object of the present invention is to provide a kind of fireproofing external wall composite thermal insulation decorative board and preparation method thereof, this fireproofing external wall composite thermal insulation decorative board has the high temperature of fire fire prevention, pre-formed quality controllable, construction assemblingization, the incorporate advantage of decorative heat preservation heat insulating function.

To achieve these goals, technical scheme of the present invention is: a kind of fireproofing external wall composite thermal insulation decorative board is characterized in that it comprises fireproof thermal-insulation layer, enhancement layer and decorative layer;

Described fireproof thermal-insulation layer is to avoid outer wall heat insulating and decorating plate premature combustion and destruction in fire.The thickness of fireproof thermal-insulation layer is 30~80mm, and fireproof thermal-insulation layer is made up of rock wool and calcium silicate board, or mineral wool and calcium silicate board form, or rock cotton board forms with calcium silicate board, or mineral wool board and calcium silicate board composition, or a kind of in mineral wool board and the rock cotton board;

Described rock wool, mineral wool, rock cotton board or mineral wool board are all handled through the organosilicon hydrophobisation;

Described enhancement layer is to exterior wall composite thermal insulation decorative board provides required shock resistance, anti-shear performance, waterproof impervious characteristic and cracking resistance.The thickness of enhancement layer is 3~8mm, and enhancement layer is any one in polymer mortar or the calcium silicate board;

Described polymer mortar proportioning is: 250~350 parts of cement, 500~800 parts of middle fine sands, 1.5~30 parts of polymer dispersion powders, 0.3~2 part of water-loss reducer, 0.3~2 part of water reducing agent, 0.1~1 part of defoamer, 200~300 parts in water;

Described decorative layer is fluorine carbon lacquer, metallic paint, any one of true mineral varnish or acrylic latex coating.

2. the preparation method of fireproofing external wall composite thermal insulation decorative board as claimed in claim 1 is characterized in that it comprises the steps:

1) hydrophobisation of fireproof thermal-insulation layer: with rock wool, mineral wool, any one thickness is processed as 30~80mm in rock cotton board or the mineral wool board; The form of construction work that adopts spraying then or soak is covered in rock wool with organosilicon moisture repellent, mineral wool, rock cotton board or mineral wool board surface;

2) preparation of fireproof thermal-insulation layer: the calcium silicate board with microporous that 3~8mm is thick is bonded in above-mentioned rock wool of handling through hydrophobisation, and mineral wool obtains fireproof thermal-insulation layer on any one in rock cotton board or the mineral wool board; Perhaps directly adopt 30~80mm thickness through the mineral wool board of hydrophobisation processing or a kind of fireproof thermal-insulation layer that obtains in the rock cotton board;

3) preparation of enhancement layer: the calcium silicate board with microporous that 3~8mm is thick is bonded in the layer that is enhanced on the thick fireproof thermal-insulation layer of 30~80mm; Perhaps cover the thick polymer mortar of one deck 3~8mm on fireproof thermal-insulation layer, and to place temperature be 20 ± 3 ℃, humidity is maintenance 7 days in the fog room more than 90%, and layer is enhanced;

4) preparation of decorative layer: after fireproof thermal-insulation layer and enhancement layer bonding, at enhancement layer surface spraying fluorine carbon lacquer, metallic paint, any one of true mineral varnish or acrylic latex coating promptly obtains decorative layer;

5) finish above-mentioned steps and promptly obtain the fireproofing external wall composite thermal insulation decorative board, this warming plate is installed on the metope by the mode that bonding combines with anchoring.

The invention has the beneficial effects as follows: the first, by the design fireprotection layer, avoid outer wall heat insulating and decorating plate premature combustion and destruction in fire, interior personnel's person life of building and property safety during the protection breaking out of fire; The second, by the design insulation layer, realize that building is energy-conservation; The 3rd, pre-formed quality controllable, construction assemblingization, the heat insulation outward appearance function integration of decorative heat preservation.

Four, description of drawings

Fig. 1 is a structure diagram of the present invention, and wherein 1 is skin, and 2 is fireproof thermal-insulation layer, and 3 is enhancement layer, and 4 is decorative layer.

Five, the specific embodiment

In order to understand the present invention better, further illustrate content of the present invention below in conjunction with embodiment, but content of the present invention not only is confined to the following examples.

Embodiment 1:

A kind of preparation method of fireproofing external wall composite thermal insulation decorative board, it comprises the steps:

1) hydrophobisation of fireproof thermal-insulation layer: rock wool is processed as 600mm * 600mm * 30mm; Adopt the form of construction work of spraying that organosilicon moisture repellent is covered in the rock wool surface then;

2) preparation of fireproof thermal-insulation layer: the calcium silicate board with microporous that 3~8mm is thick is bonded on the above-mentioned rock wool through the hydrophobisation processing and obtains fireproof thermal-insulation layer;

3) preparation of enhancement layer: according to 300 parts of cement, 600 parts of middle fine sands, 1.5 parts of polymer dispersion powders, 0.3 part of water-loss reducer, 0.3 part of water reducing agent, 0.1 part of defoamer, the ratio that water is 250 parts is mixed and stirred through mixer and to be obtained polymer mortar.The polymer mortar that 3~8mm is thick covers on the fireproof thermal-insulation layer, and to place temperature be 20 ± 3 ℃, and humidity is maintenance 7 days in the fog room more than 90%, and layer is enhanced.

4) preparation of decorative layer: after fireproof thermal-insulation layer and enhancement layer bonding,, promptly obtain decorative layer at enhancement layer surface spraying fluorine carbon lacquer;

5) finish above-mentioned steps and promptly obtain the fireproofing external wall composite thermal insulation decorative board, this warming plate is installed on the metope by the mode that bonding combines with anchoring.

Embodiment 2:

A kind of preparation method of fireproofing external wall composite thermal insulation decorative board, it comprises the steps:

1) hydrophobisation of fireproof thermal-insulation layer: mineral wool is processed as 600mm * 600mm * 50mm; Adopt the form of construction work of soaking that organosilicon moisture repellent is covered in the rock wool surface then;

2) preparation of fireproof thermal-insulation layer: the calcium silicate board with microporous that 3~8mm is thick is bonded on the above-mentioned mineral wool through the hydrophobisation processing and obtains fireproof thermal-insulation layer;

3) preparation of enhancement layer: the calcium silicate board with microporous that 600mm * 600mm * 3mm is thick is bonded in the layer that is enhanced on the fireproof thermal-insulation layer by the agent of acrylic acid gluing;

4) preparation of decorative layer: after fireproof thermal-insulation layer and enhancement layer bonding,, promptly obtain decorative layer at enhancement layer surface spraying acrylic latex coating;

5) finish above-mentioned steps and promptly obtain the fireproofing external wall composite thermal insulation decorative board, this warming plate is installed on the metope by the mode that bonding combines with anchoring.

Embodiment 3:

A kind of preparation method of fireproofing external wall composite thermal insulation decorative board, it comprises the steps:

1) hydrophobisation of fireproof thermal-insulation layer: rock cotton board is processed as 600mm * 600mm * 60mm; Adopt the form of construction work of spraying that organosilicon moisture repellent is covered in the rock cotton board surface then;

2) preparation of fireproof thermal-insulation layer: the calcium silicate board with microporous that 3~8mm is thick is bonded on the above-mentioned rock cotton board through the hydrophobisation processing and obtains fireproof thermal-insulation layer;

3) preparation of enhancement layer: the calcium silicate board with microporous that 600mm * 600mm * 3mm is thick is bonded in the layer that is enhanced on the fireproof thermal-insulation layer by the agent of acrylic acid gluing;

4) preparation of decorative layer: after fireproof thermal-insulation layer and enhancement layer bonding,, promptly obtain decorative layer at spray metal, enhancement layer surface lacquer;

5) finish above-mentioned steps and promptly obtain the fireproofing external wall composite thermal insulation decorative board, this warming plate is installed on the metope by the mode that bonding combines with anchoring.

Embodiment 4:

A kind of preparation method of fireproofing external wall composite thermal insulation decorative board, it comprises the steps:

1) hydrophobisation of fireproof thermal-insulation layer: mineral wool board is processed as 600mm * 600mm * 40mm; Adopt the form of construction work of spraying that organosilicon moisture repellent is covered in the mineral wool board surface then;

2) preparation of fireproof thermal-insulation layer: the calcium silicate board with microporous that 3~8mm is thick is bonded on the above-mentioned mineral wool board through the hydrophobisation processing and obtains fireproof thermal-insulation layer;

3) preparation of enhancement layer: the calcium silicate board with microporous that 600mm * 600mm * 3mm is thick is bonded in the layer that is enhanced on the fireproof thermal-insulation layer by the agent of acrylic acid gluing;

4) preparation of decorative layer: after fireproof thermal-insulation layer and enhancement layer bonding,, promptly obtain decorative layer at the true mineral varnish of enhancement layer surface spraying;

5) finish above-mentioned steps and promptly obtain the fireproofing external wall composite thermal insulation decorative board, this warming plate is installed on the metope by the mode that bonding combines with anchoring.

Claims (2)

1. a fireproofing external wall composite thermal insulation decorative board is characterized in that it comprises fireproof thermal-insulation layer, enhancement layer and decorative layer;
Described fireproof thermal-insulation layer is to avoid outer wall heat insulating and decorating plate premature combustion and destruction in fire.The thickness of fireproof thermal-insulation layer is 30~80mm, and fireproof thermal-insulation layer is made up of rock wool and calcium silicate board, or mineral wool and calcium silicate board form, or rock cotton board forms with calcium silicate board, or mineral wool board and calcium silicate board composition, or a kind of in mineral wool board and the rock cotton board;
Described rock wool, mineral wool, rock cotton board or mineral wool board are all handled through the organosilicon hydrophobisation;
Described enhancement layer is to exterior wall composite thermal insulation decorative board provides required shock resistance, anti-shear performance, waterproof impervious characteristic and cracking resistance.The thickness of enhancement layer is 3~8mm, and enhancement layer is any one in polymer mortar or the calcium silicate board;
Described polymer mortar proportioning is: 250~350 parts of cement, 500~800 parts of middle fine sands, 1.5~30 parts of polymer dispersion powders, 0.3~2 part of water-loss reducer, 0.3~2 part of water reducing agent, 0.1~1 part of defoamer, 200~300 parts in water;
Described decorative layer is fluorine carbon lacquer, metallic paint, any one of true mineral varnish or acrylic latex coating.
2. the preparation method of fireproofing external wall composite thermal insulation decorative board as claimed in claim 1 is characterized in that it comprises the steps:
1) hydrophobisation of fireproof thermal-insulation layer: with rock wool, mineral wool, any one thickness is processed as 30~80mm in rock cotton board or the mineral wool board; The form of construction work that adopts spraying then or soak is covered in rock wool with organosilicon moisture repellent, mineral wool, rock cotton board or mineral wool board surface;
2) preparation of fireproof thermal-insulation layer: the calcium silicate board with microporous that 3~8mm is thick is bonded in above-mentioned rock wool of handling through hydrophobisation, and mineral wool obtains fireproof thermal-insulation layer on any one in rock cotton board or the mineral wool board; Perhaps directly adopt 30~80mm thickness through the mineral wool board of hydrophobisation processing or a kind of fireprotection layer that obtains in the rock cotton board;
3) preparation of enhancement layer: the calcium silicate board with microporous that 3~8mm is thick is bonded in the layer that is enhanced on the thick fireproof thermal-insulation layer of 30~80mm; Perhaps cover the thick polymer mortar of one deck 3~8mm on fireproof thermal-insulation layer, and to place temperature be 20 ± 3 ℃, humidity is maintenance 7 days in the fog room more than 90%, and layer is enhanced;
4) preparation of decorative layer: after fireproof thermal-insulation layer and enhancement layer bonding, at enhancement layer surface spraying fluorine carbon lacquer, metallic paint, any one of true mineral varnish or acrylic latex coating promptly obtains decorative layer;
5) finish above-mentioned steps and promptly obtain the fireproofing external wall composite thermal insulation decorative board, this warming plate is installed on the metope by the mode that bonding combines with anchoring.
CNA2008101968688A 2008-09-05 2008-09-05 Fire-proof type exterior wall composite thermal insulation decorative board and manufacture method thereof CN101413332A (en)

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Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101985847A (en) * 2010-10-25 2011-03-16 陕西精艺氟碳保温有限公司 Construction method for preventing external wall thermal insulation layer from cracking and elastic composite anti-cracking fluorocarbon coating
CN102003051A (en) * 2010-12-03 2011-04-06 上海英硕聚合物材料有限公司 Fireproof decoration and heat insulation integrated board and preparation method thereof
CN102011470A (en) * 2010-12-03 2011-04-13 上海英硕聚合物材料有限公司 Fire prevention, thermal insulation and decoration integrated board
WO2011060684A1 (en) * 2009-11-20 2011-05-26 Dow Global Technologies Inc. Integrated panel for exterior thermal insulation finish systems
CN102304967A (en) * 2011-05-17 2012-01-04 上海英硕聚合材料股份有限公司 Heat preservation and decoration integrated board and preparation method thereof
CN102330474A (en) * 2011-07-12 2012-01-25 江苏康斯维信建筑节能技术有限公司 Three-dimensional reinforced hydrophobic rock wool insulation board
CN102409778A (en) * 2011-08-24 2012-04-11 赵青山 Waterproof and fireproof heat insulation wall
CN102713103A (en) * 2009-11-20 2012-10-03 陶氏环球技术有限责任公司 Integrated panel for exterior thermal insulation finish systems
CN102733495A (en) * 2012-06-18 2012-10-17 北京海纳联创无机纤维喷涂技术有限公司 Waterproof and insulating structure for curtain wall and manufacturing method for waterproof and insulating structure
CN103526874A (en) * 2013-10-31 2014-01-22 深圳海龙建筑制品有限公司 Insulating and decorating integrated composite precast concrete component and manufacturing method thereof
CN104563428A (en) * 2015-01-06 2015-04-29 何昌霖 Compound type decorating thermal insulation panel with cement polymer at double surfaces and preparation method thereof
CN106013646A (en) * 2016-05-13 2016-10-12 湖北卓宝建筑节能科技有限公司 Novel high molecular surface waterproof decoration and insulation composite board and molding process thereof
CN106480987A (en) * 2016-09-28 2017-03-08 广西吉顺能源科技有限公司 Building water-proof heat-insulation integral plate
CN106517900A (en) * 2016-09-28 2017-03-22 广西吉顺能源科技有限公司 Waterproofing, thermal-insulation and decoration integrated board for exterior walls

Cited By (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102713103A (en) * 2009-11-20 2012-10-03 陶氏环球技术有限责任公司 Integrated panel for exterior thermal insulation finish systems
WO2011060684A1 (en) * 2009-11-20 2011-05-26 Dow Global Technologies Inc. Integrated panel for exterior thermal insulation finish systems
CN101985847B (en) * 2010-10-25 2012-05-23 陕西精艺氟碳保温有限公司 Construction method for preventing external wall thermal insulation layer from cracking and elastic composite anti-cracking fluorocarbon coating
CN101985847A (en) * 2010-10-25 2011-03-16 陕西精艺氟碳保温有限公司 Construction method for preventing external wall thermal insulation layer from cracking and elastic composite anti-cracking fluorocarbon coating
CN102003051A (en) * 2010-12-03 2011-04-06 上海英硕聚合物材料有限公司 Fireproof decoration and heat insulation integrated board and preparation method thereof
CN102011470A (en) * 2010-12-03 2011-04-13 上海英硕聚合物材料有限公司 Fire prevention, thermal insulation and decoration integrated board
CN102304967B (en) * 2011-05-17 2014-03-19 上海英硕聚合材料股份有限公司 Heat preservation and decoration integrated board and preparation method thereof
CN102304967A (en) * 2011-05-17 2012-01-04 上海英硕聚合材料股份有限公司 Heat preservation and decoration integrated board and preparation method thereof
CN102330474A (en) * 2011-07-12 2012-01-25 江苏康斯维信建筑节能技术有限公司 Three-dimensional reinforced hydrophobic rock wool insulation board
CN102409778A (en) * 2011-08-24 2012-04-11 赵青山 Waterproof and fireproof heat insulation wall
CN102409778B (en) * 2011-08-24 2014-05-14 赵青山 Waterproof and fireproof heat insulation wall
CN102733495B (en) * 2012-06-18 2014-06-25 北京海纳联创无机纤维喷涂技术有限公司 Waterproof and insulating structure for curtain wall and manufacturing method for waterproof and insulating structure
CN102733495A (en) * 2012-06-18 2012-10-17 北京海纳联创无机纤维喷涂技术有限公司 Waterproof and insulating structure for curtain wall and manufacturing method for waterproof and insulating structure
CN103526874B (en) * 2013-10-31 2016-01-20 深圳海龙建筑制品有限公司 Heat preservation decoration integrative composite concrete prefabricated units and manufacture method thereof
CN103526874A (en) * 2013-10-31 2014-01-22 深圳海龙建筑制品有限公司 Insulating and decorating integrated composite precast concrete component and manufacturing method thereof
CN104563428A (en) * 2015-01-06 2015-04-29 何昌霖 Compound type decorating thermal insulation panel with cement polymer at double surfaces and preparation method thereof
CN106013646A (en) * 2016-05-13 2016-10-12 湖北卓宝建筑节能科技有限公司 Novel high molecular surface waterproof decoration and insulation composite board and molding process thereof
CN106013646B (en) * 2016-05-13 2018-08-24 湖北卓宝建筑节能科技有限公司 A kind of novel high polymer face water-proof decorative thermal insulating composite panel and its moulding process
CN106480987A (en) * 2016-09-28 2017-03-08 广西吉顺能源科技有限公司 Building water-proof heat-insulation integral plate
CN106517900A (en) * 2016-09-28 2017-03-22 广西吉顺能源科技有限公司 Waterproofing, thermal-insulation and decoration integrated board for exterior walls

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