CN108486585A - A kind of highly effective antirust metal cleaner and preparation method thereof - Google Patents
A kind of highly effective antirust metal cleaner and preparation method thereof Download PDFInfo
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- CN108486585A CN108486585A CN201810313977.7A CN201810313977A CN108486585A CN 108486585 A CN108486585 A CN 108486585A CN 201810313977 A CN201810313977 A CN 201810313977A CN 108486585 A CN108486585 A CN 108486585A
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/14—Cleaning or pickling metallic material with solutions or molten salts with alkaline solutions
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- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
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- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
Abstract
The present invention provides a kind of highly effective antirust metal cleaners and preparation method thereof, including following parts by weight of component to be prepared：18 29 parts of sodium n-alkylbenzenesulfonate, 15 24 parts of alkyl phosphate, 16 27 parts of monoalky lether phosphate potassium, 11 17 parts of trihydroxy ethylamine oleate soap, 5 14 parts of builder, 27 parts of antifoaming agent, 39 parts of antirust agent, 40 66 parts of water.The cleaning agent preparation method and application method that the present invention is prepared are simple to operation, stable in physicochemical property, have stronger cleaning force and rustless property.
Description
Technical field
The present invention relates to cleaning agent field, more particularly to a kind of highly effective antirust metal cleaner and preparation method thereof.
Background technology
In the industrial production, the process and assemble of mechanical workpieces is either used, can all makes device surface contamination various
Dirt, such as cutting fluid, rail oil, lapping liquid, various acid-alkali salts, dust, hand perspiration, greasy dirt etc..In addition, being carried out for metal device
Cleaning treatment can extend its service life, improve its performance to avoid its influence to device quality.For many need
The device of coating is carried out on surface, paint adhesion can also be improved by first carrying out cleaning treatment to it.Maintenance for instrument
Maintenance, cleaning process is also essential.Currently there are industrial cleaning agents be that cleaning ability is poor mostly, clearly
Device cannot be made to keep long-acting cleaning, rustless state after washing.It is largely harmful to environment there are many more existing in cleaning agent
Substance, select suitable cleaning agent and cleaning that can reach fabulous cleaning performance, and will not be to the performance of device
Undesirable influence is caused with quality.
Invention content
Technical problems to be solved：
Metal cleaner cleaning efficiency in the market is not high, and rustless property is poor, and the object of the present invention is to provide one kind to have
The compounded combination cleaning agent of more excellent synergistic effect, to substitute the cleaning agent in existing industrial production.
Technical solution：
The present invention provides a kind of highly effective antirust metal cleaners, including following parts by weight of component to be prepared：
18-29 parts of sodium n-alkylbenzenesulfonate,
15-24 parts of alkyl phosphate,
16-27 parts of monoalky lether phosphate potassium,
11-17 parts of trihydroxy ethylamine oleate soap,
5-14 parts of builder,
2-7 parts of antifoaming agent,
3-9 parts of antirust agent,
40-66 parts of water.
Preferably, a kind of highly effective antirust metal cleaner, the builder are prepared by following preparation methods
It arrives：
It takes the 50wt% ethanol solutions of 20mL to be added in beaker, 10g cornstarch is added, be uniformly mixed, 10g is then added
NaH2PO4Continue to be stirred until homogeneous；The 60 DEG C of heating water baths of mixed liquor that will be stirred evenly react 2h, then use salt acid for adjusting pH extremely
7.5 obtain starch phosphate ester solution；Starch phosphate is precipitated with ethyl alcohol, washs, filter, is then dried in vacuo up to forming sediment
Powder phosphate.
Preferably, a kind of highly effective antirust metal cleaner, the antifoaming agent are glycol ricinoleate.
Preferably, a kind of highly effective antirust metal cleaner, the antirust agent union diacid amide sodium, three ethyl alcohol
Amine and isononanoic acid sodium are according to weight ratio 1:5:1 mixes.
The present invention also provides a kind of preparation methods of highly effective antirust metal cleaner, including following preparation process：
（1）By 40-66 parts of heating of water, 18-29 parts of sodium n-alkylbenzenesulfonate, 15-24 parts of alkyl phosphate are then sequentially added
With 16-27 parts of monoalky lether phosphate potassium and 11-17 parts of trihydroxy ethylamine oleate soap, mixing；
（2）Then 3-9 parts of 5-14 parts of builder, 2-7 parts of antifoaming agent and antirust agent is added, continues to be uniformly mixed to obtain the final product.
Preferably, the preparation method of a kind of highly effective antirust metal cleaner, including following preparation process：
（1）Water is heated to 55 DEG C for 40-66 parts, then sequentially adds 18-29 parts of sodium n-alkylbenzenesulfonate, alkyl phosphate
15-24 parts and 11-17 parts of 16-27 part of monoalky lether phosphate potassium and trihydroxy ethylamine oleate soap mix 10min；
（2）Then 5-14 parts of builder, 2-7 parts of antifoaming agent, 3-9 parts of antirust agent is added, continues to mix 20min to obtain the final product.
Advantageous effect：
The cleaning agent that the present invention is prepared has stronger cleaning force to the mechanical processing spot of metal surface, to machinery zero
Part, equipment has good anti-rust action, and is free of strong acid-base, nitrite and volatile noxious material, to environment friend
It is good.Preparation method and application method are simple to operation, and cleaning quality is good, efficient, effect Cheng Chijiu, once purged piece surface
Cleaning does not influence the dimensional accuracy and surface state of part, has good application prospect.
Specific implementation mode
The following examples can make those skilled in the art that the present invention be more fully understood, but not limit this in any way
Invention.
Embodiment 1
（1）Water is heated to 55 DEG C for 66 parts, then sequentially adds 18 parts of sodium n-alkylbenzenesulfonate, 24 parts of alkyl phosphate and list
16 parts of alkyl ether phosphate potassium and 17 parts of trihydroxy ethylamine oleate soap, mixing 10min；
（2）Then 14 parts of builder, 2 parts of glycol ricinoleate, 9 parts of antirust agent is added, continues to mix 20min to obtain the final product.
Builder is prepared by following preparation methods：
It takes the 50wt% ethanol solutions of 20mL to be added in beaker, 10g cornstarch is added, be uniformly mixed, 10g is then added
NaH2PO4Continue to be stirred until homogeneous；The 60 DEG C of heating water baths of mixed liquor that will be stirred evenly react 2h, then use salt acid for adjusting pH extremely
7.5 obtain starch phosphate ester solution；Starch phosphate is precipitated with ethyl alcohol, washs, filter, is then dried in vacuo up to forming sediment
Powder phosphate.
Antirust agent union diacid amide sodium, triethanolamine and isononanoic acid sodium are according to weight ratio 1:5:1 mixes.
Embodiment 2
（1）Water is heated to 55 DEG C for 40 parts, then sequentially adds 29 parts of sodium n-alkylbenzenesulfonate, 15 parts of alkyl phosphate and list
11 parts of mixing 10min of 27 parts of alkyl ether phosphate potassium and trihydroxy ethylamine oleate soap；
（2）Then 5 parts of builder, 7 parts of glycol ricinoleate, 3 parts of antirust agent is added, continues to mix 20min to obtain the final product.
Builder is prepared by following preparation methods：
It takes the 50wt% ethanol solutions of 20mL to be added in beaker, 10g cornstarch is added, be uniformly mixed, 10g is then added
NaH2PO4Continue to be stirred until homogeneous；The 60 DEG C of heating water baths of mixed liquor that will be stirred evenly react 2h, then use salt acid for adjusting pH extremely
7.5 obtain starch phosphate ester solution；Starch phosphate is precipitated with ethyl alcohol, washs, filter, is then dried in vacuo up to forming sediment
Powder phosphate.
Antirust agent union diacid amide sodium, triethanolamine and isononanoic acid sodium are according to weight ratio 1:5:1 mixes.
Embodiment 3
（1）Water is heated to 55 DEG C for 57 parts, then sequentially adds 21 parts of sodium n-alkylbenzenesulfonate, 22 parts of alkyl phosphate and list
12 parts of mixing 10min of 17 parts of alkyl ether phosphate potassium and trihydroxy ethylamine oleate soap；
（2）Then 10 parts of builder, 3 parts of glycol ricinoleate, 7 parts of antirust agent is added, continues to mix 20min to obtain the final product.
Builder is prepared by following preparation methods：
It takes the 50wt% ethanol solutions of 20mL to be added in beaker, 10g cornstarch is added, be uniformly mixed, 10g is then added
NaH2PO4Continue to be stirred until homogeneous；The 60 DEG C of heating water baths of mixed liquor that will be stirred evenly react 2h, then use salt acid for adjusting pH extremely
7.5 obtain starch phosphate ester solution；Starch phosphate is precipitated with ethyl alcohol, washs, filter, is then dried in vacuo up to forming sediment
Powder phosphate.
Antirust agent union diacid amide sodium, triethanolamine and isononanoic acid sodium are according to weight ratio 1:5:1 mixes.
Embodiment 4
（1）Water is heated to 55 DEG C for 46 parts, then sequentially adds 28 parts of sodium n-alkylbenzenesulfonate, 16 parts of alkyl phosphate and list
16 parts of mixing 10min of 24 parts of alkyl ether phosphate potassium and trihydroxy ethylamine oleate soap；
（2）Then 7 parts of builder, 6 parts of glycol ricinoleate, 4 parts of antirust agent is added, continues to mix 20min to obtain the final product.
Builder is prepared by following preparation methods：
It takes the 50wt% ethanol solutions of 20mL to be added in beaker, 10g cornstarch is added, be uniformly mixed, 10g is then added
NaH2PO4Continue to be stirred until homogeneous；The 60 DEG C of heating water baths of mixed liquor that will be stirred evenly react 2h, then use salt acid for adjusting pH extremely
7.5 obtain starch phosphate ester solution；Starch phosphate is precipitated with ethyl alcohol, washs, filter, is then dried in vacuo up to forming sediment
Powder phosphate.
Antirust agent union diacid amide sodium, triethanolamine and isononanoic acid sodium are according to weight ratio 1:5:1 mixes.
Embodiment 5
（1）Water is heated to 55 DEG C for 50 parts, then sequentially adds 25 parts of sodium n-alkylbenzenesulfonate, 18 parts of alkyl phosphate and list
14 parts of mixing 10min of 20 parts of alkyl ether phosphate potassium and trihydroxy ethylamine oleate soap；
（2）Then 8 parts of builder, 4 parts of glycol ricinoleate, 5 parts of antirust agent is added, continues to mix 20min to obtain the final product.
Builder is prepared by following preparation methods：
It takes the 50wt% ethanol solutions of 20mL to be added in beaker, 10g cornstarch is added, be uniformly mixed, 10g is then added
NaH2PO4Continue to be stirred until homogeneous；The 60 DEG C of heating water baths of mixed liquor that will be stirred evenly react 2h, then use salt acid for adjusting pH extremely
7.5 obtain starch phosphate ester solution；Starch phosphate is precipitated with ethyl alcohol, washs, filter, is then dried in vacuo up to forming sediment
Powder phosphate.
Antirust agent union diacid amide sodium, triethanolamine and isononanoic acid sodium are according to weight ratio 1:5:1 mixes.
Comparative example 1
That difference lies in builders is different for this comparative example and embodiment 1.Specifically：
（1）Water is heated to 55 DEG C for 66 parts, then sequentially adds 18 parts of sodium n-alkylbenzenesulfonate, 24 parts of alkyl phosphate and list
17 parts of mixing 10min of 16 parts of alkyl ether phosphate potassium and trihydroxy ethylamine oleate soap；
（2）Then 14 parts of sodium tripolyphosphate, 2 parts of glycol ricinoleate, 9 parts of antirust agent is added, continues to mix 20min to obtain the final product.
Antirust agent union diacid amide sodium, triethanolamine and isononanoic acid sodium are according to weight ratio 1:5:1 mixes.
Comparative example 2
That difference lies in antirust agent is different for this comparative example and embodiment 1.Specifically：
（1）Water is heated to 55 DEG C for 66 parts, then sequentially adds 18 parts of sodium n-alkylbenzenesulfonate, 24 parts of alkyl phosphate and list
17 parts of mixing 10min of 16 parts of alkyl ether phosphate potassium and trihydroxy ethylamine oleate soap；
（2）Then 14 parts of builder, 2 parts of glycol ricinoleate, 9 parts of antirust agent is added, continues to mix 20min to obtain the final product；
Builder is prepared by following preparation methods：
It takes the 50wt% ethanol solutions of 20mL to be added in beaker, 10g cornstarch is added, be uniformly mixed, 10g is then added
NaH2PO4Continue to be stirred until homogeneous；The 60 DEG C of heating water baths of mixed liquor that will be stirred evenly react 2h, then use salt acid for adjusting pH extremely
7.5 obtain starch phosphate ester solution；Starch phosphate is precipitated with ethyl alcohol, washs, filter, is then dried in vacuo up to forming sediment
Powder phosphate.
Antirust agent union diacid amide sodium and triethanolamine are according to weight ratio 1:5 mix.
The cleaning agent that 1-5 and comparative example 1-2 are prepared will be implemented to test：
Cleaning model is 304 stainless steel test pieces, and size is the mm of 50 mm × 50mm × 2,25 DEG C of cleaning temperature, scavenging period 5
Min rinses 2 min, then dries up.
Cleaning rate detection refers to JB/T4323-1999, is tested using difference weight method.
Rustless property is tested：Room temperature 10d after test piece is cleaned observes the surface appearance of test piece, keeps bright, uses
Micro- sem observation workpiece surface with scale, no rust staining are considered as qualification.
Appearance detects：Solution is uniform, it is not stratified, be considered as qualification without precipitation.
PH value detection is detected using pH meter.
Test result see the table below：
1 cleaning performance of table
| Cleaning efficiency/% | Rustless property | |
| Embodiment 1 | 84.5 | It is qualified |
| Embodiment 2 | 85.7 | It is qualified |
| Embodiment 3 | 92.5 | It is qualified |
| Embodiment 4 | 91.6 | It is qualified |
| Embodiment 5 | 95.4 | It is qualified |
| Comparative example 1 | 75.1 | It is qualified |
| Comparative example 2 | 82.7 | There is slight rust staining |
2 appearance of table and stability
| PH value | Appearance | |
| Embodiment 1 | 8.6 | A small amount of precipitation |
| Embodiment 2 | 8.1 | It is qualified |
| Embodiment 3 | 8.7 | It is qualified |
| Embodiment 4 | 8.3 | It is qualified |
| Embodiment 5 | 8.5 | It is qualified |
| Comparative example 1 | 8.4 | A small amount of precipitation |
| Comparative example 2 | 8.5 | A small amount of precipitation |
Performance detection is carried out to the cleaning agent being prepared, by test result it is found that highly effective antirust metal provided by the invention
Cleaning agent has stronger cleaning force to the mechanical processing spot of metal surface, and to machine components, equipment has anti-well
Rust acts on.Formula in embodiment 5 is optimization formula, and stable in physicochemical property, cleaning efficiency can reach 95.4%, 10 after cleaning
It also can guarantee its non-corrosive without using metallic weapon.Different builders is used in comparative example 1, builder can improve clearly
The cleaning efficiency of lotion, starch phosphate and the surfactant compound in the present invention, can improve cleaning agent for dirt
Suspending power, and it is slightly poor the effect of builder sodium tripolyphosphate, it is seen that and starch phosphate is more suitable for the cleaning agent in the present invention
System.Comparative example 2 and the difference of embodiment 1 are to have lacked isononanoic acid sodium in antirust agent ingredient, after being placed 10 days after cleaning, examination
There is slight rust staining in sample surface, and its rust-proof effect of the cleaning agent in embodiment 1 is more preferable, in the cleaning agent for illustrating the present invention,
The antirust agent system added has good compatibility, rust-preventing characteristic.It is by above-mentioned test result it is found that clear with synergistic effect
The cleaning efficiency of builder system higher than no synergistic effect system, the present invention in surfactant and various auxiliary agents between have
Good compatibility, compatibility.
Claims (6)
1. a kind of highly effective antirust metal cleaner, which is characterized in that be prepared including following parts by weight of component：
18-29 parts of sodium n-alkylbenzenesulfonate,
15-24 parts of alkyl phosphate,
16-27 parts of monoalky lether phosphate potassium,
11-17 parts of trihydroxy ethylamine oleate soap,
5-14 parts of builder,
2-7 parts of antifoaming agent,
3-9 parts of antirust agent,
40-66 parts of water.
2. a kind of highly effective antirust metal cleaner according to claim 1, which is characterized in that the builder is by following
Preparation method is prepared：
It takes the 50wt% ethanol solutions of 20mL to be added in beaker, 10g cornstarch is added, be uniformly mixed, 10g is then added
NaH2PO4Continue to be stirred until homogeneous；The 60 DEG C of heating water baths of mixed liquor that will be stirred evenly react 2h, then use salt acid for adjusting pH extremely
7.5 obtain starch phosphate ester solution；Starch phosphate is precipitated with ethyl alcohol, washs, filter, is then dried in vacuo up to forming sediment
Powder phosphate.
3. a kind of highly effective antirust metal cleaner according to claim 1, which is characterized in that the antifoaming agent is glycerine
Ricinoleate ester.
4. a kind of highly effective antirust metal cleaner according to claim 1, which is characterized in that the antirust agent union two
Sour amide sodium, triethanolamine and isononanoic acid sodium are according to weight ratio 1:5:1 mixes.
5. a kind of preparation method of highly effective antirust metal cleaner, which is characterized in that including following preparation process：
（1）By 40-66 parts of heating of water, 18-29 parts of sodium n-alkylbenzenesulfonate, 15-24 parts of alkyl phosphate are then sequentially added
With the 11-17 parts of mixing of 16-27 parts of monoalky lether phosphate potassium and trihydroxy ethylamine oleate soap；
（2）Then 3-9 parts of 5-14 parts of builder, 2-7 parts of antifoaming agent and antirust agent is added, continues to be uniformly mixed to obtain the final product.
6. a kind of preparation method of highly effective antirust metal cleaner according to claim 5, which is characterized in that including following
Preparation process：
（1）Water is heated to 55 DEG C for 40-66 parts, then sequentially adds 18-29 parts of sodium n-alkylbenzenesulfonate, alkyl phosphate
15-24 parts and 16-27 part of monoalky lether phosphate potassium and 11-17 parts of trihydroxy ethylamine oleate soap,
Mix 10min；
（2）Then 5-14 parts of builder, 2-7 parts of antifoaming agent, 3-9 parts of antirust agent is added, continues to mix 20min to obtain the final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810313977.7A CN108486585A (en) | 2018-04-10 | 2018-04-10 | A kind of highly effective antirust metal cleaner and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810313977.7A CN108486585A (en) | 2018-04-10 | 2018-04-10 | A kind of highly effective antirust metal cleaner and preparation method thereof |
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| CN108486585A true CN108486585A (en) | 2018-09-04 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810313977.7A Pending CN108486585A (en) | 2018-04-10 | 2018-04-10 | A kind of highly effective antirust metal cleaner and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111944431A (en) * | 2020-07-22 | 2020-11-17 | 威科赛乐微电子股份有限公司 | Wafer grinding oil and preparation method thereof |
| CN112080251A (en) * | 2020-09-01 | 2020-12-15 | 威科赛乐微电子股份有限公司 | Wafer grinding fluid and preparation method thereof |
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| CN105463488A (en) * | 2014-08-30 | 2016-04-06 | 无锡市齐宝清洗剂有限公司 | Multifunctional metal cleaning agent |
| CN106277709A (en) * | 2016-07-20 | 2017-01-04 | 西安华诺环保股份有限公司 | A kind of disposal of oily sludge environment-friendly cleaning agent and preparation method thereof |
| CN106555197A (en) * | 2015-09-28 | 2017-04-05 | 比亚迪股份有限公司 | A kind of aqueous cleaning agent and its preparation method and application |
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| CN104514007A (en) * | 2013-09-27 | 2015-04-15 | 天津一橙垄达环保科技开发有限公司 | Efficient wheel hub descaling washing agent for vehicles, and preparation method thereof |
| CN105463488A (en) * | 2014-08-30 | 2016-04-06 | 无锡市齐宝清洗剂有限公司 | Multifunctional metal cleaning agent |
| CN106555197A (en) * | 2015-09-28 | 2017-04-05 | 比亚迪股份有限公司 | A kind of aqueous cleaning agent and its preparation method and application |
| CN106277709A (en) * | 2016-07-20 | 2017-01-04 | 西安华诺环保股份有限公司 | A kind of disposal of oily sludge environment-friendly cleaning agent and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN111944431A (en) * | 2020-07-22 | 2020-11-17 | 威科赛乐微电子股份有限公司 | Wafer grinding oil and preparation method thereof |
| CN112080251A (en) * | 2020-09-01 | 2020-12-15 | 威科赛乐微电子股份有限公司 | Wafer grinding fluid and preparation method thereof |
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