CN110819158A - Efficient environment-friendly nontoxic water-based paint remover as well as preparation method and use method thereof - Google Patents

Efficient environment-friendly nontoxic water-based paint remover as well as preparation method and use method thereof Download PDF

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Publication number
CN110819158A
CN110819158A CN201910948413.5A CN201910948413A CN110819158A CN 110819158 A CN110819158 A CN 110819158A CN 201910948413 A CN201910948413 A CN 201910948413A CN 110819158 A CN110819158 A CN 110819158A
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China
Prior art keywords
paint
paint remover
friendly
remover
environment
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CN201910948413.5A
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Inventor
迟九龙
窦梦冬
李闯
冯侠
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Huayang Yongsheng New Material Technology Hebei Co Ltd
Tianjin New Materials Co Ltd
HUAYANG XINXING TECHNOLOGY (TIANJIN) GROUP Co Ltd
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Huayang Yongsheng New Material Technology Hebei Co Ltd
Tianjin New Materials Co Ltd
HUAYANG XINXING TECHNOLOGY (TIANJIN) GROUP Co Ltd
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Priority to CN201910948413.5A priority Critical patent/CN110819158A/en
Publication of CN110819158A publication Critical patent/CN110819158A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D9/00Chemical paint or ink removers
    • C09D9/04Chemical paint or ink removers with surface-active agents
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D9/00Chemical paint or ink removers
    • C09D9/005Chemical paint or ink removers containing organic solvents

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention relates to a high-efficiency environment-friendly nontoxic aqueous paint remover, which comprises the following raw materials in parts by weight: 60-70 parts of N-methyl-2-pyrrolidone; 15-25 parts of benzyl alcohol; 1-5 parts of a paint removal accelerator; 1-4 parts of a surfactant; 5-10 parts of liquid paraffin. The paint remover has the characteristics of good paint removing effect, high paint removing speed, low volatility, small environmental pollution, safety, no toxicity, low corrosivity, low cost and the like, and has very excellent application prospect.

Description

Efficient environment-friendly nontoxic water-based paint remover as well as preparation method and use method thereof
Technical Field
The invention belongs to the technical field of paint removers, and particularly relates to an efficient environment-friendly non-toxic water-based paint remover as well as a preparation method and a use method thereof.
Background
With the high growth of national economy and the rapid development of industry in China, various coatings are adopted in industry and agriculture to protect and decorate the surfaces of materials such as metal, wood, plastic, leather and the like. The application range is wider and wider, and the variety, the performance and the coating technology of the coating are also obviously improved. High-grade paint such as high-grade polyurethane paint powder paint, water paint using water to replace organic solvent, etc. is developed rapidly. These new coatings generally have good adhesion, flexibility, abrasion resistance, shock resistance, temperature resistance, water resistance, chemical corrosion resistance and other properties, and have good decorative effects. During the use of the coating, the coating film can be damaged or gradually aged. When coating or repairing electrical appliances, mechanical equipment, vehicles and ships, the old or damaged coating needs to be removed and then sprayed. The method of removal of old paint films varies from substrate to substrate, coating and from one coating to another. The methods for removing the old paint film are various, and the common methods include a paint remover method, an alkaline solution method, a paint paste removing method, an organic solvent method, a flame method, a manual shovel method, a sand blasting method and the like. The paint remover can quickly remove the old paint by a series of physical and chemical actions such as dissolution, permeation, swelling, stripping, reaction and the like, thereby being widely applied.
At present, paint removers developed at home and abroad are various in types, and can be generally divided into organic paint removers and inorganic paint removers in composition. The inorganic paint remover is usually an alkaline aqueous solution, and the main components are charged potassium, charged sodium, sodium silicate and the like. The alkaline paint remover utilizes the saponification reaction of alkali liquor on resin, and has the advantages of low cost, safe production, small influence on human body, good paint removing effect, and the defects of heating during use, needing a certain heating device, being limited by the size of paint removing parts and long paint removing period. The treated surface is not easy to spray paint and has serious corrosion to metal. The organic paint remover has good paint removing effect, high speed, small corrosivity to metal, simple operation, toxicity, flammability and high cost. Organic strippers generally contain more methylene chloride, phenol, volatile solvents and other harmful substances, thereby causing the strippers to be more volatile and toxic. Combining the advantages and disadvantages of both inorganic and organic strippers, organic strippers are widely used, and thus the research work on them has been rapidly developed. Therefore, the research on novel paint removers with low volatility, low toxicity or no toxicity, safety to metal substrates and no harm to operators or environment is particularly necessary. The aqueous paint remover refers to paint removers which take organic solvents with strong water solubility as main solvents, and even paint removers which do not contain organic solvents at all. With the enhancement of environmental awareness, the advantages of the water-based paint remover are more and more obvious. However, the current researches on the water-based paint remover are not many, and the utilization of the water-based paint remover is limited. The water-based paint remover relieves the problem of environmental pollution caused by excessive solvent in the original paint remover, so that the water-based paint remover has more obvious advantages than an organic paint remover, especially a chlorinated hydrocarbon paint remover.
Through searching, the following patent publications related to the patent application of the invention are found:
1. a non-corrosive and non-scratch metal paint remover and a preparation method and application thereof (CN107353701A), the paint remover is convenient and simple to use, and can effectively remove various common paint layers; the paint remover has the advantages of no corrosion damage to a base material, low volatility, no damage to a human body during use, no attachments such as paraffin, kerosene and the like, convenience for secondary paint spraying, capability of improving the efficiency of paint layer wiping by the added inorganic additive carbon oxide nanotube, no scratch to the base material, safety, environmental protection, no chlorinated hydrocarbon type organic solvent, low cost of the cleaning agent, no corrosion to a metal base material by the paint remover, antibacterial property and high stability.
2. A nontoxic environment-friendly paint remover (CN102408775A) comprises aromatic alcohol, acid and emulsifier, wherein the content of aromatic alcohol is 10-60 wt%, the content of acid is 30-70 wt%, and the content of emulsifier is 5-20 wt%. The paint remover has the advantages of high paint removing speed, good effect, low toxicity, low volatility and no corrosion to various base materials, the base materials after paint removing can be directly sprayed for the second time, the adhesive force with a paint layer is good, the secondary injection molding is omitted, and the cost is saved for recycling the base materials again.
3. A paint remover composition (CN101058691) comprises aromatic alcohol, acid and emulsifier, wherein the content of the aromatic alcohol is 10-60 wt%, the content of the acid is 30-70 wt%, and the content of the emulsifier is 5-20 wt% based on the total weight of the composition. The paint remover has the advantages of high paint removing speed, good effect, low toxicity, low volatility and no corrosion to various base materials, the base materials after paint removing can be directly sprayed for the second time, the adhesive force with a paint layer is good, the secondary injection molding is omitted, and the cost is saved for recycling the base materials again.
By contrast, the present patent application is substantially different from the above patent publications. Although the paint strippers described above are effective in stripping paint films from metal surfaces, they do not contain accelerators or the accelerators are acids. Which causes problems of slow paint removal and corrosion of the metal substrate. Therefore, the requirements of quick paint removal and no corrosion to metal substrates can be met only by compounding a safe and effective accelerator and a solvent.
Disclosure of Invention
The invention aims to overcome the defects of the prior art and provides the efficient environment-friendly non-toxic water-based paint remover, the preparation method and the use method thereof.
The technical scheme adopted by the invention for solving the technical problems is as follows:
an efficient environment-friendly nontoxic aqueous paint remover comprises the following raw materials in parts by weight:
Figure BDA0002224957030000021
Figure BDA0002224957030000031
and the paint removing accelerator is one or a mixture of more of monoethanolamine, diethanolamine and triethanolamine.
And the surfactant is one or a mixture of more of linear alkyl benzene sulfonate, fatty alcohol-polyoxyethylene ether sodium sulfate, fatty alcohol-polyoxyethylene ether ammonium sulfate, sodium lauryl sulfate, lauroyl glutamic acid and nonylphenol polyoxyethylene ether.
The preparation method of the efficient environment-friendly nontoxic water-based paint remover comprises the following steps:
firstly, uniformly mixing N-methyl-2-pyrrolidone and benzyl alcohol, adding liquid paraffin into the mixture, then adding a surfactant and a paint removal accelerator into the mixture, and uniformly stirring to obtain the efficient environment-friendly nontoxic aqueous paint remover.
The use method of the efficient environment-friendly nontoxic water-based paint remover comprises the following steps:
directly soaking the object to be depainted in the paint remover at normal temperature for 5-60 min.
The invention has the advantages and positive effects that:
1. the paint remover disclosed by the invention has the characteristics of good paint removing effect, high paint removing speed, low volatility, small environmental pollution, safety, no toxicity, low corrosivity, low cost and the like, and has very excellent application prospect.
2. Compared with the traditional paint remover, the paint remover disclosed by the invention does not contain dichloromethane, phenol, a volatile solvent and other harmful substances, so that the problems of high toxicity, strong smell, environmental damage and the like of the traditional paint remover are effectively solved.
3. Compared with the traditional paint remover, the paint remover does not contain acid paint removing accelerators, thereby effectively solving the problem that the acid paint removing accelerators corrode metal substrates.
Detailed Description
The following detailed description of the embodiments of the present invention is provided for the purpose of illustration and not limitation, and should not be construed as limiting the scope of the invention.
The raw materials used in the invention are conventional commercial products unless otherwise specified; the methods used in the present invention are conventional in the art unless otherwise specified.
An efficient environment-friendly nontoxic aqueous paint remover comprises the following raw materials in parts by weight:
Figure BDA0002224957030000032
Figure BDA0002224957030000041
preferably, the paint removal accelerator is one or a mixture of monoethanolamine, diethanolamine and triethanolamine.
Preferably, the surfactant is one or a mixture of more of linear alkyl benzene sulfonate, fatty alcohol-polyoxyethylene ether sodium sulfate, fatty alcohol-polyoxyethylene ether ammonium sulfate, sodium lauryl sulfate, lauroyl glutamic acid and nonylphenol polyoxyethylene ether.
The preparation method of the efficient environment-friendly nontoxic water-based paint remover comprises the following steps:
firstly, uniformly mixing N-methyl-2-pyrrolidone and benzyl alcohol, adding liquid paraffin into the mixture, then adding a surfactant and a paint removal accelerator into the mixture, and uniformly stirring to obtain the efficient environment-friendly nontoxic aqueous paint remover.
The use method of the efficient environment-friendly nontoxic water-based paint remover comprises the following steps:
directly soaking the object to be depainted in the paint remover at normal temperature for 5-60 min.
Example 1:
the efficient environment-friendly nontoxic aqueous paint remover comprises the following raw materials in parts by weight (taking 1000g of the efficient environment-friendly nontoxic aqueous paint remover as an example):
Figure BDA0002224957030000042
the preparation method of the efficient environment-friendly nontoxic aqueous paint remover comprises the following steps: firstly, uniformly mixing N-methyl-2-pyrrolidone and benzyl alcohol according to the formula ratio, adding liquid paraffin, then adding sodium fatty alcohol polyoxyethylene ether sulfate and monoethanolamine into the mixture, and uniformly stirring.
When in use, an object needing paint removal is directly soaked in the paint remover for 5min-60min at normal temperature, and the paint remover can be used for removing epoxy paint, water-based paint, polyester paint and the like on the object. Labeled sample 1.
Example 2
An efficient environment-friendly nontoxic aqueous paint remover comprises the following raw materials in parts by weight:
Figure BDA0002224957030000043
Figure BDA0002224957030000051
the preparation method of the efficient environment-friendly nontoxic aqueous paint remover comprises the following steps: firstly, uniformly mixing N-methyl-2-pyrrolidone and benzyl alcohol according to the formula ratio, adding liquid paraffin, then adding sodium lauryl sulfate and triethanolamine into the mixture, and uniformly stirring.
When in use, an object needing paint removal is directly soaked in the paint remover for 5min-60min at normal temperature, and the paint remover can be used for removing epoxy paint, water-based paint, polyester paint and the like on the object. Labeled sample 2.
And (3) paint removal performance determination:
determination of the paint stripping time: different kinds of commercially available paints were applied to standard 45# steel test pieces, and left to age for one month at room temperature. And soaking the painted and aged paint plate in a sample to be tested. The time taken for the film to remove was recorded and the results are shown in Table 1 below. The time for removing the paint film is the time from the beginning of soaking the standard test piece of the 45# steel into the paint remover to the end of observing the surface of the standard test piece of the 45# steel by naked eyes until the paint film can not be seen.
Damage to the metal substrate: and taking the standard test piece of the 45# steel after the paint film is removed out of the paint remover, washing the standard test piece for 5 times by using clear water, and observing whether the surface of the standard test piece of the 45# steel is damaged or not by naked eyes. The measurement results are shown in table 1:
paint removal time (polyurethane paint) Paint removing time (alkyd paint) Damage to metal substrates
Sample 1 11 9 Non-damage
Sample 2 16 19 Non-damage
Commercial sample 15 20 Occurrence of rust
Although the embodiments of the present invention have been disclosed for illustrative purposes, those skilled in the art will appreciate that: various substitutions, changes and modifications are possible without departing from the spirit and scope of the invention and the appended claims, and therefore the scope of the invention is not limited to the embodiments disclosed.

Claims (5)

1. An efficient environment-friendly nontoxic water-based paint remover is characterized in that: the raw materials comprise the following components in parts by weight:
Figure FDA0002224957020000011
2. the efficient, environment-friendly and non-toxic aqueous paint remover according to claim 1, characterized in that: the paint removal accelerator is one or a mixture of more of monoethanolamine, diethanolamine and triethanolamine.
3. The efficient, environment-friendly and non-toxic aqueous paint remover according to claim 1, characterized in that: the surfactant is one or a mixture of more of linear alkyl benzene sulfonate, fatty alcohol-polyoxyethylene ether sodium sulfate, fatty alcohol-polyoxyethylene ether ammonium sulfate, sodium lauryl sulfate, lauroyl glutamic acid and nonylphenol polyoxyethylene ether.
4. A method for preparing the high-efficiency environment-friendly non-toxic water-based paint remover as claimed in any one of claims 1 to 3, wherein: the method comprises the following steps:
firstly, uniformly mixing N-methyl-2-pyrrolidone and benzyl alcohol, adding liquid paraffin into the mixture, then adding a surfactant and a paint removal accelerator into the mixture, and uniformly stirring to obtain the efficient environment-friendly nontoxic aqueous paint remover.
5. The use method of the high-efficiency environment-friendly non-toxic water-based paint remover as claimed in any one of claims 1 to 3, wherein the paint remover comprises the following steps: the method comprises the following steps:
directly soaking the object to be depainted in the paint remover at normal temperature for 5-60 min.
CN201910948413.5A 2019-10-08 2019-10-08 Efficient environment-friendly nontoxic water-based paint remover as well as preparation method and use method thereof Pending CN110819158A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109266090A (en) * 2018-09-07 2019-01-25 北京固瑞恩科技有限公司 A kind of environment-friendly type film removal material and preparation method thereof for municipal maintenance project
CN112724735A (en) * 2020-12-25 2021-04-30 江苏奥首材料科技有限公司 Water-based airplane paint remover and preparation method thereof

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Publication number Priority date Publication date Assignee Title
CN1188126A (en) * 1996-12-06 1998-07-22 埃勒夫阿托化学有限公司 Composition for stripping paints, varnishes or lacquers
CN1944547A (en) * 2006-10-11 2007-04-11 中国化工建设总公司常州涂料化工研究院 Paint remover and its preparing method and using method
CN106118213A (en) * 2016-09-23 2016-11-16 重庆理工大学 A kind of water-based plastic paint stripper and its preparation method and application

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1188126A (en) * 1996-12-06 1998-07-22 埃勒夫阿托化学有限公司 Composition for stripping paints, varnishes or lacquers
CN1944547A (en) * 2006-10-11 2007-04-11 中国化工建设总公司常州涂料化工研究院 Paint remover and its preparing method and using method
CN106118213A (en) * 2016-09-23 2016-11-16 重庆理工大学 A kind of water-based plastic paint stripper and its preparation method and application

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109266090A (en) * 2018-09-07 2019-01-25 北京固瑞恩科技有限公司 A kind of environment-friendly type film removal material and preparation method thereof for municipal maintenance project
CN112724735A (en) * 2020-12-25 2021-04-30 江苏奥首材料科技有限公司 Water-based airplane paint remover and preparation method thereof

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