CN103789776A - Non-phosphorus water-based metal cleaner - Google Patents
Non-phosphorus water-based metal cleaner Download PDFInfo
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- CN103789776A CN103789776A CN201310695208.5A CN201310695208A CN103789776A CN 103789776 A CN103789776 A CN 103789776A CN 201310695208 A CN201310695208 A CN 201310695208A CN 103789776 A CN103789776 A CN 103789776A
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- polyoxyethylene ether
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Abstract
The invention discloses a non-phosphorus water-based metal cleaner which is prepared from raw materials, namely, isodecanol polyoxyethylene ether, 1,3-butanediol, dodecanedioic acid, petroleum barium sulfonate, water, modified siloxane defoaming agent, sylvite, fatty alcohol polyoxyethylene ether, p-tertiary butyl benzoic acid, triazine polycarboxylic acid compounds, fatty alcohol-polyoxyethylene ether, benzyl alcohol fatty alcohol polyoxyethylene ether, isoundecanol polyoxyethylene ether, butyl cellosolve, n-hexane, glycol, glycerol, fatty alcohol-polyoxyethylene ether, fatty alcohol-polyoxyethylene ether, alkyl polymers or blocked polyether, castor oil polyoxyethylene ether, succinic acid derivative, boric acid, petroleum sodium sulfonate, imidazoline, methyl triazole, polyoxyethylene ether, fatty alcohol alcoxyl compounds, triazole, ether carboxylic acid organic chelating agents and the like. The non-phosphorus water-based metal cleaner is excellent in cleaning capability, long in anti-rusting period, low in foam, long in service life and applicable to ferrous metal and non-ferrous metal processing industry.
Description
Technical field
The present invention relates to Phosphorus-Free Water-Based Cleaning Agent for Metals.
Background technology
Existing water base metal cleaning agent, due to each side reasons such as its formulas, adopt phosphorous washing assistant and other additives, although there is certain cleansing power, but phosphoric can cause the eutrophication of environment water, the discharging of waste liquid of clean-out system is subject to strict restriction, can not meet market, can not reach the requirement of environmental protection.And existing water base metal cleaning agent, although metallic substance is had to certain rust-preventing characteristic, rust-proof life is shorter, is generally 1-3 days, can not meet the cleaning of inter process and do not do in slightly long-time the requirement of antirust processing.
Summary of the invention
The object of the present invention is to provide a kind of Phosphorus-Free Water-Based Cleaning Agent for Metals, it has excellent cleansing power, rust-proof life length, low bubble, and long service life, is applicable to ferrous metal and non-ferrous metals processing industry.
For achieving the above object, technical scheme of the present invention is a kind of Phosphorus-Free Water-Based Cleaning Agent for Metals of design, is made up of following raw material:
1-2 mass parts isomery ten polyoxyethylenated alcohol, 5 mass parts 1, 3-butyleneglycol, 9 mass parts bay diacid, 8 mass parts barium mahogany sulfonates, 60 mass parts water, 1 mass parts modified siloxane defoamer, 27 mass parts sylvite, 2 mass parts fatty alcohol-polyoxyethylene ether, 1 mass parts p-tert-butyl benzoic acid, 2 mass parts triazines multi-carboxylic acid compounds, 3 mass parts fatty alcohol-polyoxyethylene ether, 1 mass parts phenylcarbinol fatty alcohol-polyoxyethylene ether, 5 mass parts isomery undecyl alcohol Soxylat A 25-7s, 4 mass parts butyl glycol ethers, 3 mass parts normal hexanes, 2 mass parts ethylene glycol, 1 mass parts glycerol, 5 mass parts fatty alcohol-polyoxyethylene ether, 9 mass parts isomery undecyl alcohol Soxylat A 25-7s, 11 mass parts alkyl polymer or block polyethers, 5 mass parts castor oil polyoxyethylene ethers, 8 mass parts succinic acid derivatives, 3 mass parts boric acid, 4 mass parts petroleum sodium sulfonates, 5 mass parts tetrahydroglyoxalines, 2 mass parts methyl benzotriazoles, 2 mass parts Soxylat A 25-7s, 4 mass parts fatty alcohol alkyl oxides, 3 mass parts 124 Triazoles, 12 mass parts ether carboxylic-acid organic sequestering agents, 7 mass parts phenylcarbinol fatty alcohol-polyoxyethylene ether, 3 mass parts Soxylat A 25-7s, 6 mass parts ether carboxylic acids, 9 mass parts diisopropanolamine (DIPA), 1 mass parts calcium stearate.
Advantage of the present invention and beneficial effect are: a kind of Phosphorus-Free Water-Based Cleaning Agent for Metals is provided, and it has excellent cleansing power, rust-proof life length, low bubble, and long service life, is applicable to ferrous metal and non-ferrous metals processing industry.
Embodiment
Below in conjunction with embodiment, the specific embodiment of the present invention is further described.Following examples are only for technical scheme of the present invention is more clearly described, and can not limit the scope of the invention with this.
The concrete technical scheme of implementing of the present invention is:
Embodiment 1
A kind of Phosphorus-Free Water-Based Cleaning Agent for Metals, made by following raw material:
1 mass parts isomery ten polyoxyethylenated alcohol, 5 mass parts 1, 3-butyleneglycol, 9 mass parts bay diacid, 8 mass parts barium mahogany sulfonates, 60 mass parts water, 1 mass parts modified siloxane defoamer, 27 mass parts sylvite, 2 mass parts fatty alcohol-polyoxyethylene ether, 1 mass parts p-tert-butyl benzoic acid, 2 mass parts triazines multi-carboxylic acid compounds, 3 mass parts fatty alcohol-polyoxyethylene ether, 1 mass parts phenylcarbinol fatty alcohol-polyoxyethylene ether, 5 mass parts isomery undecyl alcohol Soxylat A 25-7s, 4 mass parts butyl glycol ethers, 3 mass parts normal hexanes, 2 mass parts ethylene glycol, 1 mass parts glycerol, 5 mass parts fatty alcohol-polyoxyethylene ether, 9 mass parts isomery undecyl alcohol Soxylat A 25-7s, 11 mass parts alkyl polymer or block polyethers, 5 mass parts castor oil polyoxyethylene ethers, 8 mass parts succinic acid derivatives, 3 mass parts boric acid, 4 mass parts petroleum sodium sulfonates, 5 mass parts tetrahydroglyoxalines, 2 mass parts methyl benzotriazoles, 2 mass parts Soxylat A 25-7s, 4 mass parts fatty alcohol alkyl oxides, 3 mass parts 124 Triazoles, 12 mass parts ether carboxylic-acid organic sequestering agents, 7 mass parts phenylcarbinol fatty alcohol-polyoxyethylene ether, 3 mass parts Soxylat A 25-7s, 6 mass parts ether carboxylic acids, 9 mass parts diisopropanolamine (DIPA), 1 mass parts calcium stearate.
Embodiment 2
A kind of Phosphorus-Free Water-Based Cleaning Agent for Metals, made by following raw material:
2 mass parts isomery ten polyoxyethylenated alcohol, 5 mass parts 1, 3-butyleneglycol, 9 mass parts bay diacid, 8 mass parts barium mahogany sulfonates, 60 mass parts water, 1 mass parts modified siloxane defoamer, 27 mass parts sylvite, 2 mass parts fatty alcohol-polyoxyethylene ether, 1 mass parts p-tert-butyl benzoic acid, 2 mass parts triazines multi-carboxylic acid compounds, 3 mass parts fatty alcohol-polyoxyethylene ether, 1 mass parts phenylcarbinol fatty alcohol-polyoxyethylene ether, 5 mass parts isomery undecyl alcohol Soxylat A 25-7s, 4 mass parts butyl glycol ethers, 3 mass parts normal hexanes, 2 mass parts ethylene glycol, 1 mass parts glycerol, 5 mass parts fatty alcohol-polyoxyethylene ether, 9 mass parts isomery undecyl alcohol Soxylat A 25-7s, 11 mass parts alkyl polymer or block polyethers, 5 mass parts castor oil polyoxyethylene ethers, 8 mass parts succinic acid derivatives, 3 mass parts boric acid, 4 mass parts petroleum sodium sulfonates, 5 mass parts tetrahydroglyoxalines, 2 mass parts methyl benzotriazoles, 2 mass parts Soxylat A 25-7s, 4 mass parts fatty alcohol alkyl oxides, 3 mass parts 124 Triazoles, 12 mass parts ether carboxylic-acid organic sequestering agents, 7 mass parts phenylcarbinol fatty alcohol-polyoxyethylene ether, 3 mass parts Soxylat A 25-7s, 6 mass parts ether carboxylic acids, 9 mass parts diisopropanolamine (DIPA), 1 mass parts calcium stearate.
Embodiment 3
A kind of Phosphorus-Free Water-Based Cleaning Agent for Metals, made by following raw material:
1.2 mass parts isomery ten polyoxyethylenated alcohol, 5 mass parts 1, 3-butyleneglycol, 9 mass parts bay diacid, 8 mass parts barium mahogany sulfonates, 60 mass parts water, 1 mass parts modified siloxane defoamer, 27 mass parts sylvite, 2 mass parts fatty alcohol-polyoxyethylene ether, 1 mass parts p-tert-butyl benzoic acid, 2 mass parts triazines multi-carboxylic acid compounds, 3 mass parts fatty alcohol-polyoxyethylene ether, 1 mass parts phenylcarbinol fatty alcohol-polyoxyethylene ether, 5 mass parts isomery undecyl alcohol Soxylat A 25-7s, 4 mass parts butyl glycol ethers, 3 mass parts normal hexanes, 2 mass parts ethylene glycol, 1 mass parts glycerol, 5 mass parts fatty alcohol-polyoxyethylene ether, 9 mass parts isomery undecyl alcohol Soxylat A 25-7s, 11 mass parts alkyl polymer or block polyethers, 5 mass parts castor oil polyoxyethylene ethers, 8 mass parts succinic acid derivatives, 3 mass parts boric acid, 4 mass parts petroleum sodium sulfonates, 5 mass parts tetrahydroglyoxalines, 2 mass parts methyl benzotriazoles, 2 mass parts Soxylat A 25-7s, 4 mass parts fatty alcohol alkyl oxides, 3 mass parts 124 Triazoles, 12 mass parts ether carboxylic-acid organic sequestering agents, 7 mass parts phenylcarbinol fatty alcohol-polyoxyethylene ether, 3 mass parts Soxylat A 25-7s, 6 mass parts ether carboxylic acids, 9 mass parts diisopropanolamine (DIPA), 1 mass parts calcium stearate.
The above is only the preferred embodiment of the present invention; it should be pointed out that for those skilled in the art, do not departing under the prerequisite of the technology of the present invention principle; can also make some improvements and modifications, these improvements and modifications also should be considered as protection scope of the present invention.
Claims (1)
1. Phosphorus-Free Water-Based Cleaning Agent for Metals, is characterized in that, is made up of following raw material:
1-2 mass parts isomery ten polyoxyethylenated alcohol, 5 mass parts 1, 3-butyleneglycol, 9 mass parts bay diacid, 8 mass parts barium mahogany sulfonates, 60 mass parts water, 1 mass parts modified siloxane defoamer, 27 mass parts sylvite, 2 mass parts fatty alcohol-polyoxyethylene ether, 1 mass parts p-tert-butyl benzoic acid, 2 mass parts triazines multi-carboxylic acid compounds, 3 mass parts fatty alcohol-polyoxyethylene ether, 1 mass parts phenylcarbinol fatty alcohol-polyoxyethylene ether, 5 mass parts isomery undecyl alcohol Soxylat A 25-7s, 4 mass parts butyl glycol ethers, 3 mass parts normal hexanes, 2 mass parts ethylene glycol, 1 mass parts glycerol, 5 mass parts fatty alcohol-polyoxyethylene ether, 9 mass parts isomery undecyl alcohol Soxylat A 25-7s, 11 mass parts alkyl polymer or block polyethers, 5 mass parts castor oil polyoxyethylene ethers, 8 mass parts succinic acid derivatives, 3 mass parts boric acid, 4 mass parts petroleum sodium sulfonates, 5 mass parts tetrahydroglyoxalines, 2 mass parts methyl benzotriazoles, 2 mass parts Soxylat A 25-7s, 4 mass parts fatty alcohol alkyl oxides, 3 mass parts 124 Triazoles, 12 mass parts ether carboxylic-acid organic sequestering agents, 7 mass parts phenylcarbinol fatty alcohol-polyoxyethylene ether, 3 mass parts Soxylat A 25-7s, 6 mass parts ether carboxylic acids, 9 mass parts diisopropanolamine (DIPA), 1 mass parts calcium stearate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310695208.5A CN103789776A (en) | 2013-12-18 | 2013-12-18 | Non-phosphorus water-based metal cleaner |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310695208.5A CN103789776A (en) | 2013-12-18 | 2013-12-18 | Non-phosphorus water-based metal cleaner |
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| CN103789776A true CN103789776A (en) | 2014-05-14 |
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| CN201310695208.5A Pending CN103789776A (en) | 2013-12-18 | 2013-12-18 | Non-phosphorus water-based metal cleaner |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104279361A (en) * | 2014-10-20 | 2015-01-14 | 苏州常熟荣大威尔科技有限公司 | Limit switch of valve |
| CN105256329A (en) * | 2015-12-04 | 2016-01-20 | 常熟市天河机械设备制造有限公司 | Metal device cleaning agent |
| CN107059023A (en) * | 2016-12-28 | 2017-08-18 | 河南恒润昌环保科技有限公司 | A kind of Treatment of Metal Surface without phosphorus cleaning agent and preparation method thereof |
| CN112251297A (en) * | 2020-11-09 | 2021-01-22 | 3M中国有限公司 | Engine carbon deposit cleaning composition, method for preparing engine carbon deposit cleaning composition and method for cleaning engine carbon deposit |
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| CN1435384A (en) * | 2002-01-30 | 2003-08-13 | 北京化工大学 | Corrosion-and scaling-inhibiting water treating agent |
| CN101195790A (en) * | 2006-12-08 | 2008-06-11 | 白马轴承技术(洛阳)有限公司 | Metallic bearing water-based detergent and rinsing agent used together with the same, and method for producing the same |
| US20100035785A1 (en) * | 1997-01-09 | 2010-02-11 | Advanced Technology Materials Inc. | Aqueous cleaning composition containing copper-specific corrosion inhibitor for cleaning inorganic residues on semiconductor substrate |
| CN102534633A (en) * | 2011-12-09 | 2012-07-04 | 北京京杰锐思技术开发有限公司 | Water-based metal cleaner |
| CN102766879A (en) * | 2012-06-30 | 2012-11-07 | 东莞市安美润滑科技有限公司 | Spray cleaning agent for metal assembly |
-
2013
- 2013-12-18 CN CN201310695208.5A patent/CN103789776A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20100035785A1 (en) * | 1997-01-09 | 2010-02-11 | Advanced Technology Materials Inc. | Aqueous cleaning composition containing copper-specific corrosion inhibitor for cleaning inorganic residues on semiconductor substrate |
| CN1435384A (en) * | 2002-01-30 | 2003-08-13 | 北京化工大学 | Corrosion-and scaling-inhibiting water treating agent |
| CN101195790A (en) * | 2006-12-08 | 2008-06-11 | 白马轴承技术(洛阳)有限公司 | Metallic bearing water-based detergent and rinsing agent used together with the same, and method for producing the same |
| CN102534633A (en) * | 2011-12-09 | 2012-07-04 | 北京京杰锐思技术开发有限公司 | Water-based metal cleaner |
| CN102766879A (en) * | 2012-06-30 | 2012-11-07 | 东莞市安美润滑科技有限公司 | Spray cleaning agent for metal assembly |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104279361A (en) * | 2014-10-20 | 2015-01-14 | 苏州常熟荣大威尔科技有限公司 | Limit switch of valve |
| CN105256329A (en) * | 2015-12-04 | 2016-01-20 | 常熟市天河机械设备制造有限公司 | Metal device cleaning agent |
| CN107059023A (en) * | 2016-12-28 | 2017-08-18 | 河南恒润昌环保科技有限公司 | A kind of Treatment of Metal Surface without phosphorus cleaning agent and preparation method thereof |
| CN112251297A (en) * | 2020-11-09 | 2021-01-22 | 3M中国有限公司 | Engine carbon deposit cleaning composition, method for preparing engine carbon deposit cleaning composition and method for cleaning engine carbon deposit |
| CN112251297B (en) * | 2020-11-09 | 2021-09-21 | 3M中国有限公司 | Engine carbon deposit cleaning composition, method for preparing engine carbon deposit cleaning composition and method for cleaning engine carbon deposit |
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Application publication date: 20140514 |