CN101268177B - 清洁剂组合物、清洁剂制品及清洁方法 - Google Patents
清洁剂组合物、清洁剂制品及清洁方法 Download PDFInfo
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- CN101268177B CN101268177B CN2006800344614A CN200680034461A CN101268177B CN 101268177 B CN101268177 B CN 101268177B CN 2006800344614 A CN2006800344614 A CN 2006800344614A CN 200680034461 A CN200680034461 A CN 200680034461A CN 101268177 B CN101268177 B CN 101268177B
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- cleanser compositions
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- spices
- alcohol
- spray dispenser
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0043—For use with aerosol devices
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2041—Dihydric alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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Abstract
本发明描述了一种清洁剂组合物，所述组合物包含表面活性剂、钠源、气味中和剂、香料和抗微生物剂，其中所述气味中和剂包括甜菜碱化合物、氨基醇、多元醇和紫罗酮，且其中当于约25℃下储存24个月时，在pH为约9.5-约11.5下，所述清洁剂组合物稳定。喷雾分配器包括清洁剂组合物和推进剂。本发明还描述了一种清洁、除臭或清洁和除臭汽车内饰的方法，所述方法包括对汽车内饰施用所公开的清洁剂组合物。
Description
相关申请的交叉引用
本申请要求2005年7月22日提交的美国临时申请序列号60/701,899的权益，该临时申请的内容通过引用结合到本文中来。
背景技术
已开发了用于各种用途的许多不同的清洁组合物。清洁剂的作用可包括除去油脂和/或粒状污物、除臭、消毒(杀灭细菌和病毒微生物)、除去污点、除去霉菌、漂白和保持待漂白材料的颜色。通常的织物清洁方法可除去或掩盖来自包含较低含量恶臭的织物的气味。但是，当织物含有较高含量恶臭物时，或当织物包含某种恶臭(例如来自宠物粪便、失禁的气味、回涌的食物、通常的食物遗撒、霉(mold)或霉菌(mildew)的恶臭)时，可存在通过通常的织物清洁方法不能除去或掩盖的残留的恶臭。在通常的织物清洁方法之后仍有恶臭的情况下，消费者会第二次或甚至第三次清洁地毯的恶臭区域。这样对织物(特别是包含恶臭的特定区域)产生过度磨损，且由于不均匀的磨损，可导致织物的外观不均匀。
已在除臭剂和清洁剂组合物中使用环糊精来控制气味。但是，当将环糊精掺入洗涤剂组合物时，可与香料和表面活性剂相互作用，且控制恶臭所需的含量非常高。气味阻挡剂(odor blocker)用于其他组合物。当某些气味阻挡剂以高含量来控制恶臭时，可同时阻挡香料的合乎需要的气味和恶臭。同样，因为反应物可破坏合乎需要的气味，某些掩饰化合物阻挡了合乎需要的气味。
因此，仍需要新型清洁剂和除臭剂组合物，特别是适用于织物的清洁剂和除臭剂组合物。
发明概述
在一个实施方案中，清洁剂组合物包含气味中和剂，其中所述气味中和剂包括甜菜碱化合物、氨基醇、多元醇和紫罗酮。
在一个示例性的实施方案中，清洁剂组合物包含表面活性剂、钠源、气味中和剂、香料和抗微生物剂，其中所述气味中和剂包括甜菜碱化合物、氨基醇、多元醇和紫罗酮；且其中当于约25℃下储存24个月时，在pH为约9.5-约11.5下，所述清洁剂组合物稳定。
在另一个实施方案中，描述了包含上述清洁剂组合物和任选的推进剂的喷雾分配器。
在再一个实施方案中，一种清洁、除臭或清洁和除臭汽车内饰的方法包括对汽车内饰施用上述清洁剂组合物。
根据以下详细说明和附随的权利要求，本领域技术人员将理解上述和其他特征。
发明详述
术语“污染物”描述在其清洁或未被污染状态下在织物中通常不会发现且通常在清洁过程中从织物中除去的大多数物质。示例性的污染物包括脂肪、脂肪酸例如甘油三酯、脂肪样的物质、盐、食物残余物(例如咖啡、苏打、调味番茄酱、芥末、巧克力和奶)、汗、血、尿、烟、污点、污物、油和油脂和在清洁纺织品中通常不会发现的许多其他合成和天然或生物学污染物。某些常见的污染物包括尿、酸奶和烟。
术语“纺织品”和“织物”用于描述包含用于制备外衣、衣服、地毯、蒙布和相关含布物品的天然和合成纤维的布和相关材料。与本发明的组合物相容的纺织品包括由天然和合成的纤维和纱制备的纺织品，例如丝、棉、羊毛、木棉、亚麻布、大麻、黄麻、蕉麻纸、芦苇草、椰子、染料木、槿麻、苎麻、剑麻、聚酯、乙酸酯、三乙酸酯、人造丝、人造丝-乙酸酯、纤维素、聚丙烯-纤维素、聚烯烃、藻酸盐、凯普(cupro)(再生纤维素)、莫代尔(modal)、再生蛋白质纤维、聚丙烯腈(polyacryl)、多氯化物、含氟纤维、改性聚丙烯腈(modacryl)、聚丙烯腈、聚酰胺(包括尼龙)、聚乙烯、聚丙烯、聚脲、聚氨酯、聚丙烯醇类(vinylal)、乙烯基类三元共聚物(trivinyl)、二烯类弹性体(elastodiene)、聚氨酯弹性体(elasthane)以及这些天然和合成的纤维的混合物等。
本文中发明人发现，由于各种组分之间的协同相互作用，清洁剂组合物还具有中和气味的性能。在一个示例性的实施方案中，清洁剂组合物包含表面活性剂、钠源、气味中和剂、香料和抗微生物剂，其中所述气味中和剂包括甜菜碱化合物、氨基醇、多元醇和紫罗酮，其中当于约25℃下储存24个月时，在pH为约9.5-约11.5下，所述清洁剂组合物稳定。
本文使用的术语“稳定”是指组合物储存稳定，也就是说，基本不形成沉淀物、发生相分离或化学降解例如水解解离。例如在稳定的制剂中，制剂的外观基本无变化。
在一个示例性的实施方案中，清洁剂组合物包含表面活性剂。所述表面活性剂可包括非离子表面活性剂、阴离子表面活性剂、阳离子表面活性剂、两性表面活性剂或包含一种或多种上述表面活性剂的组合。尽管不希望受缚于理论，但我们认为表面活性剂乳化有气味的(odiferous)材料例如油、灰尘、食品、宠物气味、尿、呕吐物等。乳化可增加气味中和的表面积和/或创造气味中和的环境。
合适的非离子表面活性剂包括但不局限于乙氧基化的醇、乙氧基化的酚、乙氧基化的脂肪酸酯、乙氧基化的甘油脂肪酸酯、脱水山梨糖醇脂肪酸酯、甘油脂肪酸酯、椰油单乙醇酰胺乙氧基化物、乙氧基化的妥尔油、乙氧基化的聚丙二醇、脂肪酸链烷醇酰胺例如椰油单-和二乙醇酰胺、氧化胺、正烷基吡咯烷酮、烷基多糖例如蔗糖酯和烷基多苷、烷基酚乙氧基化物、乙氧基化的蓖麻油、脂肪酸乙氧基化物、脂肪胺乙氧基化物、聚甘油脂肪酸酯和环氧乙烷-环氧丙烷共聚物的烷基加成物以及两种或多种上述物质的混合物。在一个实施方案中，非离子表面活性剂包括乙氧基化的醇，例如Tomadol25-7，一种C12-C15乙氧基化的醇，购自Tomah Products，Inc。在另一个实施方案中，表面活性剂包括烷基多苷例如Glucopon
425，认为该化合物是D-吡喃葡糖苷或类似的C10-C16烷基低聚物和D-葡萄糖的混合物，或Glucopon
215，认为该化合物包括D-吡喃葡糖苷或类似的C10-C16烷基低聚物，均购自Cognis。在另一个实施方案中，表面活性剂包括烷基多苷，例如Dehypound WO7(购自Cognis)，认为该化合物包括包含C10-C16烷基多苷和C8-C10醇乙氧基化物丙氧基化物加上癸烯环氧化物的混合物。在另一个实施方案中，表面活性剂包括烷基多苷，例如Dehypound HSC 5515(购自Cognis)，认为该化合物包括包含C10-C16烷基多苷以及表氯醇与异癸醇-4EO的反应产物的混合物。在再一个实施方案中，非离子表面活性剂包括GenapolEP 1024(以前称为Sandoxylate
SX-408)，为异-C10-环氧乙烷-环氧丙烷共聚物加成物。另一种合适的非离子表面活性剂为乙氧基化的壬基酚，该化合物以与另一种专有的表面活性剂Monamulse DLE的混合物形式购自Uniqema。
合适的阴离子表面活性剂包括但不局限于直链和/或支链烷基苯磺酸盐、烷基硫酸盐、醚硫酸盐、仲烷基硫酸盐、α-烯烃磺酸盐、磷酸酯盐、磺基琥珀酸盐、羟乙基磺酸盐、羧酸盐和包含一种或多种上述阴离子表面活性剂的组合。具体的阴离子表面活性剂的实例有十二烷基硫酸钠、十二烷基醚硫酸钠、三乙醇胺十二烷基硫酸盐、十二烷基硫酸镁、磺基琥珀酸酯盐、十二烷基硫酸铵、烷基磺酸盐、十二烷基硫酸钠、α-烯烃磺酸钠、烷基硫酸盐、硫酸化的醇乙氧基化物、硫酸化的烷基酚乙氧基化物、二甲苯磺酸钠、烷基苯磺酸盐例如三乙醇胺十二烷基苯磺酸盐、十二烷基苯磺酸钠、十二烷基苯磺酸钙、二甲苯磺酸、十二烷基苯磺酸、N-烷酰基(alkoyl)肌氨酸盐例如月桂酰基肌氨酸钠、二烷基磺基琥珀酸盐、N-烷酰基肌氨酸例如月桂酰基肌氨酸、烷基醚羧酸盐、皂类包括钠、钾、镁、钙、链烷醇胺和胺皂和包含一种或多种上述阴离子表面活性剂的组合。在一个实施方案中，阴离子表面活性剂为以WITCOLATE
WAC LA购自Akzo的十二烷基硫酸钠。
两性表面活性剂包括但不局限于甜菜碱、正烷基吡咯烷酮、咪唑啉和包含一种或多种上述表面活性剂的组合。
阳离子表面活性剂包括但不局限于季铵化合物，包括烷基二甲基苄基氯化铵、二烷基二甲基氯化铵、烷基三甲基氯化铵或溴化铵、有机或无机酸与脂肪胺、脂肪胺乙氧基化物的盐和包含一种或多种上述阳离子表面活性剂的组合。
可使用各种类型表面活性剂的混合物，例如非离子和阴离子表面活性剂的混合物。此类专有的混合物为购自Mona Industries，Inc的MonamulseDLE。
在一个实施方案中，表面活性剂包括环氧乙烷-环氧丙烷共聚物的烷基加成物、烷基多苷、十二烷基硫酸钠和乙氧基化的醇。在一个实施方案中，烷基多苷包括链长为C8-C16的烷基的烷基多苷。包含链长为C8-C16的烷基的合适烷基多苷的合适商品表面活性剂的示例性实例为Dehypound HSC 5515，购自Cognis。在另一个实施方案中，烷基多苷包括链长为C8-C10的烷基的烷基多苷。包含链长为C8-C10的烷基的合适烷基多苷的商品表面活性剂的实例为DehypoundWO7，购自Cognis。
在一个实施方案中，表面活性剂为所述清洁剂组合物总重量的0.0％-约2％。在另一个实施方案中，表面活性剂占约0.2％重量-约1.0％重量。在一个示例性的实施方案中，表面活性剂为所述清洁剂组合物重量的约0.95％。
在其中表面活性剂包括环氧乙烷-环氧丙烷共聚物的烷基加成物、烷基多苷、十二烷基硫酸钠和乙氧基化的醇的实施方案中，环氧乙烷-环氧丙烷共聚物为所述清洁剂组合物总重量的约0.1％-约0.3％，烷基多苷为所述清洁剂组合物总重量的约0.05％-约0.5％，十二烷基硫酸钠为所述清洁剂组合物总重量的约0.125％-约0.625％，乙氧基化的醇为所述清洁剂组合物总重量的约0.05％-约0.3％。
在一个示例性的实施方案中，清洁剂组合物包含钠源。尽管不希望受缚于理论，但我们仍然认为钠源的钠与有气味的分子相互作用，例如置换硫和/或有机基团，产生不太有气味的或没有气味的分子。合适的钠源的实例有柠檬酸钠、钠盐和十二烷基硫酸钠。
清洁剂组合物还包含气味中和剂。某些气味中和剂通过降低产生恶臭的化合物的量来掩盖恶臭。本文使用的气味中和剂为与有气味的分子反应以降低或消除气味的化合物。气味中和剂包括甜菜碱化合物、氨基醇、多元醇和紫罗酮。认为甜菜碱化合物、氨基醇、多元醇和紫罗酮与表面活性剂的协同相互作用导致中和宽范围的气味。
气味中和剂包括甜菜碱化合物。甜菜碱化合物可有效除臭碱性有味气体例如氨或三甲胺(TMA)以及酸性有味气体例如硫化氢或甲硫醇(MeSH)。合适的甜菜碱化合物的实例有甘氨酸甜菜碱，例如N-(羧甲基)-N，N-双(2-羟乙基)2-羟基乙基氯化铵(N-(carboxymethyl)-2-hydroxy-N，N-bis(2-hydroxyethyl)chloride)。包含甜菜碱的组合物例如以Epoleon
N-NZ和Epoleon
-100购自EpoleonCorporation。
气味中和剂还包括氨基醇。醛(例如乙醛、丁醛、异丁醛、2-甲基丁醛、3-甲基丁醛、己醛等)可引起污秽气味，例如尿味。氨基醇例如单乙醇胺、二乙醇胺、三乙醇胺和包含一种或多种上述氨基醇的组合可中和醛的气味。
气味中和剂包括可与有恶臭的组分络合和/或赋予清洁剂组合物令人愉快的香味的多元醇。合适的多元醇的实例有乙二醇、二甘醇、三甘醇、丙二醇、二丙二醇和包含一种或多种上述二醇的组合。在一个实施方案中，多元醇为三甘醇。三甘醇可以T.O.C(Termiticide OdorCounteractant，购自Aire-Mate，Inc)的形式加至制剂中。
气味中和剂还包括紫罗酮。紫罗酮可具有气味掩盖性能。合适的紫罗酮的实例有α-紫罗酮、β-紫罗酮、γ-紫罗酮和包含一种或多种上述紫罗酮的组合。
气味中和剂为所述清洁剂组合物总重量的约0.125％-约0.5％。在另一个实施方案中，气味中和剂为所述清洁剂组合物总重量的约0.25％-约0.5％。在再一个实施方案中，气味中和剂为所述清洁剂组合物总重量的约0.375％-约0.5％。
在一个示例性的实施方案中，清洁剂组合物包含香料。香料可通过叠加占优势的但更令人愉快的气味，使得恶臭变得较令人愉快。香料的一个优点在于通常其沸点比其他物质低，因此来自这些材料的香味快速扩散至空气中，并与恶臭竞争，与嗅觉感受部位结合。由于来自这些香料的香味更易挥发，且在恶臭之前达到嗅觉感受部位，当恶臭最终到达时，嗅觉感受部位已被占据，因此有效掩盖恶臭的识别。
合适的香料的实例有茴香醚、庚炔羧酸甲酯、乙酰乙酸乙酯、对异丙基苯甲烷、橙花醇、癸醛、对甲酚、乙酸甲基苯基甲酯、十一烯醛、十一醛、2，6-壬二烯醛、壬醛、辛醛、苯基乙醛、茴香醛、苄基丙酮、丁酸(乙基-2-甲酯)、大马酮、α-大马酮、β-大马酮、flor acetate、frutene、苹果酯、herbavert、异环柠檬醛、甲基异丁烯基四氢吡喃、异丙基喹啉、2，6-壬二烯-1-醇、2-甲氧基-3-(2-甲基丙基)-吡嗪、辛炔羧酸甲酯、十三烯-2-腈、戊基甘醇酸烯丙酯、环加蓬酸酯、cyclal C、甜瓜醛、γ-壬内酯(nonalactone)、顺式1，3-氧杂硫杂环己烷-2-甲基-4-丙基、苯甲醛、乙酸苄酯、樟脑、莰烯、香芹酮、冰片、乙酸冰片酯、癸醇、桉树脑、里哪醇、乙酸己酯、乙酸异戊酯、百里酚、香芹酚、苧烯、薄荷醇、异戊醇、苯基乙醇、α-蒎烯、萜品醇、香茅醇、α-苧酮、苄醇、β，γ-己烯醇、二甲基苄基甲醇、苯基乙基二甲基甲醇、2，6，10-三甲基-9-十一碳烯醛、环己烷丙酸烯丙酯、β-蒎烯、柠檬醛、乙酸香茅酯、香茅腈、二氢月桂烯醇、香叶醇、乙酸香叶酯、香叶腈、氢醌二甲醚、羟基香茅醛、乙酸里哪酯、苯乙醛缩二甲醇、苯基丙醇、乙酸异戊烯酯、(2，4-二甲基环己烯-3-基)甲醛、四氢里哪醇、乙酸邻叔丁基环己酯、顺式-乙酸3-己烯酯、甲基苯基缩水甘油酸乙酯、乙基香草醛、胡椒醛、吲哚、邻氨基苯甲酸甲酯、香草醛、水杨酸戊酯、香豆素、降龙涎香醚、bacdanol(檀香208)、水杨酸苄酯、邻氨基苯甲酸丁酯、cetalox、ebanol、顺式-水杨酸3-己烯酯、铃兰醛、γ-十一内酯、γ-十二内酯、γ-癸内酯、ebanol、cymal、二氢异茉莉酮酸酯、异丁子香酚、新铃兰醛、甲基β-萘基酮、β-萘酚甲基醚、对羟基苯基丁酮、8-环十六碳烯-1-酮、氧代环十六碳烯-2-酮/habanolide、florhydral、十一碳烯醛混合物、戊基肉桂醛、己基肉桂醛、水杨酸己酯、二氢茉莉酮酸甲酯、5-(2，3，3-三甲基-1-环戊烯)-3-甲基-2-戊醇、veloutone、undecavertol、环十五内酯/环十五烷内酯、姜油酮、甲基柏木酮、合成檀香(sandela)、丁酸二甲基苄基甲酯、异丁酸二甲基苄基甲酯、柠檬酸三乙酯、开司米酮、异丁酸苯氧基乙酯、乙酸异丁子香酚酯、新洋茉莉醛、iso E super、甲基γ-紫罗酮、环十五内酯、加乐麝香、丙酸苯氧基乙酯和包含一种或多种上述香料的组合。在一个实施方案中，香料包括樟脑、莰烯、水杨酸戊酯、萜品醇或包含一种或多种上述香料的组合。
在一个实施方案中，香料为所述清洁剂组合物总重量的0.0％-约0.325％。在另一个实施方案中，香料为所述清洁剂组合物总重量的约0.01％-约0.125％。在另一个实施方案中，香料为所述清洁剂组合物总重量的约0.01％-约0.25％。在再一个实施方案中，香料为所述清洁剂组合物总重量的约0.01％-约0.325％。
在一个实施方案中，所述清洁剂组合物包含抗微生物剂。合适的抗微生物剂的实例有2-甲硫基-4-叔丁基氨基-6-环丙基氨基-s-三嗪；4，4-二甲基-唑烷；3，4，4-三甲基
唑烷；5-羟基-甲基-1-氮杂-3，7-二氧杂双环(3.3.0)辛烷；2-(羟甲基)-氨基乙醇；2-(羟甲基)-氨基-2-甲基-1-丙醇；六氢(hexyhydro)-1，3，5-三乙基-5-三嗪；氯化1-(3-氯烯丙基)-3，5，7-三氮杂-1-铵杂(azonia)-金刚烷；氯化1-甲基-3，5，7-三氮杂-1-铵杂-金刚烷；对氯间甲酚；烷基胺盐酸盐；6-乙酰氧基-2，4-二甲基-1，3-二
烷；5-氯-2-甲基-4-异噻唑啉-3-酮；2-甲基-4-异噻唑啉-3-酮；1，3-双(羟甲基)-5，5-二甲基乙内酰脲；羟甲基-5，5-二甲基乙内酰脲；2-(4-噻唑基)苯并咪唑；N-三氯甲硫基-4-环己烯-1，2-二甲酰亚胺；2-正辛基-4-异噻唑啉-3-酮；2，4，5，6-四氯-间苯二腈；3-碘-2-丙炔基丁基氨基甲酸酯；N-(三氯甲硫基)邻苯二甲酰亚胺；四氯间苯二腈；N-羟基-甲基-N-甲基-二硫代氨基甲酸钾；2-巯基吡啶-1-氧化钠；对羟基苯甲酸丁酯；对羟基苯甲酸乙酯；对羟基苯甲酸甲酯；对羟基苯甲酸丙酯；2-巯基苯并噻唑；5-氯-2-甲基-3(2H)-异噻唑啉；2-甲基-3(2H)-异噻唑酮(isothiazolone)；4-(2-硝基丁基)-吗啉；4，4′-(2-乙基硝基三亚甲基)乙双吗啉；四氢-3，5-二甲基-2H-1，3，5-噻二嗪-2-硫酮；二甲基二硫代氨基甲酸钾；(二碘甲基)(对甲苯基)砜；戊二醛；二硫氰基甲烷；1，2-二溴-2，4-二-氰基丁烷；1，2-苯并异噻唑啉-3-酮；2-(硫代氰基甲硫基)苯并噻唑；2-(硫代氰基甲硫基)苯并噻唑(benzothiozole)；二硫氰基甲烷；和包含一种或多种上述抗微生物剂的组合。
在一个实施方案中，抗微生物剂为所述清洁剂组合物总重量的0.0％-约0.3％。在另一个实施方案中，抗微生物剂为所述清洁剂组合物总重量的约0.01％-约0.3％。在另一个实施方案中，抗微生物剂为所述清洁剂组合物总重量的约0.01％-约0.15％。
清洁剂组合物任选包含水溶助长剂，以帮助表面活性剂悬浮。一种合适的水溶助长剂为DeTrope CA-100，一种改性羧酸盐，购自DeForest Enterprises。由于DeTrope CA-100还可具有缓蚀性能，因此是有利的。
在一个实施方案中，水溶助长剂为所述清洁剂组合物总重量的0.0％-约0.5％。在另一个实施方案中，水溶助长剂为所述清洁剂组合物总重量的约0.3％-约0.4％。在再一个实施方案中，水溶助长剂为所述清洁剂组合物总重量的约0.3％。
清洁剂组合物任选包含缓蚀剂。合适的缓蚀剂的实例有三唑、亚硝酸盐(例如亚硝酸钠)、钼酸盐(例如钼酸钠)、苯甲酸盐(例如1，2，3-苯并三唑)、葡糖酸盐和包含一种或多种上述缓蚀剂的组合。在一个实施方案中，缓蚀剂包括亚硝酸钠。
在一个实施方案中，缓蚀剂为所述清洁剂组合物总重量的0.0％-约0.58％。在另一个实施方案中，缓蚀剂为所述清洁剂组合物总重量的约0.03％-约0.05％。在另一个实施方案中，缓蚀剂为所述清洁剂组合物总重量的约0.08％-约0.03％。在再一个实施方案中，缓蚀剂为所述清洁剂组合物总重量的约0.03％-约0.58％。
清洁剂组合物任选包含水溶性碱性碳酸钠盐作为助洗剂。助洗剂为降低表面活性剂临界胶束浓度(CMC)的化合物。本文使用的术语“碳酸盐”是指包含CO3 2-或HCO3 -阴离子的盐。可由一种或多种碳酸钠盐或碳酸氢钠提供碳酸盐。碳酸钠盐包括但不局限于碳酸钠本身、碳酸钠十水合物、碳酸钠七水合物、碳酸钠一水合物、倍半碳酸钠及其复盐和混合物。上述碳酸钠盐和碳酸氢钠的混合物也是特别有用的。
在一个实施方案中，碳酸钠盐为所述清洁剂组合物总重量的0.0％-约1.0％。在另一个实施方案中，碳酸钠盐为所述清洁剂组合物总重量的约0.05％-约1.0％。在另一个实施方案中，碳酸钠盐为所述清洁剂组合物总重量的约0.05％-约0.5％。在再一个实施方案中，碳酸钠盐为所述清洁剂组合物总重量的约0.01％-约0.05％。
所述清洁剂组合物任选包含萜化合物。本文使用的术语“萜化合物”是指一类无环和环状的不饱和化合物，该化合物衍生自具有至少10个碳原子的天然精油和树脂。萜包括醇和醛以及不饱和烃。可使用多种萜化合物，包括这些萜的组合。合适的萜化合物的实例有α-萜品烯、α-蒎烯、β-蒎烯、δ-3-蒈烯、香茅醛、香茅醇、羟基香茅醛、d-苧烯、里哪醇、γ-萜品烯、四氢里哪醇和萜品醇等。在一个实施方案中，萜化合物为d-苧烯。
萜化合物为所述清洁剂组合物总重量的0.0％-约0.02％。在另一个实施方案中，萜化合物为所述清洁剂组合物总重量的0.0％-约2.0％。
着色剂和染料可任选加至清洁剂组合物中，以增强视觉吸引力和性能印象。当使用着色剂时，可使用足以使清洁剂组合物着色，但低于可导致织物着色的含量。
在一个实施方案中描述了一种制备所公开的清洁剂组合物的方法，所述方法包括将水溶助长剂和水混合以形成第一混合物，加入表面活性剂以形成第二混合物，随后加入气味中和剂和香料以形成清洁剂组合物。
可将清洁剂组合物储存在喷雾分配器中，以便分布在织物上。喷雾分配器可为本领域已知的用于产生液滴喷雾的手动激活装置，例如触发型、泵型、非气溶胶自加压型、气溶胶型喷雾装置等。喷雾分配器可包括不显著使清洁剂组合物发泡的那些分配器。喷雾分配器任选包括刷子，以促进除去污物。
喷雾分配器可为气溶胶分配器。气溶胶分配器包括可由用于制造气溶胶容器的常规材料构造的容器。分配器能承受约20-约110psi(表压)或约20-约70psi(表压)的内压。喷雾分配器配备阀部件，该阀部件使得包含在分配器中的清洁剂组合物以精细或细粒状的颗粒或液滴的雾的形式分配。气溶胶分配器利用加压密封容器，在压力下通过调节器/阀组件从容器中分配出清洁剂组合物。通过掺入通常称为推进剂的气态组分来加压气溶胶分配器。合适的气溶胶推进剂的实例有气态烃例如异丁烷、丙烷、混合的卤代烃、压缩空气、氮气、惰性气体、二氧化碳等和包含一种或多种上述推进剂的组合。一种示例性的推进剂为Aeron NP-46，为丙烷和正丁烷的混合物，购自DiversifiedCPC International。
喷雾分配器可为具有旋绕衬里和弹性套筒的自加压非气溶胶容器。自加压分配器可包括衬里/套筒(liner/sleeve)组件，该组件在基本为圆柱形的弹性套筒内包含薄(例如约0.010-约0.020英寸厚)的柔韧的径向伸展的旋绕塑料衬里。衬里/套筒能保持大量清洁剂组合物且能使产品分配。另一种类型的气溶胶喷雾分配器为其中隔板将清洁剂组合物与推进剂(例如压缩空气或氮气)分隔的分配器。
喷雾分配器可为非气溶胶手动激活的泵-喷雾分配器。泵-喷雾分配器可包括容器和拧紧或搭锁在容器上的泵机械装置。容器包括包含待分配清洁剂组合物的容器。泵机械装置包括具有基本固定的体积、在其内部末端具有开口的泵室。泵杆位于泵室内，在泵杆末端具有活塞，活塞在泵室中往复运动。泵杆具有通路，在通路外端具有分配出口，在其内部含有轴向入口。容器和泵机械装置可由用于制造泵-喷雾分配器的常规材料构造，所述材料包括但不局限于：聚乙烯；聚丙烯；聚对苯二甲酸乙二酯；和聚乙烯、乙酸乙烯酯和橡胶弹性体的共混物。
喷雾分配器可为手动激发的触发-喷雾分配器。触发-喷雾分配器包括容器和触发器，二者均可由用于制造触发-喷雾分配器的常规材料构造，所述材料包括但不局限于：聚乙烯；聚丙烯；聚缩醛；聚碳酸酯；聚对苯二甲酸乙二酯；聚氯乙烯；聚苯乙烯；和聚乙烯、乙酸乙烯酯和橡胶弹性体的共混物。其他材料可包括不锈钢和玻璃。触发-喷雾分配器不在清洁剂组合物中掺入推进剂气体。触发-喷雾分配器可作用于离散量的清洁剂组合物本身，通常通过活塞或压平的波纹管(bellow)装置将组合物移位以通过喷嘴从而产生稀液体喷雾。触发-喷雾分配器可包括具有活塞或波纹管的泵室，活塞或波纹管响应该触发可移动有限的冲程来改变所述泵室的体积。该泵室或波纹管收集和保持用于分配的清洁剂组合物。触发喷雾分配器可具有出口止回阀，出口止回阀用来阻断流体传送和流动通过喷嘴，且对室内压力有响应。对于活塞型触发喷雾器，当压触发器时，触发器作用于室内的流体和弹簧，增加对流体的压力。对于波纹管喷雾分配器，当压波纹管时，增加对流体的压力。触发喷雾分配器内流体压力增加，使得打开顶出口止回阀。顶阀迫使清洁剂组合物通过涡流室并从喷嘴出来，形成放料模式。可使用可调节的喷嘴帽来改变流体的分配模式。对于活塞喷雾分配器，当释放触发器时，弹簧作用于活塞，使其返回初始位置。对于波纹管喷雾分配器，波纹管起弹簧的作用，使其返回初始位置。该作用引起室内真空。响应的流体起作用，关闭出口阀，同时打开入口阀，将产品从储器引入该室。
可通过分布使用清洁剂组合物，例如通过将清洁剂组合物放置在分配装置(例如喷雾分配器)中，随后将有效量的清洁剂组合物喷雾在所需的表面或制品上。本文所述的“有效量”是指其量足以清洁和/或吸收恶臭，使得通过人的嗅觉不可辨别，但不致于饱和或在制品或表面上产生一池液体，因此当干燥时，不存在易辨别的看得见的沉积物。可通过使用喷雾装置、辊、板等进行分布。
本发明的公开包括在织物和/或织物制品上喷雾有效量的清洁剂组合物雾的方法。织物和/或织物制品包括但不局限于汽车内饰，例如汽车地毯、织物汽车座位等和包含一种或多种上述制品的组合。
通过以下非限制性的实施例来进一步说明本发明。
实施例1
根据表1和2形成清洁剂组合物。
表1-本发明制剂1
| 组分 | 商品名/制造商 | 量，％重量 |
| 表面活性剂：环氧乙烷-环氧丙烷共聚物的烷基加成物 | Genapol |
0.8 |
| 表面活性剂：十二烷基硫酸钠 | Wicolate |
0.30 |
| 表面活性剂：乙氧基化的醇 | Tomodol |
0.10 |
| 表面活性剂：烷基多苷 | Dehypound HSC 5515/Cognis | 0.10 |
| 气味中和剂：多元醇 | Termiticide OdorCounteractant/Aire-Mate Inc. | 0.125 |
| 气味中和剂：甜菜碱化合物，氨基醇 | Epoleon N-Nz/New Epoleon Corp. | 0.25 |
| 气味中和剂：紫罗酮 | Cirtus Fresh Neutralizer/AlphaAromatics | 0.125 |
| 抗微生物剂 | Suricide P/Surety Laboratories，Inc. | 0.15 |
| 水溶助长剂：络合羧酸(complexcarboxylic acid) | DeTrope CA-100/DeForest Enterprises | 0.4 |
| 碳酸钠 | 碳酸钠/Spectrum | 0.5 |
| 推进剂 | NP-46推进剂/Diversified CPCInternational | 3.0 |
| 水 | 94.9 |
表2-本发明制剂2
| 组分 | 商品名/制造商 | 量，％重量 |
| 表面活性剂：环氧乙烷-环氧丙烷共聚物的烷基加成物 | Genapol |
0.8 |
| 表面活性剂：十二烷基硫酸钠 | Wicolate |
0.30 |
| 表面活性剂：乙氧基化的醇 | Tomodol |
0.10 |
| 表面活性剂：烷基多苷 | Dehypound WO7/Cognis | 0.10 |
| 气味中和剂：多元醇 | Termiticide OdorCounteractant/Aire-Mate Inc. | 0.125 |
| 气味中和剂：甜菜碱化合物，氨基醇 | Epoleon N-Nz/New Epoleon Corp. | 0.25 |
| 气味中和剂：紫罗酮 | Cirtus Fresh Neutralizer/AlphaAromatics | 0.125 |
| 抗微生物剂 | Suricide P/Surety Laboratories，Inc. | 0.15 |
| 水溶助长剂：络合羧酸 | DeTrope CA-100/DeForest Enterprises | 0.4 |
| 碳酸钠 | 碳酸钠/Spectrum | 0.5 |
| 推进剂 | NP-46推进剂/Diversified CPCInternational | 3.0 |
| 水 | 94.9 |
表3-对照制剂
| 组分 | 商品名/制造商 | 量，％重量 |
| 表面活性剂：非离子和阴离子的混合物 | Monamulse DLE/Uniqema | 0.8 |
| 表面活性剂：十二烷基硫酸钠 | Wicolate |
0.23 |
| 表面活性剂：乙氧基化的醇 | Tomodol |
0.01 |
| 表面活性剂：烷基多苷 | Dehypound HSC 5515/Cognis | 0.10 |
| 气味中和剂：多元醇 | Termiticide Odor Counteractant/Aire-MateInc. | 0.125 |
| 气味中和剂：甜菜碱化合物，氨基醇 | Epoleon N-Nz/New Epoleon Corp. | 0.25 |
| 气味中和剂：紫罗酮 | Cirtus Fresh Neutralizer/Alpha Aromatics | 0.125 |
| 抗微生物剂 | Suricide P/Surety Laboratories，Inc. | 0.15 |
| 水溶助长剂：络合羧酸 | DeTrope CA-100/DeForest Enterprises | 0.3 |
| 缓蚀剂：亚硝酸钠 | 亚硝酸钠/Young Chemical | 0.05 |
| 碳酸钠 | 碳酸钠/Spectrum | 0.5 |
| 推进剂 | NP-46推进剂/Diversified CPCInternational | 3.0 |
| 水 | 94.36 |
为了形成清洁剂组合物，将水和水溶助长剂混合以形成第一混合物。随后将表面活性剂加至第一混合物以形成第二混合物。随后将剩余的组分混入以形成最终的清洁剂组合物。当于约25℃下储存24个月时，表3中给出的对照制剂在pH为约9.5-约11.5时储存不稳定。
实施例2-清洁的客观数据(cleaning-objective data)
对实施例1的本发明的清洁剂/气味中和剂进行清洁试验和除味试验。用污物处理织物(地毯和head liner)试样。由受过训练的技师清洁织物试样(技师不知道使用了哪种清洁剂制剂)，且由受过训练的评级师评价清洁效果。清洁以机械方式进行以消除由于清洗引起的结果差异。由受过训练的评级师进行主观测试，将优选的清洁能力评级。评价的污物包括咖啡、用过的发动机油、芥末、调味番茄酱、巧克力糖浆、葡萄汁、汽水(可乐)和奶。
对于清洁试验，使用比色计利用漫反射客观地测定。这是一种工业标准测试仪。通过由于清洁引起织物颜色的变化来测定污点的除去。对于每个污点，测定初始织物与施用污点、干燥和清洁后织物颜色的总体差异。越接近初始颜色，则清洁剂越好也越安全。基于ASTMD4265在3个轴L、A和B(相应于蓝、黄和红色)上测定颜色。
首先检查方差齐性(HOV)，检查两组中的方差相同。方差不同暗示评价方法可能存在缺陷，且可使得ANOVA分析不太合理。对于总体平均值差异，特别是在n相同的情况下，且还由于该测试本身不必非常完善，因此HOV不如ANOVA的其他假设或t-测试有决定性。
接着进行ANOVA，查看平均差异，进行Tukeys测试，表明在何处出现平均差异。还进行2个试样T-试验，突出ANOVA的p值接近0.05处的差值。
对于清洁剂试验，将2种市售清洁剂与本发明制剂1相比较：
A.Blue Coral Upholstery and Carpet Cleaner(Blue Coral)
B.Turtle Wax Power Out Interior Cleaner(Turtle Wax)
表4：清洁剂组合物在尼龙底物上的DE值
| 制剂 | 用过的发动机油 | 咖啡 | 芥末 | 调味番茄酱 | 巧克力糖浆 | 葡萄汁 | 汽水(可乐) | 奶 |
| 实施例1制剂 | 1.51 | 0.99 | 6.16 | 1.56 | 2.58 | 3.62 | 1.57 | 2.39 |
| A | 1.75 | 1.30 | 5.20 | 1.15 | 2.29 | 1.14 | 1.5 | 1.03 |
| B | 3.26 | 2.43 | 4.4 | 4.37 | 1.56 | 3.01 | 1.79 | 3.98 |
本发明制剂1清洁大多数污点，这表明比竞争者结果改进，但清洁后某些污点仅与以前类似。此类清洁性能导致结果分布较宽，因此不符合正态分布(normal distribution)。
表5：清洁剂组合物在聚酯底物上的DE值
| 制剂 | 用过的发动机油 | 咖啡 | 芥末 | 调味番茄酱 | 巧克力糖浆 | 葡萄汁 | 汽水(可乐) | 奶 |
| 实施例1制剂 | 1.86 | 2.26 | 5.55 | 3.19 | 1.24 | 2.96 | 2.52 | 2.27 |
| A | 3.76 | 0.62 | 4.4 | 2.32 | 4.49 | 3.15 | 4.56 | 1.49 |
| B | 3.48 | 1.98 | 1.35 | 1.91 | 4.26 | 0.8 | 2.88 | 1.27 |
本发明制剂1清洁大多数污点，这表明比竞争者结果改进，但清洁后某些污点仅与以前类似。此类清洁性能导致结果分布较宽，因此不符合正态分布。
实施例3-清洁室内装潢的主观数据(cleaning-subjectivedata-upholstery)
实验室测试基于AS-345p地毯清洁方法，且为主观和双盲的。对结果进行ANOVA(P为确定偶然事件发生的置信限度的值-该统计分析的显著水平为95％，p值为0.05或以下)。MSE(基于ANOVA分析量规R & R(重复性和再现性)的测定系统分析)确定明显不同的种类(distinct categories)数为6，对于使用的Likert 7点量表是可接受的。
由于织物编织疏松，因此对室内装潢未成功地进行客观比色计测试。织物后面的背景影响比色计，导致测定标准偏差大。由于明显不同的种类数为0(参见MSE比色计/室内装潢)，MSE表明测试方法不能区分各试样。
表6-主观测试室内装潢
| 污点 | 性能 | P值 |
| 巧克力糖浆 | 实施例1＝A＝B | p＝0.985 |
| 咖啡 | 实施例1＝A＝B | p＝0.863 |
| 奶 | 实施例1＝A＝B | p＝0.302 |
| 发动机油 | 实施例1＝A＝B | p＝0.979 |
| 葡萄汁 | 实施例1＝A＝B | p＝0.440 |
| 调味番茄酱 | 实施例1＝A＝B | p＝0.462 |
| 芥末 | 实施例1＝A＝B | p＝0.340 |
| 可乐 | 实施例1＝A＝B | p＝0.877 |
| 所有的污物 | 实施例1＝A＝B | p＝0.679 |
因此，在对室内装潢上的污点的主观测试中，本发明实施例1的制剂与商品清洁剂相当。
实施例4-清洁地毯的主观数据(Cleaning-subjective data-carpet)
测试方案使用比色计，支持数据来自雇用评级师的室内主观实验室测试，该测试方啊基于最初的地毯清洁方法。该测试为双盲的。对结果进行ANOVA。MSE确定明显不同的种类数为6，对于使用的Likert 7点量表是可接受的。参见附随的MSE、测试方法、数据和分析结果。
表7-清洁地毯的主观数据
| 污点 | 性能 | P值 |
| 巧克力糖浆 | 实施例1＝A实施例1＞B | p＝0.016 |
| 咖啡 | 实施例1＞A实施例1＝B | p＝0.000 |
| 奶 | 实施例1＞A实施例1＝B | p＝0.021 |
| 发动机油 | 实施例1＝A＝B | p＝0.416 |
| 葡萄汁 | 实施例1＝A＝B | p＝0.440 |
| 调味番茄酱 | 实施例1＝A＝B | p＝0.462 |
| 芥末 | 实施例1＝A＝B | p＝0.302 |
| 可乐 | 实施例1＝A实施例1＞B | p＝0.000 |
| 所有的污物 | 实施例1＝A＝B | p＝0.195 |
因此，在对室内装潢上的污点的主观测试中，本发明实施例1的制剂与商品清洁剂相当。
实施例5-除味数据
使用的测试方案为主观和双盲的。材料来源不影响任一种气味中和剂的除味能力。因此，使用室内装潢和地毯两种试样。
表8-初始除味
| 污点 | 性能 | P值 |
| 奶 | 实施例1＞A＞B | p＝0.000 |
| 烟 | 实施例1＝A＝B | p＝0.778 |
| 总体 | 实施例1＞A，B | p＝0.000 |
表9-长期除味
| 污点 | 性能 | P值 |
| 奶 | 实施例1＞A＞B | p＝0.000 |
| 烟 | 实施例1＝A＝B | p＝0.459 |
| 总体 | 实施例1＝A实施例1＞B | p＝0.000 |
总之，实施例1的制剂的除味性能比商品清洁剂有改进。
本文公开的所有的范围是非穷举且是可组合的。本文中术语“第一”、“第二”等不说明任何顺序、数量或重要性，而是用于将一个要素与另一个相区分，术语“一个”或单数形式不是要限制数量，而是表示存在至少一个所引用的物质。
虽然参考优选的实施方案描述了本发明，但本领域技术人员应理解的是，在不偏离本发明范围的情况下，可进行各种变化且对其要素进行等同替换。此外，在不偏离本发明的基本范围的情况下，可进行许多改变，使具体的情况或材料适应本发明的教导。因此，本发明不局限于作为实施本发明的最佳方式所公开的具体实施方案，而是本发明包括在附随的权利要求范围内的所有实施方案。
所有引用的专利、专利申请和其他参考文献通过全文引用结合到本文中来。
Claims (25)
1.一种清洁剂组合物，所述组合物包含：
表面活性剂，
钠源，
气味中和剂，
香料，和
抗微生物剂，
其中所述气味中和剂包括甜菜碱化合物、氨基醇、多元醇和紫罗酮，和
其中当于约25℃下储存24个月时，在pH为约9.5-约11.5下，所述清洁剂组合物稳定。
2.权利要求1的清洁剂组合物，其中所述表面活性剂包括环氧乙烷-环氧丙烷共聚物的烷基加成物、烷基多苷、烷基硫酸盐和乙氧基化的醇。
3.权利要求2的清洁剂组合物，其中所述烷基多苷包括至少8个碳原子且不多于16个碳原子的烷基碳链。
4.权利要求2的清洁剂组合物，其中所述烷基多苷还包括C8-C10醇乙氧基化物丙氧基化物加上癸烯环氧化物。
5.权利要求1的清洁剂组合物，其中所述香料为樟脑、莰烯、水杨酸戊酯、萜品醇或包含一种或多种上述香料的组合。
6.权利要求1的清洁剂组合物，其中所述钠源为柠檬酸钠。
7.权利要求1的清洁剂组合物，其中所述多元醇包括三甘醇。
8.权利要求1的清洁剂组合物，其中所述甜菜碱化合物包括N-(羧甲基)-N，N-双(2-羟乙基)-2-羟基乙基氯化铵。
9.权利要求1的清洁剂组合物，其中所述氨基醇包括二乙醇胺。
10.权利要求1的清洁剂组合物，所述组合物还包含缓蚀剂。
11.权利要求1的清洁剂组合物，所述组合物还包含水溶性碱性碳酸钠。
12.权利要求1的清洁剂组合物，所述组合物还包含水溶助长剂。
13.权利要求1的清洁剂组合物，所述组合物还包含助洗剂。
14.一种喷雾分配器，所述分配器包含清洁剂组合物和任选的推进剂，其中所述清洁剂组合物包含：
表面活性剂，
钠源，
气味中和剂，
香料，和
抗微生物剂，
其中所述气味中和剂包括甜菜碱化合物、氨基醇、多元醇和紫罗酮，和
其中当于约25℃下储存24个月时，在pH为约9.5-约11.5下，所述清洁剂组合物稳定。
15.权利要求14的喷雾分配器，其中所述表面活性剂包括环氧乙烷-环氧丙烷共聚物的烷基加成物、烷基多苷、烷基硫酸盐和乙氧基化的醇。
16.权利要求14的喷雾分配器，其中所述表面活性剂为阴离子表面活性剂、非离子表面活性剂或包含一种或多种上述表面活性剂的组合。
17.权利要求14的喷雾分配器，其中所述香料为樟脑、莰烯、水杨酸戊酯、萜品醇或包含一种或多种上述香料的组合。
18.权利要求14的喷雾分配器，所述喷雾分配器还包含缓蚀剂。
19.权利要求14的喷雾分配器，所述喷雾分配器还包含水溶性碱性碳酸钠。
20.权利要求14的喷雾分配器，所述喷雾分配器还包含水溶助长剂。
21.一种清洁、除臭或清洁和除臭汽车内饰的方法，所述方法包括对被污染的汽车内饰施用清洁剂组合物，其中所述清洁剂组合物包含：
表面活性剂，
钠源，
气味中和剂，
香料，和
抗微生物剂，
其中所述气味中和剂包括甜菜碱化合物、氨基醇、多元醇和紫罗酮，和
其中当于约25℃下储存24个月时，在pH为约9.5-约11.5下，所述清洁剂组合物稳定。
22.权利要求21的方法，其中所述表面活性剂包括环氧乙烷-环氧丙烷共聚物的烷基加成物、烷基多苷、十二烷基硫酸钠和乙氧基化的醇。
23.权利要求21的方法，其中所述香料为樟脑、莰烯、水杨酸戊酯、萜品醇或包含一种或多种上述香料的组合。
24.一种清洁剂组合物，所述组合物包含：
气味中和剂，
其中所述气味中和剂包括甜菜碱化合物、氨基醇、多元醇和紫罗酮。
25.权利要求24的清洁剂组合物，所述组合物还包含一种或多种表面活性剂、钠源、香料、抗微生物剂、助洗剂或其混合物。
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| CN103255005B (zh) * | 2013-05-28 | 2014-08-06 | 上海艳紫化工科技有限公司 | 迷迭香杀菌除臭洗洁精 |
| CN103275820B (zh) * | 2013-05-28 | 2015-01-21 | 安徽省林锦记食品工业有限公司 | 芒果籽油护肤洗洁精 |
| CN103255004B (zh) * | 2013-05-28 | 2014-08-06 | 上海艳紫化工科技有限公司 | 竹醋杀菌除臭洗洁精 |
| KR102115548B1 (ko) | 2013-12-16 | 2020-05-26 | 삼성전자주식회사 | 유기물 세정 조성물 및 이를 이용하는 반도체 장치의 제조 방법 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3888797A (en) * | 1970-08-04 | 1975-06-10 | Carapus Company Limited | Detergent composition |
| GB1361627A (en) * | 1970-08-04 | 1974-07-30 | Marumo H | Detergent composition |
| JPH0657240B2 (ja) * | 1985-10-31 | 1994-08-03 | アイコ−株式会社 | 脱臭剤 |
| PL151473B2 (pl) * | 1987-10-07 | 1990-09-28 | Środek do mycia naczyń | |
| US6010994A (en) * | 1995-06-07 | 2000-01-04 | The Clorox Company | Liquid compositions containing N-alkyl ammonium acetonitrile salts |
| EG21623A (en) * | 1996-04-16 | 2001-12-31 | Procter & Gamble | Mid-chain branced surfactants |
| US5997759A (en) * | 1997-06-09 | 1999-12-07 | The Procter & Gamble Company | Uncomplexed cyclodextrin compositions for odor control |
| JP2002371299A (ja) * | 2001-04-13 | 2002-12-26 | Earth Chem Corp Ltd | エアコン用スプレー製品 |
| DE10150725A1 (de) * | 2001-10-13 | 2003-04-17 | Cognis Deutschland Gmbh | Aniontensidfreie niedrigviskose Trübungsmittel |
| US6730648B2 (en) * | 2002-08-14 | 2004-05-04 | Colgate-Palmolive Co. | Unit dose detergent film |
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2006
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- 2006-07-24 AT AT06788299T patent/ATE424444T1/de not_active IP Right Cessation
- 2006-07-24 US US11/492,192 patent/US7776811B2/en active Active
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- 2006-07-24 DE DE602006005495T patent/DE602006005495D1/de active Active
- 2006-07-24 EP EP06788299A patent/EP1910506B1/en not_active Not-in-force
- 2006-07-24 CN CN2006800344614A patent/CN101268177B/zh not_active Expired - Fee Related
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| WO2007014152A1 (en) | 2007-02-01 |
| DE602006005495D1 (de) | 2009-04-16 |
| EP1910506A1 (en) | 2008-04-16 |
| CN101268177A (zh) | 2008-09-17 |
| US7776811B2 (en) | 2010-08-17 |
| US20070021316A1 (en) | 2007-01-25 |
| EP1910506B1 (en) | 2009-03-04 |
| ATE424444T1 (de) | 2009-03-15 |
| JP2009503153A (ja) | 2009-01-29 |
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