CN101374673A - 用于标记基材的涂料组合物 - Google Patents
用于标记基材的涂料组合物 Download PDFInfo
- Publication number
- CN101374673A CN101374673A CNA2007800038929A CN200780003892A CN101374673A CN 101374673 A CN101374673 A CN 101374673A CN A2007800038929 A CNA2007800038929 A CN A2007800038929A CN 200780003892 A CN200780003892 A CN 200780003892A CN 101374673 A CN101374673 A CN 101374673A
- Authority
- CN
- China
- Prior art keywords
- composition
- methyl
- fluorane
- acid
- monomer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000758 substrate Substances 0.000 title claims abstract description 11
- 239000008199 coating composition Substances 0.000 title claims description 23
- 239000000203 mixture Substances 0.000 claims abstract description 75
- 238000000034 method Methods 0.000 claims abstract description 31
- 239000012190 activator Substances 0.000 claims abstract description 17
- 229910000040 hydrogen fluoride Inorganic materials 0.000 claims description 79
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 claims description 50
- -1 triarylmethane Chemical compound 0.000 claims description 50
- 239000000463 material Substances 0.000 claims description 29
- 239000002253 acid Substances 0.000 claims description 26
- 239000011230 binding agent Substances 0.000 claims description 20
- 239000002904 solvent Substances 0.000 claims description 16
- 150000001412 amines Chemical class 0.000 claims description 13
- WNZQDUSMALZDQF-UHFFFAOYSA-N 2-benzofuran-1(3H)-one Chemical compound C1=CC=C2C(=O)OCC2=C1 WNZQDUSMALZDQF-UHFFFAOYSA-N 0.000 claims description 11
- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 claims description 6
- BCHZICNRHXRCHY-UHFFFAOYSA-N 2h-oxazine Chemical compound N1OC=CC=C1 BCHZICNRHXRCHY-UHFFFAOYSA-N 0.000 claims description 4
- 150000003839 salts Chemical class 0.000 claims description 4
- CMLFRMDBDNHMRA-UHFFFAOYSA-N 2h-1,2-benzoxazine Chemical compound C1=CC=C2C=CNOC2=C1 CMLFRMDBDNHMRA-UHFFFAOYSA-N 0.000 claims description 3
- 230000009189 diving Effects 0.000 claims description 3
- JWVCLYRUEFBMGU-UHFFFAOYSA-N quinazoline Chemical compound N1=CN=CC2=CC=CC=C21 JWVCLYRUEFBMGU-UHFFFAOYSA-N 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 abstract description 10
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 72
- 239000000178 monomer Substances 0.000 description 50
- 229920000642 polymer Polymers 0.000 description 38
- 239000002585 base Substances 0.000 description 25
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical class OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 23
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 21
- 239000000123 paper Substances 0.000 description 16
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical group CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 15
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 15
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 15
- 150000002148 esters Chemical group 0.000 description 14
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 13
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical group C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 12
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 11
- CERQOIWHTDAKMF-UHFFFAOYSA-N alpha-methacrylic acid Natural products CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 10
- 238000000576 coating method Methods 0.000 description 10
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 9
- 125000003368 amide group Chemical group 0.000 description 9
- 239000011248 coating agent Substances 0.000 description 9
- 238000003384 imaging method Methods 0.000 description 9
- 150000005846 sugar alcohols Polymers 0.000 description 9
- 229920002554 vinyl polymer Polymers 0.000 description 9
- 239000004372 Polyvinyl alcohol Substances 0.000 description 8
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 8
- 150000001735 carboxylic acids Chemical class 0.000 description 8
- 229960004194 lidocaine Drugs 0.000 description 8
- 150000003016 phosphoric acids Chemical class 0.000 description 8
- 239000000049 pigment Substances 0.000 description 8
- 229920002451 polyvinyl alcohol Polymers 0.000 description 8
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 8
- 239000003960 organic solvent Substances 0.000 description 7
- 125000001741 organic sulfur group Chemical group 0.000 description 7
- 229920000058 polyacrylate Polymers 0.000 description 7
- 238000007070 tosylation reaction Methods 0.000 description 7
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 6
- 150000007513 acids Chemical class 0.000 description 6
- 239000007864 aqueous solution Substances 0.000 description 6
- 239000000706 filtrate Substances 0.000 description 6
- 238000001556 precipitation Methods 0.000 description 6
- 239000012266 salt solution Substances 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- BBDNZMUIQBRBJH-UHFFFAOYSA-N sulfurochloridic acid;toluene Chemical compound OS(Cl)(=O)=O.CC1=CC=CC=C1 BBDNZMUIQBRBJH-UHFFFAOYSA-N 0.000 description 6
- 238000005406 washing Methods 0.000 description 6
- 125000006564 (C4-C8) cycloalkyl group Chemical group 0.000 description 5
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 5
- 150000001299 aldehydes Chemical class 0.000 description 5
- 150000001408 amides Chemical class 0.000 description 5
- 125000003710 aryl alkyl group Chemical group 0.000 description 5
- 125000003118 aryl group Chemical group 0.000 description 5
- 150000001722 carbon compounds Chemical class 0.000 description 5
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 5
- 239000001257 hydrogen Substances 0.000 description 5
- 229910052739 hydrogen Inorganic materials 0.000 description 5
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 5
- 239000003550 marker Substances 0.000 description 5
- 229920000728 polyester Polymers 0.000 description 5
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 5
- IMNIMPAHZVJRPE-UHFFFAOYSA-N triethylenediamine Chemical compound C1CN2CCN1CC2 IMNIMPAHZVJRPE-UHFFFAOYSA-N 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 125000000081 (C5-C8) cycloalkenyl group Chemical group 0.000 description 4
- MAGFQRLKWCCTQJ-UHFFFAOYSA-N 4-ethenylbenzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=C(C=C)C=C1 MAGFQRLKWCCTQJ-UHFFFAOYSA-N 0.000 description 4
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 4
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 4
- 125000000739 C2-C30 alkenyl group Chemical group 0.000 description 4
- 241001597008 Nomeidae Species 0.000 description 4
- 239000004698 Polyethylene Substances 0.000 description 4
- 230000002745 absorbent Effects 0.000 description 4
- 239000002250 absorbent Substances 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 4
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 4
- 150000001298 alcohols Chemical class 0.000 description 4
- 125000005018 aryl alkenyl group Chemical group 0.000 description 4
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 4
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 4
- 239000000460 chlorine Substances 0.000 description 4
- 229910052801 chlorine Inorganic materials 0.000 description 4
- 239000011976 maleic acid Substances 0.000 description 4
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 4
- 229920000573 polyethylene Polymers 0.000 description 4
- 229920002635 polyurethane Polymers 0.000 description 4
- 239000004814 polyurethane Substances 0.000 description 4
- 229920002689 polyvinyl acetate Polymers 0.000 description 4
- 239000011118 polyvinyl acetate Substances 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 4
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 4
- 239000002966 varnish Substances 0.000 description 4
- LNAZSHAWQACDHT-XIYTZBAFSA-N (2r,3r,4s,5r,6s)-4,5-dimethoxy-2-(methoxymethyl)-3-[(2s,3r,4s,5r,6r)-3,4,5-trimethoxy-6-(methoxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6r)-4,5,6-trimethoxy-2-(methoxymethyl)oxan-3-yl]oxyoxane Chemical compound CO[C@@H]1[C@@H](OC)[C@H](OC)[C@@H](COC)O[C@H]1O[C@H]1[C@H](OC)[C@@H](OC)[C@H](O[C@H]2[C@@H]([C@@H](OC)[C@H](OC)O[C@@H]2COC)OC)O[C@@H]1COC LNAZSHAWQACDHT-XIYTZBAFSA-N 0.000 description 3
- LIZLYZVAYZQVPG-UHFFFAOYSA-N (3-bromo-2-fluorophenyl)methanol Chemical compound OCC1=CC=CC(Br)=C1F LIZLYZVAYZQVPG-UHFFFAOYSA-N 0.000 description 3
- IVSZLXZYQVIEFR-UHFFFAOYSA-N 1,3-Dimethylbenzene Natural products CC1=CC=CC(C)=C1 IVSZLXZYQVIEFR-UHFFFAOYSA-N 0.000 description 3
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
- ZTQSAGDEMFDKMZ-UHFFFAOYSA-N Butyraldehyde Chemical compound CCCC=O ZTQSAGDEMFDKMZ-UHFFFAOYSA-N 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- 239000004952 Polyamide Substances 0.000 description 3
- 239000004743 Polypropylene Substances 0.000 description 3
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 3
- 229930006000 Sucrose Natural products 0.000 description 3
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- LPQOADBMXVRBNX-UHFFFAOYSA-N ac1ldcw0 Chemical compound Cl.C1CN(C)CCN1C1=C(F)C=C2C(=O)C(C(O)=O)=CN3CCSC1=C32 LPQOADBMXVRBNX-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 235000013877 carbamide Nutrition 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 239000011111 cardboard Substances 0.000 description 3
- 229920002678 cellulose Polymers 0.000 description 3
- 239000001913 cellulose Substances 0.000 description 3
- 235000010980 cellulose Nutrition 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 150000002016 disaccharides Chemical class 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
- MDQRDWAGHRLBPA-UHFFFAOYSA-N fluoroamine Chemical compound FN MDQRDWAGHRLBPA-UHFFFAOYSA-N 0.000 description 3
- 229910052736 halogen Inorganic materials 0.000 description 3
- 150000002367 halogens Chemical class 0.000 description 3
- 229910001385 heavy metal Inorganic materials 0.000 description 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 3
- 229920000609 methyl cellulose Polymers 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 239000001923 methylcellulose Substances 0.000 description 3
- 229960002900 methylcellulose Drugs 0.000 description 3
- 235000010981 methylcellulose Nutrition 0.000 description 3
- 229920005615 natural polymer Polymers 0.000 description 3
- 150000002924 oxiranes Chemical class 0.000 description 3
- 229920002647 polyamide Polymers 0.000 description 3
- 229920000098 polyolefin Polymers 0.000 description 3
- 229920001155 polypropylene Polymers 0.000 description 3
- 238000003892 spreading Methods 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 239000005720 sucrose Substances 0.000 description 3
- WHOZNOZYMBRCBL-OUKQBFOZSA-N (2E)-2-Tetradecenal Chemical compound CCCCCCCCCCC\C=C\C=O WHOZNOZYMBRCBL-OUKQBFOZSA-N 0.000 description 2
- PNLVGFSEHLOUTK-UHFFFAOYSA-N 2-(bromomethyl)pentanedinitrile Chemical compound BrCC(C#N)CCC#N PNLVGFSEHLOUTK-UHFFFAOYSA-N 0.000 description 2
- AGIJRRREJXSQJR-UHFFFAOYSA-N 2h-thiazine Chemical compound N1SC=CC=C1 AGIJRRREJXSQJR-UHFFFAOYSA-N 0.000 description 2
- GPBLVTFWNRNYKR-UHFFFAOYSA-N 3-(1-ethyl-2-methylindol-3-yl)-3h-2-benzofuran-1-one Chemical compound C12=CC=CC=C2N(CC)C(C)=C1C1C2=CC=CC=C2C(=O)O1 GPBLVTFWNRNYKR-UHFFFAOYSA-N 0.000 description 2
- PYSRRFNXTXNWCD-UHFFFAOYSA-N 3-(2-phenylethenyl)furan-2,5-dione Chemical compound O=C1OC(=O)C(C=CC=2C=CC=CC=2)=C1 PYSRRFNXTXNWCD-UHFFFAOYSA-N 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 2
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical group ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- 239000001856 Ethyl cellulose Substances 0.000 description 2
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- 108010010803 Gelatin Proteins 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 2
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- 229920000877 Melamine resin Polymers 0.000 description 2
- BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 description 2
- UAEPNZWRGJTJPN-UHFFFAOYSA-N Methylcyclohexane Natural products CC1CCCCC1 UAEPNZWRGJTJPN-UHFFFAOYSA-N 0.000 description 2
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 239000004695 Polyether sulfone Substances 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- 229920000147 Styrene maleic anhydride Polymers 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- SMEGJBVQLJJKKX-HOTMZDKISA-N [(2R,3S,4S,5R,6R)-5-acetyloxy-3,4,6-trihydroxyoxan-2-yl]methyl acetate Chemical compound CC(=O)OC[C@@H]1[C@H]([C@@H]([C@H]([C@@H](O1)O)OC(=O)C)O)O SMEGJBVQLJJKKX-HOTMZDKISA-N 0.000 description 2
- 229940081735 acetylcellulose Drugs 0.000 description 2
- 239000001361 adipic acid Substances 0.000 description 2
- 235000011037 adipic acid Nutrition 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 125000003342 alkenyl group Chemical group 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- SRSXLGNVWSONIS-UHFFFAOYSA-N benzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-N 0.000 description 2
- 229940092714 benzenesulfonic acid Drugs 0.000 description 2
- 230000003115 biocidal effect Effects 0.000 description 2
- 239000003139 biocide Substances 0.000 description 2
- HQABUPZFAYXKJW-UHFFFAOYSA-N butan-1-amine Chemical compound CCCCN HQABUPZFAYXKJW-UHFFFAOYSA-N 0.000 description 2
- BTANRVKWQNVYAZ-UHFFFAOYSA-N butan-2-ol Chemical compound CCC(C)O BTANRVKWQNVYAZ-UHFFFAOYSA-N 0.000 description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 239000001768 carboxy methyl cellulose Substances 0.000 description 2
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 2
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 2
- 229940105329 carboxymethylcellulose Drugs 0.000 description 2
- 239000005018 casein Substances 0.000 description 2
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 2
- 235000021240 caseins Nutrition 0.000 description 2
- 229920002301 cellulose acetate Polymers 0.000 description 2
- 229920001940 conductive polymer Polymers 0.000 description 2
- 150000001896 cresols Chemical class 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 125000000392 cycloalkenyl group Chemical group 0.000 description 2
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 2
- PAFZNILMFXTMIY-UHFFFAOYSA-N cyclohexylamine Chemical compound NC1CCCCC1 PAFZNILMFXTMIY-UHFFFAOYSA-N 0.000 description 2
- SWXVUIWOUIDPGS-UHFFFAOYSA-N diacetone alcohol Chemical compound CC(=O)CC(C)(C)O SWXVUIWOUIDPGS-UHFFFAOYSA-N 0.000 description 2
- 150000001991 dicarboxylic acids Chemical class 0.000 description 2
- JXTHNDFMNIQAHM-UHFFFAOYSA-N dichloroacetic acid Chemical compound OC(=O)C(Cl)Cl JXTHNDFMNIQAHM-UHFFFAOYSA-N 0.000 description 2
- 125000005442 diisocyanate group Chemical group 0.000 description 2
- 125000003700 epoxy group Chemical group 0.000 description 2
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 description 2
- BSVPCNKYMRZJDJ-UHFFFAOYSA-N ethyl 4-(4-methylphenyl)sulfonylcyclohexane-1-carboxylate Chemical compound C1CC(C(=O)OCC)CCC1S(=O)(=O)C1=CC=C(C)C=C1 BSVPCNKYMRZJDJ-UHFFFAOYSA-N 0.000 description 2
- 235000019325 ethyl cellulose Nutrition 0.000 description 2
- 229920001249 ethyl cellulose Polymers 0.000 description 2
- 229960004667 ethyl cellulose Drugs 0.000 description 2
- HYBBIBNJHNGZAN-UHFFFAOYSA-N furfural Chemical compound O=CC1=CC=CO1 HYBBIBNJHNGZAN-UHFFFAOYSA-N 0.000 description 2
- 229920000159 gelatin Polymers 0.000 description 2
- 239000008273 gelatin Substances 0.000 description 2
- 235000019322 gelatine Nutrition 0.000 description 2
- 235000011852 gelatine desserts Nutrition 0.000 description 2
- 150000004676 glycans Chemical class 0.000 description 2
- 229920000578 graft copolymer Polymers 0.000 description 2
- 125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 238000005984 hydrogenation reaction Methods 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 2
- 229940071826 hydroxyethyl cellulose Drugs 0.000 description 2
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 2
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 2
- WFKAJVHLWXSISD-UHFFFAOYSA-N isobutyramide Chemical compound CC(C)C(N)=O WFKAJVHLWXSISD-UHFFFAOYSA-N 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- 125000000686 lactone group Chemical group 0.000 description 2
- 239000002648 laminated material Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- UTEFBSAVJNEPTR-RGEXLXHISA-N loprazolam Chemical compound C1CN(C)CCN1\C=C/1C(=O)N2C3=CC=C([N+]([O-])=O)C=C3C(C=3C(=CC=CC=3)Cl)=NCC2=N\1 UTEFBSAVJNEPTR-RGEXLXHISA-N 0.000 description 2
- 229960003019 loprazolam Drugs 0.000 description 2
- 229920001684 low density polyethylene Polymers 0.000 description 2
- 239000004702 low-density polyethylene Substances 0.000 description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 2
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 2
- 239000001254 oxidized starch Substances 0.000 description 2
- 235000013808 oxidized starch Nutrition 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229940044654 phenolsulfonic acid Drugs 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 2
- 229920002492 poly(sulfone) Polymers 0.000 description 2
- 229920000647 polyepoxide Polymers 0.000 description 2
- 229920006393 polyether sulfone Polymers 0.000 description 2
- 229920005644 polyethylene terephthalate glycol copolymer Polymers 0.000 description 2
- 239000004926 polymethyl methacrylate Substances 0.000 description 2
- 229920001282 polysaccharide Polymers 0.000 description 2
- 239000005017 polysaccharide Substances 0.000 description 2
- 239000004800 polyvinyl chloride Substances 0.000 description 2
- 229920000915 polyvinyl chloride Polymers 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- WGYKZJWCGVVSQN-UHFFFAOYSA-N propylamine Chemical compound CCCN WGYKZJWCGVVSQN-UHFFFAOYSA-N 0.000 description 2
- 239000006254 rheological additive Substances 0.000 description 2
- 230000000630 rising effect Effects 0.000 description 2
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 2
- 239000000779 smoke Substances 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- 125000000472 sulfonyl group Chemical group *S(*)(=O)=O 0.000 description 2
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N urea group Chemical group NC(=O)N XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 150000003672 ureas Chemical class 0.000 description 2
- 239000000080 wetting agent Substances 0.000 description 2
- 239000008096 xylene Substances 0.000 description 2
- 150000003739 xylenols Chemical class 0.000 description 2
- NOOLISFMXDJSKH-KXUCPTDWSA-N (-)-Menthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@H]1O NOOLISFMXDJSKH-KXUCPTDWSA-N 0.000 description 1
- XVOCEKOSQBFFHW-UHFFFAOYSA-N (5-methyl-2-propan-2-ylcyclohexyl) 4-methylbenzenesulfonate Chemical compound CC(C)C1CCC(C)CC1OS(=O)(=O)C1=CC=C(C)C=C1 XVOCEKOSQBFFHW-UHFFFAOYSA-N 0.000 description 1
- QVCUKHQDEZNNOC-UHFFFAOYSA-N 1,2-diazabicyclo[2.2.2]octane Chemical compound C1CC2CCN1NC2 QVCUKHQDEZNNOC-UHFFFAOYSA-N 0.000 description 1
- 150000000182 1,3,5-triazines Chemical class 0.000 description 1
- KEQGZUUPPQEDPF-UHFFFAOYSA-N 1,3-dichloro-5,5-dimethylimidazolidine-2,4-dione Chemical compound CC1(C)N(Cl)C(=O)N(Cl)C1=O KEQGZUUPPQEDPF-UHFFFAOYSA-N 0.000 description 1
- OZCMOJQQLBXBKI-UHFFFAOYSA-N 1-ethenoxy-2-methylpropane Chemical compound CC(C)COC=C OZCMOJQQLBXBKI-UHFFFAOYSA-N 0.000 description 1
- JRHWLHPETPZHDD-UHFFFAOYSA-N 1-n,1-n-dibutyl-4-chloro-3-n-fluorobenzene-1,3-diamine Chemical compound CCCCN(CCCC)C1=CC=C(Cl)C(NF)=C1 JRHWLHPETPZHDD-UHFFFAOYSA-N 0.000 description 1
- OWEGMIWEEQEYGQ-UHFFFAOYSA-N 100676-05-9 Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC2C(OC(O)C(O)C2O)CO)O1 OWEGMIWEEQEYGQ-UHFFFAOYSA-N 0.000 description 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- DPBJAVGHACCNRL-UHFFFAOYSA-N 2-(dimethylamino)ethyl prop-2-enoate Chemical compound CN(C)CCOC(=O)C=C DPBJAVGHACCNRL-UHFFFAOYSA-N 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- UXFQFBNBSPQBJW-UHFFFAOYSA-N 2-amino-2-methylpropane-1,3-diol Chemical compound OCC(N)(C)CO UXFQFBNBSPQBJW-UHFFFAOYSA-N 0.000 description 1
- DRNNATGSBCVJBN-UHFFFAOYSA-N 2-amino-2-methylpropane-1-sulfonic acid Chemical compound CC(C)(N)CS(O)(=O)=O DRNNATGSBCVJBN-UHFFFAOYSA-N 0.000 description 1
- GOJUJUVQIVIZAV-UHFFFAOYSA-N 2-amino-4,6-dichloropyrimidine-5-carbaldehyde Chemical group NC1=NC(Cl)=C(C=O)C(Cl)=N1 GOJUJUVQIVIZAV-UHFFFAOYSA-N 0.000 description 1
- 229940100555 2-methyl-4-isothiazolin-3-one Drugs 0.000 description 1
- NDVWOBYBJYUSMF-UHFFFAOYSA-N 2-methylcyclohexan-1-ol Chemical compound CC1CCCCC1O NDVWOBYBJYUSMF-UHFFFAOYSA-N 0.000 description 1
- 125000004135 2-norbornyl group Chemical group [H]C1([H])C([H])([H])C2([H])C([H])([H])C1([H])C([H])([H])C2([H])* 0.000 description 1
- ONJRTQUWKRDCTA-UHFFFAOYSA-N 2h-thiochromene Chemical class C1=CC=C2C=CCSC2=C1 ONJRTQUWKRDCTA-UHFFFAOYSA-N 0.000 description 1
- XMIOCDZWGCXLIO-UHFFFAOYSA-N 3h-benzo[f][1,4]benzoxazine Chemical compound C1=CC=CC2=C(N=CCO3)C3=CC=C21 XMIOCDZWGCXLIO-UHFFFAOYSA-N 0.000 description 1
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 1
- JCIDEANDDNSHQC-UHFFFAOYSA-N 4H-chromene Chemical compound C1=CC=C2CC=COC2=C1 JCIDEANDDNSHQC-UHFFFAOYSA-N 0.000 description 1
- RXQNKKRGJJRMKD-UHFFFAOYSA-N 5-bromo-2-methylaniline Chemical compound CC1=CC=C(Br)C=C1N RXQNKKRGJJRMKD-UHFFFAOYSA-N 0.000 description 1
- 244000215068 Acacia senegal Species 0.000 description 1
- GUBGYTABKSRVRQ-XLOQQCSPSA-N Alpha-Lactose Chemical compound O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)O[C@H](O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-XLOQQCSPSA-N 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- 125000000882 C2-C6 alkenyl group Chemical group 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 229920000858 Cyclodextrin Polymers 0.000 description 1
- GUBGYTABKSRVRQ-CUHNMECISA-N D-Cellobiose Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-CUHNMECISA-N 0.000 description 1
- YTBSYETUWUMLBZ-UHFFFAOYSA-N D-Erythrose Natural products OCC(O)C(O)C=O YTBSYETUWUMLBZ-UHFFFAOYSA-N 0.000 description 1
- UNXHWFMMPAWVPI-QWWZWVQMSA-N D-Threitol Natural products OC[C@@H](O)[C@H](O)CO UNXHWFMMPAWVPI-QWWZWVQMSA-N 0.000 description 1
- YTBSYETUWUMLBZ-IUYQGCFVSA-N D-erythrose Chemical compound OC[C@@H](O)[C@@H](O)C=O YTBSYETUWUMLBZ-IUYQGCFVSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- WQZGKKKJIJFFOK-QTVWNMPRSA-N D-mannopyranose Chemical compound OC[C@H]1OC(O)[C@@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-QTVWNMPRSA-N 0.000 description 1
- HMFHBZSHGGEWLO-SOOFDHNKSA-N D-ribofuranose Chemical compound OC[C@H]1OC(O)[C@H](O)[C@@H]1O HMFHBZSHGGEWLO-SOOFDHNKSA-N 0.000 description 1
- NOOLISFMXDJSKH-UHFFFAOYSA-N DL-menthol Natural products CC(C)C1CCC(C)CC1O NOOLISFMXDJSKH-UHFFFAOYSA-N 0.000 description 1
- 239000004375 Dextrin Substances 0.000 description 1
- 229920001353 Dextrin Polymers 0.000 description 1
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical group COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 description 1
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- UNXHWFMMPAWVPI-UHFFFAOYSA-N Erythritol Natural products OCC(O)C(O)CO UNXHWFMMPAWVPI-UHFFFAOYSA-N 0.000 description 1
- 206010056474 Erythrosis Diseases 0.000 description 1
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical group OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 1
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- 229930091371 Fructose Natural products 0.000 description 1
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 description 1
- 239000005715 Fructose Substances 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- CTKINSOISVBQLD-UHFFFAOYSA-N Glycidol Chemical compound OCC1CO1 CTKINSOISVBQLD-UHFFFAOYSA-N 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- WZUVPPKBWHMQCE-UHFFFAOYSA-N Haematoxylin Chemical compound C12=CC(O)=C(O)C=C2CC2(O)C1C1=CC=C(O)C(O)=C1OC2 WZUVPPKBWHMQCE-UHFFFAOYSA-N 0.000 description 1
- 244000043261 Hevea brasiliensis Species 0.000 description 1
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 1
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 1
- BWRPYSJNBVBIRP-FLFBIERCSA-N Ineketone Chemical compound O[C@H]1C[C@@](C)(C=C)C=C2C(=O)C[C@]3(O)C(C)(C)CCC[C@H]3[C@@]21C BWRPYSJNBVBIRP-FLFBIERCSA-N 0.000 description 1
- BWRPYSJNBVBIRP-UHFFFAOYSA-N Ineketone Natural products OC1CC(C)(C=C)C=C2C(=O)CC3(O)C(C)(C)CCCC3C21C BWRPYSJNBVBIRP-UHFFFAOYSA-N 0.000 description 1
- GUBGYTABKSRVRQ-QKKXKWKRSA-N Lactose Natural products OC[C@H]1O[C@@H](O[C@H]2[C@H](O)[C@@H](O)C(O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@H]1O GUBGYTABKSRVRQ-QKKXKWKRSA-N 0.000 description 1
- NNJVILVZKWQKPM-UHFFFAOYSA-N Lidocaine Chemical compound CCN(CC)CC(=O)NC1=C(C)C=CC=C1C NNJVILVZKWQKPM-UHFFFAOYSA-N 0.000 description 1
- PEEHTFAAVSWFBL-UHFFFAOYSA-N Maleimide Chemical compound O=C1NC(=O)C=C1 PEEHTFAAVSWFBL-UHFFFAOYSA-N 0.000 description 1
- GUBGYTABKSRVRQ-PICCSMPSSA-N Maltose Natural products O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-PICCSMPSSA-N 0.000 description 1
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical class CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 1
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 1
- 229920002292 Nylon 6 Polymers 0.000 description 1
- 229920002302 Nylon 6,6 Polymers 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- PYMYPHUHKUWMLA-LMVFSUKVSA-N Ribose Natural products OC[C@@H](O)[C@@H](O)[C@@H](O)C=O PYMYPHUHKUWMLA-LMVFSUKVSA-N 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 1
- 231100000768 Toxicity label Toxicity 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- 230000002152 alkylating effect Effects 0.000 description 1
- HMFHBZSHGGEWLO-UHFFFAOYSA-N alpha-D-Furanose-Ribose Natural products OCC1OC(O)C(O)C1O HMFHBZSHGGEWLO-UHFFFAOYSA-N 0.000 description 1
- SRBFZHDQGSBBOR-LECHCGJUSA-N alpha-D-xylose Chemical compound O[C@@H]1CO[C@H](O)[C@H](O)[C@H]1O SRBFZHDQGSBBOR-LECHCGJUSA-N 0.000 description 1
- 239000005030 aluminium foil Substances 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- 229910021502 aluminium hydroxide Inorganic materials 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 125000002490 anilino group Chemical group [H]N(*)C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- PYMYPHUHKUWMLA-WDCZJNDASA-N arabinose Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)C=O PYMYPHUHKUWMLA-WDCZJNDASA-N 0.000 description 1
- PYMYPHUHKUWMLA-UHFFFAOYSA-N arabinose Natural products OCC(O)C(O)C(O)C=O PYMYPHUHKUWMLA-UHFFFAOYSA-N 0.000 description 1
- 125000004097 arachidonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])/C([H])=C([H])\C([H])([H])/C([H])=C([H])\C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000001204 arachidyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- SRBFZHDQGSBBOR-UHFFFAOYSA-N beta-D-Pyranose-Lyxose Natural products OC1COC(O)C(O)C1O SRBFZHDQGSBBOR-UHFFFAOYSA-N 0.000 description 1
- GUBGYTABKSRVRQ-QUYVBRFLSA-N beta-maltose Chemical compound OC[C@H]1O[C@H](O[C@H]2[C@H](O)[C@@H](O)[C@H](O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@@H]1O GUBGYTABKSRVRQ-QUYVBRFLSA-N 0.000 description 1
- 229940106691 bisphenol a Drugs 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical group C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 235000014633 carbohydrates Nutrition 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000005660 chlorination reaction Methods 0.000 description 1
- XTHPWXDJESJLNJ-UHFFFAOYSA-N chlorosulfonic acid Substances OS(Cl)(=O)=O XTHPWXDJESJLNJ-UHFFFAOYSA-N 0.000 description 1
- 238000004587 chromatography analysis Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000002322 conducting polymer Substances 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 description 1
- 125000000596 cyclohexenyl group Chemical group C1(=CCCCC1)* 0.000 description 1
- FNIATMYXUPOJRW-UHFFFAOYSA-N cyclohexylidene Chemical group [C]1CCCCC1 FNIATMYXUPOJRW-UHFFFAOYSA-N 0.000 description 1
- LPIQUOYDBNQMRZ-UHFFFAOYSA-N cyclopentenylidene Natural products C1CC=CC1 LPIQUOYDBNQMRZ-UHFFFAOYSA-N 0.000 description 1
- 125000004979 cyclopentylene group Chemical group 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 235000019425 dextrin Nutrition 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- 229960005215 dichloroacetic acid Drugs 0.000 description 1
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 description 1
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 1
- 229960001760 dimethyl sulfoxide Drugs 0.000 description 1
- 125000002147 dimethylamino group Chemical group [H]C([H])([H])N(*)C([H])([H])[H] 0.000 description 1
- 238000003618 dip coating Methods 0.000 description 1
- GLCGEJFIZRSXBL-UHFFFAOYSA-N dodeca-1,3,5,7,9,11-hexaene Chemical compound C=CC=CC=CC=CC=CC=C GLCGEJFIZRSXBL-UHFFFAOYSA-N 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 238000006735 epoxidation reaction Methods 0.000 description 1
- UNXHWFMMPAWVPI-ZXZARUISSA-N erythritol Chemical compound OC[C@H](O)[C@H](O)CO UNXHWFMMPAWVPI-ZXZARUISSA-N 0.000 description 1
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 1
- BZKQJSLASWRDNE-UHFFFAOYSA-N ethyl 4-hydroxycyclohexane-1-carboxylate Chemical compound CCOC(=O)C1CCC(O)CC1 BZKQJSLASWRDNE-UHFFFAOYSA-N 0.000 description 1
- VXNZUUAINFGPBY-UHFFFAOYSA-N ethyl ethylene Natural products CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 1
- 125000000219 ethylidene group Chemical group [H]C(=[*])C([H])([H])[H] 0.000 description 1
- 239000006025 fining agent Substances 0.000 description 1
- FWQHNLCNFPYBCA-UHFFFAOYSA-N fluoran Chemical compound C12=CC=CC=C2OC2=CC=CC=C2C11OC(=O)C2=CC=CC=C21 FWQHNLCNFPYBCA-UHFFFAOYSA-N 0.000 description 1
- UQSQSQZYBQSBJZ-UHFFFAOYSA-N fluorosulfonic acid Chemical compound OS(F)(=O)=O UQSQSQZYBQSBJZ-UHFFFAOYSA-N 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000002223 garnet Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 125000002791 glucosyl group Chemical group C1([C@H](O)[C@@H](O)[C@H](O)[C@H](O1)CO)* 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- HLUCICHZHWJHLL-UHFFFAOYSA-N hematein Chemical group C12=CC=C(O)C(O)=C2OCC2(O)C1=C1C=C(O)C(=O)C=C1C2 HLUCICHZHWJHLL-UHFFFAOYSA-N 0.000 description 1
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical group O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 1
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 1
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 1
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 description 1
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 description 1
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 description 1
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 description 1
- 229940071676 hydroxypropylcellulose Drugs 0.000 description 1
- 229910000765 intermetallic Inorganic materials 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 150000002596 lactones Chemical class 0.000 description 1
- 239000008101 lactose Substances 0.000 description 1
- 125000005644 linolenyl group Chemical group 0.000 description 1
- 125000005645 linoleyl group Chemical group 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical group O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- BEGLCMHJXHIJLR-UHFFFAOYSA-N methylisothiazolinone Chemical compound CN1SC=CC1=O BEGLCMHJXHIJLR-UHFFFAOYSA-N 0.000 description 1
- MEFBJEMVZONFCJ-UHFFFAOYSA-N molybdate Chemical compound [O-][Mo]([O-])(=O)=O MEFBJEMVZONFCJ-UHFFFAOYSA-N 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- RHFUXPCCELGMFC-UHFFFAOYSA-N n-(6-cyano-3-hydroxy-2,2-dimethyl-3,4-dihydrochromen-4-yl)-n-phenylmethoxyacetamide Chemical compound OC1C(C)(C)OC2=CC=C(C#N)C=C2C1N(C(=O)C)OCC1=CC=CC=C1 RHFUXPCCELGMFC-UHFFFAOYSA-N 0.000 description 1
- MGNPLIACIXIYJE-UHFFFAOYSA-N n-fluoroaniline Chemical compound FNC1=CC=CC=C1 MGNPLIACIXIYJE-UHFFFAOYSA-N 0.000 description 1
- YPHQUSNPXDGUHL-UHFFFAOYSA-N n-methylprop-2-enamide Chemical compound CNC(=O)C=C YPHQUSNPXDGUHL-UHFFFAOYSA-N 0.000 description 1
- 125000001624 naphthyl group Chemical group 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- LYGJENNIWJXYER-UHFFFAOYSA-N nitromethane Chemical compound C[N+]([O-])=O LYGJENNIWJXYER-UHFFFAOYSA-N 0.000 description 1
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 125000001117 oleyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000002902 organometallic compounds Chemical class 0.000 description 1
- 125000002524 organometallic group Chemical group 0.000 description 1
- 239000005026 oriented polypropylene Substances 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- HDBWAWNLGGMZRQ-UHFFFAOYSA-N p-Vinylbiphenyl Chemical group C1=CC(C=C)=CC=C1C1=CC=CC=C1 HDBWAWNLGGMZRQ-UHFFFAOYSA-N 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 239000013034 phenoxy resin Substances 0.000 description 1
- 229920006287 phenoxy resin Polymers 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 description 1
- 125000005506 phthalide group Chemical group 0.000 description 1
- 150000003053 piperidines Chemical class 0.000 description 1
- 229920001490 poly(butyl methacrylate) polymer Polymers 0.000 description 1
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920005990 polystyrene resin Polymers 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- AOHJOMMDDJHIJH-UHFFFAOYSA-N propylenediamine Chemical class CC(N)CN AOHJOMMDDJHIJH-UHFFFAOYSA-N 0.000 description 1
- 150000003233 pyrroles Chemical class 0.000 description 1
- 150000003235 pyrrolidines Chemical class 0.000 description 1
- SBYHFKPVCBCYGV-UHFFFAOYSA-N quinuclidine Chemical compound C1CC2CCN1CC2 SBYHFKPVCBCYGV-UHFFFAOYSA-N 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- HFHDHCJBZVLPGP-UHFFFAOYSA-N schardinger α-dextrin Chemical compound O1C(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(O)C2O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC2C(O)C(O)C1OC2CO HFHDHCJBZVLPGP-UHFFFAOYSA-N 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- PNGLEYLFMHGIQO-UHFFFAOYSA-M sodium;3-(n-ethyl-3-methoxyanilino)-2-hydroxypropane-1-sulfonate;dihydrate Chemical compound O.O.[Na+].[O-]S(=O)(=O)CC(O)CN(CC)C1=CC=CC(OC)=C1 PNGLEYLFMHGIQO-UHFFFAOYSA-M 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- HXJUTPCZVOIRIF-UHFFFAOYSA-N sulfolane Chemical compound O=S1(=O)CCCC1 HXJUTPCZVOIRIF-UHFFFAOYSA-N 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 238000010345 tape casting Methods 0.000 description 1
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical compound FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- WJCNZQLZVWNLKY-UHFFFAOYSA-N thiabendazole Chemical compound S1C=NC(C=2NC3=CC=CC=C3N=2)=C1 WJCNZQLZVWNLKY-UHFFFAOYSA-N 0.000 description 1
- 125000002769 thiazolinyl group Chemical group 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- YNJBWRMUSHSURL-UHFFFAOYSA-N trichloroacetic acid Chemical compound OC(=O)C(Cl)(Cl)Cl YNJBWRMUSHSURL-UHFFFAOYSA-N 0.000 description 1
- 125000003258 trimethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- IKXFIBBKEARMLL-UHFFFAOYSA-N triphenoxy(sulfanylidene)-$l^{5}-phosphane Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=S)OC1=CC=CC=C1 IKXFIBBKEARMLL-UHFFFAOYSA-N 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 229960003487 xylose Drugs 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- PAPBSGBWRJIAAV-UHFFFAOYSA-N ε-Caprolactone Chemical compound O=C1CCCCCO1 PAPBSGBWRJIAAV-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/30—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used using chemical colour formers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S430/00—Radiation imagery chemistry: process, composition, or product thereof
- Y10S430/1053—Imaging affecting physical property or radiation sensitive material, or producing nonplanar or printing surface - process, composition, or product: radiation sensitive composition or product or process of making binder containing
- Y10S430/1055—Radiation sensitive composition or product or process of making
- Y10S430/106—Binder containing
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S430/00—Radiation imagery chemistry: process, composition, or product thereof
- Y10S430/145—Infrared
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S430/00—Radiation imagery chemistry: process, composition, or product thereof
- Y10S430/146—Laser beam
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S430/00—Radiation imagery chemistry: process, composition, or product thereof
- Y10S430/165—Thermal imaging composition
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
- Y10T428/31938—Polymer of monoethylenically unsaturated hydrocarbon
Landscapes
- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Heat Sensitive Colour Forming Recording (AREA)
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
组合物,包含潜活化剂和成色物质,用于制备这些组合物的方法、用这些组合物涂布的基材和它们的制备方法、使用这些组合物制备有标记基材的方法和可通过后者方法获得的有标记的基材。
Description
本发明涉及基材标记用涂料组合物、涉及这些组合物的制备方法、涉及用这些组合物涂布的基材和涉及它们的制备方法、涉及使用这些组合物制备有标记基材的方法、还涉及可通过后者方法获得的有标记基材。
包装通常需要用信息(例如品牌标识、条形码、商品有效期或批号)进行标记。做到这一点的一条途径是用一种组合物涂布该包装,该组合物一经用能量(如热量)处理便形成可见标记。当使用激光辐射作为能量时,该标记甚至可以很小以致于它对于人眼是不可见或基本不可见的。
WO 02/074548描述了包含多价金属的含氧阴离子(oxyanion)(例如八钼酸铵(AOM)),粘结剂和溶剂的涂料组合物。将这些组合物涂布在基材上例如卡通纸板上、干燥并暴露于IR激光以产生黑色标记。
WO 2004/043704描述了包含钼、钨或钒的胺化合物,有机溶剂,和任选地聚合物粘结剂和/或成色物质的涂料组合物。“钼酸胺”的实例是八钼酸二(2-乙基己基)胺。将该组合物涂布在基材上例如聚对苯二甲酸乙二醇酯薄膜、铝箔或聚丙烯包装薄膜,干燥并暴露于IR激光或热印刷机以产生灰/黑或有色标记。
WO 2005/012442描述了包含颜料、水或有机溶剂、导电聚合物(conductive polymer)和任选地粘结剂的涂料组合物。颜料可以是钼酸盐或钨酸盐的含氧阴离子(oxyanion)。
WO 02/074548、WO 2004/043704和WO 2005/012442的涂料组合物的缺点是它们基于重金属。
WO 02/068205描述了用于标记物体的方法,其中该物体包含或涂有制剂,该制剂包含具有官能团(如,多羟基化合物)的材料和金属化合物(如碱金属、碱土金属、铁氧化物或盐和有机金属化合物(organo-metallics))。该两种组分在用激光辐照下反应形成黄色或灰色/绿色标记。
WO 02/068205的组合物具有以下缺点:它们仅仅提供黄色或灰色/绿色标记,而不提供任何所希望的颜色的高对比彩色标记。另外,所述组合物不适用于涂布纸或塑料制品。
本发明的一个目的为提供涂料组合物,其一旦暴露于能量便产生具有任何所希望的颜色的高对比彩色标记并且它不是基于重金属。
这些目的通过包含潜活化剂(latent activator)和成色物质的涂料组合物进行解决。
本发明的组合物包含潜活化剂和成色物质。
该潜活化剂可以是酸衍生物或者酸与胺的盐。
该酸衍生物可以是在25℃时在水中的pKa低于10.0的酸的任何衍生物。优选地,它是pKa低于5.0的酸的衍生物,更优选低于3.0。
优选的酸衍生物是硫酸类、磷酸类或羧酸类的衍生物。
硫酸类的实例是硫酸、氟磺酸、氯磺酸、亚硝基硫酸、4-苯乙烯磺酸、对-甲苯磺酸、苯磺酸、二甲苯磺酸、苯酚磺酸、甲烷磺酸、三氟甲烷磺酸、聚(4-苯乙烯磺酸)和包含4-苯乙烯磺酸单元的共聚物,如聚(4-苯乙烯磺酸-共-马来酸)。磷酸类的实例是磷酸、氟磷酸和六氟磷酸。羧酸类的实例是二氯乙酸、三氯乙酸、草酸和马来酸。
更优选的酸衍生物是硫酸类、磷酸类或羧酸类的酯、酰胺和硫代酯衍生物。
硫酸类、磷酸类或羧酸类的酯、酰胺和硫代酯衍生物可以是具有至少一个OH-基团被以下取代的硫酸类、磷酸类或羧酸类:OR1、NR2R3或SR4,其中R1、R2、R3和R4可以是C1-30-烷基、C2-30-链烯基、C4-8-环烷基、C7-12-双环烷基、C5-8-环烯基、芳烷基、芳烯基或芳基,其可以是未被取代的或用C1-6-烷基、C1-6-烷氧基、卤素、羟基、C(O)OC1-6-烷基或OC(O)C1-6-烷基取代的。
硫酸类、磷酸类或羧酸类的酯、酰胺和硫代酯还可以是两种酸,其选自硫酸类、磷酸类和羧酸类,它们通过O-A-O、NR5-E-R6N或S-J-S基团连接,其中R5和R6可以如对R1、R2、R3和R4所定义,A、E和J可以是C2-14-亚烷基、C2-14-亚烯基、C4-8-亚环烷基、C4-8-亚环烯基或亚芳基、其可以是未被取代的或用C1-6-烷基、C1-6-烷氧基、卤素、羟基、C(O)OC1-6-烷基或OC(O)C1-6-烷基取代的。
C1-30-烷基的实例是甲基、乙基、丙基、异丙基、丁基、仲丁基、异丁基、叔丁基、戊基、己基、庚基、辛基、壬基、癸基、十一基、十二烷基、十四烷基、十六烷基、十八烷基和二十烷基(arachinyl)。C2-30烯基的实例是乙烯基、烯丙基、十八碳三烯基(linolenyl)、二十二碳六烯基(docosahexaenoyl)、二十碳五烯基(eicosapentaenoyl)、十八碳二烯基(linoleyl)、花生四烯基(arachidonyl)和十八碳单烯基(oleyl)。C4-8环烷基的实例是环戊基和环己基。C7-12-双环烷基的实例是2-降莰烷基(2-norbornyl)。C5-8-环烯基的实例是环己烯基。芳烷基的实例是苄基和2-苯乙基。芳基的实例是苯基、1,3,5-三嗪基或萘基。C1-6-烷基的实例是甲基、乙基、丙基、异丙基、丁基、仲丁基、异丁基、叔丁基、戊基和己基。C1-6-烷氧基的实例是甲氧基、乙氧基、丙氧基、异丙氧基、丁氧基、仲-丁氧基、叔-丁氧基(butxy)、异丁氧基、戊氧基和己氧基。卤素的实例是氯和溴。C2-14-亚烷基的实例是亚乙基、1,3-亚丙基(trimethylene)、1,4-亚丁基、乙基亚乙基(ethylethylene)、1,5-亚戊基、1,6-亚己基、1,7-亚庚基、1,8-亚辛基。C4-8-亚环烷基的实例是亚环戊基和亚环己基。C4-8-亚环烯基的实例是亚环戊烯基和亚环己烯基。亚芳基的实例是亚苯基。
优选地,C1-30-烷基是C1-6-烷基和优选地C2-30-链烯基是C2-6-链烯基。C2-6-链烯基的实例是乙烯基和烯丙基。
更加优选的酸衍生物是硫酸类的酯、酰胺和硫代酯衍生物。尤其优选的酸衍生物是硫酸类的,特别是有机硫酸类的酯衍生物。
有机硫酸类的实例是4-苯乙烯磺酸、对-甲苯磺酸、苯磺酸、二甲苯磺酸、苯酚磺酸、甲烷磺酸、三氟甲烷磺酸、聚(4-苯乙烯磺酸)和包含4-苯乙烯磺酸单元的共聚物,如聚(4-苯乙烯磺酸-共-马来酸)。
优选的有机硫酸类的酯衍生物是至少一个OH-基团被OR1取代的有机硫酸类,其中R1可以是C1-6-烷基或C4-8-环烷基,其可以是未取代的或用C1-6-烷基或C(O)OC1-6烷基取代。优选的有机硫酸类的酯衍生物同样是通过O-A-O基团被连接的两种硫酸,其中A是C4-8-亚环烷基。优选的有机磺酸是对-甲苯磺酸。
更优选的有机硫酸类的酯衍生物是对-甲苯磺酸环己酯、对-甲苯磺酸2-甲基环己酯、对-甲苯磺酸薄荷基酯(menthyl-p-toluenesulfonate)、二-对-甲苯磺酸1,4-环己二醇酯(1,4-cyclohexanediol di-p-toluenesulfonate)、4-甲苯磺酰基环己烷羧酸乙酯(4-tosylcyclohexanecarboxylic acid ethyl ester)和对-甲苯磺酸2,2-二甲基丙酯。
酸衍生物或者是在市场上可买到的或者可通过已知的方法进行制备,例如,通过合适的醇与合适的磺酰氯在催化剂存在下反应。
酸在25℃时在水中的pKa低于10.0。优选地,它的pKa低于5.0,更优选地低于3.0。
优选的酸是硫酸类、磷酸类或羧酸类。更优选的酸是硫酸类。最优选的酸是有机硫酸类。
该胺可以具有式NR7R8R9,其中R7、R8和R9可以相同或不同,并且可以是氢、C1-30-烷基、C2-30-链烯基、C4-8-环烷基、C5-8-环烯基、芳烷基、芳烯基或芳基,它们可以是未被取代的或用氨基和/或羟基取代,或R8和R9与胺的氮原子一起形成5-7元环。
具有式NR7R8R9的胺的实例是氨、甲胺、乙胺、丙胺、丁胺、二乙胺、乙二胺、1,2-二氨基丙烷、乙醇胺、环己胺、苯胺、三聚氰胺、吡咯、吗啉、吡咯烷和哌啶。
优选地,胺具有式NR7R8R9,其中R7是氢,R8和R9可以相同或不同,并且可以是氢、C1-30-烷基、C2-30-链烯基、C4-8-环烷基、C5-8-环烯基、芳烷基、芳烯基或芳基,其可以是未被取代的或用氨基和/或羟基取代,或R8和R9与胺的氮原子一起形成5-7元环。
更优选地,胺具有式NR7R8R9,其中R7和R8是氢,R9可以是氢、C1-30-烷基、C2-30-链烯基、C4-8-环烷基、C5-8-环烯基、芳烷基、芳烯基或芳基,其可以是未被取代的或用氨基和/或羟基取代。
最优选地,该潜活化剂是酸衍生物。
成色物质可以是任何合适的成色物质,例如苯酞(phthalide)、荧烷、三芳基甲烷、苯并噁嗪、喹唑啉、螺吡喃、醌、噻嗪、或噁嗪或其混合物。
苯酞的实例是结晶紫内酯(crystal voilet lactone)(3,3-二(对二甲氨基苯基)-6-二甲氨基-苯酞)、3,3-二(对二甲氨基苯基)-苯酞、3,3-二(1-乙基-2-甲基吲哚-3-基)-苯酞、3,3-二(1-辛基-2-甲基吲哚-3-基)-苯酞、3-(4-二乙氨基苯基)-3-(1-乙基-2-甲基吲哚-3-基)-苯酞、7-(N-乙基-N-异戊基氨基)-3-甲基-1-苯基螺[4H-色烯并(chromeno)[2,3-c]吡唑-4(1H)-3’-苯酞]、3,6,6’-三(二甲氨基)螺[芴-9,3’-苯酞]、3,6,6’-三(二乙氨基)螺[芴-9,3’-苯酞]、3,3-二[2-(对二甲氨基苯基)-2-(对-甲氧基苯基)乙烯基]-4,5,6,7-四溴-苯酞、3,3-二[2-(对二甲氨基苯基)-2-(对-甲氧基苯基)乙烯基]-4,5,6,7-四氯-苯酞、3,3-二[1,1-二(4-吡咯烷基(pyrrolidino)苯基)乙烯-2-基]-4,5,6,7-四溴-苯酞、3,3-二[1-(4-甲氧基苯基)-1-(4-吡咯烷基(pyrrolidino)苯基)乙烯-2-基]-4,5,6,7-四氯-苯酞、3-(4-二乙氨基-2-乙氧基苯基)-3-(1-乙基-2-甲基吲哚-3-基)-4-氮杂-苯酞、3-(4-二乙氨基-2-乙氧基苯基)-3-(1-辛基-2-甲基吲哚-3-基)-4-氮杂-苯酞和3-(4-环己基乙基氨基-2-甲氧基苯基)-3-(1-乙基-2-甲基吲哚-3-基)-4-氮杂-苯酞。
该苯酞可以用本领域已知的方法制备,例如,结晶紫内酮可以如GB 1,347,467所描述的那样进行制备,3,3-二(1-乙基-2-甲基吲哚-3-基)-苯酞可以如GB 1,389,716中所描述的那样进行制备。
荧烷的实例是3-二(乙基)氨基-6-甲基-7-(叔丁氧羰基)苯胺基荧烷、3-二乙氨基-7-二苄氨基荧烷、3-二丁氨基-7-二苄氨基荧烷、3-二乙氨基-6-甲基-7-(二苄氨基)荧烷、3-二乙氨基-6-甲基荧烷、3-二乙氨基-6-氯-7-甲基荧烷、3-二乙氨基-6-甲基-7-氯荧烷、3-二乙氨基-7-叔丁基荧烷、3-二乙氨基-7-羧乙基荧烷、3-二乙氨基-7-甲基荧烷、3-二乙氨基-6,8-二甲基荧烷、3-二乙氨基-7-氯荧烷、3-二丁氨基-6-甲基荧烷、3-环己氨基-6-氯荧烷、3-二乙氨基苯并[a]荧烷、3-二乙氨基苯并[c]荧烷、3-二甲氨基-6-甲基-7-苯胺基荧烷、3-二乙氨基-6-甲基-7-苯胺基荧烷、3-二乙氨基-6-甲基-7-(2,4-二甲基苯胺基)荧烷、3-二乙氨基-6-甲基-7-(3-三氟甲基苯胺基)荧烷、3-二乙氨基-6-甲基-7-(2-氯苯胺基)荧烷、3-二乙氨基-6-甲基-7-(对氯苯胺基)荧烷、3-二乙氨基-6-甲基-7-(2-氟苯胺基)荧烷、3-二乙氨基-6-甲基-7-(对辛基苯胺基)荧烷、3-二乙氨基-7-(对辛基苯胺基)荧烷、3-二乙氨基-6-甲基-7-(对-甲基苯胺基)荧烷、3-二乙氨基-6-乙氧乙基-7-苯胺基荧烷、3-二乙氨基-6-甲基-7-(3-甲基苯胺基)荧烷、3-二乙氨基-7-(3-三氟甲基苯胺基)荧烷、3-二乙氨基-7-(2-氯苯胺基)荧烷、3-二乙氨基-7-(2-氟苯胺基)荧烷、3-二乙氨基-6-氯-7-苯胺基荧烷、3-二丁氨基-6-甲基-7-苯胺基荧烷、3-二丁氨基-6-甲基-7-(2,4-二甲基苯胺基)荧烷、3-二丁氨基-6-甲基-7-(2-氯苯胺基)荧烷、3-二丁氨基-6-甲基-7-(4-氯苯胺基)荧烷、3-二丁氨基-6-甲基-7-(2-氟苯胺基)荧烷、3-二丁氨基-6-甲基-7-(3-三氟甲基苯胺基)荧烷、3-二丁氨基-6-乙氧乙基-7-苯胺基荧烷、3-二丁氨基-6-氯苯胺基荧烷、3-二丁氨基-6-甲基-7-(4-甲基苯胺基)荧烷、3-二丁氨基-7-(2-氯苯胺基)荧烷、3-二丁氨基-7-(2-氟苯胺基)荧烷、3-二戊氨基-6-甲基-7-苯胺基荧烷、3-二戊氨基-6-甲基-7-(4-2-氯苯胺基)荧烷、3-二戊氨基-7-(3-三氟甲基苯胺基)荧烷、3-二戊氨基-6-氯-7-苯胺基荧烷、3-二戊氨基-7-(4-氯苯胺基)荧烷、3-吡咯烷基-6-甲基-7-苯胺基荧烷、3-哌啶子基-6-甲基-7-苯胺基荧烷、3-(N-甲基-N-丙基氨基)-6-甲基-7-苯胺基荧烷、3-(N-甲基-N-环己基氨基)-6-甲基-7-苯胺基荧烷、3-(N-乙基-N-环己基氨基)-6-甲基-7-苯胺基荧烷、3-(N-乙基-N-己基氨基)-7-苯胺基荧烷、3-(N-乙基-对-甲苯氨基)氨基-6-甲基-7-苯胺基荧烷、3-(N-乙基-对-甲苯氨基)氨基-7-甲基荧烷、3-(N-乙基-N-异戊基氨基)-6-甲基-7-苯胺基荧烷、3-(N-乙基-N-异戊基氨基)-7-(2-氯苯胺基)荧烷、3-(N-乙基-N-异戊基氨基)-6-氯-7-苯胺基荧烷、3-(N-乙基-N-四氢糠基氨基)-6-甲基-7-苯胺基荧烷、3-(N-乙基-N-异丁基氨基)-6-甲基-7-苯胺基荧烷、3-(N-丁基-N-异戊基氨基)-6-甲基-7-苯胺基荧烷、3-(N-异丙基-N-3-戊基氨基)-6-甲基-7-苯胺基荧烷、3-(N-乙基-N-乙氧丙基氨基)-6-甲基-7-苯胺基荧烷、2-甲基-6-对(对二甲氨基苯基)氨基苯胺基荧烷、2-甲氧基-6-对(对二甲氨基苯基)氨基苯胺基荧烷、2-氯-3-甲基-6-对(对苯胺基苯基)氨基苯胺基荧烷、2-二乙氨基-6-对(对二甲氨基苯基)氨基苯胺基荧烷、2-苯基-6-甲基-6-对(对苯胺基苯基)氨基苯胺基荧烷、2-苄基-6-对(对苯胺基苯基)氨基苯胺基荧烷、3-甲基-6-对(对二甲氨基苯基)氨基苯胺基荧烷、3-二乙氨基-6-对(对二乙氨基苯基)氨基苯胺基荧烷、3-二乙氨基-6-对(对二丁氨基苯基)氨基苯胺基荧烷和2,4-二甲基-6-[4-(二甲氨基)苯胺基]荧烷。
荧烷类可以用本领域已知的方法制备,例如,3-二乙氨基-7-二苄氨基荧烷、3-二乙氨基-7-叔丁基荧烷、3-二乙氨基-6-甲基-7-苯胺基荧烷和3-二乙氨基-6-甲基-7-(2,4-二甲基苯胺基)荧烷,和可以如US5,166,350 A中所描述的那样进行制备,3-二乙氨基-6-甲基-7-(3-甲基苯胺基)荧烷可以如EP 0 546 557 A1中所描述的那样进行制备,3-二乙氨基-6-氯-7-苯胺基荧烷可以如DE 2 130 845中所描述的那样进行制备,3-吡咯烷基-6-甲基-7-苯胺基荧烷和3-哌啶子基-6-甲基-7-苯胺基荧烷可以如US 3,959,571 A中所描述的那样进行制备,3-(N-乙基-N-异戊基氨基)-6-甲基-7-苯胺基荧烷可以如GB 2 002 801 A中所描述的那样进行制备,且3-(N-甲基-N-丙基氨基)-6-甲基-7-苯胺基荧烷可以如GB 2 154 597 A中所描述的那样进行制备。
苯并噁嗪的实例是2-苯基-4-(4-二乙氨基苯基)-4-(4-甲氧基苯基)-6-甲基-7-二甲氨基-3,1-苯并噁嗪(其可以如EP 0 187 329 A1中所描述的那样进行制备)和2-苯基-4-(4-二乙氨基苯基)-4-(4-甲氧基苯基)-8-甲基-7-二甲氨基-3,1-苯并噁嗪。
喹唑啉的实例是4,4’-[(1-甲基亚乙基)二(4,1-亚苯基氧基-4,2-喹唑啉二基)]二[N,N-二乙基苯胺]。三芳基甲烷的实例是二(N-甲基二苯胺)-4-基-(N-丁基咔唑)-3-基-甲烷,其可以如GB1,548,059中所描述的那样进行制备。
螺吡喃的实例是1’,3’,3’-三甲基螺[2H-1-苯并吡喃-2,2’-吲哚啉]、1,3,3-三甲基螺[吲哚啉-2,3’-[3H]吩[2,1-b][1,4]噁嗪(naphth[2,1-b][1,4]oxazine]和1’,3’,3’-三甲基螺[2H-1-苯并噻喃-2,2’-吲哚啉]。
醌的实例是苏木精(hematoxyline)。噁嗪的实例是3,7-二(二甲氨基)-10-苯甲酰基吩噁嗪。噻嗪的实例是3,7-二(二甲氨基)-10-苯甲酰基吩噻嗪。
优选地,该成色物质是苯酞或荧烷或其混合物。
更优选地,该成色物质是结晶紫内酯或例如以商品名 Blue1-2RN销售的3,3-二(对二甲氨基苯基)-6-二甲氨基-苯酞、例如以商品名 Red I-6B销售的3,3-二(1-辛基-2-甲基吲哚-3-基)-苯酞或例如以商品名 Orange1-G)销售的3-二乙氨基-7-(乙氧羰基)荧烷。
优选地,组合物还包含溶剂。该溶剂可以是水、有机溶剂、液体单体或它们的混合物。优选地,该溶剂是水、有机溶剂或它们的混合物。
有机溶剂的实例是C1-4-烷醇、C2-4-多元醇、C3-6-酮、C4-6-醚、C2-3腈、硝基甲烷、二甲亚砜、二甲基甲酰胺、二甲基乙酰胺、N-甲基吡咯烷酮和环丁砜,其中C1-4烷醇和C2-4-多元醇可以用C1-4-烷氧基取代。C1-4-烷醇的实例是甲醇、乙醇、丙醇、异丙醇或丁醇、异丁醇、仲丁醇和叔丁醇。其C1-4-烷氧基衍生物的实例是2-乙氧基乙醇和1-甲氧基-2-丙醇。C2-4多元醇的实例是乙二醇(glycol)和甘油。C3-6-酮的实例是丙酮和甲基乙基酮。C4-6醚的实例是二甲氧基乙烷、二异丙基乙基和四氢呋喃。C2-3腈的实例是乙腈。
更优选地,溶剂是有机溶剂。
还更优选地,溶剂是选自以下的有机溶剂:C1-4-烷醇、C2-4-多元醇、C3-6-酮、二甲基甲酰胺和二甲基乙酰胺,其中C1-4烷醇和C2-4-多元醇可以用C1-4-烷氧基取代。
最优选地,该溶剂是丙酮、甲基乙基酮和其混合物。
优选地,本发明的组合物还包含聚合物粘结剂。
聚合物粘结剂的实例是丙烯酸类聚合物、苯乙烯类聚合物和其加氢产物、乙烯基类聚合物和其衍生物、聚烯烃和其加氢或环氧化产物、醛类聚合物、环氧类聚合物、聚酰胺、聚酯、聚氨酯、砜基聚合物和天然聚合物和其衍生物。该聚合物粘结剂还可以是聚合物粘结剂的混合物。它还可以是液体单体和合适的光引发剂的混合物,其在涂布后在UV辐照下形成上面所列出的聚合物粘结剂中的一种。在这种情况下,该单体起溶剂作用。
丙烯酸类聚合物是由至少一种丙烯酸单体或由至少一种丙烯酸单体和至少一种其他烯属不饱和的聚合物(如苯乙烯单体、乙烯基单体、烯烃单体或马来酸类单体(maleic monomer))形成的聚合物。
丙烯酸类单体的实例是(甲基)丙烯酸或其盐、(甲基)丙烯酰胺、(甲基)丙烯腈、(甲基)丙烯酸C1-6烷基酯,如(甲基)丙烯酸乙酯、(甲基)丙烯酸丁酯或(甲基)丙烯酸己酯、(甲基)丙烯酸2-乙基己酯、取代的(甲基)丙烯酸C1-6-烷基酯,如甲基丙烯酸缩水甘油酯和异丁烯酸乙酰乙酰氧基乙酯、(甲基)丙烯酸二(C1-4烷基氨基)C1-6烷基酯,如丙烯酸二甲氨基乙酯或丙烯酸二乙氨基乙酯、由C1-6-烷基胺形成的酰胺、取代的C1-6-烷基胺,如2-氨基-2-甲基-1-丙烷磺酸、铵盐或二(C1-4烷基-氨基)C1-6-烷基胺和(甲基)丙烯酸和其C1-4-烷基卤加合物。
苯乙烯类单体的实例是苯乙烯、4-甲基苯乙烯和4-乙烯基联苯。乙烯类单体的实例是乙烯醇、氯乙烯、偏二氯乙烯、乙烯基异丁基醚和乙酸乙烯酯。烯烃类单体的实例是乙烯、丙烯、丁二烯和异戊二烯及其氯化或氟化衍生物例如四氟乙烯。马来酸类单体的实例是马来酸、马来酸酐和马来酰亚胺。
丙烯酸类聚合物的实例是聚(甲基丙烯酸甲酯)和聚(甲基丙烯酸丁酯)。
苯乙烯类聚合物是由至少一种苯乙烯类单体和至少一种乙烯类单体、烯烃单体和/或马来酸类单体形成的聚合物。苯乙烯类聚合物的实例是苯乙烯/丁二烯/苯乙烯嵌段聚合物、苯乙烯/乙烯/丁二烯嵌段聚合物、苯乙烯/乙烯/丙烯/苯乙烯嵌段聚合物和苯乙烯-马来酸酐共聚物。
乙烯基类聚合物是由至少一种乙烯基类单体或由至少一种乙烯类单体和至少一种烯烃单体或马来酸类单体形成的聚合物。乙烯基类聚合物的实例是聚氯乙烯、聚乙烯醇、聚乙酸乙烯酯、部分水解的聚乙酸乙烯酯和甲基乙烯醚-马来酸酐共聚物。其衍生物的实例为羧酸-改性的聚乙烯醇、乙酰乙酰基-改性的聚乙烯醇、双丙酮(diacetone)-改性的聚乙烯醇和硅-改性的聚乙烯醇。
聚烯烃是由至少一种烯烃单体或由至少一种烯烃类单体或马来酸类单体形成的聚合物。聚烯烃的实例是聚乙烯、聚丙烯、聚丁二烯和异丙烯-马来酸酐共聚物。
醛类聚合物是由至少一种醛类单体或聚合物和至少一种醇类单体或聚合物、胺类单体或聚合物和/或脲类单体或聚合物形成的聚合物。醛类单体的实例是甲醛、糠醛和缩丁醛(butyral)。醇类单体的实例是苯酚、甲酚、间苯二酚和二甲苯酚。聚醇(polyalcohol)的实例是聚乙烯醇。胺类单体的实例是苯胺和蜜胺。脲类单体的实例是脲、硫脲和双氰胺。醛类聚合物的实例是由缩丁醛和聚乙烯醇形成的聚乙烯醇缩丁醛。
环氧类聚合物是由至少一种环氧类单体和至少一种醇类单体和/或胺类单体形成的聚合物。环氧类单体的实例是表氯醇和缩水甘油。醇类单体的实例是苯酚、甲酚、间苯二酚、二甲苯酚、双酚A和乙二醇(glycol)。环氧类聚合物的实例是由表氯醇和双酚A形成的苯氧基树脂。
聚酰胺是由至少一种具有酰氨基或氨基以及羧基的单体或由至少一种具有2个氨基的单体和至少一种具有2个羧基的单体形成的聚合物。具有酰氨基的单体的实例是己内酰胺。二胺的实例是1,6-二氨基己烷。二羧酸的实例是己二酸、对苯二甲酸、间苯二甲酸、和1,4-萘二羧酸。聚酰胺的实例是聚己二酰己二胺和聚己内酰胺。
聚酯聚合物是由至少一种具有羟基以及羧基的单体或由至少一种具有2个羟基的单体和至少一种具有2个羧基或内酯基的单体形成的。具有羟基以及羧基的单体的实例是己二酸。二醇的实例是乙二醇。具有内酯基的单体的实例是己内酯。二羧酸的实例是对苯二甲酸、间苯二甲酸和1,4-萘二羧酸。聚酯的实例是聚对苯二甲酸乙二醇酯。所谓的醇酸树脂也视为属于聚酯聚合物。
聚氨酯是由至少一种二异氰酸酯单体和至少一种多醇单体和/或多胺单体形成的聚合物。二异氰酸酯单体的实例是六亚甲基二异氰酸酯、甲苯二异氰酸酯、和二苯甲烷二异氰酸酯。
砜基聚合物的实例是聚芳基砜、聚醚砜、聚苯基砜和聚砜。聚砜是由4,4-二氯二苯砜和双酚A形成的聚合物。
天然聚合物的实例是淀粉、纤维素、明胶、酪蛋白(caesin)和天然橡胶。衍生物的实例是氧化淀粉、淀粉-乙酸乙烯酯接枝共聚物、羟乙基纤维素、羟基丙基纤维素、甲基纤维素、乙基纤维素、羧甲基纤维素和乙酰纤维素。
聚合物粘结剂是本领域已知的并且可以通过已知的方法进行生产,例如通过从合适单体开始的聚合。
优选地,聚合物粘结剂选自丙烯酸类聚合物、苯乙烯类聚合物、乙烯基类聚合物和其衍生物、聚烯烃、聚氨酯和天然聚合物和其衍生物。
更优选地,聚合物粘结剂选自丙烯酸类聚合物、苯乙烯丁二烯共聚物、苯乙烯-马来酸酐共聚物、聚乙烯醇、聚乙酸乙烯酯、部分水解的聚乙酸乙烯酯、甲基乙烯基醚-马来酸酐共聚物、羧酸-改性聚乙烯醇、乙酰乙酰基-改性聚乙烯醇、双丙酮-改性聚乙烯醇、和硅-改性聚乙烯醇、异丙烯-马来酸酐共聚物、聚氨酯、纤维素、明胶、酪蛋白、氧化淀粉、淀粉-乙酸乙烯酯接枝共聚物、羟乙基纤维素、甲基纤维素、乙基纤维素、羧甲基纤维素和乙酰纤维素。
更加优选地,该聚合物粘结剂是丙烯酸类聚合物。最优选地,聚合物粘结剂是聚(甲基丙烯酸甲酯)。
优选地,本发明的组合物还可以包含另外组分。
该涂料组合物中可以包括的另外组分可以是形成碳的化合物(char forming compound)或适合于改善组合物的性能的组分。
形成碳的化合物的实例是碳水化合物如单糖、二糖和多糖和其衍生物,其中羰基已经被还原为羟基,即所谓的糖醇。
单糖的实例是葡萄糖、甘露糖、半乳糖、阿拉伯糖、果糖、核糖、赤藓糖和木糖。二糖的实例是麦芽糖、纤维二糖、乳糖和蔗糖。多糖的实例是纤维素、淀粉、阿拉伯树胶、糊精和环糊精。糖醇的实例是内消旋-赤藻糖醇、山梨糖醇、甘露醇和季戊四醇。
优选的形成碳的化合物是单糖和二糖。更优选的形成碳的化合物是蔗糖和半乳糖。最优选的形成碳的化合物是蔗糖。
适合改善该组合物的性能的组分可以吸收入射能并且以热的形式或者其他方式将这种能量转移到系统,如IR吸收剂或UV吸收剂。改善组合物性能的其他类型的另外组分的实例是颜料、稳定剂、抗氧化剂、流变性调节剂、润湿剂、杀生物剂、防烟剂和标记剂(taggants)。标记剂是各种被加到产品中以显示它的制造来源地(source ofmanufacture)的物质。
可以添加颜料以增强未成像区(unimaged areas)与成像区(imagedareas)之间的对比度或作为安全特征。
为增强未成像区与成像区之间的对比度而可以添加的颜料是实例是二氧化钛、碳酸钙、高岭土、煅烧高岭土、氢氧化铝、滑石、氧化锌、无定形二氧化硅、硫酸钡、聚苯乙烯树脂、脲醛树脂、中空塑料颜料、及其混合物。
可以作为安全特征添加的颜料的实例是荧光颜料或磁性颜料。
杀生物剂的实例是MBS,其包括氯甲基异噻唑啉酮和甲基异噻唑啉酮的混合物,410,其包括2-二溴-2,4-二氰基丁烷和1,2-苯并异噻唑啉-3-酮的组合,721M,其包括1,2-二溴-2,4-二氰基丁烷和2-溴-2-硝基-1,3-丙二醇的混合物和TK100,其包括2-(4-噻唑基)-苯并咪唑。
防烟剂的实例是八钼酸铵。
由本发明的涂料组合物所形成的涂层可以被涂敷以层压材料层(laminate layer)或复印清漆(overprint varnish)。如果对该层压材料层或复印清漆的材料进行选择,这样它在成像激光的波长上不吸收,则激光敏感涂层可以透过该层压材料层成像而不损害或标记该层压材料。此外,对该层压材料或复印清漆进行理想选择,这样在能量处理之前它不会导致该涂层变色。
基于总组合物的重量,本发明的组合物可以包含1-50wt%,优选地1-40wt%,更优选地1-20wt%,最优选地1-5wt%的潜活化剂。
基于总组合物的重量,本发明的组合物可以包含0.1-50wt%,优选地0.1-40wt%,更优选地0.1-20wt%和最优选地0.1-5wt%的成色物质。
基于总组合物的重量,本发明的组合物可以包含10-95wt%,优选地20-95wt%,更优选地50-95wt%和最优选地70-90wt%的溶剂。
基于总组合物的重量,本发明的组合物可以包含1-80wt%,优选地1-60wt%,更优选地1-40wt%和最优选地1-20wt%的聚合物粘结剂。
基于总组合物的重量,本发明的组合物可以包含0-30wt%,优选地0-20wt%,更优选地0-10wt%和最优选地0-5wt%的另外组分。
本发明的组合物可以由1-50wt%的潜活化剂、0.1-50wt%的成色物质、10-95wt%的溶剂、1-80wt%的聚合物粘结剂和0-30wt%的另外组分组成,所有都基于总组合物的重量。
优选地,本发明的组合物可以由1-40wt%的潜活化剂、0.1-40wt%的成色物质、20-95wt%的溶剂、1-60wt%的聚合物粘结剂和0-20wt%的另外组分组成,所有都基于总组合物的重量。
更优选地,本发明的组合物可以由1-20wt%的潜活化剂、0.1-20wt%的成色物质、50-95wt%的溶剂、1-40wt%的聚合物粘结剂和0-10wt%的另外组分组成,所有都基于总组合物的重量。
最优选地,本发明的组合物可以由1-5wt%的潜活化剂、0.1-5wt%的成色物质、70-90wt%的溶剂、1-20wt%的聚合物粘结剂和0-5wt%的另外组分组成,所有都基于总组合物的重量。
本发明另一部分是用于制备本发明组合物的方法,该方法包括混合潜活化剂和成色物质。优选地,该方法包括混合潜活化剂、成色物质和溶剂。更优选地,该方法包括混合潜活化剂、成色物质、溶剂、聚合物粘结剂和任选地另外组分。
本发明的又一部分是用本发明涂料组合物涂布的基材。
该基材可以是一种片材或任何其它三维物体,它可以是透明的或不透明的和它可以具有平坦或不平坦的表面。具有不平坦表面的基材的实例是填充纸袋(filled paper bag),如水泥纸袋(paper bag ofcement)。该基材可以由纸、纸板、金属、木材、纺织品、玻璃、陶瓷和/或聚合物制造。该基材还可以是药物片剂或食品。聚合物的实例是聚对苯二甲酸乙二醇酯、低密度聚乙烯、聚丙烯、双轴取向聚丙烯、聚醚砜、聚氯乙烯、聚酯和聚苯乙烯。优选地,该基材是由纸、纸板或聚合物制造的。
涂层的厚度通常经选择为0.1-1000μm。优选地,它为1-500μm。更优选地,它为1-200μm。最优选地,它为1-120μm。
本发明的另一方面是用于制备被涂布的基材的方法,其包括用本发明的组合物涂布基材的步骤。
该基材可以通过使用标准涂布施用法例如棒涂器施用法、滚涂法、喷涂法、帘涂法、浸涂法、空气施用法、刀涂法、刮涂法或辊涂法来涂布本发明组合物。该组合物也可以由各种印刷方法例如丝网印刷、凹版印刷、胶版印刷、和柔版印刷施用到该基材上。若该基材是纸,则该组合物也可以在胶涂压机中或纸机的湿端施用。
该涂料组合物可以,例如,在常温或升高的温度下干燥。理想地选择升高的温度,以避免在暴露于能量之前图像形成。
此外,本发明的又一部分是一种有标记基材的制备方法,包括下列步骤:i)用本发明组合物涂布基材,和ii)使意图进行标记的被涂布的基材的那些部分暴露于能量以产生标记。
该能量可以是热量或任何其它能量,其当被施加到涂布了本发明组合物的基材上时产生标记。这种能量的实例是UV、IR、可见光或微波辐照。
该能量可以以任何适用方式施加到被涂布的基材上,例如,热量可以使用热打印机来施加,UV、可见光和IR辐照可以使用UV、可见光或IR激光器来施加。IR激光器的实例是CO2激光器,Nd:YAG(钕-钇铝石榴石)激光器和IR半导体激光器。
优选地,该能量是IR辐照。更优选地,该能量是其波长在780~1’000’000nm范围内的IR辐照。还更优选地,该能量是由CO2激光器或Nd:YAG激光器产生的IR辐照。最优选地,该能量是具有10’600nm波长的CO2激光器产生的IR辐照。
典型地,该IR激光器的确切功率和线速度决定于该应用,而且进行选择以足以产生该图像,例如,当该IR激光器的波长是10600nm且该激光束的直径是0.35mm时,功率典型地是0.5~4W,且线速度典型地是300~1000mm/s。
本发明的另一个方面是由上述方法得到的有标记的基材。
本发明的涂料组合物有下列优点,即可以产生任何希望的颜色的透明的、高对比彩色图像而不使用重金属。
实施例
实施例1将5.0g(0.05mol)环己醇和11.2g(0.1mol)1,4-二氮杂双环[2.2.2]辛烷加入到50mL乙酸乙酯中。该溶液在冰浴中冷却,在15分钟期间,滴加在30ml乙酸乙酯中的14.3g(0.075mol)甲苯磺酰氯。移去冰浴并且使该混合物在室温下搅拌4天。然后,过滤并冲洗固体沉淀。然后将乙酸乙酯滤液和洗涤物合并并且依次用10%HCl、NaHCO3的饱和水溶液和盐水进行冲洗。然后蒸发出乙酸乙酯,通过柱色层分离法纯化该获得的油以得到11.5g(90%)的对-甲苯磺酸环己酯。
实施例2:将5.7g(0.05mol)2-甲基环己醇和11.2g(0.1mol)1,4-二氮杂双环[2.2.2]辛烷加入到50mL乙酸乙酯中。该溶液在冰浴中冷却,在20分钟期间,滴加在30ml乙酸乙酯中的14.3g(0.075mol)甲苯磺酰氯。移去冰浴并且使该混合物在室温下搅拌4天。然后,过滤并冲洗固体沉淀。然后将乙酸乙酯滤液和洗涤物合并并且依次用10%HCl、NaHCO3的饱和水溶液和盐水进行冲洗。然后蒸发出乙酸乙酯以得到12.7g(95%)的对-甲苯磺酸2-甲基环己酯。
实施例3:将7.8g(0.05mol)DL-薄荷醇和11.2g(0.1mol)1,4-二氮杂双环[2.2.2]辛烷加入到50mL乙酸乙酯中。该溶液在冰浴中冷却,在15分钟期间,滴加在30ml乙酸乙酯中的14.3g(0.075mol)甲苯磺酰氯。移去冰浴并且使该混合物在室温下搅拌4天。然后,过滤并冲洗固体沉淀。然后将乙酸乙酯滤液和洗涤物合并并且依次用10%HCl、NaHCO3的饱和水溶液和盐水进行冲洗。然后蒸发出乙酸乙酯以得到11.5g(74%)的对-甲苯磺酸薄荷基酯。
实施例4:将5.8g(0.05mol)1,4-环己二醇和22.4g(0.2mol)1,4-二氮杂双环[2.2.2]辛烷加入到75mL乙酸乙酯中。该溶液在冰浴中冷却,在15分钟期间,滴加在75ml乙酸乙酯中的28.6g(0.15mol)甲苯磺酰氯。移去冰浴并且使该混合物在室温下搅拌4天。然后,过滤并冲洗固体沉淀。然后将乙酸乙酯滤液和洗涤物合并并且依次用10%HCl、NaHCO3的饱和水溶液和盐水进行冲洗。然后蒸发出乙酸乙酯以得到20.2g(95%)的对-甲苯磺酸薄荷基酯。
实施例5:将4.3g(0.025mol)4-羟基环己烷羧酸乙酯和5.6g(0.05mol)1,4-二氮杂双环[2.2.2]辛烷加入到25mL乙酸乙酯中。该溶液在冰浴中冷却,在15分钟期间,滴加在20ml乙酸乙酯中的7.15g(0.0375mol)的甲苯磺酰氯。移去冰浴并且使该混合物在室温下搅拌4天。然后,过滤并冲洗固体沉淀。然后将乙酸乙酯滤液和洗涤物合并并且依次用10%HCl、NaHCO3的饱和水溶液和盐水进行冲洗。然后蒸发出乙酸乙酯以得到7.0g(90%)的对-甲苯磺酸薄荷基酯。
实施例6:将4.3g(0.025mol)2,2-二甲基-1-丙醇和5.6g(0.05mol)1,4-二氮杂双环[2.2.2]辛烷加入到25mL乙酸乙酯中。该溶液在冰浴中冷却,在15分钟期间,滴加在20ml乙酸乙酯中的7.15g(0.0375mol)的甲苯磺酰氯。移去冰浴并且使该混合物在室温下搅拌4天。然后,过滤并冲洗固体沉淀。然后将乙酸乙酯滤液和洗涤物合并并且依次用10%HCl、NaHCO3的饱和水溶液和盐水进行冲洗。然后蒸发出乙酸乙酯以得到5.6g(92%)的对-甲苯磺酸薄荷基酯。
实施例7
如实施例1中所描述的那样进行制备的对-甲苯磺酸环己酯(1.0g)在丙酮(8.6g)中搅拌。按以下顺序向此混合物中添加:结晶紫内酯(1.0g),例如以 Blue1-2RN销售的,聚(甲基丙烯酸甲酯)(3.4g),2-羟基-4-甲氧基苯酰苯(0.6g)和甲乙酮(17.6g)。然后,该涂料组合物用涂布棒施用到普通纸(plain paper)、涂布纸或聚对苯二甲酸乙二醇酯薄膜上,形成120μm的涂层,在常温下干燥,使用CO2激光器(波长10600nm,功率0.5~4W,激光束直径0.35mm,线速度300~1000mm/s)成像,得到蓝色标记。
实施例8
如实施例7中所描述的那样制备一种涂料组合物,所不同的是使用如实施例2中所描述的那样制备的甲苯磺酰化醇(tosylatedalcohol)(1.0g)。
实施例9
如实施例7中所描述的那样制备一种涂料组合物,所不同的是使用如实施例3中所描述的那样制备的甲苯磺酰化醇(1.0g)。
实施例10
如实施例7中所描述的那样制备一种涂料组合物,所不同的是使用如实施例4中所描述的那样制备的甲苯磺酰化醇(1.0g)。
实施例11
如实施例7中所描述的制备一种涂料组合物,不同在于使用如实施例5中所描述的那样制备的甲苯磺酰化醇(1.0g)。
实施例12
如实施例7中所描述的制备一种涂料组合物,不同在于使用如实施例6中所描述的那样制备的甲苯磺酰化醇(1.0g)。
实施例13
如实施例5中所描述的那样制备的甲苯磺酰化醇(1.0g)在丙酮(8.6g)中搅拌。按以下顺序向此混合物中添加: RedI-6B(0.25g),聚(甲基丙烯酸甲酯)(3.4g),2-羟基-4-甲氧基苯酰苯(0.6g)和甲乙酮(17.6g)。然后,该涂料组合物用涂布棒施用到普通纸、涂布纸或聚对苯二甲酸乙二醇酯薄膜上,形成120μm的涂层,在常温下干燥,并使用CO2激光器(波长10600nm,功率0.5~4W,激光束直径0.35mm,线速度300~1000mm/s)成像,得到红色标记。
实施例14
Claims (11)
1.一种组合物,包含潜活化剂和成色物质。
2.权利要求1的组合物,其中该潜活化剂是酸衍生物或酸和胺的盐。
3.权利要求1~2中任一项的组合物,其中该成色物质选自:苯酞、荧烷、三芳基甲烷、苯并噁嗪、喹唑啉、螺吡喃、醌、噻嗪和噁嗪和其混合物。
4.权利要求1~3中任何一项的组合物,其中该组合物还包含溶剂。
5.权利要求1~4中任何一项的组合物,其中该组合物还包含聚合物粘结剂。
6.一种用于制备权利要求1~5中任一项的组合物的方法,包括使潜活化剂与成色物质混合的步骤。
7.一种基材,涂布了权利要求1~5中任何一项的涂料组合物。
8.一种用于制备被涂布的基材的方法,包括用权利要求1~5中任何一项的组合物涂布基材的步骤。
9.一种用于制备有标记的基材的方法,包括下列步骤:i)用权利要求1~5中任何一项的组合物涂布基材,和ii)使意图进行标记的被涂布的基材的那些部分暴露于能量,以产生标记。
10.权利要求9的方法,其中该能量选自UV、IR、可见光和微波辐照。
11.一种有标记的基材,其通过权利要求8~10中任一项的方法获得。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP06101082 | 2006-01-31 | ||
EP06101082.3 | 2006-01-31 |
Publications (1)
Publication Number | Publication Date |
---|---|
CN101374673A true CN101374673A (zh) | 2009-02-25 |
Family
ID=36648550
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNA2007800038929A Pending CN101374673A (zh) | 2006-01-31 | 2007-01-17 | 用于标记基材的涂料组合物 |
Country Status (12)
Country | Link |
---|---|
US (1) | US8021820B2 (zh) |
EP (1) | EP1981717A1 (zh) |
JP (1) | JP2009525369A (zh) |
KR (1) | KR20080091285A (zh) |
CN (1) | CN101374673A (zh) |
AU (1) | AU2007211586A1 (zh) |
BR (1) | BRPI0706785A2 (zh) |
CA (1) | CA2637139A1 (zh) |
IL (1) | IL192729A0 (zh) |
RU (1) | RU2008135122A (zh) |
WO (1) | WO2007088104A1 (zh) |
ZA (1) | ZA200805853B (zh) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108290434A (zh) * | 2015-11-30 | 2018-07-17 | 爱克发-格法特公司 | 可激光标记的组合物和用其制造包装的方法 |
Families Citing this family (31)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2099615B1 (en) * | 2007-01-09 | 2017-08-02 | DataLase Ltd | Electromagnetic radiation or thermally sensitive composition |
JP5448853B2 (ja) | 2007-03-15 | 2014-03-19 | データレース リミテッド | レゾルシニルトリアジン誘導体を主成分とする感熱性コーティング組成物 |
KR20100037148A (ko) | 2007-07-18 | 2010-04-08 | 바스프 에스이 | 레이저 감응성 코팅 제제 |
ATE538185T1 (de) * | 2007-08-22 | 2012-01-15 | Datalase Ltd | Laserempfindliche beschichtungszusammensetzung |
US8900414B2 (en) | 2007-11-07 | 2014-12-02 | Datalase, Ltd. | Fiber products |
US8557510B2 (en) * | 2008-09-10 | 2013-10-15 | Datalase Ltd. | Colour forming composition |
ES2400585T3 (es) * | 2008-10-02 | 2013-04-10 | Basf Se | Composiciones de color cambiante, multicolor, fotoactivas, y dosímetros de UV |
US8853314B2 (en) | 2008-10-23 | 2014-10-07 | Datalase Ltd. | Heat absorbing additives |
WO2010049281A1 (en) | 2008-10-27 | 2010-05-06 | Basf Se | Aqueous laser-sensitive composition for marking substrates |
EP2342295A1 (en) | 2008-10-27 | 2011-07-13 | DataLase Ltd | Coating composition for marking substrates |
US20110054085A1 (en) * | 2009-08-28 | 2011-03-03 | Dgel Sciences | Label for polymer gel and methods thereof |
US20120288690A1 (en) * | 2009-11-16 | 2012-11-15 | Basf Se | Multi color, photoactive, color changing compositions |
CN103561962B (zh) | 2011-05-25 | 2016-08-24 | 利乐拉瓦尔集团及财务有限公司 | 改进的近红外吸收剂 |
WO2013023673A1 (en) | 2011-08-12 | 2013-02-21 | Tetra Laval Holdings & Finance S.A. | Novel marking compound |
CN103619606B (zh) | 2011-08-12 | 2016-04-27 | 利乐拉瓦尔集团及财务有限公司 | 含有氨基酸的过氧基钼复合物的用途、包含该复合物的组合物、基底以及标记该基底的方法 |
ES2577016T3 (es) | 2011-11-10 | 2016-07-12 | Datalase Ltd | Método de formar una imagen sobre un sustrato |
US8871424B2 (en) * | 2012-01-20 | 2014-10-28 | Cryovac, Inc. | Laser imageable polyolefin film |
GB201222955D0 (en) | 2012-12-19 | 2013-01-30 | Innovia Films Ltd | Film |
GB201222961D0 (en) | 2012-12-19 | 2013-01-30 | Innovia Films Ltd | Label |
DE102015005672A1 (de) | 2015-05-04 | 2016-11-10 | Giesecke & Devrient Gmbh | Sicherheitsmerkmal und Verfahren zu dessen Herstellung |
EP3313571A1 (en) * | 2015-06-24 | 2018-05-02 | AM Technology Limited | Photocatalytic composition based on an aerial binder and use thereof for the production of water-based paints, in particular for interior applications |
DE102016002120A1 (de) | 2016-02-24 | 2017-08-24 | Giesecke & Devrient Gmbh | Sicherheitsmerkmal und Verfahren zu dessen Herstellung |
EP3219503A1 (en) * | 2016-03-16 | 2017-09-20 | Agfa-Gevaert | Process for manufacturing a laser markable packaging |
DE102016004424A1 (de) | 2016-04-12 | 2017-10-12 | Giesecke+Devrient Currency Technology Gmbh | Laserung einer Beschichtung mit Effektpigmenten |
DE102016006929A1 (de) | 2016-06-06 | 2017-12-07 | Giesecke+Devrient Currency Technology Gmbh | Sicherheitsmerkmal und Verfahren zu dessen Herstellung |
DE102016006931A1 (de) | 2016-06-06 | 2017-12-07 | Giesecke+Devrient Currency Technology Gmbh | Sicherheitsmerkmal und Verfahren zu dessen Herstellung |
US11612897B2 (en) * | 2017-05-24 | 2023-03-28 | Basf Se | Alkylated triphenyl phosphorothionates as selective metal sulphide collectors |
EP3415498A1 (en) | 2017-06-12 | 2018-12-19 | Agfa Nv | A developing agent precursor for laser markable compositions |
CN110831778B (zh) | 2017-07-03 | 2022-07-01 | 爱克发有限公司 | 可近红外(nir)激光标记的组合物 |
EP3924191A1 (de) | 2019-02-15 | 2021-12-22 | Lacotra GmbH | Verfahren zur übertragung farbiger markierungen auf kunststoffoberflächen |
CN112063302A (zh) * | 2020-09-23 | 2020-12-11 | 何志强 | 一种环保木器油漆及其制备方法 |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4820683A (en) * | 1987-12-04 | 1989-04-11 | Appleton Papers Inc. | Thermally-responsive record material |
JP2751089B2 (ja) | 1992-11-30 | 1998-05-18 | 大日本インキ化学工業株式会社 | レーザーマーキング方法及び印刷インキ |
JPH07223371A (ja) | 1993-04-30 | 1995-08-22 | Ricoh Co Ltd | 感熱記録材料 |
TW363016B (en) * | 1996-01-08 | 1999-07-01 | Nippon Kayaku Kk | Laser marking article having two or more layers of thin films on the surface thereof, method for laser marking of the article and ground composition for use in laser marking |
JP4296644B2 (ja) * | 1999-01-29 | 2009-07-15 | 豊田合成株式会社 | 発光ダイオード |
US6210472B1 (en) * | 1999-04-08 | 2001-04-03 | Marconi Data Systems Inc. | Transparent coating for laser marking |
US6888095B2 (en) | 2001-02-28 | 2005-05-03 | Sherwood Technology, Inc. | Laser coding |
GB0114265D0 (en) * | 2001-06-12 | 2001-08-01 | Ciba Sc Holding Ag | Polymeric material containing a latent acid |
ATE517756T1 (de) | 2002-11-12 | 2011-08-15 | Datalase Ltd | Verwendung von übergangsmetallverbindungen in bilderzeugenden beschichtungen |
GB0228647D0 (en) * | 2002-12-09 | 2003-01-15 | Ciba Sc Holding Ag | Polyeric material containing a latent acid |
ATE406421T1 (de) * | 2003-07-30 | 2008-09-15 | Datalase Ltd | Lasermarkierbare zusammensetzungen |
US7144676B2 (en) * | 2004-02-06 | 2006-12-05 | Rohm And Haas Electronic Materials Llc | Imaging compositions and methods |
US7163909B2 (en) | 2004-04-23 | 2007-01-16 | Appleton Papers Inc. | Authenticity indicator |
GB0428299D0 (en) * | 2004-12-24 | 2005-01-26 | Ciba Sc Holding Ag | Coating compositions for marking substrates |
-
2007
- 2007-01-17 BR BRPI0706785-2A patent/BRPI0706785A2/pt not_active IP Right Cessation
- 2007-01-17 WO PCT/EP2007/050421 patent/WO2007088104A1/en active Application Filing
- 2007-01-17 AU AU2007211586A patent/AU2007211586A1/en not_active Abandoned
- 2007-01-17 CA CA 2637139 patent/CA2637139A1/en not_active Abandoned
- 2007-01-17 CN CNA2007800038929A patent/CN101374673A/zh active Pending
- 2007-01-17 JP JP2008552769A patent/JP2009525369A/ja not_active Withdrawn
- 2007-01-17 US US12/087,806 patent/US8021820B2/en active Active
- 2007-01-17 EP EP07712043A patent/EP1981717A1/en not_active Withdrawn
- 2007-01-17 RU RU2008135122/12A patent/RU2008135122A/ru not_active Application Discontinuation
- 2007-01-17 KR KR1020087021320A patent/KR20080091285A/ko not_active Application Discontinuation
-
2008
- 2008-07-04 ZA ZA200805853A patent/ZA200805853B/xx unknown
- 2008-07-09 IL IL192729A patent/IL192729A0/en unknown
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108290434A (zh) * | 2015-11-30 | 2018-07-17 | 爱克发-格法特公司 | 可激光标记的组合物和用其制造包装的方法 |
Also Published As
Publication number | Publication date |
---|---|
EP1981717A1 (en) | 2008-10-22 |
ZA200805853B (en) | 2009-10-28 |
US20090191420A1 (en) | 2009-07-30 |
BRPI0706785A2 (pt) | 2011-04-05 |
JP2009525369A (ja) | 2009-07-09 |
AU2007211586A1 (en) | 2007-08-09 |
IL192729A0 (en) | 2009-02-11 |
RU2008135122A (ru) | 2010-03-10 |
US8021820B2 (en) | 2011-09-20 |
KR20080091285A (ko) | 2008-10-09 |
CA2637139A1 (en) | 2007-08-09 |
WO2007088104A1 (en) | 2007-08-09 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN101374673A (zh) | 用于标记基材的涂料组合物 | |
EP1828296B1 (en) | Coating compositions for marking substrates | |
CN101801676B (zh) | 激光敏感涂料制剂 | |
EP2349734B1 (en) | Aqueous laser-sensitive composition for marking substrates | |
KR20090118106A (ko) | 언더코팅 층을 가지는 레이저―감응성 기록 재료 | |
US9267042B2 (en) | Coating composition for marking substrates |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
WD01 | Invention patent application deemed withdrawn after publication |
Open date: 20090225 |