CN106495616A - A kind of high-strength water-base epoxy colour self-leveling cement - Google Patents

A kind of high-strength water-base epoxy colour self-leveling cement Download PDF

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Publication number
CN106495616A
CN106495616A CN201610988479.3A CN201610988479A CN106495616A CN 106495616 A CN106495616 A CN 106495616A CN 201610988479 A CN201610988479 A CN 201610988479A CN 106495616 A CN106495616 A CN 106495616A
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parts
groups
water
self
epoxy
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CN201610988479.3A
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CN106495616B (en
Inventor
彭鹏飞
吴玉生
陈镇衫
秦宪明
髙言立
陈晓寒
黄舟
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CHINA BUILDING MATERIAL TEST & CERTIFICATION GROUP XIAMEN HONGYE Co Ltd
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CHINA BUILDING MATERIAL TEST & CERTIFICATION GROUP XIAMEN HONGYE Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/04Portland cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/80Optical properties, e.g. transparency or reflexibility
    • C04B2111/82Coloured materials

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The invention discloses a kind of high-strength water-base epoxy colour self-leveling cement, including liquid portion and powder section, the raw material of powder section group by weight is divided into:21 24 parts of white portland cement, 15.6 17.6 parts of white high belite sulfur aluminum cement, white 58 61 parts of quartz sand, 0.10 0.12 parts of powder body water reducer, 0.17 0.20 parts of powder body defoamer, 0.09 0.11 parts of aluminium-magnesium silicate, 0.05 0.07 parts of tartaric acid;The liquid portion is made up of A groups and B groups:A groups add the reactive diluent of its mass fraction 10% for epoxy resin;B groups add appropriate mill base for self-control aqueous epoxy curing agent.Have water consumption wide ranges, do not ftracture, good leveling property, surface effect is good after hardening, uniform color, intensity are high, 1d is 40MPa, 28d up to more than 80MPa, excellent in abrasion resistance, durable in use the features such as.

Description

A kind of high-strength water-base epoxy colour self-leveling cement
Technical field
The present invention relates to building material field, specifically a kind of high-strength water-base epoxy colour self-leveling cement.
Background technology
Colored self-leveling cement is that a kind of scientific and technological content is higher, constituent is more, the preferable novel environment friendly of decorative effect Material.It adds water mix use through scene, slightly spreads out through instrument, you can obtain smooth ground and good decorative effect.It Quick construction, setting rate are fast, improve speed of application and civilization degree, construct comfortable space lucuriant in design, low cost Honest and clean, it is widely used in various industrial premises, workshop, market, lounge, the exhibition Room, gymnasium, hospital and entertainment for children The workplace grounds such as place.
With living standard and the lifting of aesthetical standard, construction and the technological progress of surface aesthetics effect, colored Self-leveling Cement Market is progressively opened, or even robs the share that account for PART EPOXY terrace, in great demand.But used by domestic relatively large project The most specified import brands of colored self-leveling cement, only several home brands can squeeze into colored self-leveling cement market. Trace it to its cause, main or domestic correlation technique is not mature enough, it is poor that product has high insufficient strength, color and luster sense organ and uniformity With easy problems of crack.
Content of the invention
It is an object of the invention to provide a kind of have water consumption wide ranges, do not ftracture, good leveling property, surface effect after hardening Really good, uniform color, intensity are high, and 1d is 40MPa, 28d up to more than 80MPa, excellent in abrasion resistance, durable in use the features such as water Property epoxy self-leveling cement, with solve the problems, such as in above-mentioned background technology propose.
For achieving the above object, the present invention provides following technical scheme:
A kind of high-strength water-base epoxy colour self-leveling cement, including liquid portion and powder section,
The raw material of powder section group by weight is divided into:White portland cement 21-24 parts, white high belite Sulfur aluminum cement 15.6-17.6 parts, white quartz sand 58-61 parts, powder body water reducer 0.10-0.12 parts, powder body defoamer 0.17- 0.20 part, aluminium-magnesium silicate 0.09-0.11 parts, tartaric acid 0.05-0.07 parts;
The liquid portion is made up of A groups and B groups:A groups add the reactive diluent of its mass fraction 10% for epoxy resin; B groups add appropriate mill base for aqueous epoxy curing agent.
Preferably, the raw material of powder section group by weight is divided into:22.5 parts of white portland cement, white are high 16.6 parts of belite sulfur aluminum cement, white 59.5 parts of quartz sand, 0.11 part of powder body water reducer, 0.19 part of powder body defoamer, silicic acid 0.1 part of magnalium, 0.06 part of tartaric acid.
As further scheme of the invention:The mixed proportion of the powder section, liquid portion and water is powder section: A groups:B groups:Water=100:3.5:3.5:(12-14).
As further scheme of the invention:Aqueous epoxy curing agent in liquid portion B groups is self-control modified amine solidification Agent, main method of modifying is:Based on TEPA so as to primary amine and epoxy resin and other bis-epoxy functional group materials Mixture reaction, then anhydride is connected, then block, pH value is adjusted to 8-9.
As further scheme of the invention:The granular size of the white quartz sand is 80-120 mesh.
As further scheme of the invention:The water-base epoxy self-leveling cement is using front preparation method:First will The A groups and B groups of liquid portion stirs by being mixed in proportion, and adds appropriate mixing water and powder section.
As further scheme of the invention:The mixing time of the A groups and B groups of the liquid portion is 1.5-2 minutes.
As further scheme of the invention:The time that the liquid portion, powder section and water are mixed is 1.5-2 Minute, it is stirred using handheld stirring machine or planetary mortar mixer.
Compared with prior art, the invention has the beneficial effects as follows:
(1) using white high belite sulfur aluminum cement, do not ftracture after rationally compounding:It is commonly made to colored self-leveling cement all It is that white cement is to eliminate the color mineral C4AF in grog and obtain as major gelled material with white cement, due to its C3S, C3A contents are high, easily ftracture in the larger Self-leveling series of water consumption;Present invention uses a kind of white high belite sulfur aluminum Cement, this cement are that C2S contents are higher, and a kind of new cement for also constituting containing sulfur aluminum cement and Gypsum Fibrosum, with volume Good stability, microdilatancy, the features such as hydration reaction is very fast, during compound use reasonable with white cement, can make up which and shrink especially It is the chemical shrinkage for making up early stage so as to do not ftracture;
(2) using homemade high-performance water-based epoxy component, intensity, uniformity are improved:Aqueous epoxy curing agent oil emulsion Property epoxy resin so as to can be compatible with water, so as to play in self-leveling cement improve intensity, density, cementitiousness, carry High viscosity, makes component uniformity more preferably, produces certain flexibility, cracking resistance;The present invention is using a kind of synthesis certainly suitable for certainly The aqueous epoxy curing agent of levelling cement, makes self-leveling cement intensity higher, and optimum adding quantity of pulverized is the 7% or so of powder quality, makes Obtain 1d of the present invention and reach 40MPa, 28d is up to more than 80MPa;
(3) additive such as preferred aluminium-magnesium silicate, the more excellent effect of rationally compounding acquisition:Aluminium-magnesium silicate is that a kind of thixotroping suspends Agent, can improve the viscosity of cement slurry, make slurry evenly, surface more smooth after solidification, and make with water-base epoxy collective effect Self-leveling cement is insensitive to water, and the slightly many also not bleedings of water, intensity also do not reduce;The height for being more suitable for self-leveling cement is used Performance polycarboxylate water-reducer, water-reducing rate further improve self-leveling cement mobility and intensity up to more than 30%;Use more Suitable for eliminating the defoamer of organic emulsion bubble cement, the degree of compaction and intensity of self-leveling cement can be improved, reduce surface The defects such as pin hole, improve surface effect.
Specific embodiment
Below in conjunction with the embodiment of the present invention, to the embodiment of the present invention in technical scheme be clearly and completely described, Obviously, described embodiment is only a part of embodiment of the invention, rather than whole embodiment.In based on the present invention Embodiment, the every other embodiment obtained under the premise of creative work is not made by those of ordinary skill in the art, all Belong to the scope of protection of the invention.
Embodiment 1
The preparation (green) of high-strength water-base epoxy colour self-leveling cement
(1) powder section:21 parts of white portland cement, white 15.6 parts of High-belite Cement, white 58 parts of quartz sand, 0.10 part of powder body water reducer, 0.17 part of powder body defoamer, 0.09 part of aluminium-magnesium silicate, 0.05 part of tartaric acid;
(2) liquid portion A groups:3.18 parts of 128# epoxy resin, 0.32 part of BGE reactive diluents;
(3) liquid portion B groups:3.18 parts of aqueous epoxy curing agent of self-control, green 0.32 part of mill base.
Preparation method and using front preparation:
First by above-mentioned (2)-(3) mix homogeneously, appropriate mixing water and (1) is added.
(2)-(3) are poured into agitator specially, stirred 1.5 minutes, then will add appropriate mixing water and (1), and make Stirred 1.5 minutes with planetary mortar mixer, the 0.12-0.14 parts of water consumption for (1) total amount.
Embodiment 2:
The preparation (redness) of high-strength water-base epoxy colour self-leveling cement
(1) powder section:22 parts of white portland cement, white 16.5 parts of High-belite Cement, white quartz sand 58.62 Part, 0.12 part of powder body water reducer, 0.18 part of powder body defoamer, 0.10 part of aluminium-magnesium silicate, 0.06 part of tartaric acid;
(2) liquid portion A groups:3.18 parts of 128# epoxy resin, 0.32 part of BGE reactive diluents;
(3) liquid portion B groups:3.18 parts of aqueous epoxy curing agent of self-control, red 0.24 part of mill base.
Preparation method and using front preparation with embodiment 1.
Embodiment 3:
The preparation (blueness) of high-strength water-base epoxy colour self-leveling cement
(1) powder section:24 parts of white portland cement, 17.6 parts of white high belite sulfur aluminum cement, white quartz sand 61 parts, 0.12 part of powder body water reducer, 0.20 part of powder body defoamer, 0.11 part of aluminium-magnesium silicate, 0.07 part of tartaric acid;
(2) liquid portion A groups:3.18 parts of 128# epoxy resin, 0.32 part of BGE reactive diluents;
(3) liquid portion B groups:3.18 parts of aqueous epoxy curing agent of self-control, blue 0.28 part of mill base.
Preparation method and using front preparation with embodiment 1.
Comparative example:
Certain producer's colour self-leveling cement (green) commercially available
Below by way of description of test beneficial effects of the present invention:
The performance of high-strength water-base epoxy colour self-leveling cement prepared by above-described embodiment 1-3 is tested, test knot Fruit is as shown in table 1.
Table 1:The performance test results of high-strength water-base epoxy colour self-leveling cement
Can see, properties of the present invention are satisfied by national standard requirement, in change in size, wear-resisting, especially in intensity Prominent in index, more than one times of existing products in markets is higher by, is a kind of high-strength and high performance colour self-leveling cement.
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, Er Qie In the case of spirit or essential attributes without departing substantially from the present invention, the present invention can be realized in other specific forms.Therefore, no matter From the point of view of which point, embodiment all should be regarded as exemplary, and be nonrestrictive, the scope of the present invention is by appended power Profit is required rather than described above is limited, it is intended that all in the implication and scope of the equivalency of claim by falling Change is included in the present invention.
Moreover, it will be appreciated that although this specification is been described by according to embodiment, not each embodiment is only wrapped Contain an independent technical scheme, this narrating mode of description is only that those skilled in the art should for clarity Using description as an entirety, the technical scheme in each embodiment can also form those skilled in the art through appropriately combined Understandable other embodiment.

Claims (8)

1. a kind of high-strength water-base epoxy colour self-leveling cement, it is characterised in that including liquid portion and powder section,
The raw material of powder section group by weight is divided into:White portland cement 21-24 parts, white high belite sulfur aluminum Cement 15.6-17.6 parts, white quartz sand 58-61 parts, powder body water reducer 0.10-0.12 parts, powder body defoamer 0.17-0.20 Part, aluminium-magnesium silicate 0.09-0.11 parts, tartaric acid 0.05-0.07 parts;
The liquid portion is made up of A groups and B groups:A groups add the reactive diluent of its mass fraction 10% for epoxy resin;B groups For aqueous epoxy curing agent plus appropriate mill base.
2. a kind of high-strength water-base epoxy colour self-leveling cement according to claim 1, it is characterised in that the powder body portion The raw material for dividing group by weight is divided into:22.5 parts of white portland cement, 16.6 parts of white high belite sulfur aluminum cement, white 59.5 parts of quartz sand, 0.11 part of powder body water reducer, 0.19 part of powder body defoamer, 0.1 part of aluminium-magnesium silicate, 0.06 part of tartaric acid.
3. a kind of high-strength water-base epoxy colour self-leveling cement according to claim 1 and 2, it is characterised in that the powder The mixed proportion of body portion, liquid portion and water is powder section:A groups:B groups:Water=100:3.5:3.5:(12-14).
4. a kind of high-strength water-base epoxy colour self-leveling cement according to claim 3, it is characterised in that liquid portion B In group, aqueous epoxy curing agent is that self-control modified amine curing agent, main method of modifying are:Based on TEPA so as to primary Amine and epoxy resin and other bis-epoxy functional group mixture of substances reactions, then anhydride is connected, then block, pH value is adjusted to 8-9 ?.
5. a kind of high-strength water-base epoxy colour self-leveling cement according to claim 1 and 2, it is characterised in that described white The granular size of colored stone sand is 80-120 mesh.
6. a kind of high-strength water-base epoxy colour self-leveling cement according to claim 1 or 3, it is characterised in that the water Property epoxy self-leveling cement using front preparation method:First that the A groups and B groups of liquid portion is equal by stirring is mixed in proportion Even, add appropriate mixing water and powder section.
7. a kind of high-strength water-base epoxy colour self-leveling cement according to claim 6, it is characterised in that the liquid portion The A groups that divides and the mixing time of B groups are 1.5-2 minutes.
8. a kind of high-strength water-base epoxy colour self-leveling cement according to claim 6, it is characterised in that the liquid portion Divide, the time that powder section and water are mixed is 1.5-2 minutes, be stirred using planetary mortar mixer.
CN201610988479.3A 2016-11-10 2016-11-10 A kind of high-strength water-base epoxy colour self-leveling cement Active CN106495616B (en)

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Cited By (5)

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Publication number Priority date Publication date Assignee Title
CN107382213A (en) * 2017-08-26 2017-11-24 广州漠克建材科技有限公司 A kind of water-base epoxy cement self-leveling waterproof mortar and its preparation technology
CN108298842A (en) * 2018-03-20 2018-07-20 徐州东兴能源有限公司 A kind of cement
CN108516736A (en) * 2018-03-20 2018-09-11 徐州东兴能源有限公司 One kind building movable cement by hand suitable for children
CN108996967A (en) * 2018-08-24 2018-12-14 江西牧石建材有限公司 A kind of clear water floor paint and preparation method thereof
CN110642574A (en) * 2019-10-22 2020-01-03 中山市武汉理工大学先进工程技术研究院 Multi-component extrusion-injection type mortar, and preparation method and application method thereof

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CN105936592A (en) * 2016-04-15 2016-09-14 马清浩 Cement-based self-leveling mortar for ground and preparation method thereof

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Cited By (5)

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CN107382213A (en) * 2017-08-26 2017-11-24 广州漠克建材科技有限公司 A kind of water-base epoxy cement self-leveling waterproof mortar and its preparation technology
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CN108996967A (en) * 2018-08-24 2018-12-14 江西牧石建材有限公司 A kind of clear water floor paint and preparation method thereof
CN110642574A (en) * 2019-10-22 2020-01-03 中山市武汉理工大学先进工程技术研究院 Multi-component extrusion-injection type mortar, and preparation method and application method thereof

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