CN101307234A - Organic modifying agent for low-yield soil and method for preparing same - Google Patents

Organic modifying agent for low-yield soil and method for preparing same Download PDF

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Publication number
CN101307234A
CN101307234A CNA2008100282977A CN200810028297A CN101307234A CN 101307234 A CN101307234 A CN 101307234A CN A2008100282977 A CNA2008100282977 A CN A2008100282977A CN 200810028297 A CN200810028297 A CN 200810028297A CN 101307234 A CN101307234 A CN 101307234A
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modifying agent
percent
low
decoction
dregs
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CN101307234B (en
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刘奋安
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Guangdong Hengfeng Biotechnology Co ltd
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/10Lime cements or magnesium oxide cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B18/00Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/04Waste materials; Refuse
    • C04B18/0481Other specific industrial waste materials not provided for elsewhere in C04B18/00
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00758Uses not provided for elsewhere in C04B2111/00 for agri-, sylvi- or piscicultural or cattle-breeding applications
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Civil Engineering (AREA)
  • Fertilizers (AREA)
  • Treatment Of Sludge (AREA)

Abstract

The invention relates to an organic modifying agent for low yield land soils and a method for preparing the same. The modifying agent comprises the following materials in weight percentage: 40 to 50 percent of urban dewatered sludge, 20 to 30 percent of dregs of decoction, 10 to 20 percent of calcic alkali material, 5 to 10 percent of swelling dispersant and 3 to 5 percent of mushroom source microbe fungous material, wherein the water content of the mixing materials is between 50 and 60 percent, the pH value is between 7 and 9, the C/N rate is between 20 and 30/1 and the C/P rate is between 50 and 75/1; the aim of the materials and the proportion used in the invention is to quickly make composts become thoroughly decomposed, so that the modifying agent and the method have the advantages of time conservation, excellent quality, low cost and simple making process; the modifying agent and the method are established in the circular utilization of local renewable resources and seek and dig out the organic modifying agent which is easy bought and low-priced and can replace the expensive soil modifying agent conventionally made by macromolecular resins, thereby having technical innovation and practicability.

Description

A kind of organic modifying agent for low-yield soil and preparation method thereof
Technical field:
The present invention relates to a kind of soil organic amendment technical field, refer in particular to a kind of industrial waste and town and country organic waste of utilizing and be prepared from, and the method for suitable southern acid organic modifying agent for low-yield soil.
Background technology:
Along with developing rapidly of city, population increases, and the sanitary sewage quantity discharged increases severely.The treatment rate of domestic sewage of American and Britain, method, moral, day, Australia, developed country such as new all reaches 100%; Domestic gap is bigger, and it is 25% that the exemplary city of national environmental protection also only requires wastewater treatment rate.According to reports, domestic each treatment rate of domestic sewage in 2000 only reaches 3%; Guangdong reaches 12% approximately, and only concentrates on Guangzhou, Shenzhen, Zhuhai, several cities such as Foshan.In addition, to the treatment process of dewatered sludge, then with landfill, burn and drop into river, river, lake, Hai Weizhu, resource utilization is agricultural still to belong to pre-test.In recent years owing to introduce external comparatively advanced dewatering machine equipment, and in settling tank, add polymeric flocculant and make body refuse directly form the lower fine and close small muddy pill of water content, thereby be the mud that solid form has changed the flow morphology of dewatering machine formation in the past, and also eliminated stink greatly.But this solid-state moisture percentage in sewage sludge still reaches about 75%, and volume is big, also has a lot of unfavorable factors in the farmland if directly be back to use as fertilizer or soil improvement agent.If this mud is directly carried out drying, also remain at following point: the one, the energy consumption height, processing cost is big; The 2nd, dried material is hard especially, increases the difficulty of pulverizing again; The 3rd, the market outlook of pulverizing exsiccant mud merely are limited; The 4th, if product marketing is bad, scheme jettisons disposal in addition, and this not only increases trucking costs, also can cause secondary environmental pollution.Therefore, the problem that exists at its physicochemical character is in conjunction with other waste material, and the treatment of wastes with processes of wastes against one another is turned waste into wealth, and carries out biochemistry and piles harmless treatments such as corruption, opens up out the channel of agricultural resource utilization, is a kind of essential measure.
In addition, Guangdong is the native place of south of the Five Ridges medical science, also is the main product ground of south of the Five Ridges herbal medicine.Guangdong Provincial Party committee, " about building the strong decision that economizes of Chinese materia medica " made by provincial government, issued that " the strong enforcement outline of economizing (2006~the year two thousand twenty) of Chinese materia medica is built in Guangdong " and " Guangdong Province's Chinese materia medica development " Eleventh-Five Year Plan " " have further promoted developing rapidly of Guangdong Chinese materia medica.According to statistics, between the existing herbal medicine processing in Guangdong pharmaceutical factory more than 120, year processing medium-height grass spice (siccative) nearly 500,000 tons produces the organic solid waste material dregs of a decoction about 1,500,000 tons (weight in wet bases).Herbal medicine is with woody, the root of draft, stem, leaf, flower, really, seed or complete stool be used as medicine, through the effectively purification of medicinal component, its dregs of a decoction moisture about 70%, the dry organic content reaches 80~90%, the nutrient total content of mineral elements such as nitrogenous, phosphorus, potassium, calcium, magnesium is up to 3% to 5%, and pH5.38~6.04 are a kind of fine organic materialss.Only there are at present indivedual places to utilize the small portion draft dregs of a decoction as the organic materials of culturing edible mushrooms, the feed that also has small portion flower, fruit waste material to be used as the fowl poultry or to breed fish, minimum part is arranged by near the flower-grower the pharmaceutical factory, the orchard worker is as fertilizer, but the dregs of a decoction that the whole province utilizes as agriculture and animal husbandry are less than 30%, still have the dregs of a decoction 70% or more to go out of use in the deserted mountain, the rural area is outside of the city or the sink node fire burns, or it is smelly to let alone to become corruption, both waste resource, polluted environment again.And over nearly 30 years, Agricultural Development has relied on chemical energy source excessively, a large amount of executes partially, lavishment chemical fertilizer causes soil organic matter content sharply to be reduced, the sandization of soil, acidifying are very serious, sand, acid, sticking, thin, harden, organic poor, nutrient is uneven, heavy metal contamination etc. has become southern low-yield land general character, the serious loss of water and soil, the pollution that superfluous chemical nutrient element is serious rivers water resources and underground water; And the qualitative change of agricultural byproducts product is bad, also has influence on human body health.Therefore, improve the soil, enrich organic fertilizer, improve Food Quality, become the tight demand of social sustainable development.Along with the development of world economy, the facility cultivation of agricultural more and more plays an important role; But also there are many shortcomings in the facility soil cultivation, and being difficult to regulation and control, disease and pest difficulty as soil secondary salinization, nutrition, to give prevention, production operation heavy etc.; Therefore the facility soilless substyate cultureization is trend of the times.The facility cultivation development of the nearly agricultural industry of flowers and plants during the last ten years is rapid, particularly green agricultural product production.
Summary of the invention:
The objective of the invention is to overcome the shortcoming of existing soil improvement agent product, a kind of city dehydrated sludge that utilizes is provided, materials such as herbal medicine pharmacy waste residue and calcium carbonate alkalescence industrial waste, the expensive soil improvement agent of the alternative tradition of development and production, more inexpensive than currently available products, the soil organic amendment of improving the soil with better function.
For achieving the above object, the technical scheme that is adopted among the present invention is:
1. raw material is prepared:
The main raw material that adopts is the city dehydrated sludge, the raw sludge of discharging behind the treated factory of sanitary sewage Chemical Regulation, settling tank flocculation sediment, the mechanical dehydration, it contains mineral elements such as a large amount of organic matters such as nitrogen, phosphorus, potassium, calcium, magnesium, zinc, iron, be the ideal soil improvement agent, plant full nutrition part can be provided; But also contain volatile organic matter, pathogenic bacteria, parasite, heavy metal and some difficult organic poison that decomposes.Along with the improvement of dewatering machine technology, present most sludge of sewage treatment plants are solid form basically, but water content still reaches 75%~85%, and stink is less relatively, and the dry organic content reaches 45%~60%, full nitrogen (N), phosphorus (P 2O 5) and potassium (K 2O) content is 2.5%~5.5%, 1.5%~5.0% or 0.5%~0.8% respectively, and arsenic (As), cadmium (Cd), plumbous (Pb), chromium (Cr), mercury several harmful heavy metal content such as (Hg) meet pollutent control criterion (GB4284-84) in the national agricultural mud.The fine and close ball of solid form can make the conduction difficulty of moisture if do not anticipate, and increases dry difficulty; Dry thing all becomes very hard, is unfavorable for pulverizing.Therefore the method for handling can add the diffusing material of separating that expands.
In addition, another main raw material of the present invention's employing is a herbal medicine pharmacy waste residue.It is the root, stem, leaf, flower of draft and xylophyta, really, seed or complete stool, the waste residue after boiling the purification medicinal ingredients.It is about 70% that these dregs of a decoction drain the back moisture content, dry organic content 85%~90%, and wherein robust fibre, rugose wood element and crude ash content are about 30% and 28% respectively, mineral element content about 2%~4%.
Wherein we select for use the meticulous high-quality part dregs of a decoction through inoculation Mierocrystalline cellulose, xylogen decomposer (selecting ascomycetes or basidiomycetes for use), and the well-established law fermentation culture is made fruiting source microbial bacteria material.
It is the calcium carbonate alkaline material that the present invention also adopts a kind of raw material, and it is that ammonia alkali legal system alkali produces, through the waste residue (being called alkaline residue) that harmless treatment process such as rinsing, desalination, press filtration form, and its physicochemical property: moisture about 30%, pH9~11, lime carbonate (CaCO 3) 〉=50%, activated carbon 〉=5% also is rich in beneficial mineral prime elements such as silicon (Si), potassium (K), zinc (Zn), iron; Also can regulate the pH value of the dregs of a decoction, make it be weakly alkaline, the actinomycetic breeding activity of favourable beneficial microorganism can quicken the decomposition to Mierocrystalline cellulose, xylogen.
Used raw material expands to loose and separates agent and select wood sawdust or perlite powder for use, and effect is to improve dehydration.
2. preparation method:
The present invention is with the raw material of following weight ratio: dewatered sludge, the dregs of a decoction, calcium carbonate alkaline material, the ratio of separating agent and mushroom source microbial bacteria material of loosing of expanding are respectively 40%~50%, 20%~30%, 10%~20%, 5%~10% and 3%~5%; The even stirring of above-mentioned mixing of materials put the rotten fermentation of heap in the fermentation vat, mixture moisture content 50%~60%, pH value 7~9, C/N is than 20~30/1, C/P is than 50~75/1, control heap back after 24~36 hours compost temperature reach 50~65 ℃, keep turning after 5~8 days, two to three weeks of summer and autumn become thoroughly decomposed; Winter-spring season three to around become thoroughly decomposed.40% of the back compost moisture content of becoming thoroughly decomposed, volume subtracts 1/3, organic content 〉=30%, N+P 2O 5+ K 2O 〉=4%, the pH value is 7~8, is rich in trace element among Ca, Mg, Si, the Zn etc.; Through natural air drying or artificial heat drying, moisture≤20%, this product will above or meet national organic fertilizer standard (Ny525-2002 organic fertilizer).
Principle of the present invention is: mainly utilize city dehydrated sludge, herbal medicine pharmacy waste residue, alkaline residue and mushroom source microbial bacteria material, with development and production a kind of have the improvement southern acid organic modifying agent for low-yield soil, thereby provide fully nutrient to plant, increase soil fertility comprehensively, increase crop yield, improve product quality, improve agricultural performance, make the peasant obtain increasing both production and income.The present invention is typical disposal of waste gas, water and industrial residue environmental protection project, is to make full use of resource recovery, fundamentally eliminates the pollution to environment.
Utilize to expand loose and to separate agent and the materialization modification is carried out in the city dehydrated sludge handle, make it to help subsequent techniques such as drying, fermentation and pulverizing.The employing medium-height grass dregs of a decoction, inoculation Mierocrystalline cellulose, xylogen decomposer (being ascomycetes or basidiomycetes) are piled rotten fermentation, produce fruiting source microbial bacteria material, provide the microbial bacteria material for enlarging in enormous quantities to produce.Utilize soda-manufacturing waste residue to regulate pH value to 7~9 of mixture, make it to help the actinomycetic breeding activity of microorganism, thereby accelerating fibers element, xylogen decompose promotion compost maturityization, stabilization; Also for modifying agent has increased trace element in calcium, magnesium, potassium, silicon, the zinc etc., thereby improve the effect of soil organic amendment.
Beneficial effect of the present invention is:
The present invention is based on recycling of local renewable resources, seek and excavation be easy to get inexpensive, the expensive soil improvement agent of alternative traditional macromolecule resin development, novelty that this possesses skills and practicality.
This product not only can be improved southern low-yield land acid soil, also helps to plant-growth full nutrition is provided; A kind of multiple town and country solid waste that utilizes is provided, and according to physicochemical property separately, blending in proportion reaches coordination republicanism, modification, the treatment of wastes with processes of wastes against one another mutually, turns waste into wealth; To improve the technical process of products production, cut down the consumption of energy, save cost, help the large scale application of soil improvement agent.
This product has good improving effect to the acid low-yield soil in south, also is a kind of functional organic fertilizer.Manufacture craft of the present invention is simple, and is with low cost, application easy to implement to promote.
Embodiment:
Below be the case description that technical solution of the present invention adopted, therefore do not limit protection scope of the present invention.
Embodiment 1
1, get 100 kilograms of dregs of a decoction earlier, the inoculation ascomycetes, the well-established law fermentative preparation becomes mushroom source microbial bacteria material standby.
2, get 420 kilograms of dewatered sludges, 230 kilograms of the dregs of a decoction, 150 kilograms of calcium carbonate alkaline substance (alkaline residue), expanding looses separates 60 kilograms of agent, and mushroom source microbial bacteria material is put in the fermentation vat for 30 kilograms and fermented, fermentation is 18 days when July, turning in average 6 days once is total to turning three times, gets product.
Embodiment 2
1, get 100 kilograms of dregs of a decoction, the inoculation basidiomycetes, it is standby that mushroom source microbial bacteria material is made in the well-established law fermentation.
2, get 450 kilograms of dewatered sludges, 280 kilograms of the dregs of a decoction, 180 kilograms of calcium carbonate alkaline substance, diffusing 80 kilograms of agent, 40 kilograms in the mushroom source microbial bacteria material separated of expansion, put in the fermentation vat and ferment, fermentation is 25 days during December, and turning in average 5 days once, turning is five times altogether, gets product.

Claims (3)

1, a kind of organic modifying agent for low-yield soil, it is characterized in that: the raw material that contains following weight ratio: dewatered sludge 40%~50%, the dregs of a decoction 20%~30%, calcium carbonate alkaline material 10%~20%, expanding looses separates agent 5%~10%, mushroom source microbial bacteria material 3%~5%;
Mixture contains moisture 50%~60%, pH7~9, and the C/N ratio is 20~30/1, the C/P ratio is 50~75/1;
Expanding looses separates the mixture that a kind of or arbitrary proportion in wood sawdust, the perlite powder is selected in agent for use;
Mushroom source microbial bacteria material selects for use the meticulous high-quality part dregs of a decoction to produce through the mixed bacterium of a kind of or arbitrary proportion of inoculation Mierocrystalline cellulose, xylogen decomposer, and wherein the xylogen decomposer is selected ascomycetes or basidiomycetes for use;
The calcium carbonate basic material is that ammonia alkali legal system alkali produces, and through the alkaline residue that harmless treatments such as rinsing, desalination, press filtration form, its physicochemical property: moisture content is about 30%, and pH 9~11, lime carbonate 〉=50%, activated carbon 〉=5%.
2, a kind of organic modifying agent for low-yield soil according to claim 1, it is characterized in that: the raw material that contains following weight ratio: dewatered sludge 42%~45%, the dregs of a decoction 23%~28%, calcium carbonate alkaline material 15%~18%, expanding looses separates agent 6%~8%, mushroom source microbial bacteria material 3%~4%.
3, the preparation method of a kind of claim 1 or 2 described organic modifying agent for low-yield soil, it is characterized in that: above-mentioned mixing of materials is stirred to put carry out half aerobic fermentation heap corruption in the fermentation vat, control stacks that compost temperature reaches 50~65 ℃ after 24~36 hours, turning in 5~8 days once, summer and autumn became thoroughly decomposed for two thoughtful three weeks; Winter-spring season become thoroughly decomposed three thoughtful around.
CN2008100282977A 2008-05-27 2008-05-27 Organic modifying agent for low-yield soil and method for preparing same Expired - Fee Related CN101307234B (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102515901A (en) * 2011-12-02 2012-06-27 南京市环境保护科学研究院 Method for utilizing sludge from municipal sewage treatment plant as forestry soil matrix
CN104031648A (en) * 2014-05-19 2014-09-10 黑龙江省科学院自然与生态研究所 City garden soil secondary salinization improving agent and preparation method thereof
CN104312589A (en) * 2014-09-03 2015-01-28 云南尚呈生物科技有限公司 Fermented brown coal residue soil conditioner and processing method thereof
CN105566014A (en) * 2016-03-10 2016-05-11 广西鸿生源环保股份有限公司 Land improvement nutrient soil prepared from sludge of town sewage plants and preparation method thereof
CN107586224A (en) * 2017-09-08 2018-01-16 大连青松智慧生态科技有限公司 A kind of sludge and alkaline residue mixed method

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102515901A (en) * 2011-12-02 2012-06-27 南京市环境保护科学研究院 Method for utilizing sludge from municipal sewage treatment plant as forestry soil matrix
CN104031648A (en) * 2014-05-19 2014-09-10 黑龙江省科学院自然与生态研究所 City garden soil secondary salinization improving agent and preparation method thereof
CN104312589A (en) * 2014-09-03 2015-01-28 云南尚呈生物科技有限公司 Fermented brown coal residue soil conditioner and processing method thereof
CN104312589B (en) * 2014-09-03 2017-06-16 云南尚呈生物科技有限公司 Fermentation brown coal residue soil conditioner and its processing method
CN105566014A (en) * 2016-03-10 2016-05-11 广西鸿生源环保股份有限公司 Land improvement nutrient soil prepared from sludge of town sewage plants and preparation method thereof
CN107586224A (en) * 2017-09-08 2018-01-16 大连青松智慧生态科技有限公司 A kind of sludge and alkaline residue mixed method

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