CN101328418A - 一种利用植物油制造生物柴油的方法 - Google Patents

一种利用植物油制造生物柴油的方法 Download PDF

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Publication number
CN101328418A
CN101328418A CNA2007101233314A CN200710123331A CN101328418A CN 101328418 A CN101328418 A CN 101328418A CN A2007101233314 A CNA2007101233314 A CN A2007101233314A CN 200710123331 A CN200710123331 A CN 200710123331A CN 101328418 A CN101328418 A CN 101328418A
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China
Prior art keywords
mixture
condenser
vegetables oil
oil
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CNA2007101233314A
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English (en)
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俞炳宇
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Yantai Bodesi Chemical Co Ltd
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Individual
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Priority to CNA2007101233314A priority Critical patent/CN101328418A/zh
Priority to PCT/KR2008/003565 priority patent/WO2009002065A1/en
Publication of CN101328418A publication Critical patent/CN101328418A/zh
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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
    • C11C3/00—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
    • C11C3/04—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by esterification of fats or fatty oils
    • C11C3/06—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by esterification of fats or fatty oils with glycerol
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
    • C11C3/00—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
    • C11C3/003—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by esterification of fatty acids with alcohols
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1011—Biomass
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/10—Biofuels, e.g. bio-diesel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock

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  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Liquid Carbonaceous Fuels (AREA)

Abstract

本发明涉及一种利用植物油制造生物柴油的方法，具体是一种利用植物油在酸性或碱性催化剂的作用下，通过与低分子酒精发生反应而形成脂肪酸酯，再利用乙醇酸类物质经过离心分离，最后得到生物柴油。本发明可降低大气环境污染物质的排放度，并属可再生利用资源。

Description

一种利用植物油制造生物柴油的方法
技术领域
本发明涉及内燃机所用柴油及其生产方法，特别是涉及到利用植物油制造生物柴油的生产技术。
背景技术
普通柴油是不可在生能源，随着人类社会的进步正逐渐消耗待尽，同时普通柴油的燃烧率不高，燃烧热量不足，有些燃料含水分过高，容易使发动机发生腐蚀，燃烧不完全，燃烧过后还会产生许多残渣，对环境产生污染。
发明内容
本发明的目的，是提供一种燃烧率高、燃烧热量充足、低含水量、燃烧残留物环保的利用植物油制造生物柴油的生产方法。
本发明将植物油，在酸性或碱性催化剂的作用下，通过与低分子酒精发生反应而形成的脂肪酸酯。
本发明的技术方案如下：
本发明利用冷凝器将植物油，在酸性或碱性催化剂的作用下，通过与低分子酒精发生反应而形成脂肪酸酯；
然后通过离心分离将反应产生的甘油从脂肪酸酯中分离出来；
最后加入乙醇酸钠进行过滤将反应附加产生的碱等残余物从脂肪酸酯中分离出来；
具体实施方式
实施例1。按照下列步骤制作本发明的生物柴油：
a、在冷凝器中加入植物油30升，再加入乙醇50升，然后加入10升的溶剂油，再加入10升的氢氧化钠；
b、将冷凝器中的混合物加热至60℃，恒温反应三个小时；
c、在蒸馏后得到的混合物中加入3升的乙醇酸钠；
d、将c中的混合物进行离心分离，得到成品。

Claims (8)

1、一种利用植物油制造生物柴油方法，其特征在于：该生物柴油原料组成的体积百分比如下：
植物油    30％    乙醇        50％
溶剂油    10％    氢氧化钠    10％
2、根据权利要求1所述的一种利用植物油制造生物柴油方法，其特征在于：乙醇可以用甲醇代替。
3、根据权利要求1所述的一种利用植物油制造生物柴油方法，其特征在于：氢氧化钠可以用氢氧化钾代替。
4、根据权利要求1所述的一种利用植物油制造生物柴油方法，其特征在于：氢氧化钠可以用碳酸钠代替。
5、根据权利要求1所述的一种利用植物油制造生物柴油方法，其特征在于：按下述步骤制作：
a、在冷凝器中加入植物油、乙醇、溶剂油、氢氧化钠；
b、将冷凝器中的混合物加热至60℃，恒温反应；
c、在蒸馏后得到的混合物中加入乙醇酸钠；
d、将c中的混合物进行离心分离，得到成品。
6、根据权利要求2所述的一种含乙醇的替代燃料，其特征在于：按下述步骤制作：
e、在冷凝器中加入植物油、甲醇、溶剂油、氢氧化钠；
f、将冷凝器中的混合物加热至60℃，恒温反应；
g、在蒸馏后得到的混合物中加入乙醇酸钠；
h、将c中的混合物进行离心分离，得到成品。
7、根据权利要求3所述的一种含乙醇的替代燃料，其特征在于：按下述步骤制作：
i、在冷凝器中加入植物油、乙醇、溶剂油、氢氧化钾；
j、将冷凝器中的混合物加热至60℃，恒温反应；
k、在蒸馏后得到的混合物中加入乙醇酸钠；
l、将c中的混合物进行离心分离，得到成品。
8、根据权利要求4所述的一种含乙醇的替代燃料，其特征在于：按下述步骤制作：
m、在冷凝器中加入植物油、乙醇、溶剂油、碳酸钠；
n、将冷凝器中的混合物加热至60℃，恒温反应；
o、在蒸馏后得到的混合物中加入乙醇酸钠；
p、将c中的混合物进行离心分离，得到成品。
CNA2007101233314A 2007-06-22 2007-06-22 一种利用植物油制造生物柴油的方法 Pending CN101328418A (zh)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CNA2007101233314A CN101328418A (zh) 2007-06-22 2007-06-22 一种利用植物油制造生物柴油的方法
PCT/KR2008/003565 WO2009002065A1 (en) 2007-06-22 2008-06-23 Method for manufacturing biodiesel fuel from vegetable oil

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CNA2007101233314A CN101328418A (zh) 2007-06-22 2007-06-22 一种利用植物油制造生物柴油的方法

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101831280A (zh) * 2010-05-19 2010-09-15 濮阳市诚信钻采助剂有限公司 消泡剂有效成分的载体及其制备方法
WO2012171326A1 (zh) 2011-06-13 2012-12-20 易高环保能源研究院有限公司 从生物性油脂制备燃料的方法
CN111408298A (zh) * 2020-04-03 2020-07-14 王磊 一种生物液体燃料及其制备系统与方法

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3028282B2 (ja) * 1996-02-28 2000-04-04 有限会社染谷商店 廃食用油を原資源として精製する重油バーナー用燃料および廃食用油を原資源としての再利用方法
JP4556268B2 (ja) * 2000-02-17 2010-10-06 住友化学株式会社 脂肪酸エステルの製造方法
JP4392529B2 (ja) * 2003-04-04 2010-01-06 日立造船株式会社 廃油脂からのディーゼル燃料油の製造方法
JP4374219B2 (ja) * 2003-08-18 2009-12-02 ダイキ株式会社 廃油脂のケミカルリサイクル方法
KR20060108141A (ko) * 2005-04-12 2006-10-17 김재종 폐식용유를 이용한 디젤연료의 제조방법

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101831280A (zh) * 2010-05-19 2010-09-15 濮阳市诚信钻采助剂有限公司 消泡剂有效成分的载体及其制备方法
CN101831280B (zh) * 2010-05-19 2013-12-18 濮阳市诚信钻采助剂有限公司 消泡剂有效成分的载体及其制备方法
WO2012171326A1 (zh) 2011-06-13 2012-12-20 易高环保能源研究院有限公司 从生物性油脂制备燃料的方法
US9938468B2 (en) 2011-06-13 2018-04-10 Eco Environmental Energy Research Institute Limited Method for preparing fuel by using biological oils and fats
CN111408298A (zh) * 2020-04-03 2020-07-14 王磊 一种生物液体燃料及其制备系统与方法
CN111408298B (zh) * 2020-04-03 2022-06-03 贵州六维新能源股份有限公司 一种生物液体燃料及其制备系统与方法

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Owner name: YANTAI BODESI CHEMICAL CO., LTD.

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Applicant before: Yu Bingyu

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Application publication date: 20081224