CN103666871A - Cotton picker spindle cleaning solution and preparation and application methods thereof - Google Patents
Cotton picker spindle cleaning solution and preparation and application methods thereof Download PDFInfo
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- CN103666871A CN103666871A CN201310570336.7A CN201310570336A CN103666871A CN 103666871 A CN103666871 A CN 103666871A CN 201310570336 A CN201310570336 A CN 201310570336A CN 103666871 A CN103666871 A CN 103666871A
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Abstract
The invention relates to the technical field of cotton picker spindle cleaning solutions and provides a cotton picker spindle cleaning solution. The cotton picker spindle cleaning solution comprises the following components by weight percent: 0.5-15% of fatty alcohol-polyoxyethylene ether, 0.1-15% of polyol ester, 0.01-10% of solubilizers, 0.01-8% of antirust agents and the balance of base oil. The cotton picker spindle cleaning solution has the beneficial effects that the cotton picker spindle cleaning solution has strong emulsifying capacity, can be uniformly dispersed in water to form stable emulsion, and has excellent cleaning effects through synergy of the solubilizers; the emulsion formed in the working process is uniform and stable, and the phenomenon of filter device blockage caused by agglomeration can not happen; the cotton picker spindle cleaning solution has good antirust property and does not corrode the cotton picker spindle; an application method is simple and is easy to operate; the raw materials do not contain the substances harmful to human bodies or environments, such as sulfur, phosphorus, aromatic rings and the like, so that the cotton picker spindle cleaning solution is environment-friendly.
Description
Technical field
the present invention relates to Spindling cleaning solution of cotton picker technical field, is a kind of Spindling cleaning solution of cotton picker.
Background technology
the application of mechanize cotton picking technology, has not only greatly reduced labour intensity, and has improved greatly cotton picking efficiency.The cotton harvester of mechanize, is often referred to cotton picker.Cotton picker mainly consists of parts such as chassis, picking desk, strength cotton transport system, hopper, pouring profit systems.When cotton picker passes through cotton field, cotton stalk is held up and is led device by cotton plant support importing picking desk, and along with cotton picker travels forward, the ingot of plucking rotating is separated cotton from cotton plant.De-cotton dish is taken off the cotton of plucking on ingot, the cotton of taking off by gas delivery to the hopper after cotton picker.Cotton picker special grease is lubricated the ingot of plucking of high speed rotating by drenching profit system, and the useless lubricating grease after use oozes out from plucking the afterbody of ingot, remains in and plucks on ingot together with cotton plant water, cotton-wool, earth etc.Spindling cleaning solution of cotton picker cleans plucking ingot by drenching profit system after water dilution, removes and plucks the residue on ingot in time, guarantees to pluck the work that ingot completes cotton picking and de-cotton link smoothly.Owing to there is no mixed stirring device in Spindling cleaning solution of cotton picker work system, in the outlet of scavenging solution liquid-storing box and remover liquid nozzle front end, be equipped with filtration unit, therefore, require Spindling cleaning solution of cotton picker product homogeneous, and after water dilution, do not can be uniformly dispersed and form stable emulsion in the situation that having to stir, in order to avoid stop up, drench profit system, affect the normal work of equipment.Be different from the conventional scavenging solution using in process of metal working, the cleaning object of Spindling cleaning solution of cotton picker is varied, not only will have higher cleansing power, and will have good emulsifying ability.Publication number is that the american documentation literature of US3816346A discloses a kind of ingot cleaning and lubricant plucked, and its formula is: the unsaturated fatty acids of 8% to 12% weight; The glycol ether solvent of 2% to 4% weight; The alcoholic solvent of 2% to 4% weight; The alkoxide phenol of 2% to 4% weight; The acid amides cosurfactant of 3% to 7% weight; The poly carboxylic acid of 0% to 4% weight; The alkaline agent of 0.5% to 2% weight; Water to 100% weight, its defect is in raw material, to have adopted the alkoxide phenol component that contains aromatic ring, learns that it has certain detrimentally affect to soil and environment, simultaneously from knowledge, its main component unsaturated fatty acids is organic acid, and parts are had to certain corrodibility.Publication number is that the Chinese patent literature of CN101838593A discloses a kind of Spindling cleaning solution of cotton picker, and its formula is: mineral oil: 70% to 90%; Nonionogenic tenside: 3% to 20%; Rust-preventive agent: 0% to 5.0%; Alcohols antifreezing agent 0% to 6%; Inhibiter 0% to 3.0%; Alcamines alkaline agent 0% to 2%.This clean-out system can be according to being used after the water dilution with 150 to 300 times, and its defect is in production process, to need to be heated to 70 ℃ of left and right, has certain energy consumption, and have caking phenomenon in product stock process, will certainly affect storage and the use of product.Publication number is that the Chinese patent literature of CN101503804A discloses a kind of cleaning liquid composition and uses thereof, and its formula is the fatty alcohol-polyoxyethylene ether of 0.5% to 20% weight; The alkylphenol polyoxyethylene of 0.1% to 10% weight; The polyvalent alcohol of 0.01% to 8% weight; The sulfonate of 0.01% to 12% weight; The base oil of 50% to 95% weight.Its defect is in scavenging solution raw material, to have adopted the sulfonate of sulfur-bearing and the component of the alkylphenol polyoxyethylene that contains aromatic ring, learns that it has certain detrimentally affect to soil and environment from knowledge.
Summary of the invention
the invention provides a kind of Spindling cleaning solution of cotton picker, overcome the deficiency of above-mentioned prior art, it can effectively solve, and existing Spindling cleaning solution of cotton picker production energy consumption is high, storage process easily lumps and soil and environment are had to dysgenic problem.
one of technical scheme of the present invention realizes by following measures: a kind of Spindling cleaning solution of cotton picker, raw material by weight percentage ratio forms the base oil that comprises fatty alcohol-polyoxyethylene ether 0.5% to 15%, polyol ester 0.1% to 15%, solubilizing agent 0.01% to 10%, rust-preventive agent 0.01% to 8% and surplus.
the further optimization and/or improvements to one of foregoing invention technical scheme below:
above-mentioned Spindling cleaning solution of cotton picker, raw material by weight percentage ratio forms the base oil that comprises fatty alcohol-polyoxyethylene ether 2% to 10%, polyol ester 1% to 10%, solubilizing agent 0.1% to 5%, rust-preventive agent 0.1% to 5% and surplus.
above-mentioned fatty alcohol-polyoxyethylene ether has following general formula: R-O-(CH
2
cH
2
0)
n
-H, wherein, R is for containing C
7
to C
18
alkyl, the adduct number that n is oxyethane; Or/and, polyol ester is more than one in sorbitol ester, polyoxyethylene sorbitan ester, wherein, sorbitol ester is more than one in Span-20, Span-40, Span-60, Span-65, Span-80 and Span-85, and polyoxyethylene sorbitan ester is more than one in Tween-20, Tween-40, Tween-60, Tween-65, Tween-80 and Tween-85; Or/and solubilizing agent is more than one in diethylene glycol monomethyl ether, propylene glycol monomethyl ether, dipropylene glycol dme, ethylene glycol monobutyl ether, triglycol monobutyl ether, triethylene glycol butyl ether and triethylene glycol butyl ether; Or/and rust-preventive agent is alkynol, wherein, alkynol is more than one in acetylene alcohol, propiolic alcohol or 3-methylbutynol; Or/and base oil is that kinematic viscosity (40 ℃) is 1 mm
2
/ s to 100mm
2
more than one in mineral type base oil, plant type base oil and the synthesis type base oil of/s.
the kinematic viscosity of above-mentioned base oil (40 ℃) is 3 mm
2
/ s to 70mm
2
/ s; Mineral type base oil is that kerosene or diesel oil or total loss system oil, plant type base oil are that plam oil or Oleum Cocois, synthesis type base oil are polyalphaolefin; Or/and R is for being C
12
to C
18
alkyl, n be ethoxymer distribution: n=3 to n=20.
above-mentioned fatty alcohol-polyoxyethylene ether is more than one in AEO-3, AEO-7, AEO-9, MOA-3, MOA-5, MOA-7, peregal-15 and peregal-20.
above-mentioned Spindling cleaning solution of cotton picker obtains as follows: to the base oil that adds aequum in reactor, base oil is heated to after 20 ℃ to 30 ℃, again successively to the fatty alcohol-polyoxyethylene ether, polyol ester, solubilizing agent and the rust-preventive agent that add aequum in reactor, and insulated and stirred to material dissolves completely and forms transparent liquid and obtain Spindling cleaning solution of cotton picker at this temperature.
above-mentioned churning time is 0.5 hour to 2 hours.
two of technical scheme of the present invention realizes by following measures: a kind of preparation method of Spindling cleaning solution of cotton picker, it is characterized in that carrying out as follows: to the base oil that adds aequum in reactor, base oil is heated to after 20 ℃ to 30 ℃, again successively to the fatty alcohol-polyoxyethylene ether, polyol ester, solubilizing agent and the rust-preventive agent that add aequum in reactor, and insulated and stirred to material dissolves completely and forms transparent liquid and obtain Spindling cleaning solution of cotton picker at this temperature.
the further optimization and/or improvements to two of foregoing invention technical scheme below:
above-mentioned churning time is 0.5 hour to 2 hours.
three of technical scheme of the present invention realizes by following measures: a kind of method of Spindling cleaning solution of cotton picker, during use, after adding water that Spindling cleaning solution of cotton picker is diluted to and is 1% to 5% solution containing Spindling cleaning solution of cotton picker mass percent to Spindling cleaning solution of cotton picker, clean use.
emulsifying capacity of the present invention is strong, can be in water the dispersed and emulsion-stabilizing that forms, by the synergistic effect of solubilizing agent, there is good cleaning performance, the emulsion forming is in the course of the work uniform and stable, can there is not the phenomenon that caking causes filtration unit to stop up, and this Spindling cleaning solution of cotton picker has good rustless property, cotton picker spindle is not corroded, using method is simple, easy to operate, in raw material, do not contain the material that sulphur, phosphorus, aromatic ring etc. are harmful or environment is harmful, environmentally friendly.
Embodiment
the present invention is not subject to the restriction of following embodiment, can determine concrete embodiment according to technical scheme of the present invention and practical situation.
below in conjunction with embodiment, the invention will be further described:
embodiment 1, and this Spindling cleaning solution of cotton picker raw material by weight percentage ratio forms the base oil that comprises fatty alcohol-polyoxyethylene ether 0.5% to 15%, polyol ester 0.1% to 15%, solubilizing agent 0.01% to 10%, rust-preventive agent 0.01% to 8% and surplus.
embodiment 2, and this Spindling cleaning solution of cotton picker raw material by weight percentage ratio forms and to comprise fatty alcohol-polyoxyethylene ether 0.5% or 15%, polyol ester 0.1% or 15%, solubilizing agent 0.01% or 10%, rust-preventive agent 0.01% or 8% and the base oil of surplus.
embodiment 3, as above-described embodiment preferably, raw material by weight percentage ratio forms the base oil that comprises fatty alcohol-polyoxyethylene ether 2% to 10%, polyol ester 1% to 10%, solubilizing agent 0.1% to 5%, rust-preventive agent 0.1% to 5% and surplus.
embodiment 4, as above-described embodiment preferably, raw material by weight percentage ratio forms and comprises fatty alcohol-polyoxyethylene ether 2% or 10%, polyol ester 1% or 10%, solubilizing agent 0.1% or 5%, rust-preventive agent 0.1% or 5% and the base oil of surplus.
embodiment 5, as above-described embodiment preferably, fatty alcohol-polyoxyethylene ether has following general formula: R-O-(CH
2
cH
2
0)
n
-H, wherein, R is for containing C
7
to C
18
alkyl, the adduct number that n is oxyethane; Or/and, polyol ester is more than one in sorbitol ester, polyoxyethylene sorbitan ester, wherein, sorbitol ester is more than one in Span-20, Span-40, Span-60, Span-65, Span-80 and Span-85, and polyoxyethylene sorbitan ester is more than one in Tween-20, Tween-40, Tween-60, Tween-65, Tween-80 and Tween-85; Or/and solubilizing agent is more than one in diethylene glycol monomethyl ether, propylene glycol monomethyl ether, dipropylene glycol dme, ethylene glycol monobutyl ether, triglycol monobutyl ether, triethylene glycol butyl ether and triethylene glycol butyl ether; Or/and rust-preventive agent is alkynol, wherein, alkynol is more than one in acetylene alcohol, propiolic alcohol or 3-methylbutynol; Or/and base oil is that kinematic viscosity (40 ℃) is 1 mm
2
/ s to 100mm
2
more than one in mineral type base oil, plant type base oil and the synthesis type base oil of/s.Span-20, Span-40, Span-60, Span-65, Span-80, Span-85, Tween-40, Tween-60, Tween-65, Tween-80 and Tween-85 are respectively Baodi District, Tianjin City Gang Fei auxiliary agent company limited and produce; Diethylene glycol monomethyl ether, propylene glycol monomethyl ether, dipropylene glycol dme, ethylene glycol monobutyl ether, triglycol monobutyl ether, triethylene glycol butyl ether and triethylene glycol butyl ether are respectively Shanghai De Mao Chemical Co., Ltd. and produce; Acetylene alcohol, propiolic alcohol or 3-methylbutynol are respectively Nanjing Tian Xie Chemical Co., Ltd. and produce.
embodiment 6, as above-described embodiment preferably, the kinematic viscosity of base oil (40 ℃) is 3 mm
2
/ s to 70mm
2
/ s; Mineral type base oil is that kerosene or diesel oil or total loss system oil, plant type base oil are that plam oil or Oleum Cocois, synthesis type base oil are polyalphaolefin; Or/and R is for being C
12
to C
18
alkyl, n be ethoxymer distribution: n=3 to n=20.The model that polyalphaolefin can adopt NCM to produce is PAO2, PAO10, PAO25, the product of PAO100.
embodiment 7, as above-described embodiment preferably, fatty alcohol-polyoxyethylene ether is more than one in AEO-3, AEO-7, AEO-9, MOA-3, MOA-5, MOA-7, peregal-15 and peregal-20.AEO-3, AEO-7 and AEO-9 are respectively Baodi District, Tianjin City Gang Fei auxiliary agent company limited and produce, and MOA-3, MOA-5 and MOA-7 are respectively Xingtai Ke Wang auxiliary agent company limited, and peregal-15 and peregal-20 are respectively Zibo Hai Jie Chemical Co., Ltd. and produce.
embodiment 8, as above-described embodiment preferably, Spindling cleaning solution of cotton picker obtains as follows: to the base oil that adds aequum in reactor, base oil is heated to after 20 ℃ to 30 ℃, again successively to the fatty alcohol-polyoxyethylene ether, polyol ester, solubilizing agent and the rust-preventive agent that add aequum in reactor, and insulated and stirred to material dissolves completely and forms transparent liquid and obtain Spindling cleaning solution of cotton picker at this temperature.
embodiment 9, as embodiment 8 preferably, churning time is 0.5 hour to 2 hours.
embodiment 10, the preparation method of this Spindling cleaning solution of cotton picker carries out as follows: to the base oil that adds aequum in reactor, base oil is heated to after 20 ℃ to 30 ℃, again successively to the fatty alcohol-polyoxyethylene ether, polyol ester, solubilizing agent and the rust-preventive agent that add aequum in reactor, and insulated and stirred to material dissolves completely and forms transparent liquid and obtain Spindling cleaning solution of cotton picker at this temperature.
embodiment 11, the preparation method of this Spindling cleaning solution of cotton picker carries out as follows: to the base oil that adds aequum in reactor, base oil is heated to after 20 ℃ or 30 ℃, again successively to the fatty alcohol-polyoxyethylene ether, polyol ester, solubilizing agent and the rust-preventive agent that add aequum in reactor, and insulated and stirred to material dissolves completely and forms transparent liquid and obtain Spindling cleaning solution of cotton picker at this temperature.
embodiment 12, as embodiment 10 and embodiment 11 preferably, churning time is 0.5 hour to 2 hours.
embodiment 13, and the using method of this Spindling cleaning solution of cotton picker, during use, after adding water that Spindling cleaning solution of cotton picker is diluted to and is 1% to 5% solution containing Spindling cleaning solution of cotton picker mass percent, is cleaned use to Spindling cleaning solution of cotton picker.
embodiment 14, and the using method of this Spindling cleaning solution of cotton picker, during use, after adding water that Spindling cleaning solution of cotton picker is diluted to and is 1% or 5% solution containing Spindling cleaning solution of cotton picker mass percent, is cleaned use to Spindling cleaning solution of cotton picker.
performance index to the Spindling cleaning solution of cotton picker obtaining according to the above embodiment of the present invention detect, and the performance index average data obtaining is as shown in table 1.
table 1
Performance index project | Quality index |
Outward appearance | Homogeneous transparent liquid |
Flash-point >= | 80℃ |
Condensation point≤ | -5℃ |
Dispersed in water | Dispersed |
Stability of emulsion | Stable, not stratified |
wherein, dispersed in water: refer to this product in 1% to 5%(W) ratio and water mix the outward appearance of observing emulsifying aq after latter standing 2 hours; Stability of emulsion: after adding water that Spindling cleaning solution of cotton picker is diluted to and is 1% to 5% solution containing Spindling cleaning solution of cotton picker mass percent to Spindling cleaning solution of cotton picker, the outward appearance of observing emulsified soln after centrifugal 30 minutes under the rotating speed of 3000 revs/min.
by data in table 1, can be found out the stable performance of the Spindling cleaning solution of cotton picker obtaining according to the above embodiment of the present invention.
the Spindling cleaning solution of cotton picker obtaining according to the above embodiment of the present invention, owing to making full use of fatty alcohol-polyoxyethylene ether, the synergy of polyol ester and solubilizing agent, emulsifying capacity is strong, can be in water the dispersed and emulsion-stabilizing that forms, by the synergistic effect of solubilizing agent, there is good cleaning performance, this Spindling cleaning solution of cotton picker is for the working process of cotton picker, can meet the pouring profit system service requirements of the cotton picker that there is no external force stirring, the emulsion forming is uniform and stable, can there is not the phenomenon that caking causes filtration unit to stop up, and the Spindling cleaning solution of cotton picker obtaining according to the above embodiment of the present invention has good rustless property, cotton picker spindle is not corroded, using method is simple, easy to operate, in raw material, do not contain sulphur, phosphorus, the material that aromatic ring etc. are harmful or environment is harmful, environmentally friendly.
above technical characterictic has formed embodiments of the invention, and it has stronger adaptability and implementation result, can increase and decrease according to actual needs non-essential technical characterictic, meets the demand of different situations.
Claims (10)
1. a Spindling cleaning solution of cotton picker, it is characterized in that raw material by weight percentage ratio form the base oil that comprises fatty alcohol-polyoxyethylene ether 0.5% to 15%, polyol ester 0.1% to 15%, solubilizing agent 0.01% to 10%, rust-preventive agent 0.01% to 8% and surplus.
2. Spindling cleaning solution of cotton picker according to claim 1, it is characterized in that raw material by weight percentage ratio form the base oil that comprises fatty alcohol-polyoxyethylene ether 2% to 10%, polyol ester 1% to 10%, solubilizing agent 0.1% to 5%, rust-preventive agent 0.1% to 5% and surplus.
3. Spindling cleaning solution of cotton picker according to claim 1 and 2, is characterized in that fatty alcohol-polyoxyethylene ether has following general formula: R-O-(CH
2cH
20)
n-H, wherein, R is for containing C
7to C
18alkyl, the adduct number that n is oxyethane; Or/and, polyol ester is more than one in sorbitol ester, polyoxyethylene sorbitan ester, wherein, sorbitol ester is more than one in Span-20, Span-40, Span-60, Span-65, Span-80 and Span-85, and polyoxyethylene sorbitan ester is more than one in Tween-20, Tween-40, Tween-60, Tween-65, Tween-80 and Tween-85; Or/and solubilizing agent is more than one in diethylene glycol monomethyl ether, propylene glycol monomethyl ether, dipropylene glycol dme, ethylene glycol monobutyl ether, triglycol monobutyl ether, triethylene glycol butyl ether and triethylene glycol butyl ether; Or/and rust-preventive agent is alkynol, wherein, alkynol is more than one in acetylene alcohol, propiolic alcohol or 3-methylbutynol; Or/and base oil is that kinematic viscosity (40 ℃) is 1 mm
2/ s to 100mm
2more than one in mineral type base oil, plant type base oil and the synthesis type base oil of/s.
4. Spindling cleaning solution of cotton picker according to claim 3, is characterized in that the kinematic viscosity (40 ℃) of base oil is 3 mm
2/ s to 70mm
2/ s; Mineral type base oil is that kerosene or diesel oil or total loss system oil, plant type base oil are that plam oil or Oleum Cocois, synthesis type base oil are polyalphaolefin; Or/and R is for being C
12to C
18alkyl, n be ethoxymer distribution: n=3 to n=20.
5. according to the Spindling cleaning solution of cotton picker described in claim 1 or 2 or 3 or 4, it is characterized in that fatty alcohol-polyoxyethylene ether is more than one in AEO-3, AEO-7, AEO-9, MOA-3, MOA-5, MOA-7, peregal-15 and peregal-20.
6. according to the Spindling cleaning solution of cotton picker described in claim 1 or 2 or 3 or 4 or 5, it is characterized in that obtaining as follows: to the base oil that adds aequum in reactor, base oil is heated to after 20 ℃ to 30 ℃, again successively to the fatty alcohol-polyoxyethylene ether, polyol ester, solubilizing agent and the rust-preventive agent that add aequum in reactor, and insulated and stirred to material dissolves completely and forms transparent liquid and obtain Spindling cleaning solution of cotton picker at this temperature.
7. Spindling cleaning solution of cotton picker according to claim 6, is characterized in that churning time is 0.5 hour to 2 hours.
8. the preparation method of a Spindling cleaning solution of cotton picker according to claim 7, it is characterized in that carrying out as follows: to the base oil that adds aequum in reactor, base oil is heated to after 20 ℃ to 30 ℃, again successively to the fatty alcohol-polyoxyethylene ether, polyol ester, solubilizing agent and the rust-preventive agent that add aequum in reactor, and insulated and stirred to material dissolves completely and forms transparent liquid and obtain Spindling cleaning solution of cotton picker at this temperature.
9. the preparation method of Spindling cleaning solution of cotton picker according to claim 8, is characterized in that churning time is 0.5 hour to 2 hours.
10. a use is according to the method for the Spindling cleaning solution of cotton picker described in claim 1 or 2 or 3 or 4 or 5 or 6 or 7, while it is characterized in that using, after adding water that Spindling cleaning solution of cotton picker is diluted to and is 1% to 5% solution containing Spindling cleaning solution of cotton picker mass percent to Spindling cleaning solution of cotton picker, clean use.
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CN109705961A (en) * | 2019-02-21 | 2019-05-03 | 新疆甲子工贸有限公司 | A kind of cotton picker cleaning agent, its composition, its emulsion and preparation method thereof |
CN111040856A (en) * | 2019-12-27 | 2020-04-21 | 新疆美拓特种油品有限公司 | Cleaning solution for spindle of cotton picker |
CN112457908A (en) * | 2020-06-08 | 2021-03-09 | 山东三晶润滑科技有限公司 | Antirust emulsified oil |
CN115301711A (en) * | 2022-08-04 | 2022-11-08 | 江山市虎鼎环保科技有限公司 | Anti-blocking method for washing and filter pressing fly ash |
CN116179284A (en) * | 2023-04-24 | 2023-05-30 | 克拉玛依市加士伦化工有限责任公司 | Cleaning liquid for spindle device of cotton picker and preparation method of cleaning liquid |
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