CN101195790A - Metallic bearing water-based detergent and rinsing agent used together with the same, and method for producing the same - Google Patents
Metallic bearing water-based detergent and rinsing agent used together with the same, and method for producing the same Download PDFInfo
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- CN101195790A CN101195790A CNA2006101284222A CN200610128422A CN101195790A CN 101195790 A CN101195790 A CN 101195790A CN A2006101284222 A CNA2006101284222 A CN A2006101284222A CN 200610128422 A CN200610128422 A CN 200610128422A CN 101195790 A CN101195790 A CN 101195790A
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Abstract
The invention relates to metal bearing water-based cleaning agent, rinsing agent matched with the water-based cleaning agent, and the preparation method thereof. Petroleum sodium sulfonate, triethanol amine oleate, fatty alcohol-polyoxyethylene ether, emulgator, and cocoanut oil diethanolamine phosphoric acid ester are mixed with tiethanolamine and ethanolamine according to the weight percentage, are stirred uniformly at room temperature, then are mixed with other raw materials and water, then antibubbling agent AF9020 is added, and therefore the brown yellow and transparent concentrated cleaning agent is formed; nitrous acid dicyclohexylamine, oleic acid triethanolamine and petroleum sodium sulfonate are respectively dissolved into the mixed solvent of tiethanolamine and mono ethanolamine, then benzotriazole is dissolved into water to mix the two solvent, to form the brown yellow and transparent concentrated rinsing agent; the cleaning agent and the rinsing agent are mixed into 5 percent treatment fluid and 1 percent of treatment fluid, then the treatment fluid is cleaned for 30 seconds to 1 minute under ultrasonic wave, rinsed for 30 seconds, and then hot air seasoning, drying and 48 h rust preventing are performed. The invention can replace gasoline cleaning agent, kerosene cleaning agent, and universal water-based cleaning agent, the used raw material is easy to be acquired, the production cost is low, and the invention without parkerizing process can effectively prevent the environmental pollution.
Description
Technical field:
The invention belongs to metal bearing cleaning technique field, particularly metallic bearing water-based clean-out system and matching used purificant and preparation method thereof.
Background technology:
The clean-out system of traditional metal bearing manufacturing centre bearer is as clean-out system with kerosene, gasoline etc.This volatile, incendive organic hydrocarbon compound constitutes great potential safety hazard in cleaning process, the health to operator produces greatly influence simultaneously.In today of energy worsening shortages, Production of bearing enterprise still uses kerosene, the gasoline clean-out system as bearing, will inevitably cause the significant wastage of the energy, increases problems such as enterprise's production cost and environmental pollution.
At present aqueous cleaning agent has been applied in the bearing spare and accessory parts washing process production line of some Production of bearing enterprise, this class clean-out system since used a large amount of yellow soda ash as alkali source, use phosphoric acid salt as water-softening chemicals, use nitrite as rust inhibitor; And the bearing spare and accessory parts after the washing must just can reach matching requirements through rinsing completely; And bearing is by the integral body of each parts assembling, there is raceway groove and invisible position, and small particle all can influence the quality of product; Consider the material of bearing, as Cr
3+Can influence the result of use of some promoting agent, even produce precipitation, have a strong impact on the result of use of washing composition, so this class aqueous cleaning agent be not suitable as the special purpose detergent of bearing.
Summary of the invention:
For overcoming the problem that above-mentioned metal bearing clean-out system exists, the present invention proposes a kind of metallic bearing water-based clean-out system and matching used purificant and preparation method thereof, can substitute gasoline, kerosene and general aqueous cleaning agent, raw materials used being easy to get, cheap for manufacturing cost.
For achieving the above object, the present invention adopts following technical scheme:
Described metallic bearing water-based clean-out system and matching used purificant, its cleaning agent formula weight percent is:
Fatty alcohol-polyoxyethylene ether 2-5
Emulsifying agent 2-4
Oleum Cocois diethanolamine phosphoric acid ester 10-16
Triethanolamine oleate 10-18
Trolamine 15-19
Thanomin 10-14
Petroleum sodium sulfonate 2-6
Benzotriazole 0.1-0.7
EDTA 1-1.5
Na
2CO
3 0-4
NaOH 0-2
Defoamer AF 1
Pure water 46.9-8.8
Its matching used purificant formulation weight per-cent is:
Triethanolamine oleate 10-20
Trolamine 7-15
Thanomin 9-15
Petroleum sodium sulfonate 4-8
Benzotriazole 0.1-0.5
Nitrous acid cyclohexanediamine 1-2
Pure water 68.9-39.5
Described metallic bearing water-based clean-out system and matching used purificant preparation method, its clean-out system preparation method is:
1), A component: will add triethanolamine oleate and petroleum sodium sulfonate in the mixed solvent of trolamine and thanomin, the stirring at room dissolving; Under agitation add fatty alcohol-polyoxyethylene ether, emulsifying agent, Oleum Cocois diethanolamine phosphoric acid ester again, stir 30min and form brown clear solution;
2), B component: in pure water, add benzotriazole, EDTA, NaOH, Na
2CO
3, the about 10min of stirring at room dissolving forms the water white aqueous solution;
3), the B component is poured in the A component of quick stirring, room temperature stirs 1h fast; Add defoamer AF at last, form spissated brown thickness clean-out system;
4), spissated brown thickness clean-out system is made into 5% work agent;
Its matching used purificant preparation method is:
1), the nitrous acid cyclohexanediamine is added in the mixed solvent of trolamine and thanomin stirring at room 30min, dissolving formation clear solution;
2) add triethanolamine oleate and petroleum sodium sulfonate, again, stirring at room 20min forms the dark-brown clear solution;
3), the pure water that will be furnished with benzotriazole pours into to above-mentioned brown clear solution, stirring at room 30min obtains spissated transparent purificant;
4), spissated transparent purificant is made into 1% work agent.
Because adopt aforesaid technical scheme, the present invention has following superiority:
1, metallic bearing water-based clean-out system of the present invention and matching used purificant have been avoided in the cleaning process or the suffered corrosion of washing rear bearing, have good anti-rust properties and low-corrosiveness etc.
2, metallic bearing water-based clean-out system of the present invention and matching used purificant are applicable to the automatization washing device, also are convenient to the automatization washing operation.
3, metallic bearing water-based clean-out system of the present invention and matching used purificant have enrichment, enrichment clear, the purificant consumption is few, saves packing, reduces the accumulating expense.
4, metallic bearing water-based clean-out system of the present invention and matching used purificant have no phosphatization, have prevented environmental pollution effectively.
Embodiment:
Embodiment one:
The preparation method of concentrated cleaner:
1), get and add triethanolamine oleate 18% and petroleum sodium sulfonate 6% in the mixed solvent of trolamine 19% and thanomin 14%, stirring at room 30min dissolving forms brown transparent liquid; Under agitation, add fatty alcohol-polyoxyethylene ether 5%, emulsifying agent 4%, Oleum Cocois diethanolamine phosphoric acid ester 16% again, stir 30min, form the brown clear solution of A component;
2), in pure water 14.8%, add benzotriazole 0.7%, EDTA1.5%, the about 5min of stirring at room dissolving, the water white aqueous solution of formation B component.
3), the B component is poured in the A component of quick stirring, room temperature stirs 1h fast; Add defoamer AF1% at last, form the transparent concentrated cleaner of brown heavy-gravity.
Embodiment two:
Concentrate and clean dense dose preparation method:
1), in the mixed solvent of trolamine 17% and thanomin 12%, adds triethanolamine oleate 14% and petroleum sodium sulfonate 4%, the brown transparent liquid of stirring at room 30min dissolving formation; Under agitation, add fatty alcohol-polyoxyethylene ether 3.5%, emulsifying agent 3%, Oleum Cocois diethanolamine phosphoric acid ester 13% again, stir 30min, form the brown clear solution of A component;
2), in pure water 27.85%, add benzotriazole 0.4%, EDTA1.25%, NaOH2%, Na
2CO
31%, the about 5min of stirring at room dissolving, the water white aqueous solution of formation B component.
3), the B component is poured in the A component of quick stirring, room temperature stirs 1h fast; Add defoamer AF1% at last, form the transparent concentrated cleaner of brown heavy-gravity.
Embodiment three:
Concentrate and clean dense dose preparation method:
1), in the mixed solvent of trolamine 15% and thanomin 10%, adds triethanolamine oleate 10% and petroleum sodium sulfonate 2%, the brown transparent liquid of stirring at room 30min dissolving formation; Under agitation, add fatty alcohol-polyoxyethylene ether 2%, emulsifying agent 2%, Oleum Cocois diethanolamine phosphoric acid ester 10% again, stir 30min, form the brown clear solution of A component;
2), in pure water 40.9%, add benzotriazole 0.1%, EDTA1%, NaOH4%, Na
2CO
32%, the about 5min of stirring at room dissolving, the water white aqueous solution of formation B component.
3), the B component is poured in the A component of quick stirring, room temperature stirs 1h fast; Add defoamer AF1% at last, form the transparent concentrated cleaner of brown heavy-gravity.
Embodiment four:
The preparation method of concentrated bleaching agent:
1), nitrous acid cyclohexanediamine 2% is added in the mixed solvent of trolamine 15% and thanomin 15% stirring at room 30min, dissolving formation clear solution;
2) add triethanolamine oleate 20% and petroleum sodium sulfonate 8%, again, stirring at room 20min forms the dark-brown clear solution;
3) will be furnished with the pure water 39.5% of benzotriazole 0.5%, at last and pour into to above-mentioned brown clear solution, stirring at room 30min forms the transparent concentrated bleaching agent that obtains.
Embodiment five:
The preparation method of concentrated bleaching agent:
1), nitrous acid cyclohexanediamine 1.5% is added in the mixed solvent of trolamine 11% and thanomin 12% stirring at room 30min, dissolving formation clear solution;
2) add triethanolamine oleate 15% and petroleum sodium sulfonate 6%, again, stirring at room 20min forms the dark-brown clear solution;
3) will be furnished with the pure water 54.2% of benzotriazole 0.3%, at last and pour into to above-mentioned brown clear solution, stirring at room 30min forms the transparent concentrated bleaching agent that obtains.
Embodiment six:
The preparation method of concentrated bleaching agent:
1), nitrous acid cyclohexanediamine 1% is added in the mixed solvent of trolamine 7% and thanomin 9% stirring at room 30min, dissolving formation clear solution;
2) add triethanolamine oleate 10% and petroleum sodium sulfonate 4%, again, stirring at room 20min forms the dark-brown clear solution;
3) will be furnished with the pure water 68.9% of benzotriazole 0.1%, at last and pour into to above-mentioned brown clear solution, stirring at room 30min forms the transparent concentrated bleaching agent that obtains.
Metallic bearing water-based as mentioned above clean-out system and matching used purificant using method and characterization processes:
1), elder generation is made into concentrated cleaner with pure water 5% working fluid 1000ml; It is stand-by that the concentrated bleaching agent is made into 1% working fluid 1000ml;
2), get 50 cover bearings under the cooperation of ultrasonoscope, room temperature is cleaned 30 seconds/cover, 30 seconds/cover of room temperature rinsing in purificant again, hot-air seasoning;
3), degree of cleaning or stay dirty value test: get 10 and overlap the bearing of hot-air seasoning, clean twice with the 1000ml sherwood oil in ultrasonoscope, use the filter paper suction filtration of constant weight again, constant weight, weighing stay dirty value 0.045mg/ to overlap;
4), rustless property test: get 8 and overlap the bearing of hot-air seasoning, at indoor 4 covers that hang up, folding 4 covers check under magnifying glass behind the 48h that corrosion is qualified; Get the bearing of the own hot-air seasoning of 4 covers again, the antirust detection of 24h is qualified in 35 ℃ of constant-temperature constant-humidity environments;
5), vibration values detects: get 30 and overlap the bearing of hot-air seasoning and carry out vibration values and detect qualifiedly, add slushing oil again, room temperature places that to detect vibration values again after 30 days qualified.
Claims (2)
1. a metallic bearing water-based clean-out system and matching used purificant, it is characterized in that: its cleaning agent formula weight percent is:
Fatty alcohol-polyoxyethylene ether 2-5
Emulsifying agent 2-4
Oleum Cocois diethanolamine phosphoric acid ester 10-16
Triethanolamine oleate 10-18
Trolamine 15-19
Thanomin 10-14
Petroleum sodium sulfonate 2-6
Benzotriazole 0.1-0.7
EDTA 1-1.5
Na
2CO
3 0-4
NaOH 0-2
Defoamer AF 1
Pure water 46.9-8.8
Its matching used purificant formulation weight per-cent is:
Triethanolamine oleate 10-20
Trolamine 7-15
Thanomin 9-15
Petroleum sodium sulfonate 4-8
Benzotriazole 0.1-0.5
Nitrous acid cyclohexanediamine 1-2
Pure water 68.9-39.5
2. a metallic bearing water-based clean-out system and matching used purificant preparation method, it is characterized in that: its clean-out system preparation method is:
1), A component: will add triethanolamine oleate and petroleum sodium sulfonate in the mixed solvent of trolamine and thanomin, the stirring at room dissolving; Under agitation add fatty alcohol-polyoxyethylene ether, emulsifying agent, Oleum Cocois diethanolamine phosphoric acid ester again, stir 30min and form brown clear solution;
2), B component: in pure water, add benzotriazole, EDTA, NaOH, Na
2CO
3, the about 10min of stirring at room dissolving forms the water white aqueous solution;
3), the B component is poured in the A component of quick stirring, room temperature stirs 1h fast; Add defoamer AF at last, form spissated brown thickness clean-out system;
4), spissated brown thickness clean-out system is made into 5% work agent;
Its matching used purificant preparation method is:
1), the nitrous acid cyclohexanediamine is added in the mixed solvent of trolamine and thanomin stirring at room 30min, dissolving formation clear solution;
2) add triethanolamine oleate and petroleum sodium sulfonate, again, stirring at room 20min forms the dark-brown clear solution;
3), the pure water that will be furnished with benzotriazole pours into to above-mentioned brown clear solution, stirring at room 30min obtains spissated transparent purificant;
4), spissated transparent purificant is made into 1% work agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2006101284222A CN101195790A (en) | 2006-12-08 | 2006-12-08 | Metallic bearing water-based detergent and rinsing agent used together with the same, and method for producing the same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2006101284222A CN101195790A (en) | 2006-12-08 | 2006-12-08 | Metallic bearing water-based detergent and rinsing agent used together with the same, and method for producing the same |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101195790A true CN101195790A (en) | 2008-06-11 |
Family
ID=39546417
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA2006101284222A Pending CN101195790A (en) | 2006-12-08 | 2006-12-08 | Metallic bearing water-based detergent and rinsing agent used together with the same, and method for producing the same |
Country Status (1)
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| CN (1) | CN101195790A (en) |
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| CN101545206B (en) * | 2009-04-20 | 2010-12-29 | 徐维青 | Method for preparing natural fiber and synthetic fiber antistatic agent |
| CN101634031B (en) * | 2009-08-26 | 2011-01-12 | 广州机械科学研究院 | Phosphate-free metal cleaner and preparation method and application thereof |
| CN102242369A (en) * | 2011-07-05 | 2011-11-16 | 白马轴承技术(洛阳)有限公司 | Metal bearing water-based cleaning agent and preparation method and application thereof |
| CN102732899A (en) * | 2012-07-19 | 2012-10-17 | 长沙艾森设备维护技术有限公司 | Water-based anti-rusting type washing agent for metal parts |
| CN102747378A (en) * | 2012-07-24 | 2012-10-24 | 中国第一汽车股份有限公司 | Environment-friendly water-based metal cleaner |
| CN103122460A (en) * | 2011-11-18 | 2013-05-29 | 维希艾防锈新材料(上海)有限公司 | Novel formula and preparation process for vci environment-friendly water-soluble antirust agent |
| CN103666871A (en) * | 2013-11-16 | 2014-03-26 | 克拉玛依市金山石油化工有限公司 | Cotton picker spindle cleaning solution and preparation and application methods thereof |
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| CN103937619A (en) * | 2014-03-28 | 2014-07-23 | 杨文礼 | Industrial detergent |
| CN107216956A (en) * | 2017-05-27 | 2017-09-29 | 中国人民解放军空军工程大学 | A kind of airplane wheel bearing cleaning agent |
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| CN110791392A (en) * | 2019-11-21 | 2020-02-14 | 华阳新兴科技（天津）集团有限公司 | Lubricating grease cleaning agent for railway train wheel bearing and preparation method thereof |
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2006
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101545206B (en) * | 2009-04-20 | 2010-12-29 | 徐维青 | Method for preparing natural fiber and synthetic fiber antistatic agent |
| CN101634031B (en) * | 2009-08-26 | 2011-01-12 | 广州机械科学研究院 | Phosphate-free metal cleaner and preparation method and application thereof |
| CN102242369A (en) * | 2011-07-05 | 2011-11-16 | 白马轴承技术(洛阳)有限公司 | Metal bearing water-based cleaning agent and preparation method and application thereof |
| CN103122460A (en) * | 2011-11-18 | 2013-05-29 | 维希艾防锈新材料(上海)有限公司 | Novel formula and preparation process for vci environment-friendly water-soluble antirust agent |
| CN102732899A (en) * | 2012-07-19 | 2012-10-17 | 长沙艾森设备维护技术有限公司 | Water-based anti-rusting type washing agent for metal parts |
| CN102732899B (en) * | 2012-07-19 | 2014-08-06 | 长沙艾森设备维护技术有限公司 | Water-based anti-rusting type washing agent for metal parts |
| CN102747378A (en) * | 2012-07-24 | 2012-10-24 | 中国第一汽车股份有限公司 | Environment-friendly water-based metal cleaner |
| CN102747378B (en) * | 2012-07-24 | 2016-01-20 | 中国第一汽车股份有限公司 | Environmentally-friendly water-based metal cleaner |
| CN103666871B (en) * | 2013-11-16 | 2016-06-29 | 克拉玛依市金山石油化工有限公司 | Spindling cleaning solution of cotton picker and preparation, using method |
| CN103666871A (en) * | 2013-11-16 | 2014-03-26 | 克拉玛依市金山石油化工有限公司 | Cotton picker spindle cleaning solution and preparation and application methods thereof |
| CN103789776A (en) * | 2013-12-18 | 2014-05-14 | 常熟市天河机械设备制造有限公司 | Non-phosphorus water-based metal cleaner |
| CN103937619A (en) * | 2014-03-28 | 2014-07-23 | 杨文礼 | Industrial detergent |
| CN107365640A (en) * | 2016-05-12 | 2017-11-21 | 无锡市久嘉科技有限公司 | A kind of water base bearing cleaning agent of safety and environmental protection and its preparation method and application |
| CN107216956A (en) * | 2017-05-27 | 2017-09-29 | 中国人民解放军空军工程大学 | A kind of airplane wheel bearing cleaning agent |
| CN107236608A (en) * | 2017-06-20 | 2017-10-10 | 中国人民解放军空军工程大学 | The cleaning fluid and cleaning method of high temperature aviation grease |
| CN110791392A (en) * | 2019-11-21 | 2020-02-14 | 华阳新兴科技（天津）集团有限公司 | Lubricating grease cleaning agent for railway train wheel bearing and preparation method thereof |
| CN112479907A (en) * | 2020-11-27 | 2021-03-12 | 德旭新材料(佛冈)有限公司 | Triisopropanolamine n-heptanoate soap, preparation method and application thereof, and metal cleaning agent |
| CN112479907B (en) * | 2020-11-27 | 2023-08-22 | 德旭新材料(佛冈)有限公司 | Triisopropanolamine soap n-heptanoic acid, preparation method and application thereof, and metal cleaning agent |
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Open date: 20080611 |