CN101379979B - Sterilizing composition - Google Patents
Sterilizing composition Download PDFInfo
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- CN101379979B CN101379979B CN 200810132986 CN200810132986A CN101379979B CN 101379979 B CN101379979 B CN 101379979B CN 200810132986 CN200810132986 CN 200810132986 CN 200810132986 A CN200810132986 A CN 200810132986A CN 101379979 B CN101379979 B CN 101379979B
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- Prior art keywords
- tpn
- bacterium ester
- composition
- oxime bacterium
- chlorothalonil
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000203 mixture Substances 0.000 title claims abstract description 35
- 230000001954 sterilising effect Effects 0.000 title abstract description 5
- 241000894006 Bacteria Species 0.000 claims description 21
- 150000002148 esters Chemical class 0.000 claims description 20
- 150000002923 oximes Chemical group 0.000 claims description 20
- 239000000375 suspending agent Substances 0.000 claims description 8
- 238000002360 preparation method Methods 0.000 claims description 7
- 230000003641 microbiacidal effect Effects 0.000 claims description 6
- 229940124561 microbicide Drugs 0.000 claims description 6
- 239000002855 microbicide agent Substances 0.000 claims description 6
- 241000233679 Peronosporaceae Species 0.000 claims description 5
- 238000009736 wetting Methods 0.000 claims description 5
- 239000004480 active ingredient Substances 0.000 claims description 4
- 239000000843 powder Substances 0.000 claims description 4
- 239000012752 auxiliary agent Substances 0.000 claims description 3
- 239000008187 granular material Substances 0.000 claims description 2
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 10
- 239000003899 bactericide agent Substances 0.000 abstract description 5
- 239000005747 Chlorothalonil Substances 0.000 abstract description 4
- CRQQGFGUEAVUIL-UHFFFAOYSA-N chlorothalonil Chemical compound ClC1=C(Cl)C(C#N)=C(Cl)C(C#N)=C1Cl CRQQGFGUEAVUIL-UHFFFAOYSA-N 0.000 abstract description 4
- 201000010099 disease Diseases 0.000 abstract description 4
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 abstract description 4
- 239000003814 drug Substances 0.000 abstract description 4
- 239000000575 pesticide Substances 0.000 abstract description 4
- 241001223281 Peronospora Species 0.000 abstract description 3
- 230000000694 effects Effects 0.000 abstract description 3
- 238000001228 spectrum Methods 0.000 abstract description 3
- 229940079593 drug Drugs 0.000 abstract description 2
- 230000010534 mechanism of action Effects 0.000 abstract description 2
- 238000004659 sterilization and disinfection Methods 0.000 abstract description 2
- 239000005857 Trifloxystrobin Substances 0.000 abstract 3
- ONCZDRURRATYFI-TVJDWZFNSA-N trifloxystrobin Chemical compound CO\N=C(\C(=O)OC)C1=CC=CC=C1CO\N=C(/C)C1=CC=CC(C(F)(F)F)=C1 ONCZDRURRATYFI-TVJDWZFNSA-N 0.000 abstract 3
- 239000002131 composite material Substances 0.000 abstract 2
- 239000004615 ingredient Substances 0.000 abstract 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- -1 polyoxyethylene triphenyl phosphorus Polymers 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 238000009472 formulation Methods 0.000 description 4
- 239000000417 fungicide Substances 0.000 description 4
- 238000011835 investigation Methods 0.000 description 4
- 240000008067 Cucumis sativus Species 0.000 description 3
- 235000010799 Cucumis sativus var sativus Nutrition 0.000 description 3
- 230000009102 absorption Effects 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 3
- 239000002270 dispersing agent Substances 0.000 description 3
- 230000000855 fungicidal effect Effects 0.000 description 3
- 230000002195 synergetic effect Effects 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 239000005995 Aluminium silicate Substances 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- 125000005210 alkyl ammonium group Chemical group 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- 230000002528 anti-freeze Effects 0.000 description 2
- 239000013530 defoamer Substances 0.000 description 2
- 239000002552 dosage form Substances 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 238000007689 inspection Methods 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- 230000000361 pesticidal effect Effects 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000002562 thickening agent Substances 0.000 description 2
- 229920001285 xanthan gum Polymers 0.000 description 2
- RNMDNPCBIKJCQP-UHFFFAOYSA-N 5-nonyl-7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-ol Chemical compound C(CCCCCCCC)C1=C2C(=C(C=C1)O)O2 RNMDNPCBIKJCQP-UHFFFAOYSA-N 0.000 description 1
- 241000198596 Alternaria tomatophila Species 0.000 description 1
- NOWKCMXCCJGMRR-UHFFFAOYSA-N Aziridine Chemical compound C1CN1 NOWKCMXCCJGMRR-UHFFFAOYSA-N 0.000 description 1
- 240000004160 Capsicum annuum Species 0.000 description 1
- 235000008534 Capsicum annuum var annuum Nutrition 0.000 description 1
- 240000001008 Dimocarpus longan Species 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 241000221785 Erysiphales Species 0.000 description 1
- 235000000235 Euphoria longan Nutrition 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- 235000007688 Lycopersicon esculentum Nutrition 0.000 description 1
- 239000005802 Mancozeb Substances 0.000 description 1
- JHXVRRJXCDAINK-UHFFFAOYSA-N NC(=O)N.N#CC#N Chemical compound NC(=O)N.N#CC#N JHXVRRJXCDAINK-UHFFFAOYSA-N 0.000 description 1
- 241000233614 Phytophthora Species 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 240000003768 Solanum lycopersicum Species 0.000 description 1
- 244000061456 Solanum tuberosum Species 0.000 description 1
- 235000002595 Solanum tuberosum Nutrition 0.000 description 1
- 235000009754 Vitis X bourquina Nutrition 0.000 description 1
- 235000012333 Vitis X labruscana Nutrition 0.000 description 1
- 240000006365 Vitis vinifera Species 0.000 description 1
- 235000014787 Vitis vinifera Nutrition 0.000 description 1
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 description 1
- 238000001720 action spectrum Methods 0.000 description 1
- 239000003905 agrochemical Substances 0.000 description 1
- WMGSQTMJHBYJMQ-UHFFFAOYSA-N aluminum;magnesium;silicate Chemical compound [Mg+2].[Al+3].[O-][Si]([O-])([O-])[O-] WMGSQTMJHBYJMQ-UHFFFAOYSA-N 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N benzene Substances C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 239000003139 biocide Substances 0.000 description 1
- OIPMQULDKWSNGX-UHFFFAOYSA-N bis[[ethoxy(oxo)phosphaniumyl]oxy]alumanyloxy-ethoxy-oxophosphanium Chemical compound [Al+3].CCO[P+]([O-])=O.CCO[P+]([O-])=O.CCO[P+]([O-])=O OIPMQULDKWSNGX-UHFFFAOYSA-N 0.000 description 1
- 210000005252 bulbus oculi Anatomy 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 230000000857 drug effect Effects 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 230000036039 immunity Effects 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 230000002147 killing effect Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- LCRMGUFGEDUSOG-UHFFFAOYSA-N naphthalen-1-ylsulfonyloxymethyl naphthalene-1-sulfonate;sodium Chemical compound [Na].C1=CC=C2C(S(=O)(OCOS(=O)(=O)C=3C4=CC=CC=C4C=CC=3)=O)=CC=CC2=C1 LCRMGUFGEDUSOG-UHFFFAOYSA-N 0.000 description 1
- 125000003261 o-tolyl group Chemical group [H]C1=C([H])C(*)=C(C([H])=C1[H])C([H])([H])[H] 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- KSVSZLXDULFGDQ-UHFFFAOYSA-M sodium;4-aminobenzenesulfonate Chemical compound [Na+].NC1=CC=C(S([O-])(=O)=O)C=C1 KSVSZLXDULFGDQ-UHFFFAOYSA-M 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 230000009885 systemic effect Effects 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000001238 wet grinding Methods 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a bactericide composite, belonging to the technical field of compounded pesticide. The trifloxystrobin and chlorothalonil compounded pesticide is characterized in that the mixture ratio of the trifloxystrobin and the chlorothalonil is 1:70-20:1. The trifloxystrobin and chlorothalonil compounded pesticide can be used for multiple crops in order to control multiple plant diseases, and has good effects on the Peronospora and the immunoenzyme germina; furthermore, as the ingredients have different mechanism of action to have mutual synergy, the drug fastness of germina is reduced, and the sterilizing effect of the composite is obviously higher than the sterilizing effect when each of the ingredients is singly used, thus having the advantages of synergy and expanding sterilization spectrum, etc.
Description
Technical field
The present invention relates to a kind of microbicide compositions that contains oxime bacterium ester and tpn.Above-mentioned two series bactericidal agents are mixed, can produce unexpected synergistic effect.The invention further relates to the various formulations, particularly bactericidal suspending agent of above-mentioned composition.
Background technology
Oxime bacterium ester biological is a class systemic fungicide, and Peronospora, Phytophthora fungi are had good killing effect.But when alone the sterilization duration short, protection effect is not ideal, if with some in absorption or protective fungicide make composition, their bactericidal effect can have the increase of surprising degree.
The composition of absorption in some, contact and soil fungicides and oxime bacterium ester biological composition has been introduced by Switzerland Novartis Co.,Ltd in patent EP472300, in these, absorptions, contact and soil fungicides comprise Jiameiling, white urea cyanogen, aliette, mancozeb, the spirit of gram bacterium etc.Above-mentioned composition is made the regular dosage forms such as wetting powder, suspending agent, emulsion, and these formulations are generally that after the prolonged application dilution, foliar spray uses, and effect is bad, resistance produces fast.
Tpn is the protectiveness wide-spectrum bactericide, at plant surface, good adhesivity is arranged, and longevity of residure 7-10 days, can prevent and treat downy mildew on crop, gray mold, powdery mildew, anthracnose, early blight of tomato etc.Various mix preparations to tpn in prior art have report, as disclosing the tpn biocide preparation in CN1212834.
When above-mentioned oxime bacterium ester and chlorothalonil used separately, the bactericidal action spectrum was narrow, and dosage is large, and the longevity of residure is short, easily develops immunity to drugs.In order to overcome above-mentioned weak point, the inventor is surprised to find that oxime bacterium ester is mixed use with tpn to have unexpected synergistic effect through the further investigation screening.The inventor has also developed the various formulations of above-mentioned composition, particularly its bactericide suspending agent, thereby has completed the present invention.
Summary of the invention
The present invention relates to a kind of microbicide compositions that contains oxime bacterium ester and tpn.The structure formula as described below (I) of oxime bacterium ester in the present invention:
At above-mentioned oxime bacterium ester bactericide chemical name: (E)-methoxy imino-(E)-a-[1--(a, a, a-trifluoromethyl-m-phenyl) ethyleneimine oxygen] and o-tolyl } methyl acetate.The chemical name of tpn is tetrachloro-1,3-benzene diformazan eyeball.
Also have the oxime bacterium ester of formula (I) of synergy effective dose and the tpn of formula (II) in the application's composition.Preferably, the mixing ratio of the formula that contains in the present composition (I) oxime bacterium ester and tpn, with the weight of active constituent count 1: 70～20: 1, preferred 1: 50～10: 1, more preferably 1: 20～5: 1.
Above-mentioned composition of the present invention can be mixed with various dosage forms, the formulations such as wetting powder, granule, suspended emulsion.Can also comprise various surfactants, auxiliary agent or the carrier of preparing pesticidal preparations in above-mentioned preparation.Active ingredient accounts for 0.5%～95% weight of composition total weight in preparation, preferred 1%～70% weight.
The mechanism of action of the various compositions of composition of the present invention is different, synergy mutually between them, and the pesticide resistance of germ reduces, so the bactericidal effect the when bactericidal effect of composition is alone apparently higher than each component namely have synergistic effect, and fungicidal spectrum is wider.
Composition of the present invention can be used for various crop prevent and treat multiple diseases, mainly to Peronospora, the epidemic disease enzyme belongs to germ that good inhibition is arranged.Can be used for cucumber, grape, tomato, potato, longan, pimento etc., double controlling by other germ disease.And has a good control efficiency.
Embodiment
Embodiment 1:
The auxiliary agent of suspending agent has wetting agent 1～11%, antifreeze 1～3%, thickener 0.1～3%, defoamer 0.1～3% and media assemblage, and per distribution ratio is for accounting for composition raw bactericidal material weight percent proportioning.Wetting dispersing agent in suspending agent adopts a kind of or mixture in polyoxyethylene triphenyl phosphorus hydrochlorate, alkylnaphthalene sulfonate, polyaryl phenol polyoxy ethyl ether phosphate alkylammonium salt; Antifreeze adopts a kind of in propane diols, glycerine, ethylene glycol; Thickener adopts xanthans or aluminium-magnesium silicate; Defoamer adopts silicone defoaming agent; Filler adopts water; With oxime bacterium ester 10g, tpn 40g, polyaryl phenol polyoxy ethyl ether phosphate alkylammonium salt 6g, ethylene glycol 8g, xanthans 0.4g, organosilicon 0.1g, water is mended to 100g.Through processing to get 50% oxime bacterium ester tpn suspending agent.
Embodiment 2:
Oxime bacterium ester 5g, tpn 45g, polyoxyethylene nonylphenol ether 4g, dispersing agent NNO 3g, polyvinyl alcohol 1.2g, sodium bicarbonate 1g, bentonite 30g, kaolin are added to 100g, make 50% oxime bacterium ester tpn dispersibility granula through pulverizing granulation.
Embodiment 3:
With oxime bacterium ester 20g, tpn 50g, detergent LS (to methoxyl group fatty acid Sodium p-aminobenzene sulfonat) 2g, dispersing agent NNO (sodium methylene bis-naphthalene sulfonate) 4g, white carbon 5g, kaolin adds to 100g, mixture carries out air-flow crushing, makes 70% oxime bacterium ester tpn wetting powder.
Test with the pesticidal preparations control cucumber downy mildew that above-described embodiment makes.
1, test is processed: this test medicine consumption is established respectively three concentration for the treatment of according to the difference of each composition, but the contrast medicament is respectively commercially available agricultural chemicals 70% tpn wet-milling (WP) and 12.5% oxime bacterium ester suspending agent and the test of blank clear water.
2, test method: each residential quarter area repeats 3 times for becoming the age fruit tree to be no less than 2 strains; Inspection drug effect method after the front Investigation and Prevention of dispenser is: investigation two strains in every residential quarter, every strain press East, West, South, North, in 5 samplings, every some investigation 2 fringes record total spike number and sick spike number at different levels, inspection downy mildew occurrence degree.
3, result of the test is as follows:
Annotate: a is illustrated on α=0.05 level remarkable, and b is illustrated on α=0.05 level variant, and c is illustrated on α=0.05 level not remarkable.
The field efficacy result shows, oxime bacterium ester and tpn composition have good control efficiency to cucumber downy mildew, and control efficiency all is better than the single dose kind.
Claims (4)
1. microbicide compositions, active ingredient is oxime bacterium ester and tpn, it is characterized in that: the weight ratio of oxime bacterium ester and tpn is 2: 5～1: 9.
2. microbicide compositions according to claim 1, is characterized in that, adds auxiliary agent to make suspending agent, granule, wetting powder, and in preparation, the content of active ingredient accounts for 0.5%～95% weight of composition total weight.
3. microbicide compositions according to claim 2, is characterized in that, the content of active ingredient accounts for 1%～70% weight of composition total weight.
4. composition according to claim 1 is used for preventing and treating the purposes of downy mildew.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200810132986 CN101379979B (en) | 2008-07-04 | 2008-07-04 | Sterilizing composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200810132986 CN101379979B (en) | 2008-07-04 | 2008-07-04 | Sterilizing composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101379979A CN101379979A (en) | 2009-03-11 |
| CN101379979B true CN101379979B (en) | 2013-06-05 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200810132986 Expired - Fee Related CN101379979B (en) | 2008-07-04 | 2008-07-04 | Sterilizing composition |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101379979B (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5793883B2 (en) | 2010-03-03 | 2015-10-14 | 住友化学株式会社 | Plant disease control composition and plant disease control method |
| CN102047875A (en) * | 2010-12-21 | 2011-05-11 | 威海韩孚生化药业有限公司 | Trifloxystrobin suspending agent and preparation method thereof |
| GB2532700B (en) * | 2013-11-26 | 2016-08-31 | Upl Ltd | A method for controlling rust |
| CN110199993B (en) * | 2019-06-06 | 2021-05-04 | 青岛润农化工有限公司 | Sterilization composition containing chlorothalonil, trifloxystrobin and cyproconazole and application thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1212834A (en) * | 1997-09-26 | 1999-04-07 | 化学工业部沈阳化工研究院 | Dimetachlone-chlorothalonil bactericidal agent |
| CN1228919A (en) * | 1998-12-16 | 1999-09-22 | 余永功 | Cymoxanil and chlorothalonil compound agent |
| CN1922997A (en) * | 2006-09-14 | 2007-03-07 | 同济大学 | Trifloxystrobin water dispersion particles and preparing method thereof |
-
2008
- 2008-07-04 CN CN 200810132986 patent/CN101379979B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1212834A (en) * | 1997-09-26 | 1999-04-07 | 化学工业部沈阳化工研究院 | Dimetachlone-chlorothalonil bactericidal agent |
| CN1228919A (en) * | 1998-12-16 | 1999-09-22 | 余永功 | Cymoxanil and chlorothalonil compound agent |
| CN1922997A (en) * | 2006-09-14 | 2007-03-07 | 同济大学 | Trifloxystrobin water dispersion particles and preparing method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 汪汉成等.肟菌酯对9 种植物病原真菌室内活性测定.《农药》.2006,第45卷(第11期),780、781、789. * |
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| CN101379979A (en) | 2009-03-11 |
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Effective date of registration: 20161221 Address after: 715500 Shaanxi Pucheng County agricultural base industrial park Patentee after: Shaanxi Meibang Pesticides Co., Ltd. Address before: 715500 Pucheng province Shaanxi County Chengguan Town Food City Street No. 23 Patentee before: Zhang Shaowu |
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