CN102964100A - Macromolecular adhesive cement - Google Patents
Macromolecular adhesive cement Download PDFInfo
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- CN102964100A CN102964100A CN2012104533129A CN201210453312A CN102964100A CN 102964100 A CN102964100 A CN 102964100A CN 2012104533129 A CN2012104533129 A CN 2012104533129A CN 201210453312 A CN201210453312 A CN 201210453312A CN 102964100 A CN102964100 A CN 102964100A
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Abstract
The invention relates to a cement-based self-leveling mortar, and more particularly relates to a macromolecular adhesive cement. The macromolecular adhesive cement comprises the components in parts by weight: 80-100 parts of water-borne epoxy resin, 16-20 parts of water-borne epoxy curing agent, 120-150 parts of complex portland cement, 30-50 parts of quartz silt powder, 10-15 parts of water, 35-50 parts of pigments and fillers, 0.3-0.5 parts of wetting dispersant, 2-6 parts of self-leveling additives, and 2-5 parts of water-borne color paste. The macromolecular adhesive cement disclosed by the invention is a single-component, dry-powder-shaped and water-borne self-leveling cement-based hard/soft type waterproof adhesion-blocking and leveling material which is processed via scientific proportioning, integrates the functions of water prevention, adhesion, blockage and leveling, as well as is non-toxic and odorless, and belongs to cement-based macromolecular polymer water-borne dry-powder waterproof mortars.
Description
Technical field
The present invention relates to a kind of cement-based self-leveling mortar, more specifically relate to a kind of polymer clay.
Background technology
Traditional floor leveling constructional method be with conventional cement mortar mix make after, adopt Manual, strike off, wipe one's face, before mortar final set, also must finish three times compactings, put forward the operations such as slurry, troweling.The method of multilayer construction in this minute, production efficiency is very low, and waste of material is very large.Most importantly its quality also is difficult to obtain assurance, and the quality problems such as dusting, peeling, hollowing, cracking often appear in the ground after the construction.Have a strong impact on impression and the result of use of building surface, become the common quality defect on conventional cement mortar ground, and effectively effected a radical cure.Ground is as an important component part of building, and its quality also more and more causes people's concern.
Cement-based self-leveling mortar grows up for the problems referred to above.It is a kind of take cement as main gelling material, adds suitable additive and fine sand etc. and mixes, and is used for the earth material of floor leveling or facing.Only need water cement ratio scope in accordance with regulations add the water uniform mixing during use, behind mechanical pumping or the artificial construction, need not manually floatingly, form flat surface by slurry in self gravitation effect current downflow.Self-leveling material has low, bright and clean smooth, the advantage such as intensity level is high, the thin and water-fast acid resistance of levelling layer thickness is good of flowability and good stability, easy construction, labour intensity, it is the ideal material of the ground surface consolidations such as large supermarket, market, parking lot, factory floor, warehouse, also be a developing direction of present building ground construction, market potential is very large.
Summary of the invention
The object of the present invention is to provide a kind of polymer clay, collection waterproof, bonding, leak stopping and leveling function are integrated in one, and are a kind of multifunction cement based self-leveling mortars.
The technical scheme that the present invention takes is as follows:
Polymer clay of the present invention comprises by weight: 80 parts～100 parts of aqueous epoxy resins, 16 ~ 20 parts of aqueous epoxy curing agents, 120～150 parts of composite Portland cements, 30～50 parts of quartzy flour sand fillers, 10～15 parts in water, 35～50 parts of color stuffings, 0.3～0.5 part of wetting dispersing agent, 2～6 parts of Self-leveling additives, 2～5 parts of aqueous color pastes.
Described quartzy flour sand filler by weight percentage ratio is: the mixture of 80～90% quartz sands and silica powder, 10～20% additives.Described additive comprises lubricant.
The preparation method of described quartzy flour sand filler is: use the dry-mix stirrer, in secluding air or protection of inert gas situation, 100～120 purpose quartz sands and silica powder are mixed, add additive, fully mix and blend.
Aqueous epoxy resins, aqueous epoxy curing agent prepare according to patent (CN 100532480C aqueous epoxide resin paint and preparation method thereof).
Described Self-leveling additive comprises retardant, setting accelerator, flow agent, defoamer, hardening accelerator.
The promoter additive that the present invention adopts is the universal auxiliary agent of coating.
The preparation method of described polymer clay is as follows:
First with a part of water, auxiliary agent and whole color stuffing reduction of speed after disperseing 8～30 minutes under 900～1200r/min speed, add again aqueous epoxy curing agent, under 600～900r/min speed, mix 3～10min, then add all the other auxiliary agents and mill base and disperse 8～20min, filter and package.Then add aqueous epoxy resins, mixing about 3min under 400～800r/min speed and can construct.
A kind of polymer clay of the present invention, single-component, dry powder, the water-based that processes by scientific matching, the nonpoisonous and tasteless water-based self-leveling cement base that collection waterproof, bonding, leak stopping and leveling function are integrated in one the temper toughness with gentleness leak stopping of type water-proof sticking and alignment material belong to cement based high molecular polymer water-based dry powder waterproof mortar.
Its main raw brief introduction is as follows:
Epoxy refers to add in the middle of the carbochain Sauerstoffatom in organism, also connecting together such as two carbon of modal oxyethane (CH2-O-CH2) forms a trilateral.Resin can form three kinds of water-dispersion forms by different Water-borne modification approach: 1. water-soluble; 2. micella decentralized; 3. emulsion.Resins, epoxy is from as thermoplastic linear structure, the rear solid-state liquid state that becomes of being heated, and high viscosity becomes low viscosity, only has to be used with solidifying agent just to have practical value.Therefore water-borne epoxy systems should comprise aqueous epoxy resins and aqueous epoxy curing agent, and same, they can form three kinds of water-dispersion forms by different Water-borne modification approach respectively.Therefore water-borne epoxy systems has more Selection and Constitute (form families that has in theory 9 kinds), but has also increased the selection difficulty.In actual application, by adding a large amount of color stuffings, auxiliary agent etc., improve deficiency even major defect that the water-borne epoxy systems application performance has also been covered water-borne epoxy systems simultaneously simultaneously, this will increase more uncertain factor and complicacy.
No matter select aqueous epoxy resins and the aqueous epoxy curing agent of which kind of form, the water-borne epoxy systems that finally has actual application value is a kind of dispersion heterogeneous structure, by aqueous epoxy resins, aqueous epoxy curing agent, the heterogeneous composition such as water, its membrane formation mechanism is different from general polymer emulsion such as the film forming of the ACRYLIC EMULSION (film forming of condensing, physical process), simultaneously also incomplete same with the film forming of solvent type epoxy, in the solvent type epoxy system, Resins, epoxy and solidifying agent all are dissolved in the organic solvent with molecular form, the system that forms is homogeneous phase, curing reaction carries out between molecule, thereby curing reaction carries out more fully, and formed cured article also is homogeneous phase.
Water-base epoxy is heterogeneous system, Resins, epoxy and solidifying agent are dispersed in aqueous phase with the disperse phase form, the crosslinking curing process is the internal divergence crosslinking reaction process that interpenetrates between the particulate in the process of moisture evaporation, so the state of cure of water-base epoxy depends on following four factors:
A) consistency: the consistency of aqueous epoxy resins and aqueous epoxy curing agent is better, more is conducive to solidifying agent particulate and the mutual internal divergence of Resins, epoxy particulate, is conducive to the carrying out of curing reaction;
B) particle diameter: particle diameter hour reaches more completely state of cure thereby aqueous epoxy resins and aqueous epoxy curing agent dispersed phase particles can be interpenetrated to kernel more fully;
C) hydrophile-lipophile balance value: the hydrophile-lipophile balance value of aqueous epoxy resins and aqueous epoxy curing agent approaches, reach consistent coexistence steady state at aqueous phase, if differ greatly, the component that wetting ability is stronger can be gathered in aqueous phase gradually, thereby causes resin-phase and solidifying agent to be separated;
D) degree that is uniformly dispersed: under the state of multi-phase separation, only have by certain mechanical agitation, resin-phase could be uniformly distributed in aqueous phase mutually with solidifying agent.
Composite Portland cement (abbreviation complex cement), wherein 425 and No. 525 cement divide two types by early strength.Each age strength of each label, all types of cement must not be lower than following table numerical value:
Large, impervious good, water-fast, the resistance to cracking of polymer clay cohesive force, weathering resistance are strong, surfacing, hardened ground intensity are high, and water resistance is excellent; Have good flowability during the levelling construction technology, the gravity flow levelling need not vibrated; Firm, the gentle mutually network structure of Ji of its uniqueness makes it have very strong impermeability and good construction adaptability.Can be at facade; carry out operation on the dry or moist basal plane; can be used as civilian and industrial building waterproof layer; interfacial agents; thermal insulation layer; also as moistureproof crack-resistant layer and tack coat; also can be used for wall face; the external wall outer insulation anti-seepage and anti-crack layer; also can be used for ceramic tile; vitrified tile; the stickup of the stone slabs such as marble and (be a kind of ground construction technology by doing water-based self-flatting ground making level layer behind certain proportioning dilute with water; it is the fluent meterial that many materials mix with water; after pouring ground into; this material can be taken advantage of a situation mobile according to being uneven of ground; Automatic Levelling is carried out on ground; and very fast drying, the ground after the curing can form smooth; smooth; seamless new basic unit).And coating is thin, consumption is few, intensity is high, the technique Simple fast, and the thickness of coating can be regulated according to actual needs voluntarily, and waterproof, stickup, levelling only need a procedure.Construction costs is low, construction quality good, has not only saved cost but also reduction of erection time.
The polymer clay belongs to the single-component material, do not need during use to add again any auxiliary agent, as long as add suitable quantity of water with machinery or artificial can operate construction after disperseing to stir, to construction equipment, operator also without particular requirement, the technique Simple fast.
The polymer clay is generally done middle Tu screed-coat structure when floor construction, bonding interface agent or sealing or permeable primer and various inorganic, organic finish paint consist of various layered structure, basically satisfy the widespread use of present various terraces.
Embodiment
Polymer clay of the present invention comprises by weight: 80 parts～100 parts of aqueous epoxy resins, 16 ~ 20 parts of aqueous epoxy curing agents, 120～150 parts of composite Portland cements, 30～50 parts of quartzy flour sand fillers, 10～15 parts in water, 35～50 parts of color stuffings, 0.3～0.5 part of wetting dispersing agent, 2～6 parts of Self-leveling additives, 2～5 parts of aqueous color pastes.
Described quartzy flour sand filler by weight percentage ratio is: the mixture of 80～90% quartz sands and silica powder, 10～20% additives.
Described additive comprises lubricant.
The preparation method of described quartzy flour sand filler is: use the dry-mix stirrer, in secluding air or protection of inert gas situation, 100～120 purpose quartz sands and silica powder are mixed, add additive, fully mix and blend.
Aqueous epoxy resins, aqueous epoxy curing agent prepare according to patent (CN 100532480C aqueous epoxide resin paint and preparation method thereof).
Described Self-leveling additive comprises retardant, setting accelerator, flow agent, defoamer, hardening accelerator.
The promoter additive that the present invention adopts is the universal auxiliary agent of coating.
The preparation method of described polymer clay is as follows:
First with a part of water, auxiliary agent and whole color stuffing reduction of speed after disperseing 8～30 minutes under 900～1200r/min speed, add again aqueous epoxy curing agent, under 600～900r/min speed, mix 3～10min, then add all the other auxiliary agents and mill base and disperse 8～20min, filter and package.Then add aqueous epoxy resins, mixing about 3min under 400～800r/min speed and can construct.
The standard of polymer clay foundation and reference is as follows:
Embodiment 1
Polymer clay of the present invention is by weight: 80 parts of aqueous epoxy resins, 16 parts of aqueous epoxy curing agents, 120 parts of composite Portland cements, 30 parts of quartzy flour sand fillers, 10 parts in water, 35 parts of color stuffings, 0.3 part of wetting dispersing agent, 2 parts of Self-leveling additives, 2 parts of aqueous color pastes.
Described quartzy flour sand filler by weight percentage ratio is: the mixture of 90% quartz sand and silica powder, 10% additive.Described additive is lubricant.
The preparation method of described quartzy flour sand filler is: use the dry-mix stirrer, in secluding air or protection of inert gas situation, 100～120 purpose quartz sands and silica powder are mixed, add additive, fully mix and blend.
Aqueous epoxy resins, aqueous epoxy curing agent prepare according to patent (CN 100532480C aqueous epoxide resin paint and preparation method thereof).
Described Self-leveling additive is 0.5 part of retardant, 0.5 part of setting accelerator, 0.5 part of flow agent, 0.5 part of defoamer, 0.5 part of hardening accelerator.
The preparation method of described polymer clay is as follows:
First with a part of water, auxiliary agent and whole color stuffing reduction of speed after disperseing 8～30 minutes under 900～1200r/min speed, add again aqueous epoxy curing agent, under 600～900r/min speed, mix 3～10min, then add all the other auxiliary agents and mill base and disperse 8～20min, filter and package.Then add aqueous epoxy resins, mixing about 3min under 400～800r/min speed and can construct.Product meets DB35/516-2005.
Embodiment 2
Polymer clay of the present invention is by weight: 100 parts of aqueous epoxy resins, 20 parts of aqueous epoxy curing agents, 150 parts of composite Portland cements, 50 parts of quartzy flour sand fillers, 15 parts in water, 50 parts of color stuffings, 0.5 part of wetting dispersing agent, 6 parts of Self-leveling additives, 5 parts of aqueous color pastes.
Described quartzy flour sand filler by weight percentage ratio is: the mixture of 80% quartz sand and silica powder, 20% lubricant.
All the other preparations are such as embodiment 1.Product meets DB35/516-2005.
Embodiment 3
Polymer clay of the present invention is by weight: 90 parts of aqueous epoxy resins, 18 parts of aqueous epoxy curing agents, 130 parts of composite Portland cements, 40 parts of quartzy flour sand fillers, 15 parts in water, 40 parts of color stuffings, 0.4 part of wetting dispersing agent, 5 parts of Self-leveling additives, 4 parts of aqueous color pastes.
Described quartzy flour sand filler by weight percentage ratio is: the mixture of 80% quartz sand and silica powder, 20% lubricant.
All the other preparations are such as embodiment 1.Product meets DB35/516-2005.
Claims (5)
1. polymer clay, it is characterized in that: described polymer clay comprises by weight: 80 parts～100 parts of aqueous epoxy resins, 16 ~ 20 parts of aqueous epoxy curing agents, 120～150 parts of composite Portland cements, 30～50 parts of quartzy flour sand fillers, 10～15 parts in water, 35～50 parts of color stuffings, 0.3～0.5 part of wetting dispersing agent, 2～6 parts of Self-leveling additives, 2～5 parts of aqueous color pastes.
2. polymer clay according to claim 1, it is characterized in that: described quartzy flour sand filler by weight percentage ratio is: the mixture of 80～90% quartz sands and silica powder, 10～20% additives.
3. described additive comprises lubricant.
4. polymer clay according to claim 1 and 2; it is characterized in that: the preparation method of described quartzy flour sand filler is: use the dry-mix stirrer; in secluding air or protection of inert gas situation; 100～120 purpose quartz sands and silica powder are mixed; add additive, fully mix and blend.
5. polymer clay according to claim 1, it is characterized in that: described Self-leveling additive comprises retardant, setting accelerator, flow agent, defoamer, hardening accelerator.
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| CN201210453312.9A CN102964100B (en) | 2012-11-13 | 2012-11-13 | Macromolecular adhesive cement |
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| CN201210453312.9A CN102964100B (en) | 2012-11-13 | 2012-11-13 | Macromolecular adhesive cement |
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| CN102964100B CN102964100B (en) | 2014-12-17 |
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Cited By (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103274653A (en) * | 2013-05-09 | 2013-09-04 | 清华大学 | High-flexibility and low-shrinkage fiber reinforced cement-based composite material |
| CN104261765A (en) * | 2014-09-29 | 2015-01-07 | 小浪底水利水电工程有限公司 | Epoxy resin polymer mortar and production process thereof |
| CN104496345A (en) * | 2014-11-26 | 2015-04-08 | 芜湖中民科技建材有限公司 | Dry-mixed thermal insulation mortar and its preparation method and use |
| CN105669099A (en) * | 2015-12-31 | 2016-06-15 | 富思特新材料科技发展股份有限公司 | Aqueous epoxy coating for terraces, and preparation method thereof |
| CN106145817A (en) * | 2016-06-27 | 2016-11-23 | 浙江共创建材科技有限公司 | A kind of strong waterproof reinforced dedicated modified epoxy emulsion mortar of back side superelevation |
| CN106396543A (en) * | 2016-08-30 | 2017-02-15 | 福州皇家地坪有限公司 | Aqueous epoxy self-leveling cement terrace |
| CN106495616A (en) * | 2016-11-10 | 2017-03-15 | 中国建材检验认证集团厦门宏业有限公司 | A kind of high-strength water-base epoxy colour self-leveling cement |
| CN106628655A (en) * | 2016-12-20 | 2017-05-10 | 安徽长庚光学科技有限公司 | High-temperature storage method for resin of raw materials used for lens |
| CN106697603A (en) * | 2016-12-20 | 2017-05-24 | 安徽长庚光学科技有限公司 | Low-temperature antifreezing preservation method for resin in raw materials for glasses |
| CN106893541A (en) * | 2016-08-23 | 2017-06-27 | 南通久聚高分子科技有限公司 | One kind sealing Polymer Mortar |
| CN106892615A (en) * | 2016-08-23 | 2017-06-27 | 南通久聚高分子科技有限公司 | A kind of Polymer Mortar of good weatherability |
| CN107628784A (en) * | 2017-08-25 | 2018-01-26 | 南通成山高分子材料有限公司 | A kind of Macromolecular adhesive cement |
| CN108675692A (en) * | 2018-05-03 | 2018-10-19 | 广州挚业化工有限公司 | A kind of fast solidification water epoxy concrete repair paint and preparation method thereof |
| CN108996967A (en) * | 2018-08-24 | 2018-12-14 | 江西牧石建材有限公司 | Clear water floor paint and preparation method thereof |
| CN109516740A (en) * | 2018-12-24 | 2019-03-26 | 广州协堡建材有限公司 | The dedicated clay of the levelling integrated construction of floor tile paving and its construction method |
| CN112341094A (en) * | 2020-11-19 | 2021-02-09 | 广西帝品建材有限公司 | Water-based nano resin mortar |
| CN115710478A (en) * | 2022-11-23 | 2023-02-24 | 广东包清贴装饰工程有限公司 | Tile edge sealing adhesive and paving method thereof |
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Cited By (20)
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| CN103274653B (en) * | 2013-05-09 | 2014-12-24 | 清华大学 | High-flexibility and low-shrinkage fiber reinforced cement-based composite material |
| CN103274653A (en) * | 2013-05-09 | 2013-09-04 | 清华大学 | High-flexibility and low-shrinkage fiber reinforced cement-based composite material |
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| CN104496345A (en) * | 2014-11-26 | 2015-04-08 | 芜湖中民科技建材有限公司 | Dry-mixed thermal insulation mortar and its preparation method and use |
| CN105669099A (en) * | 2015-12-31 | 2016-06-15 | 富思特新材料科技发展股份有限公司 | Aqueous epoxy coating for terraces, and preparation method thereof |
| CN106145817A (en) * | 2016-06-27 | 2016-11-23 | 浙江共创建材科技有限公司 | A kind of strong waterproof reinforced dedicated modified epoxy emulsion mortar of back side superelevation |
| CN106892615A (en) * | 2016-08-23 | 2017-06-27 | 南通久聚高分子科技有限公司 | A kind of Polymer Mortar of good weatherability |
| CN106893541A (en) * | 2016-08-23 | 2017-06-27 | 南通久聚高分子科技有限公司 | One kind sealing Polymer Mortar |
| CN106396543A (en) * | 2016-08-30 | 2017-02-15 | 福州皇家地坪有限公司 | Aqueous epoxy self-leveling cement terrace |
| CN106495616A (en) * | 2016-11-10 | 2017-03-15 | 中国建材检验认证集团厦门宏业有限公司 | A kind of high-strength water-base epoxy colour self-leveling cement |
| CN106495616B (en) * | 2016-11-10 | 2018-08-28 | 中国建材检验认证集团厦门宏业有限公司 | A kind of high-strength water-base epoxy colour self-leveling cement |
| CN106697603A (en) * | 2016-12-20 | 2017-05-24 | 安徽长庚光学科技有限公司 | Low-temperature antifreezing preservation method for resin in raw materials for glasses |
| CN106628655A (en) * | 2016-12-20 | 2017-05-10 | 安徽长庚光学科技有限公司 | High-temperature storage method for resin of raw materials used for lens |
| CN107628784A (en) * | 2017-08-25 | 2018-01-26 | 南通成山高分子材料有限公司 | A kind of Macromolecular adhesive cement |
| CN108675692A (en) * | 2018-05-03 | 2018-10-19 | 广州挚业化工有限公司 | A kind of fast solidification water epoxy concrete repair paint and preparation method thereof |
| CN108996967A (en) * | 2018-08-24 | 2018-12-14 | 江西牧石建材有限公司 | Clear water floor paint and preparation method thereof |
| CN109516740A (en) * | 2018-12-24 | 2019-03-26 | 广州协堡建材有限公司 | The dedicated clay of the levelling integrated construction of floor tile paving and its construction method |
| CN112341094A (en) * | 2020-11-19 | 2021-02-09 | 广西帝品建材有限公司 | Water-based nano resin mortar |
| CN115710478A (en) * | 2022-11-23 | 2023-02-24 | 广东包清贴装饰工程有限公司 | Tile edge sealing adhesive and paving method thereof |
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Effective date of registration: 20191031 Address after: 314100 room 427, No.16 Fuxing Avenue, Xitang Town, Jiashan County, Jiaxing City, Zhejiang Province Patentee after: Zhejiang Xitang Industry Co.,Ltd. Address before: Fuqing City, Fuzhou City, Fujian Province, Yang Dang street 350300 No. 2 bucket Patentee before: FUZHOU ROYAL FLOOR Co.,Ltd. |
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Application publication date: 20130313 Assignee: Jiashan County Xitang Entrepreneurship and Innovation Service Co.,Ltd. Assignor: Zhejiang Xitang Industry Co.,Ltd. Contract record no.: X2023330000544 Denomination of invention: Polymer adhesive Granted publication date: 20141217 License type: Common License Record date: 20230822 |