CN101328379A - Epoxy cement based road antiskid coating and preparation thereof - Google Patents
Epoxy cement based road antiskid coating and preparation thereof Download PDFInfo
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- CN101328379A CN101328379A CNA2007100424545A CN200710042454A CN101328379A CN 101328379 A CN101328379 A CN 101328379A CN A2007100424545 A CNA2007100424545 A CN A2007100424545A CN 200710042454 A CN200710042454 A CN 200710042454A CN 101328379 A CN101328379 A CN 101328379A
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- solidifying agent
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Abstract
Epoxy cement group road nonskid paint consists of three components, namely epoxy latex, a curing agent and powder materials. The curing agent is prepared from triethylene triamine or triethylene tetramine and versamid resin which are mixed. The powder materials consist of silicate cement, quartz sand and a water reducing agent. The invention also discloses a preparation method for the epoxy cement group road nonskid paint. The epoxy cement group road nonskid paint saves resources with healthfulness, environmental friendliness, safety and convenience during use.
Description
Technical field
The present invention relates to a kind of epoxy cement based road antiskid coating, be suitable for the ground under the various environment, anti-skidding such as office, room, playground, drome, steamer, mill floor the invention still further relates to the preparation method of this epoxy cement based road antiskid coating.
Background technology
The existing road skid-resistant coating is a binding agent with Resins, epoxy or urethane resin mostly both at home and abroad at present, is skid-resistant coating with quartz sand, silicon carbide, titanium oxide and common rubber grain.These products at aspects such as anti-collision performance, abrasion resistance properties and sticking power, still can not satisfy high-intensity service requirements mostly, exist easily cracked, come off and defective such as work-ing life is short.
It is a kind of with the skid-resistant coating of polyurethane elastomer particle as main anti-skidding pellet that Chinese patent 96116347.X provides, it comprises first component polyurethane performed polymer, component B chainextender or solidifying agent and the third component solid grain, the third component solid grain is the scrap stock that are ground into 10-80 purpose polyurethane product.But adopt base polyurethane prepolymer for use as usually to be accompanied by the phenomenon of film coated surface foaming or pin hole.
Summary of the invention
One of technical problem to be solved by this invention is to provide a kind of epoxy cement based road antiskid coating, this epoxy cement-based adhesive adopts the oil-in-water epoxy emulsion that forms through special emulsifying process, given full play to the high cohesive force of Resins, epoxy, aqueous, environmental protective, the advantage that is easy to construct add inorganic coagulation material cement and have solved anti-slip material tackiness, endurance issues again.
Two of technical problem to be solved by this invention is to provide the preparation method of above-mentioned epoxy cement based road anti-slip material.
Epoxy cement based road antiskid coating as first aspect present invention is characterized in that, is made up of epoxy emulsion, solidifying agent, powder three components, and the weight ratio between the three is 100: 0.05-0.1: 200-300.
In epoxy cement based road anti-slip material of the present invention, the solids content of epoxy emulsion is preferably 25-30.Described epoxy emulsion is an aqueous epoxy emulsion.
In epoxy cement based road anti-slip material of the present invention, described solidifying agent is mixed by triethylene triamine and low molecule pa resin, and both weight ratios are 1-2: 1-3.Perhaps described solidifying agent is mixed by triethylene tetramine and low molecule pa resin, and both weight ratios are 1-2: 1-3.
In epoxy cement based road anti-slip material of the present invention, described powder is made up of silicate cement, quartz sand, water reducer, and the weight ratio between them is a silicate cement: quartz sand: water reducer 100: 150-180: 0.2-0.4.
Described quartz sand is mixed by the 16 order quartz sands and the 40 order quartz sands of equal proportion.
Described silicate cement is preferably early-strength type 42.5 ordinary Portland cements.Described water reducer is a naphthalene water reducer.
As epoxy cement based road anti-slip material preparation method of the present invention, comprise the steps:
1, the preparation of epoxy emulsion
Epoxy emulsion is diluted to solids content to 25-30;
2, the preparation of solidifying agent
Triethylene triamine or triethylene tetramine and low molecule pa resin be mixed in proportion make solidifying agent;
3, the preparation of powder
A, water reducer weight 30-50 60 order quartz sands were doubly put into the ball mill mixing 3-5 minute with water reducer;
B, remaining quartz sand and the silicate cement that takes by weighing in proportion put into together carry out dried stirring in the mortar mixer?-5 minutes;
C, the compound of step a gained is put in the compound of step b gained, stirred;
4, the epoxy emulsion of step 1 gained, the solidifying agent of step 2, the powder of step 3 are packed separately, mixed during use and get final product.
Oil-in-water epoxy emulsion of the present invention is a response type because of having epoxy group(ing) and hydroxyl to give emulsion, makes the cured article of emulsion have very strong force of cohesion and bonding force, and ehter bond and hydroxyl are polar groups, help to improve wetting property and bonding strength.Ehter bond and C-C key make macromole have snappiness.Phenyl ring is given polymer emulsion with heat-resisting, freeze-thawing resistant and rigidity.The bond energy height of-C-O-key, thus the alkali resistance of emulsion improved.The Water Soluble Compound solidifying agent is soluble in the emulsion of water-based, also changes its set of dispense ratio because of construction environment or changes of seasons, to adapt to different requirements.Cement, high grade quartz sand have been given the intensity, weather resistance of epoxy cement based road antiskid coating, lower shrinkage value.Water reducer gives tackiness agent mix, intensity height, characteristics that wetting property is good.The present invention is health environment-friendly in use, economizes on resources, safe ready.
Embodiment
For technique means, creation characteristic that the present invention is realized, reach purpose and effect is easy to understand, below in conjunction with embodiment, further set forth the present invention.
Embodiment 1
Epoxy cement based road antiskid coating is made up of 100kg epoxy emulsion, 5kg solidifying agent, 250.2kg powder three components.
Epoxy emulsion is oil-in-water aqueous epoxy emulsion, and its solids content is 25-30.
Solidifying agent is mixed by triethylene triamine and low molecule pa resin, and wherein the triethylene triamine is 2.5kg, and low molecule pa resin is 2.5kg.
250.2kg powder is made up of 100kg early-strength type 42.5 ordinary Portland cements, 75kg16 order quartz sand, 75kg60 order quartz sand, 0.2kg naphthalene water reducer,
The preparation method of above-mentioned epoxy cement based road antiskid coating comprises the steps:
1, the preparation of epoxy emulsion
Epoxy emulsion is diluted to 100kg, and its solids content is to 25-30;
2, the preparation of solidifying agent
With 2.5kg triethylene triamine and the mixed solidifying agent that gets of 2.5kg low molecule pa resin;
3, the preparation of powder
A, the 60 order quartz sands and the water reducer of 50 times of water reducer weight are put into ball mill mixed 5 minutes;
B, remaining quartz sand and early-strength type 42.5 ordinary Portland cements that take by weighing are in proportion put into together carry out dried stirring 5 minutes in the mortar mixer;
C, the compound of step a gained is put in the compound of step b gained, stirred about half hour;
4, the epoxy emulsion of step 1 gained, the solidifying agent of step 2, the powder of step 3 are packed separately, mixed during use and get final product.
Above-mentioned water reducer is not limited to naphthalene water reducer, and other water reducer is also passable.
Embodiment 2
Epoxy cement based road antiskid coating is made up of 100kg epoxy emulsion, 8kg solidifying agent, 250.3kg powder three components.
Epoxy emulsion is oil-in-water aqueous epoxy emulsion, and its solids content is 25-30.
Solidifying agent is mixed by triethylene tetramine and low molecule pa resin, and wherein triethylene tetramine is 4kg, and low molecule pa resin is 4kg.
250.3kg powder is made up of 100kg early-strength type 42.5 ordinary Portland cements, 75kg16 order quartz sand, 75kg60 order quartz sand, 0.3kg naphthalene water reducer,
Above-mentioned epoxy cement based road antiskid coating preparation method comprises the steps:
1, the preparation of epoxy emulsion
Epoxy emulsion is diluted to 100kg, and its solids content is to 25-30;
2, the preparation of solidifying agent
With 4kg triethylene tetramine and the mixed solidifying agent that gets of 4kg low molecule pa resin;
3, the preparation of powder
A, the 60 order quartz sands and the water reducer of 50 times of water reducer weight are put into ball mill mixed 5 minutes;
B, remaining quartz sand and early-strength type 42.5 ordinary Portland cements that take by weighing are in proportion put into together carry out dried stirring 5 minutes in the mortar mixer;
C, the compound of step a gained is put in the compound of step b gained, stirred about half hour;
4, the epoxy emulsion of step 1 gained, the solidifying agent of step 2, the powder of step 3 are packed separately, mixed during use and get final product.
Embodiment 3
Epoxy cement based road antiskid coating is made up of 100kg epoxy emulsion, 6kg solidifying agent, 250.4kg powder three components.
Epoxy emulsion is oil-in-water aqueous epoxy emulsion, and its solids content is 25-30.
Solidifying agent is mixed by triethylene triamine and low molecule pa resin, and wherein triethylene tetramine is 2kg, and low molecule pa resin is 4kg.
250.4kg powder 100kg early-strength type 42.5 ordinary Portland cements, 75kg16 order quartz sand, 75kg60 order quartz sand, 0.4kg naphthalene water reducer are formed,
Above-mentioned epoxy cement based road antiskid coating preparation method comprises the steps:
1, the preparation of epoxy emulsion
Epoxy emulsion is diluted to 100kg, and its solids content is to 25-30;
2, the preparation of solidifying agent
With 2kg triethylene triamine and the mixed solidifying agent that gets of 4kg low molecule pa resin;
3, the preparation of powder
A, the 60 order quartz sands and the water reducer of 50 times of water reducer weight are put into ball mill mixed 5 minutes;
B, remaining quartz sand and early-strength type 42.5 ordinary Portland cements that take by weighing are in proportion put into together carry out dried stirring 5 minutes in the mortar mixer;
C, the compound of step a gained is put in the compound of step b gained, stirred about half hour;
4, the epoxy emulsion of step 1 gained, the solidifying agent of step 2, the powder of step 3 are packed separately, mixed during use and get final product.
More than show and described ultimate principle of the present invention, principal character and advantage of the present invention.The technician of the industry should understand; the present invention is not restricted to the described embodiments; that describes in the foregoing description and the specification sheets just illustrates principle of the present invention; the present invention also has various changes and modifications without departing from the spirit and scope of the present invention, and these changes and improvements all fall in the claimed scope of the invention.The claimed scope of the present invention is defined by appending claims and equivalent thereof.
Claims (11)
1, epoxy cement based road antiskid coating is characterized in that, is made up of epoxy emulsion, solidifying agent, powder three components, and the weight ratio between the three is 100: 0.05-0.1: 200-300.
2, epoxy cement based road antiskid coating according to claim 1 is characterized in that, the solids content of described epoxy emulsion is preferably 25-30.
3, epoxy cement based road antiskid coating according to claim 1 and 2 is characterized in that, described epoxy emulsion is an aqueous epoxy emulsion.
4, epoxy cement based road antiskid coating according to claim 1 is characterized in that, described solidifying agent is mixed by triethylene triamine and low molecule pa resin, and both weight ratios are 1-2: 1-3.
5, epoxy cement based road antiskid coating according to claim 1 is characterized in that, described solidifying agent is mixed by triethylene tetramine and low molecule pa resin, and both weight ratios are 1-2: 1-3.
6, according to claim 4 or 5 described epoxy cement based road antiskid coatings, it is characterized in that described low molecule pa resin.
7, epoxy cement based road antiskid coating according to claim 1, it is characterized in that, described powder is made up of silicate cement, quartz sand, water reducer, and the weight ratio between them is a silicate cement: quartz sand: water reducer 100: 150-200: 0.2-0.4.
8, epoxy cement based road antiskid coating according to claim 7 is characterized in that, described quartz sand is mixed by the 16 order quartz sands and the 40 order quartz sands of equal proportion.
9, epoxy cement based road antiskid coating according to claim 1 is characterized in that, described silicate cement is preferably early-strength type 42.5 ordinary Portland cements.
10, epoxy cement based road antiskid coating according to claim 1 is characterized in that, described water reducer is a naphthalene water reducer.
11, a kind ofly prepare the method that aforesaid right requires described epoxy cement based road anti-slip material, it is characterized in that, comprise the steps:
(1), the preparation of epoxy emulsion
Epoxy emulsion is diluted to solids content to 25-30;
(2), the preparation of solidifying agent
Triethylene triamine or triethylene tetramine and low molecule pa resin be mixed in proportion make solidifying agent;
(3), the preparation of powder
A, water reducer weight 30-50 60 order quartz sands were doubly put into the ball mill mixing 3-5 minute with water reducer;
B, remaining quartz sand and the silicate cement that takes by weighing in proportion put into together carry out dried stirring in the mortar mixer?-5 minutes;
C, the compound of step a gained is put in the compound of step b gained, stirred;
(4), the epoxy emulsion with step (1) gained, the solidifying agent of step (2), the powder of step (3) pack separately, mix during use to get final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2007100424545A CN101328379A (en) | 2007-06-22 | 2007-06-22 | Epoxy cement based road antiskid coating and preparation thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2007100424545A CN101328379A (en) | 2007-06-22 | 2007-06-22 | Epoxy cement based road antiskid coating and preparation thereof |
Publications (1)
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| CN101328379A true CN101328379A (en) | 2008-12-24 |
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| CNA2007100424545A Pending CN101328379A (en) | 2007-06-22 | 2007-06-22 | Epoxy cement based road antiskid coating and preparation thereof |
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Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101798481A (en) * | 2010-03-19 | 2010-08-11 | 徐峰 | Method for preparing high-performance color anti-skid road surface paint and using method thereof |
| CN103865239A (en) * | 2012-07-23 | 2014-06-18 | 重庆市智翔铺道技术工程有限公司 | Binding material for roads |
| CN103965727A (en) * | 2014-05-20 | 2014-08-06 | 长安大学 | Road coating material capable of adsorbing fine particulate matters in air |
| CN105038493A (en) * | 2015-06-17 | 2015-11-11 | 牛无畏 | Formula for preparing water-based epoxy paint |
| WO2015171360A1 (en) | 2014-05-09 | 2015-11-12 | 3M Innovative Properties Company | Slip resistant liquid, slip resistant article and the method for preparing the same |
| CN105386407A (en) * | 2015-10-19 | 2016-03-09 | 苏州群力防滑材料有限公司 | Non-skid strip of which surface is coated with non-skid materials |
| CN105669099A (en) * | 2015-12-31 | 2016-06-15 | 富思特新材料科技发展股份有限公司 | Aqueous epoxy coating for terraces, and preparation method thereof |
| CN105860824A (en) * | 2016-04-21 | 2016-08-17 | 苏州群力防滑材料有限公司 | Non-slip composition for coating ground of shopping center |
| CN107500713A (en) * | 2017-05-18 | 2017-12-22 | 唐峰翔 | Anti-slip material and anti-slip construction method thereof |
| CN108103877A (en) * | 2017-12-22 | 2018-06-01 | 苏州希尔盖森新材料有限公司 | A kind of environmental protection noctilucence concrete road surface |
| CN110305561A (en) * | 2019-07-15 | 2019-10-08 | 信和新材料股份有限公司 | A kind of preserved aqueous leaf network grain effect paint and preparation method thereof and construction method |
| CN113402237A (en) * | 2021-08-05 | 2021-09-17 | 高县卓越商品混凝土有限公司 | Diamond sand concrete and preparation method thereof |
-
2007
- 2007-06-22 CN CNA2007100424545A patent/CN101328379A/en active Pending
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101798481A (en) * | 2010-03-19 | 2010-08-11 | 徐峰 | Method for preparing high-performance color anti-skid road surface paint and using method thereof |
| CN103865239A (en) * | 2012-07-23 | 2014-06-18 | 重庆市智翔铺道技术工程有限公司 | Binding material for roads |
| CN103865239B (en) * | 2012-07-23 | 2015-11-04 | 重庆市智翔铺道技术工程有限公司 | The preparation method of a kind of road matrix material |
| WO2015171360A1 (en) | 2014-05-09 | 2015-11-12 | 3M Innovative Properties Company | Slip resistant liquid, slip resistant article and the method for preparing the same |
| CN103965727B (en) * | 2014-05-20 | 2016-04-27 | 长安大学 | The road coated material of fine particle in a kind of adsorbable air |
| CN103965727A (en) * | 2014-05-20 | 2014-08-06 | 长安大学 | Road coating material capable of adsorbing fine particulate matters in air |
| CN105038493A (en) * | 2015-06-17 | 2015-11-11 | 牛无畏 | Formula for preparing water-based epoxy paint |
| CN105386407A (en) * | 2015-10-19 | 2016-03-09 | 苏州群力防滑材料有限公司 | Non-skid strip of which surface is coated with non-skid materials |
| CN105669099A (en) * | 2015-12-31 | 2016-06-15 | 富思特新材料科技发展股份有限公司 | Aqueous epoxy coating for terraces, and preparation method thereof |
| CN105860824A (en) * | 2016-04-21 | 2016-08-17 | 苏州群力防滑材料有限公司 | Non-slip composition for coating ground of shopping center |
| CN107500713A (en) * | 2017-05-18 | 2017-12-22 | 唐峰翔 | Anti-slip material and anti-slip construction method thereof |
| CN108103877A (en) * | 2017-12-22 | 2018-06-01 | 苏州希尔盖森新材料有限公司 | A kind of environmental protection noctilucence concrete road surface |
| CN110305561A (en) * | 2019-07-15 | 2019-10-08 | 信和新材料股份有限公司 | A kind of preserved aqueous leaf network grain effect paint and preparation method thereof and construction method |
| CN113402237A (en) * | 2021-08-05 | 2021-09-17 | 高县卓越商品混凝土有限公司 | Diamond sand concrete and preparation method thereof |
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Open date: 20081224 |