CN101321798B - 耐候性提高的聚氨酯弹性体 - Google Patents

耐候性提高的聚氨酯弹性体 Download PDF

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Publication number
CN101321798B
CN101321798B CN2006800452943A CN200680045294A CN101321798B CN 101321798 B CN101321798 B CN 101321798B CN 2006800452943 A CN2006800452943 A CN 2006800452943A CN 200680045294 A CN200680045294 A CN 200680045294A CN 101321798 B CN101321798 B CN 101321798B
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weight
component
molecular weight
trimeric
functionality
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Expired - Fee Related
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CN2006800452943A
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Chinese (zh)
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CN101321798A (zh
Inventor
S·J·哈拉辛
R·R·罗斯勒
R·V·斯塔彻
C·L·金尼
J·T·加勒特
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Covestro LLC
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Bayer MaterialScience LLC
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/78—Nitrogen
    • C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4866—Polyethers having a low unsaturation value
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
    • C08G18/20—Heterocyclic amines; Salts thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/22—Catalysts containing metal compounds
    • C08G18/24—Catalysts containing metal compounds of tin
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4804—Two or more polyethers of different physical or chemical nature
    • C08G18/482—Mixtures of polyethers containing at least one polyether containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4833—Polyethers containing oxyethylene units
    • C08G18/4837—Polyethers containing oxyethylene units and other oxyalkylene units
    • C08G18/4841—Polyethers containing oxyethylene units and other oxyalkylene units containing oxyethylene end groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/50—Polyethers having heteroatoms other than oxygen
    • C08G18/5021—Polyethers having heteroatoms other than oxygen having nitrogen
    • C08G18/5024—Polyethers having heteroatoms other than oxygen having nitrogen containing primary and/or secondary amino groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6666—Compounds of group C08G18/48 or C08G18/52
    • C08G18/667—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
    • C08G18/6674—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/78—Nitrogen
    • C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
    • C08G18/791—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups
    • C08G18/792—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups formed by oligomerisation of aliphatic and/or cycloaliphatic isocyanates or isothiocyanates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2120/00—Compositions for reaction injection moulding processes

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Injection Moulding Of Plastics Or The Like (AREA)
CN2006800452943A 2005-12-15 2006-12-12 耐候性提高的聚氨酯弹性体 Expired - Fee Related CN101321798B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US11/304,265 2005-12-15
US11/304,265 US20070142607A1 (en) 2005-12-15 2005-12-15 Weather resistant polyurethane elastomer
PCT/US2006/047370 WO2007078725A1 (en) 2005-12-15 2006-12-12 Improved weather resistant polyurethane elastomer

Publications (2)

Publication Number Publication Date
CN101321798A CN101321798A (zh) 2008-12-10
CN101321798B true CN101321798B (zh) 2011-09-21

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CN2006800452943A Expired - Fee Related CN101321798B (zh) 2005-12-15 2006-12-12 耐候性提高的聚氨酯弹性体

Country Status (9)

Country Link
US (1) US20070142607A1 (enExample)
EP (1) EP1963395A1 (enExample)
JP (1) JP5588614B2 (enExample)
KR (1) KR20080080537A (enExample)
CN (1) CN101321798B (enExample)
BR (1) BRPI0619825A2 (enExample)
CA (1) CA2632971A1 (enExample)
RU (1) RU2008128305A (enExample)
WO (1) WO2007078725A1 (enExample)

Families Citing this family (12)

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US20090221703A1 (en) 2006-07-09 2009-09-03 Chongxi Yu High penetration composition and uses thereof
RU2452742C2 (ru) * 2007-01-30 2012-06-10 ДАУ ГЛОБАЛ ТЕКНОЛОДЖИЗ ЭлЭлСи Инициированные аминами полиолы и жесткие полиуретановые пенопласты, изготовленные из них
KR20210103586A (ko) 2007-06-04 2021-08-23 테크필즈 인크 매우 높은 피부 및 막 침투율을 가지는 비스테로이드성 소염제(ｎｓａｉａ) 약물전구체 및 이들의 새로운 의약적 용도
JP2013525583A (ja) * 2010-05-07 2013-06-20 バイエル・インテレクチュアル・プロパティ・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング ポリウレタンエラストマー、その製造方法およびその使用
EP2621987B1 (en) * 2010-10-01 2015-07-29 Dow Global Technologies LLC Process for making low density high resiliency flexible polyurethane foam
US20140265000A1 (en) * 2013-03-14 2014-09-18 Bayer Materialscience, Llc Water-clear aliphatic polyurethane pultrusion formulations and processes
MX2017010578A (es) * 2015-02-16 2017-11-16 Basf Se Sistema para formar composiciones elastomericas para aplicacion al metal.
CN107735475B (zh) * 2015-06-18 2021-05-07 陶氏环球技术有限责任公司 用红外辐射固化的潜伏型双组分聚氨基甲酸酯粘合剂
KR102793931B1 (ko) 2015-11-23 2025-04-14 훈츠만 어드밴스트 머티리얼스 라이센싱 (스위처랜드) 게엠베하 옥외 물품을 제조하기 위한 경화성 폴리우레탄 조성물 및 이로부터 얻어지는 물품
ES2952150T3 (es) * 2017-05-03 2023-10-27 Henkel Ag & Co Kgaa Polímeros modificados con silano, de características mejoradas para composiciones de adhesivo
CN110283290B (zh) * 2019-05-31 2022-08-19 佳化化学科技发展（上海）有限公司 一种耐水解聚氨酯弹性体及其制备方法
CN113185662B (zh) * 2021-04-29 2022-07-26 郑州大学 一种耐低温耐紫外老化的热塑性聚氨酯弹性体及其制备方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0275010A2 (de) * 1987-01-14 1988-07-20 Bayer Ag Verfahren zur Herstellung von Polyurethan-Formteilen
US5470813A (en) * 1993-11-23 1995-11-28 Arco Chemical Technology, L.P. Double metal cyanide complex catalysts
US6242555B1 (en) * 1996-10-01 2001-06-05 Recticel Light-stable elastomeric polyurethane mouldings and process for the production thereof
US6765080B2 (en) * 2002-06-06 2004-07-20 Bayer Corporation High performance RIM elastomers and a process for their production

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DE3033860A1 (de) * 1980-09-09 1982-04-15 Bayer Ag, 5090 Leverkusen Neue isocyanato-isocyanurate, ein verfahren zu ihrer herstellung, sowie ihre verwendung als isocyanatkomponente in polyurethanlacken
US4525491A (en) * 1982-12-24 1985-06-25 Asahi Glass Company, Ltd. Process for producing a polyurethane elastomer by reaction injection molding
US4642320A (en) * 1983-11-02 1987-02-10 The Dow Chemical Company Reaction injection molded polyureas employing high molecular weight amine-terminated polyethers
US4764543A (en) * 1987-08-03 1988-08-16 The Dow Chemical Company Microcellular foamed or reaction injection molded polyurethane/polyureas employing amine terminated polymers and diamine chain extenders
US5656677A (en) * 1989-01-20 1997-08-12 Recticel Method for preparing and applying a sprayable, light stable polyurethane
GB9125918D0 (en) * 1991-12-05 1992-02-05 Ici Plc Reaction system for preparing polyurethane/polyurea
US5437822A (en) * 1992-01-29 1995-08-01 Asahi Glass Company Ltd. Method for producing a skin-formed polyurethane foam molded product
DE4215760A1 (de) * 1992-05-13 1993-11-18 Basf Ag Verfahren zur Herstellung von Isocyanurat- und Uretdiongruppen enthaltenden Polyisocyanatmischungen mit reduzierter Farbzahl sowie nach diesem Verfahren hergestellte Produkte
US5502147A (en) * 1993-12-21 1996-03-26 Bayer Corporation Aliphatic rim elastomers
US5502150A (en) * 1994-06-29 1996-03-26 Bayer Corporation Linear HDI urethane prepolymers for rim application
US5670601A (en) * 1995-06-15 1997-09-23 Arco Chemical Technology, L.P. Polyurethane elastomers having improved green strength and demold time and polyoxyalkylene polyols suitable for their preparation
US6056239A (en) * 1998-08-12 2000-05-02 Carlos Martinez Celis Cantu Convertible seating and sleeping accommodations for aircraft
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JP3808006B2 (ja) * 2002-05-29 2006-08-09 住化バイエルウレタン株式会社 意匠面に使用されるインストルメントパネル用インテグラルスキンポリウレタンフォームの製造方法
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Patent Citations (4)

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Publication number Priority date Publication date Assignee Title
EP0275010A2 (de) * 1987-01-14 1988-07-20 Bayer Ag Verfahren zur Herstellung von Polyurethan-Formteilen
US5470813A (en) * 1993-11-23 1995-11-28 Arco Chemical Technology, L.P. Double metal cyanide complex catalysts
US6242555B1 (en) * 1996-10-01 2001-06-05 Recticel Light-stable elastomeric polyurethane mouldings and process for the production thereof
US6765080B2 (en) * 2002-06-06 2004-07-20 Bayer Corporation High performance RIM elastomers and a process for their production

Also Published As

Publication number Publication date
JP2009520065A (ja) 2009-05-21
CN101321798A (zh) 2008-12-10
EP1963395A1 (en) 2008-09-03
CA2632971A1 (en) 2007-07-12
WO2007078725A1 (en) 2007-07-12
US20070142607A1 (en) 2007-06-21
RU2008128305A (ru) 2010-01-20
KR20080080537A (ko) 2008-09-04
BRPI0619825A2 (pt) 2011-10-18
JP5588614B2 (ja) 2014-09-10

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Granted publication date: 20110921

Termination date: 20171212