CN101160170B - 具有以稀土元素改性氧化物载体的贵金属水煤气轮换催化剂 - Google Patents

具有以稀土元素改性氧化物载体的贵金属水煤气轮换催化剂 Download PDF

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CN101160170B
CN101160170B CN2006800126520A CN200680012652A CN101160170B CN 101160170 B CN101160170 B CN 101160170B CN 2006800126520 A CN2006800126520 A CN 2006800126520A CN 200680012652 A CN200680012652 A CN 200680012652A CN 101160170 B CN101160170 B CN 101160170B
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catalyst
inorganic oxide
rare earth
oxide carrier
weight
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CN101160170A (zh
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O·M·伊里尼齐
R·J·法劳托
W·F·鲁廷格
X·杨
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BASF Catalysts LLC
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BASF Catalysts LLC
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/06Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen with inorganic reducing agents
    • C01B3/12Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen with inorganic reducing agents by reaction of water vapour with carbon monoxide
    • C01B3/16Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen with inorganic reducing agents by reaction of water vapour with carbon monoxide using catalysts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04Alumina
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56Platinum group metals
    • B01J23/63Platinum group metals with rare earths or actinides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/32Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air
    • C01B3/34Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents
    • C01B3/38Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents using catalysts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00Constitutive chemical elements of heterogeneous catalysts
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041Composition of the catalyst
    • C01B2203/1047Group VIII metal catalysts
    • C01B2203/1064Platinum group metal catalysts
    • C01B2203/107Platinum catalysts
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041Composition of the catalyst
    • C01B2203/1082Composition of support materials
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Hydrogen, Water And Hydrids (AREA)
CN2006800126520A 2005-02-16 2006-02-15 具有以稀土元素改性氧化物载体的贵金属水煤气轮换催化剂 Expired - Fee Related CN101160170B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US11/059,148 2005-02-16
US11/059,148 US7704486B2 (en) 2005-02-16 2005-02-16 Precious metal water-gas shift catalyst with oxide support modified with rare earth elements
PCT/US2006/005294 WO2006088936A2 (en) 2005-02-16 2006-02-15 Precious metal water-gas shift catalyst with oxide support modified with rare earth elements

Publications (2)

Publication Number Publication Date
CN101160170A CN101160170A (zh) 2008-04-09
CN101160170B true CN101160170B (zh) 2012-02-08

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CN2006800126520A Expired - Fee Related CN101160170B (zh) 2005-02-16 2006-02-15 具有以稀土元素改性氧化物载体的贵金属水煤气轮换催化剂

Country Status (8)

Country Link
US (2) US7704486B2 (https=)
EP (3) EP2548643A1 (https=)
JP (1) JP5105420B2 (https=)
KR (1) KR20070112802A (https=)
CN (1) CN101160170B (https=)
BR (1) BRPI0607746A2 (https=)
CA (1) CA2597920A1 (https=)
WO (1) WO2006088936A2 (https=)

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US20070183968A1 (en) * 2005-08-03 2007-08-09 Todd Healey Water-gas shift and reforming catalyst and method of reforming alcohol
KR101320388B1 (ko) * 2006-02-18 2013-10-22 삼성에스디아이 주식회사 탄화수소 개질 촉매, 그 제조방법 및 이를 포함하는연료처리장치
US20090264277A1 (en) * 2007-04-17 2009-10-22 Dr. Rishi Raj Picoscale catalysts for hydrogen catalysis
US8119558B2 (en) 2008-03-14 2012-02-21 Süd-Chemie Inc. Ultra high temperature shift catalyst with low methanation
DE102008021084A1 (de) * 2008-04-28 2009-10-29 Süd-Chemie AG Verwendung eines Katalysators auf Edelmetallbasis zur Verringerung des Teergehalts in Gasen aus Vergasungsprozessen
DE102008021081A1 (de) * 2008-04-28 2009-10-29 Süd-Chemie AG Verfahren zur katalytischen Verringerung des Teergehalts in Gasen aus Vergasungsprozessen unter Verwendung eines Katalysators auf Edelmetallbasis
AU2010302213B2 (en) 2009-07-20 2015-07-02 Council Of Scientific & Industrial Research CeAlO3 perovskites containing transition metal
US8658554B2 (en) * 2009-11-04 2014-02-25 The United States Of America, As Represented By The Secretary Of The Navy Catalytic support for use in carbon dioxide hydrogenation reactions
ES2595937B1 (es) * 2015-06-02 2017-10-11 Universidad De Sevilla Complejo catalítico conformado por la mezcla de catalizador y conductor iónico
CN106669650A (zh) * 2016-12-16 2017-05-17 池州方达科技有限公司 一种催化剂载体陶瓷微球的预处理方法
US10906808B2 (en) 2017-11-15 2021-02-02 Gas Technology Institute Noble metal catalysts and processes for reforming of methane and other hydrocarbons
US10738247B2 (en) 2017-11-15 2020-08-11 Gas Technology Institute Processes and systems for reforming of methane and light hydrocarbons to liquid hydrocarbon fuels
US11111142B2 (en) * 2018-09-18 2021-09-07 Gas Technology Institute Processes and catalysts for reforming of impure methane-containing feeds
US12122962B2 (en) 2018-09-18 2024-10-22 Gti Energy Processes and catalysts for reforming of impure methane-containing feeds
AU2024216218A1 (en) * 2023-02-03 2025-07-24 Shell Internationale Research Maatschappij B.V. Sorbent structures for carbon dioxide capture and methods for making thereof

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GB2046118A (en) * 1979-03-22 1980-11-12 American Cyanamid Co Auto Exhaust Catalysts
US4738946A (en) * 1983-07-01 1988-04-19 Hitachi, Ltd. High temperature stable catalyst and process for preparing same
EP1161991A1 (en) * 1999-03-18 2001-12-12 Matsushita Electric Works, Ltd. Catalyst for water gas shift reaction, method for removing carbon monoxide in hydrogen gas and electric power-generating system of fuel cell
EP1433745A2 (en) * 2002-12-26 2004-06-30 Matsushita Electric Industrial Co., Ltd. Catalyst for the removal of carbon monoxide, its method of manufacture and its uses
CN1578700A (zh) * 2001-11-07 2005-02-09 南方化学触媒株式会社 制备一氧化碳转移反应催化剂的方法

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GB2046118A (en) * 1979-03-22 1980-11-12 American Cyanamid Co Auto Exhaust Catalysts
US4738946A (en) * 1983-07-01 1988-04-19 Hitachi, Ltd. High temperature stable catalyst and process for preparing same
EP1161991A1 (en) * 1999-03-18 2001-12-12 Matsushita Electric Works, Ltd. Catalyst for water gas shift reaction, method for removing carbon monoxide in hydrogen gas and electric power-generating system of fuel cell
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Publication number Publication date
JP2008529791A (ja) 2008-08-07
EP2548643A1 (en) 2013-01-23
BRPI0607746A2 (pt) 2010-03-16
KR20070112802A (ko) 2007-11-27
WO2006088936A3 (en) 2006-12-14
US7704486B2 (en) 2010-04-27
US20060182679A1 (en) 2006-08-17
CN101160170A (zh) 2008-04-09
WO2006088936A2 (en) 2006-08-24
EP2548642A1 (en) 2013-01-23
US20100113261A1 (en) 2010-05-06
CA2597920A1 (en) 2006-08-24
EP1879695A2 (en) 2008-01-23
JP5105420B2 (ja) 2012-12-26

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